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Theoretical and experimental studies on the self-healing properties of metallised capacitor films under multiple stresses
IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-05-24 DOI: 10.1049/hve2.12459
Zhiyuan Wu, Shangshu Liu, Tong Tong, Shaolong Zhong, Jiantao Wang, Hongbin Qi, Zhimin Dang, Wei Wang

Metallised film capacitors, for the most important merits is the excellent self-healing property, have significant electrical insulation advantage. The essential factors affecting the self-healing properties of metallised polypropylene film capacitors (MPPFCs) are first analysed, and a self-healing performance characterisation test platform for metallised polypropylene capacitor films was built. Both the voltage/current waveforms and discharge patterns of the self-healing process under multiple stresses including temperature, voltage and inter-layer pressure were recorded and discussed. The correlation between self-healing performance characterisation and the carbon that appeared on the surface of the dielectric layer during the arc extinction time is clarified. Finally, by virtue of an equivalent dynamic circuit model, the influence of square resistance and the equivalent capacitance of the power grid on self-healing has been theoretically studied.

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引用次数: 0
Degradation of superhydrophobic aluminium overhead line conductor surfaces 超疏水性架空线路铝导体表面的降解
IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-05-22 DOI: 10.1049/hve2.12455
Xu Zhang, Chorphaka Plaengpraphan, Chengxing Lian, Wenyuan Li, Qinghua Han, Simon M. Rowland, Ian Cotton, Qi Li

It has been shown that noise emissions from HV overhead line conductors can be reduced under rain conditions by making their surfaces superhydrophobic. The working environment makes ensuring the longevity of any treatment a major challenge. The degradation of various superhydrophobic surfaces generated by applying a superhydrophobic coating and patterning microscale channels is assessed under an AC electric field (18 kV/cm) with continuous water spray. By examining the droplet distribution on the surfaces during the degradation and the surface roughness before and after degradation, the authors demonstrate that no water droplets were found on the microscale patterned surface, but droplets were formed on the coated surface after degradation. The surface roughness reduction of the coated surface and microscale patterned surface was 29.8% and 11.3%, respectively, indicating that the microscale patterned surface has better durability than the superhydrophobic coating under the AC electric stress.

研究表明,通过对高压架空线路导线表面进行超疏水处理,可以降低导线在雨水条件下产生的噪音。工作环境使确保任何处理的使用寿命成为一大挑战。在交流电场(18 kV/cm)和持续喷水的条件下,对通过涂抹超疏水涂层和绘制微米级通道图案而产生的各种超疏水表面的降解情况进行了评估。通过研究降解过程中表面上的水滴分布以及降解前后的表面粗糙度,作者证明在微尺度图案化表面上没有发现水滴,但在降解后的涂层表面上形成了水滴。涂层表面和微尺度图案表面的表面粗糙度分别降低了 29.8% 和 11.3%,这表明在交流电应力作用下,微尺度图案表面比超疏水涂层具有更好的耐久性。
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引用次数: 0
Effect of electric field on bubble generation and dissolution characteristics in oil–paper insulation 电场对油纸绝缘层中气泡生成和溶解特性的影响
IF 4.4 2区 工程技术 Q1 Engineering Pub Date : 2024-05-22 DOI: 10.1049/hve2.12456
Chaojie Yang, Tao Zhao, Yunpeng Liu, Jiajun Yang, Jiaxue Xu, Yingcong Xu
The interturn paper insulation of oil‐immersed power transformer windings, under the combined influence of electric fields, moisture, and conductor heating, will produce bubbles, which pose a significant threat to the insulation system. However, there is limited research on the characteristics of bubble evolution in oil–paper insulation under the influence of electric fields and the subsequent dissolution process. Based on the continuous observation of bubble size using electron microscopes, experimental and theoretical investigations into the formation and dissolution of bubbles under electric field conditions are presented. The effects of different field strengths on bubble evolution and dissolution characteristics were studied. The results showed that the electric field promoted both the generation and dissolution of bubbles, with a more pronounced effect observed at higher field strengths (below partial discharge (PD) inception electric field, hereafter referred to as PDIE). However, when the field strength exceeded PDIE, the bubbles tended to shrink and gradually increase in size. The changes in bubble volume were related to not only gas diffusion but also oxygen consumption and fault gases generation due to PD. A better understanding of the formation and dissolution characteristics of bubbles under varying field strengths is achieved. Furthermore, it also provides a reference for assessing the risk of bubble generation and conducting bubble‐related fault diagnosis during the overload operation of oil‐immersed power equipment.
油浸电力变压器绕组的匝间纸绝缘在电场、湿气和导体加热的共同作用下会产生气泡,对绝缘系统构成重大威胁。然而,关于油纸绝缘在电场影响下气泡演变的特征以及随后的溶解过程的研究还很有限。本文基于电子显微镜对气泡大小的连续观察,对电场条件下气泡的形成和溶解进行了实验和理论研究。研究了不同电场强度对气泡演化和溶解特性的影响。结果表明,电场对气泡的生成和溶解都有促进作用,在较高的电场强度(低于部分放电(PD)萌生电场,以下简称 PDIE)下观察到的效果更为明显。然而,当电场强度超过 PDIE 时,气泡趋于收缩并逐渐增大。气泡体积的变化不仅与气体扩散有关,还与 PD 产生的氧气消耗和故障气体有关。这有助于更好地理解气泡在不同场强下的形成和溶解特性。此外,它还为在油浸式发电设备过载运行期间评估气泡产生风险和进行气泡相关故障诊断提供了参考。
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引用次数: 0
Experiment of electrothermal stress for different types of end turn grading in the inverter-fed form-wound windings 变频器馈电形式绕组中不同类型端部匝数分级的电热应力实验
IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-05-22 DOI: 10.1049/hve2.12449
Wenhuan Zhao, Peng Wang, Yingwei Zhu, Yue Zhang, Shuai Yang, Yan Liu, Yang Shi, Chaofan Yu

End turn grading with resistive–capacitive coupling experiences severe electrothermal stress when subjected to pulse width modulation (PWM) voltage. In this paper, several experiments and simulations were carried conducted for four types of end turn grading. First of all, the temperature rise in the end turn grading increased with a decrease in rise time. When the rise time was less than 500 ns, the temperature rise at the terminal was higher owing to the increased capacitive current coupled from the main wall insulation. Further, the current in the linear region exhibited minimal variation at different fundamental frequencies resulting in synchronized the temperature rise at the terminal and overlap. Furthermore, the jump voltage was the key factor influencing temperature rise in end turn grading, confirmed by comparing different voltage magnitudes. Finally, the transient behaviour of the maximum field in the stress grading material was determined at rise time. The experimental and simulation results indicate that balancing and interdependently addressing the electrical and thermal stress protection in end turn grading is crucial. The study aims to provide an experimental and theoretical foundation for an insulation system of inverter-fed rotating machinery operating under PWM voltage.

在脉宽调制(PWM)电压作用下,电阻-电容耦合的端面匝级会产生严重的电热应力。本文针对四种类型的端部转弯分级进行了多次实验和模拟。首先,随着上升时间的缩短,端部转弯分级的温升增加。当上升时间小于 500 ns 时,由于主壁绝缘耦合的电容电流增加,终端的温升较高。此外,线性区域的电流在不同基频下的变化极小,导致终端和重叠处的温升同步。此外,跃变电压是影响末端转弯分级温升的关键因素,这一点通过比较不同的电压幅度得到了证实。最后,确定了应力分级材料中最大电场在上升时的瞬态行为。实验和模拟结果表明,平衡并相互依存地解决端部转弯分级中的电应力和热应力保护问题至关重要。本研究旨在为在 PWM 电压下运行的变频器驱动旋转机械的绝缘系统提供实验和理论基础。
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引用次数: 0
Intelligent identification method of insulation pull rod defects based on intactness-aware Mosaic data augmentation and fusion of YOLOv5s 基于完好性感知 Mosaic 数据增强和 YOLOv5s 融合的绝缘拉杆缺陷智能识别方法
IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-05-21 DOI: 10.1049/hve2.12447
Changyun Li, Yuze Hua, Yilin Liu, Kai Liu, Sanyi Zhang

The authors introduce the intactness-aware Mosaic data augmentation strategy, designed to tackle challenges such as low accuracy in detecting defects in insulation pull rods, limited timeliness in intelligent analysis, and the absence of a comprehensive database for information on insulation pull rod defects. The proposed strategy incorporates the YOLOv5s algorithm for detecting defects in insulation pull rods. Initially, the YOLOv5s network was constructed, and a dataset containing photos of insulation pull rods with white spots, fractures, impurities, and bubble flaws was compiled to capture images of defects. The research presented a data enhancement approach to improve the images and establish a dataset for insulation pull rod defects. The YOLOv5s algorithm was applied for both training and testing purposes. A comparative analysis was conducted to assess the detection performance of YOLOv5s against a conventional target detector for identifying defects in insulation pull rods. Furthermore, the utility of Mosaic's data augmentation technique, which incorporates intactness awareness, was evaluated to enhance the accuracy of identifying insulation pull rod defects. The research findings indicate that the YOLOv5s algorithm is employed for intelligent detection and precise localisation of flaws. The intactness-aware Mosaic data augmentation strategy significantly improves the accuracy of detecting faults in insulation pull rods. The YOLOv5s model used achieves a performance index [email protected]:0.95 of 0.563 on the test set, distinct from the training set data. With a threshold of 0.5, the [email protected] score is 0.904, indicating a substantial improvement in both detection efficiency and accuracy compared to conventional target detection methods. Innovative approaches for identifying defects in insulation pull rods are introduced.

作者介绍了具有完好性意识的 Mosaic 数据增强策略,旨在解决绝缘拉杆缺陷检测精度低、智能分析的及时性有限以及缺乏绝缘拉杆缺陷信息综合数据库等难题。拟议的战略采用 YOLOv5s 算法检测绝缘拉杆中的缺陷。首先,构建了 YOLOv5s 网络,并编制了包含有白点、断裂、杂质和气泡缺陷的绝缘拉杆照片的数据集,以捕捉缺陷图像。研究提出了一种数据增强方法,以改进图像并建立绝缘拉杆缺陷数据集。YOLOv5s 算法被用于训练和测试目的。通过比较分析,评估了 YOLOv5s 与传统目标检测器在识别绝缘拉杆缺陷方面的检测性能。此外,还评估了 Mosaic 数据增强技术的实用性,该技术结合了完好性意识,可提高识别绝缘拉杆缺陷的准确性。研究结果表明,YOLOv5s 算法可用于智能检测和精确定位缺陷。完好性感知 Mosaic 数据增强策略显著提高了绝缘拉杆故障检测的准确性。所使用的 YOLOv5s 模型在测试集上的性能指数 mAP@0.5:0.95 为 0.563,与训练集数据截然不同。当阈值为 0.5 时,mAP@0.5 得分为 0.904,表明与传统的目标检测方法相比,检测效率和准确性都有大幅提高。介绍了识别绝缘拉杆缺陷的创新方法。
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引用次数: 0
Characteristics of perfluoromethyl vinyl ether: A new eco-friendly alternative gas for SF6 全氟甲基乙烯基醚的特性:替代 SF6 的新型环保气体
IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-05-17 DOI: 10.1049/hve2.12454
Song Xiao, Yijiang Chen, Mingjun Tang, Shuangshuang Tian, Haoran Xia, Yifan Wang, Ju Tang, Yi Li, Xiaoxing Zhang

The exploration of eco-friendly insulating gas to substitute the most potent greenhouse gas sulphur hexafluoride (SF6) has consistently garnered significant attention. Herein, the authors evaluated the feasibility of utilising perfluoromethyl vinyl ether (PMVE, C3F6O) as a new branch of eco-friendly insulating gas for the first time. The primary dielectric and stability characteristics of PMVE regarding AC breakdown, partial discharge, dielectric recovery, and decomposition properties were revealed under various gas pressure and electrical field conditions. It was found that PMVE demonstrated superior dielectric strength, with the AC breakdown and PD inception voltage (PDIV) 1.10 and 1.14 times that of pure SF6. Furthermore, the dielectric strength of PMVE exhibits stability even after undergoing 100 cycles of AC breakdowns, and there is no observable formation of solid precipitation on the electrode surface. The discharge decomposition of PMVE mainly generates fluorocarbon (CF4, C2F6, C3F6, C3F8, etc.) and CO. Overall, the exceptional insulation stability and no absence of solid precipitation features endow PMVE to be utilised as a new eco-friendly gas for SF6-free gas-insulated equipment.

探索环保绝缘气体以替代最有害的温室气体六氟化硫(SF6)一直备受关注。在本文中,作者首次评估了利用全氟甲基乙烯基醚(PMVE,C3F6O)作为新型环保绝缘气体的可行性。研究揭示了 PMVE 在各种气体压力和电场条件下的主要介电特性和稳定性,包括交流击穿、局部放电、介电恢复和分解特性。研究发现,PMVE 具有优异的介电强度,其交流击穿电压和局部放电起始电压(PDIV)分别是纯 SF6 的 1.10 倍和 1.14 倍。此外,即使经历 100 次交流击穿,PMVE 的介电强度也很稳定,而且电极表面没有观察到固体沉淀的形成。PMVE 的放电分解主要产生碳氟化合物(CF4、C2F6、C3F6、C3F8 等)和 CO。总之,PMVE 具有优异的绝缘稳定性和无固体沉淀的特点,可作为一种新型环保气体用于不含 SF6 的气体绝缘设备。
{"title":"Characteristics of perfluoromethyl vinyl ether: A new eco-friendly alternative gas for SF6","authors":"Song Xiao,&nbsp;Yijiang Chen,&nbsp;Mingjun Tang,&nbsp;Shuangshuang Tian,&nbsp;Haoran Xia,&nbsp;Yifan Wang,&nbsp;Ju Tang,&nbsp;Yi Li,&nbsp;Xiaoxing Zhang","doi":"10.1049/hve2.12454","DOIUrl":"10.1049/hve2.12454","url":null,"abstract":"<p>The exploration of eco-friendly insulating gas to substitute the most potent greenhouse gas sulphur hexafluoride (SF<sub>6</sub>) has consistently garnered significant attention. Herein, the authors evaluated the feasibility of utilising perfluoromethyl vinyl ether (PMVE, C<sub>3</sub>F<sub>6</sub>O) as a new branch of eco-friendly insulating gas for the first time. The primary dielectric and stability characteristics of PMVE regarding AC breakdown, partial discharge, dielectric recovery, and decomposition properties were revealed under various gas pressure and electrical field conditions. It was found that PMVE demonstrated superior dielectric strength, with the AC breakdown and PD inception voltage (PDIV) 1.10 and 1.14 times that of pure SF<sub>6</sub>. Furthermore, the dielectric strength of PMVE exhibits stability even after undergoing 100 cycles of AC breakdowns, and there is no observable formation of solid precipitation on the electrode surface. The discharge decomposition of PMVE mainly generates fluorocarbon (CF<sub>4</sub>, C<sub>2</sub>F<sub>6</sub>, C<sub>3</sub>F<sub>6</sub>, C<sub>3</sub>F<sub>8</sub>, etc.) and CO. Overall, the exceptional insulation stability and no absence of solid precipitation features endow PMVE to be utilised as a new eco-friendly gas for SF<sub>6</sub>-free gas-insulated equipment.</p>","PeriodicalId":48649,"journal":{"name":"High Voltage","volume":"9 3","pages":"509-517"},"PeriodicalIF":4.4,"publicationDate":"2024-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/hve2.12454","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141127082","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
How do the non-linear I–V curves of ZnO-based adaptive composites behave with electrodes placed on the opposite sides with a series of horizontal distances? 氧化锌基自适应复合材料的非线性 I-V 曲线在电极相对放置并保持一系列水平距离的情况下表现如何?
IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-05-12 DOI: 10.1049/hve2.12444
Ya Sun, Zhikang Yuan, Zhiwen Huang, Jun Hu, Jinliang He, Qi Li

Recently, ZnO-based composites have been widely applied in the field of electric power. To meet the diverse application requirements, it is necessary to figure out the I–V characteristics of ZnO composites whose high-voltage and ground-voltage electrodes are arranged on the opposite sides with a certain horizontal distance. 30 vol%, 40 vol% and 50 vol% ZnO-based silicone rubber composites were prepared. The horizontal distance between their electrodes was set as 50, 100, 500 μm, 1 and 2 mm, respectively. Results showed that with the increase of ZnO fillers volume fraction under a fixed horizontal distance of 100 μm, from 30 vol% to 50 vol%, the I–V curves shifted left, the leakage current increased and the switching voltage decreased. When the horizontal distance between electrodes increased from 50 μm to 1 mm under a fixed doping concentration of 40%, the I–V curves shifted to the right, the leakage current dropped and the switching voltage rose. The mathematical and physical models were established to explain the results. This work provides a referential significance for the practical application of ZnO composites, such as 5G folding mobile phones and power electronic modules.

最近,氧化锌基复合材料被广泛应用于电力领域。为了满足不同的应用要求,有必要研究高压电极和接地电极以一定的水平距离相对排列的氧化锌复合材料的 I-V 特性。研究人员制备了 30vol%、40vol% 和 50vol% 的氧化锌硅橡胶复合材料。其电极之间的水平距离分别为 50、100、500 μm、1 和 2 mm。结果表明,在水平距离为 100 μm 的固定条件下,随着 ZnO 填料体积分数从 30 vol% 增加到 50 vol%,I-V 曲线左移,漏电流增加,开关电压降低。在掺杂浓度为 40% 的固定条件下,当电极之间的水平距离从 50 μm 增加到 1 mm 时,I-V 曲线右移,漏电流下降,开关电压上升。建立的数学和物理模型解释了这些结果。这项工作为氧化锌复合材料的实际应用(如 5G 折叠手机和电力电子模块)提供了参考意义。
{"title":"How do the non-linear I–V curves of ZnO-based adaptive composites behave with electrodes placed on the opposite sides with a series of horizontal distances?","authors":"Ya Sun,&nbsp;Zhikang Yuan,&nbsp;Zhiwen Huang,&nbsp;Jun Hu,&nbsp;Jinliang He,&nbsp;Qi Li","doi":"10.1049/hve2.12444","DOIUrl":"10.1049/hve2.12444","url":null,"abstract":"<p>Recently, ZnO-based composites have been widely applied in the field of electric power. To meet the diverse application requirements, it is necessary to figure out the <i>I–V</i> characteristics of ZnO composites whose high-voltage and ground-voltage electrodes are arranged on the opposite sides with a certain horizontal distance. 30 vol%, 40 vol% and 50 vol% ZnO-based silicone rubber composites were prepared. The horizontal distance between their electrodes was set as 50, 100, 500 μm, 1 and 2 mm, respectively. Results showed that with the increase of ZnO fillers volume fraction under a fixed horizontal distance of 100 μm, from 30 vol% to 50 vol%, the <i>I–V</i> curves shifted left, the leakage current increased and the switching voltage decreased. When the horizontal distance between electrodes increased from 50 μm to 1 mm under a fixed doping concentration of 40%, the <i>I–V</i> curves shifted to the right, the leakage current dropped and the switching voltage rose. The mathematical and physical models were established to explain the results. This work provides a referential significance for the practical application of ZnO composites, such as 5G folding mobile phones and power electronic modules.</p>","PeriodicalId":48649,"journal":{"name":"High Voltage","volume":"9 5","pages":"981-988"},"PeriodicalIF":4.4,"publicationDate":"2024-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/hve2.12444","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140987136","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Relationship between radar reflectivity thresholds and very low frequency/low frequency total lightning for thunderstorm identification 用于识别雷暴的雷达反射率阈值与极低频/低频总闪电之间的关系
IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-05-10 DOI: 10.1049/hve2.12441
Yijun Huang, Jianguo Wang, Li Cai, Yadong Fan, Hongbin Wang, Tao Zhang

To improve our knowledge of the spatio-temporal correspondence between radar reflectivity and VLF/LF total lightning data, this paper proposes indexes to quantify the horizontal distribution and temporal evolution characteristics between radar composite reflectivity images and total lightning density map, lightning clusters and radar cells with different radar reflectivity thresholds (30, 35, 40, 45 and 50 dBZ), respectively. It is found that the number of radar grid cells with radar reflectivity over 30 dBZ is ten times the number of lightning grid cells. At the identification stage, the lightning activity regions in a radar cell account for less than 30% using thresholds of 30, 35 and 40 dBZ, respectively, and the radar cell has more than one lightning cluster, which means that the mesoscale convective systems typically have more than one draft, and drafts are only small part of the convection. The majority of the centroid deviations is less than 10 km, indicating that there are some shifts between electrically active regions and convective regions. Results suggest that VLF/LF total lightning data are consistent with radar data and total lightning data can be used individually on a smaller spatio-temporal scale than radar data.

为了提高我们对雷达反射率与 VLF/LF 总闪电数据之间时空对应关系的认识,本文提出了一些指标来量化雷达复合反射率图像与不同雷达反射率阈值(30、35、40、45 和 50 dBZ)的总闪电密度图、闪电群和雷达格室之间的水平分布和时间演变特征。研究发现,雷达反射率超过 30 dBZ 的雷达网格单元数量是闪电网格单元数量的 10 倍。在识别阶段,使用阈值分别为 30、35 和 40 dBZ 时,雷达单元中的闪电活动区域占比小于 30%,且雷达单元中的闪电群不止一个,这说明中尺度对流系统通常不止一个牵风,牵风只是对流的一小部分。大部分中心点偏差小于 10 km,表明电活动区和对流区之间存在一定的偏移。结果表明,VLF/LF 总闪电数据与雷达数据是一致的,总闪电数据可单独用于比雷达数据更小的时空尺度。
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引用次数: 0
Predicting transformer temperature field based on physics-informed neural networks 基于物理信息神经网络的变压器温度场预测
IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-05-09 DOI: 10.1049/hve2.12435
Pengfei Tang, Zhonghao Zhang, Jie Tong, Tianhang Long, Can Huang, Zihao Qi

The safe operation of oil-immersed transformers is critical to the safety and stability of the power grid. As the operating time increases, the failure rate of oil-immersed transformers shows an increasing trend, posing serious challenges to safe operation. It is necessary to investigate the internal state of the oil-immersed transformer to improve the digital degree and achieve digitalisation and intelligent operation and maintenance. A physics-informed neural network (PINN) for oil-immersed transformers was introduced to reconstruct the temperature distribution inside the transformer. According to the approach, the loss function of the network would be optimised by incorporating physical constraint loss terms including heat transfer equations, initial conditions and boundary conditions. The results show that the method proposed can be used to reconstruct and predict the temperature field of transformers in a few seconds with satisfactory accuracy. In conclusion, the PINN proposed outperforms deep neural networks in terms of accuracy, reliability and interpretability, especially in data-poor cases.

油浸式变压器的安全运行对电网的安全和稳定至关重要。随着运行时间的延长,油浸式变压器的故障率呈上升趋势,给安全运行带来严峻挑战。有必要对油浸式变压器的内部状态进行研究,提高数字化程度,实现数字化、智能化运维。针对油浸式变压器引入了物理信息神经网络(PINN)来重建变压器内部的温度分布。根据该方法,网络的损失函数将通过纳入物理约束损失项(包括传热方程、初始条件和边界条件)来优化。结果表明,所提出的方法可用于在几秒钟内重建和预测变压器的温度场,且精度令人满意。总之,所提出的 PINN 在准确性、可靠性和可解释性方面优于深度神经网络,尤其是在数据匮乏的情况下。
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引用次数: 0
Adsorption and sensing characteristics of insulating gas C4F7N on 3d late transition metal-phthalocyanine: Theoretical and experimental study 三维晚过渡金属酞菁对绝缘气体 C4F7N 的吸附和传感特性:理论与实验研究
IF 4.4 2区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-05-07 DOI: 10.1049/hve2.12437
Dachang Chen, Ziang Zheng, Cong Zhang, Yi Luo, Song Xiao, Qing Miao, Ke Liu, Beibei Xiao

Heptafluoroisobutyronitrile (C4F7N) is being considered as a promising alternative to the greenhouse gas SF6 in the electrical industry. However, its biotoxicity necessitates the development of gas sensing technology to detect leaked C4F7N. A combination of density functional theory and experiments was employed to evaluate the adsorption and sensing performance of different metal-phthalocyanines as potential sensing materials for C4F7N detection. The study included exploring adsorption configurations with adsorption energies, electron transfer, and adsorption distance, as well as comparisons of electronic properties, electron distribution, and density of states (DOS) among the MPcs. Furthermore, gas sensing experiments were conducted using different MPcs to detect 25–100 ppm C4F7N. The results revealed that Mn-Pc, Fe-Pc, Co-Pc, and Zn-Pc exhibited considerable chemical interactions, while Ni-Pc and Cu-Pc showed weaker adsorption strength. These findings were further elucidated based on the electron density and DOS of atomic orbitals. Moreover, gas sensing experiments indicated that Co-Pc demonstrated a higher response compared to Fe-Pc at the same concentration of C4F7N. Overall, the theoretical and experimental insights offer valuable guidance for C4F7N detection and provide a systematic approach to screen and explore organometallic polymer-based gas sensors applicable in various fields.

七氟异丁腈(C4F7N)被认为是电气工业中替代温室气体 SF6 的一种前景看好的气体。然而,由于其生物毒性,有必要开发气体传感技术来检测泄漏的 C4F7N。研究人员结合密度泛函理论和实验,评估了不同金属酞菁作为潜在 C4F7N 检测传感材料的吸附和传感性能。研究包括探索吸附构型的吸附能、电子转移和吸附距离,以及比较不同金属酞菁的电子特性、电子分布和状态密度(DOS)。此外,还利用不同的 MPcs 进行了气体传感实验,以检测 25-100 ppm 的 C4F7N。结果显示,Mn-Pc、Fe-Pc、Co-Pc 和 Zn-Pc 具有相当大的化学相互作用,而 Ni-Pc 和 Cu-Pc 的吸附强度较弱。根据原子轨道的电子密度和 DOS 进一步阐明了这些发现。此外,气体传感实验表明,在相同浓度的 C4F7N 中,Co-Pc 的响应高于 Fe-Pc。总之,这些理论和实验见解为 C4F7N 的检测提供了宝贵的指导,并为筛选和探索适用于各个领域的有机金属聚合物气体传感器提供了系统的方法。
{"title":"Adsorption and sensing characteristics of insulating gas C4F7N on 3d late transition metal-phthalocyanine: Theoretical and experimental study","authors":"Dachang Chen,&nbsp;Ziang Zheng,&nbsp;Cong Zhang,&nbsp;Yi Luo,&nbsp;Song Xiao,&nbsp;Qing Miao,&nbsp;Ke Liu,&nbsp;Beibei Xiao","doi":"10.1049/hve2.12437","DOIUrl":"10.1049/hve2.12437","url":null,"abstract":"<p>Heptafluoroisobutyronitrile (C<sub>4</sub>F<sub>7</sub>N) is being considered as a promising alternative to the greenhouse gas SF<sub>6</sub> in the electrical industry. However, its biotoxicity necessitates the development of gas sensing technology to detect leaked C<sub>4</sub>F<sub>7</sub>N. A combination of density functional theory and experiments was employed to evaluate the adsorption and sensing performance of different metal-phthalocyanines as potential sensing materials for C<sub>4</sub>F<sub>7</sub>N detection. The study included exploring adsorption configurations with adsorption energies, electron transfer, and adsorption distance, as well as comparisons of electronic properties, electron distribution, and density of states (DOS) among the MPcs. Furthermore, gas sensing experiments were conducted using different MPcs to detect 25–100 ppm C<sub>4</sub>F<sub>7</sub>N. The results revealed that Mn-Pc, Fe-Pc, Co-Pc, and Zn-Pc exhibited considerable chemical interactions, while Ni-Pc and Cu-Pc showed weaker adsorption strength. These findings were further elucidated based on the electron density and DOS of atomic orbitals. Moreover, gas sensing experiments indicated that Co-Pc demonstrated a higher response compared to Fe-Pc at the same concentration of C<sub>4</sub>F<sub>7</sub>N. Overall, the theoretical and experimental insights offer valuable guidance for C<sub>4</sub>F<sub>7</sub>N detection and provide a systematic approach to screen and explore organometallic polymer-based gas sensors applicable in various fields.</p>","PeriodicalId":48649,"journal":{"name":"High Voltage","volume":"9 4","pages":"870-878"},"PeriodicalIF":4.4,"publicationDate":"2024-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/hve2.12437","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141004606","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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