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Carbon Capture and Storage: From Global Cycles to Global Solutions 碳捕集与封存:从全球循环到全球解决方案
3区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-10-01 DOI: 10.7185/geochempersp.12.2
Eric Oelkers, Sigurdur Gislason
Anthropogenic carbon emissions have overwhelmed the natural carbon cycle, leading to a dramatic increase in atmospheric CO2 concentration. The rate of this increase may be unprecedented in Earth’s history and is leading to a substantial increase in global temperatures, ocean acidification, sea level rise and potentially human health challenges. In this Geochemical Perspectives we review the natural carbon cycle and its link to global climate. Notably, as directly observed by field observations summarised in this volume, there is a natural negative feedback loop between increasing global temperature, continental weathering rates, and CO2 that has tended to limit Earth climate changes over geological time scales. Due to the rapid increase in atmospheric carbon concentrations, global average temperatures have increased by more than 1.2 °C since the start of the industrial revolution. One way to slow or even arrest this increasing global average temperature is through Carbon Capture and Storage (CCS). Carbon dioxide can be captured either from large industrial point sources or directly from the atmosphere. Taking account of the natural carbon cycle, the most secure approach to storing captured CO2 is by reacting it with mafic or ultramafic rocks to form stable carbonate minerals, a process referred to as “mineral carbonation”. Although mineral carbonation can occur and be accelerated at the Earth’s surface, due to the required scale and required time frames it is most effective in the subsurface. This subsurface mineralisation approach was developed into an industrial scale process through an academic-industrial collaboration called CarbFix. The history of CarbFix, from its beginnings as a concept through its installation as an industrial process is presented in detail. This Geochemical Perspectives concludes with an assessment of the future of subsurface mineralisation as a means to help address the global warming challenge, as well as a detailed list of potential research directions that need to be addressed to further upscale and optimise this carbon storage approach.
人为碳排放已经超过了自然碳循环,导致大气中二氧化碳浓度急剧增加。这种增长速度可能是地球历史上前所未有的,并正在导致全球气温大幅上升、海洋酸化、海平面上升以及潜在的人类健康挑战。在这篇地球化学展望中,我们回顾了自然碳循环及其与全球气候的联系。值得注意的是,正如本卷总结的实地观测直接观察到的那样,在全球温度上升、大陆风化率和二氧化碳之间存在一个自然的负反馈循环,这一循环倾向于在地质时间尺度上限制地球气候变化。由于大气中碳浓度的迅速增加,自工业革命开始以来,全球平均气温上升了1.2°C以上。减缓甚至阻止全球平均气温上升的一种方法是通过碳捕获和储存(CCS)。二氧化碳既可以从大型工业点源捕获,也可以直接从大气中捕获。考虑到自然碳循环,储存捕获的二氧化碳最安全的方法是将其与基性或超基性岩石反应形成稳定的碳酸盐矿物,这一过程被称为“矿物碳酸化”。虽然矿物碳酸化可以在地球表面发生并加速,但由于所需的规模和所需的时间框架,它在地下最有效。通过一项名为CarbFix的学术-工业合作,这种地下矿化方法发展成为一种工业规模的工艺。详细介绍了CarbFix的历史,从它作为一个概念的开始,到它作为一个工业过程的安装。《地球化学展望》最后评估了地下矿化作为应对全球变暖挑战的一种手段的未来,并详细列出了需要解决的潜在研究方向,以进一步提升和优化这种碳储存方法。
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引用次数: 0
A journey in Noble Gas Cosmochemistry and Geochemistry 稀有气体宇宙化学和地球化学之旅
IF 3.8 3区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-04-01 DOI: 10.7185/geochempersp.12.1
R. Wieler
I started my journey in science by studying noble gases implanted by the solar wind in dust grains on the surface of the Moon, and with many colleagues I have studied solar wind implanted noble gases in natural and artificial samples throughout my career, the latter exposed primarily by the Genesis space mission. Major questions are what noble gases in the solar wind can tell us about the present and the past Sun, and how they can contribute to understanding the formation and history of the planets and their building blocks, represented, for example, by meteorites. Since my early years as a postdoc, I have also been interested in noble gases (and radioactive nuclides) produced in meteorites and other extraterrestrial samples by interactions with energetic elementary particles from galactic cosmic radiation (and the Sun). These so called “cosmogenic” nuclides allow us to study the transport of meteorites to Earth, and the dynamics of the top surface layers (“regoliths”) on the Moon, asteroids, and comets. Cosmogenic noble gases are also crucial for studying even more exotic topics such as the history of tiny presolar grains that formed in the cooling envelopes of earlier generations of stars towards the end of their lives and were eventually incorporated into the meteoritic matter where they are found today. Cosmogenic noble gases in some tiny phases in meteorites are also likely tracers of our highly active Sun at a very early stage in its history. A few years later, I started my third major research topic in cosmochemistry, the study of primordial noble gases in meteorites and other extraterrestrial samples. These noble gases were incorporated into meteorites or their precursors in the early solar system or even in a presolar environment. I also participated in studies by colleagues of isotopic anomalies of other elements important in cosmochemistry, my expertise being mainly in aspects of the influence of cosmic rays on these elements. Although working in an Earth Science institution, it took quite a while before I started to also study noble gases (and radionuclides) in terrestrial samples. This is described in the second part of this contribution. A major focus was on cosmogenic noble gases and radionuclides produced in samples near the Earth’s surface. Although production rates of cosmogenic nuclides on Earth are several orders of magnitude lower than in space, making their analysis more challenging, they have become an important tool in geomorphology. Because stable noble gas nuclides are particularly well suited to the study of ancient landscapes, much of our work focused on areas with arid climates, such as Antarctica and the Andes in Chile, in collaboration with geoscience colleagues. We also participated in the large multinational CRONUS collaboration, funded by the European Union, a community effort to improve our knowledge of nuclide production rates at the Earth’s surface. In another major collaboration with external colleagues we ar
我的科学之旅始于研究太阳风在月球表面尘埃颗粒中注入的稀有气体,在我的职业生涯中,我与许多同事一起研究了太阳风在天然和人造样本中注入的惰性气体,后者主要是在创世纪太空任务中暴露的。主要问题是太阳风中的稀有气体可以告诉我们现在和过去的太阳,以及它们如何有助于理解行星及其组成部分的形成和历史,例如陨石。自从我早年做博士后以来,我也对陨石和其他地外样本中通过与银河系宇宙辐射(和太阳)中的高能基本粒子相互作用产生的稀有气体(和放射性核素)感兴趣。这些所谓的“宇宙成因”核素使我们能够研究陨石向地球的传输,以及月球、小行星和彗星顶表面层(“风化层”)的动力学。宇宙成因惰性气体对于研究更具异国情调的主题也至关重要,例如在前几代恒星生命末期的冷却包层中形成的微小太阳前颗粒的历史,这些颗粒最终被纳入今天发现的陨石物质中。陨石中一些微小相中的宇宙成因惰性气体也可能是我们历史早期高度活跃的太阳的示踪剂。几年后,我开始了我在宇宙化学方面的第三个主要研究课题,即陨石和其他地外样本中原始稀有气体的研究。这些稀有气体在早期太阳系甚至在前太阳系环境中被并入陨石或其前身中。我还参与了同事们对宇宙化学中其他重要元素同位素异常的研究,我的专业知识主要是宇宙射线对这些元素的影响。尽管我在地球科学机构工作,但我花了很长一段时间才开始研究地球样本中的稀有气体(和放射性核素)。本文第二部分对此进行了描述。主要关注的是地球表面附近样本中产生的宇宙成因惰性气体和放射性核素。尽管地球上宇宙成因核素的产生率比太空中低几个数量级,使其分析更具挑战性,但它们已成为地貌学的重要工具。由于稳定的稀有气体核素特别适合研究古代景观,我们与地球科学同事合作,将大部分工作集中在气候干旱的地区,如南极洲和智利的安第斯山脉。我们还参加了由欧洲联盟资助的大型多国CRONUS合作,这是一项社区努力,旨在提高我们对地球表面核素生产率的了解。在与外部同事的另一项重大合作中,我们参与了对水样的惰性气体分析,从湖泊到含水层,再到石笋中的微小内含物。这项研究的重点是研究湖泊和地下水动力学,包括地幔衍生的稀有气体的贡献,如火山湖。溶解在合适样本中的大气稀有气体也是古温度指标,补充了氧同位素等其他指标的信息。
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引用次数: 1
Anoxia-Related Biogeochemistry of North Indian Ocean 北印度洋缺氧相关生物地球化学
IF 3.8 3区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2022-10-01 DOI: 10.7185/geochempersp.11.2
S. Naqvi
Complex interactions between microbial communities and geochemical processes drive the major element cycles and control the function of marine sediments as a dynamic reservoir of organic matter. Sulfate reduction is globally the dominant pathway of anaerobic mineralisation and is the main source of sulfide. The effective re-oxidation of this sulfide at the direct or indirect expense of oxygen is a prerequisite for aerobic life on our planet. Although largely hidden beneath the oxic sediment surface, the sulfur cycle is therefore critical for Earth’s redox state. This Geochemical Perspectives begins with a brief primer on the sulfur cycle of marine sediments and a description of my own scientific journey through nearly fifty years of studies of sulfur geochemistry and microbiology. Among the main objectives of these studies were to quantify the main processes of the sulfur cycle and to identify the microbial communities behind them. Radiotracers in combination with chemical analyses have thereby been used extensively for laboratory experiments, supported by diverse molecular microbiological methods. The following sections discuss the main processes of sulfate reduction, sulfide oxidation and disproportionation of the inorganic sulfur intermediates, especially of elemental sulfur and thiosulfate. The experimental approaches used enable the analysis of how environmental factors such as substrate concentration or temperature affect process rates and how concurrent processes of sulfate reduction and sulfide oxidation drive a cryptic sulfur cycle. The chemical energy of sulfide is used by chemolithotrophic bacteria, including fascinating communities of big sulfur bacteria and cable bacteria, and supports their dark CO2 fixation, which produces new microbial biomass. During the burial and aging of marine sediments, the predominant mineralisation processes change through a cascade of redox reactions, and the rate of organic matter degradation drops continuously over many orders of magnitude. The main pathways of anaerobic mineralisation and the age control of the organic matter turnover are discussed. In the deep methanic zone, only a few percent of the entire degradation process remains, which provides a small boost of substrate for sulfate reduction through the process of anaerobic methane oxidation. The stable isotopes of sulfur provide an additional tool to understand these diagenetic processes, whereby the combination of microbial isotope fractionation and open system diagenesis generate a differential diffusion flux of the isotopes. In relation to the organic carbon cycle of the seabed and the contribution of methane, the paper discusses the global sulfur budget and the role of sulfate reduction for organic matter mineralisation in different depth regions of the ocean - from coast to deep sea. The published estimates of these parameters are evaluated and compared. Finally, the paper looks at future perspectives with respect to gaps in our current u
微生物群落与地球化学过程之间的复杂相互作用驱动了主要元素循环,并控制着海洋沉积物作为有机物质动态储层的功能。硫酸盐还原是全球厌氧矿化的主要途径,也是硫化物的主要来源。在直接或间接消耗氧气的情况下,这种硫化物的有效再氧化是我们星球上有氧生命的先决条件。虽然大部分隐藏在含氧沉积物表面之下,但硫循环对地球的氧化还原状态至关重要。这本地球化学展望书首先简要介绍了海洋沉积物的硫循环,并描述了我自己近五十年来对硫地球化学和微生物学的研究。这些研究的主要目标之一是量化硫循环的主要过程,并确定其背后的微生物群落。因此,放射性示踪剂与化学分析相结合已广泛用于实验室实验,并得到各种分子微生物学方法的支持。下面几节讨论了无机硫中间体,特别是单质硫和硫代硫酸盐的硫酸盐还原、硫化物氧化和歧化的主要过程。所使用的实验方法能够分析环境因素(如底物浓度或温度)如何影响过程速率,以及硫酸盐还原和硫化物氧化的同时过程如何驱动隐硫循环。硫化物的化学能被化能岩石营养细菌所利用,包括迷人的大型硫细菌和电缆细菌群落,并支持它们的暗CO2固定,从而产生新的微生物生物量。在海洋沉积物的埋藏和老化过程中,主要的矿化过程通过一系列氧化还原反应发生变化,有机物降解的速度连续下降了许多数量级。讨论了厌氧矿化的主要途径和有机质周转的年龄控制。在深层甲烷区,整个降解过程只剩下百分之几,这为通过厌氧甲烷氧化过程还原硫酸盐提供了一个小的底物。硫的稳定同位素为了解这些成岩过程提供了一个额外的工具,微生物同位素分馏和开放体系成岩作用的结合产生了同位素的微分扩散通量。关于海底有机碳循环和甲烷的贡献,本文讨论了全球硫收支和硫酸盐还原对海洋不同深度区域(从海岸到深海)有机质矿化的作用。对已公布的这些参数估计值进行评估和比较。最后,本文着眼于未来的观点,考虑到我们目前的理解差距和进一步研究的需要。
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引用次数: 1
Academic Reminiscences and Thermodynamics-Kinetics of Thermo-Barometry-Chronology 学术回忆与热力学-热气压计动力学-年代学
IF 3.8 3区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2021-04-01 DOI: 10.7185/geochempersp.10.1
J. Ganguly
This article has three major components that include, in addition to the technical aspects, reminiscences of my academic upbringing, my move to the USA from India, and my professional career. I have recounted many stories that I hope convey some sense of time, especially in these two countries with vastly different cultures, my personal journey with its ups and downs and how I made the transition to an academic career path in USA even though that was not in my future plan as a young man. The development of the field of thermobarometry and its integration with diffusion and crystal kinetic modelling of compositional zoning (or lack thereof) and cation ordering in minerals have led to important quantitative constraints on the pressure-temperature-time evolution of terrestrial rocks and meteorites. I review the historical developments in these areas and a segment of my own research spanning the period of 1964-2021. The foundational works of the thermometry of metamorphic rocks and palaeothermometry were laid at the University of Chicago around 1950. Subsequently, the synergetic growth of thermodynamics and experimental studies in petrology in the 1960s and 1970s, along with the introduction of electron microprobe as a nondestructive analytical tool with micron scale resolution, gave a major boost to the field of thermobarometry. There were also significant new developments in the field of thermodynamics of solid solutions in the petrology community and demonstration from observational data, countering strong scepticism, that the principles of classical thermodynamics were applicable to “complex natural systems”. The section on thermodynamic basis of thermobarometry concludes with a discussion of the thermodynamics of trace element and single mineral thermometry. I further deal with the experimental protocols, along with selected examples, for phase equilibrium studies that provide the bedrock foundation for the field of thermobarometry based on elemental compositions of coexisting minerals in a rock. It is followed by an account of the controversies and international meetings relating to the aluminum silicate and peridotite phase diagrams that play crucial roles in the thermobarometry of metamorphic rocks and mantle xenoliths, respectively. The construction of quantitative petrogenetic grids to display stability relations of minerals in multicomponent–multiphase systems came into play in the field of metamorphic petrology in the mid-1960s and early 1970s. Augmented by experimental data, these petrogenetic grids led to important discoveries about the P-T-f(O2) and bulk compositional controls on the stability of certain “index” minerals that are used to define metamorphic isograds and different types of regional metamorphism; one such grid also opened up a new field that came to be known as ultra-high temperature metamorphism. The construction of petrogenetic grids has now evolved to computer based calculations of complex equilibrium P-T phase diagram
这篇文章有三个主要组成部分,除了技术方面,还包括我的学术成长回忆、我从印度移居美国的经历以及我的职业生涯。我讲述了许多故事,我希望这些故事能传达一些时间感,尤其是在这两个文化截然不同的国家,我的个人旅程跌宕起伏,以及我是如何在美国过渡到学术生涯的,尽管这不是我年轻时的未来计划。热气压测量领域的发展及其与矿物中成分分区(或缺乏成分分区)和阳离子有序的扩散和晶体动力学建模的结合,对岩石和陨石的压力-温度-时间演化产生了重要的定量约束。我回顾了这些领域的历史发展,以及我自己在1964-2021年期间的一部分研究。变质岩测温和古测温的基础工作于1950年左右在芝加哥大学奠基。随后,20世纪60年代和70年代热力学和岩石学实验研究的协同发展,以及电子探针作为微米级分辨率的无损分析工具的引入,极大地推动了热气压测量领域的发展。岩石学界在固溶体热力学领域也有了重大的新进展,观测数据也证明了经典热力学原理适用于“复杂自然系统”,这与强烈的怀疑相反。热气压测量的热力学基础部分最后讨论了微量元素热力学和单矿物测温。我进一步讨论了相平衡研究的实验方案,以及选定的例子,这些研究为基于岩石中共存矿物的元素组成的热气压测量领域提供了基础。随后介绍了与硅酸铝和橄榄岩相图有关的争议和国际会议,这两张相图分别在变质岩和地幔捕虏体的热气压测量中起着至关重要的作用。20世纪60年代中期和70年代初,在变质岩石学领域开始构建定量的岩石成因网格,以显示多组分-多相系统中矿物的稳定性关系。在实验数据的补充下,这些岩石成因网格导致了关于P-T-f(O2)和对某些“指数”矿物稳定性的整体成分控制的重要发现,这些“指数”矿物质用于定义变质等梯度和不同类型的区域变质作用;一个这样的网格也开辟了一个新的领域,后来被称为超高温变质作用。岩石成因网格的构建现在已经发展到基于计算机的复杂平衡P-T相图的计算,通常被称为“假截面”,通过最小化具有固定体积组成的系统的吉布斯自由能。我讨论这些历史发展和现代进步。随后,我重点介绍了选定自然样品的热气压测量和扩散动力学建模的一些方面及其更广泛的含义,并对自然组合的热气压测定的不同方案进行了批判性讨论。在介绍古测温发展的历史观点之后,我用密度泛函理论(DFT)讨论了现代进展。已经显示了基于DFT的计算实例,用于矿泉水/氢系统中的氢同位素分馏和“聚集同位素”测温。氢同位素分馏数据引领了使用蛇纹石-滑石/水镁石矿物对开发新的低温古温度计。这些结果使得能够同时解决岩石蛇纹石化过程中的温度和流体来源。最后一节专门讨论高温热年代学,处理矿物衰变系统的闭合温度问题,以及根据特定衰变系统使用体积和空间重置矿物年龄来确定主岩的冷却速率。在解释由176Lu-176Hf或53Mn-53Cr等衰变系统确定的矿物年龄时会出现复杂情况,其中母体核素的闭合温度比相应的子产物低得多。数值模拟有助于解释变质岩中石榴石的176Lu-176Hf和147Sm-143Nd年龄之间的差异,并能够根据差异年龄和一些额外的约束条件构建整个T-T旋回。
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引用次数: 0
Origins and Early Evolution of the Atmosphere and the Oceans 大气和海洋的起源和早期演变
IF 3.8 3区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2020-10-01 DOI: 10.7185/geochempersp.9.2
B. Marty
My journey in science began with the study of volcanic gases, sparking an interest in the origin, and ultimate fate, of the volatile elements in the interior of our planet. How did these elements, so crucial to life and our surface environment, come to be sequestered within the deepest regions of the Earth, and what can they tell us about the processes occurring there? My approach has been to establish geochemical links between the noble gases, physical tracers par excellence, with major volatile elements of environmental importance, such as water, carbon and nitrogen, in mantle-derived rocks and gases. From these analyses we have learned that the Earth is relatively depleted in volatile elements when compared to its potential cosmochemical ancestors (e.g., ~2 ppm nitrogen compared to several hundreds of ppm in primitive meteorites) and that natural fluxes of carbon are two orders of magnitude lower than those emitted by current anthropogenic activity. Further insights into the origin of terrestrial volatiles have come from space missions that documented the composition of the proto-solar nebula and the outer solar system. The consensus behind the origin of the atmosphere and the oceans is evolving constantly, although recently a general picture has started to emerge. At the dawn of the solar system, the volatile-forming elements (H, C, N, noble gases) that form the majority of our atmosphere and oceans were trapped in solid dusty phases (mostly in ice beyond the snowline and organics everywhere). These phases condensed from the proto-solar nebula gas, and/or were inherited from the interstellar medium. These accreted together within the next few million years to form the first planetesimals, some of which underwent differentiation very early on. The isotopic signatures of volatiles were also fixed very early and may even have preceded the first episodes of condensation and accretion. Throughout the accretion of the Earth, volatile elements were delivered by material from both the inner (dry, volatile-poor) and outer (volatile-rich) solar system. This delivery was concomitant with the metals and silicates that form the bulk of the planet. The contribution of bodies that formed in the far outer solar system, a region now populated by comets, is likely to have been very limited. In that sense, volatile elements were contributed continuously throughout Earth’s accretion from inner solar system reservoirs, which also provided the silicates and metal building blocks of the inner planets. Following accretion, it likely took a few hundred million years for the Earth’s atmosphere and oceans to stabilise. Luckily, we have been able to access a compositional record of the early atmosphere and oceans through the analysis of palaeo-atmospheric fluids trapped in Archean hydrothermal quartz. From these analyses, it appears that the surface reservoirs of the Earth evolved due to interactions between the early Sun and the top of the atmosphere, as well as the de
我的科学之旅始于对火山气体的研究,激发了人们对地球内部挥发性元素的起源和最终命运的兴趣。这些对生命和地表环境至关重要的元素是如何被隔离在地球最深处的,它们能告诉我们那里发生的过程吗?我的方法是在稀有气体(卓越的物理示踪剂)与地幔衍生岩石和气体中具有重要环境意义的主要挥发性元素(如水、碳和氮)之间建立地球化学联系。从这些分析中,我们了解到,与潜在的宇宙化学祖先相比,地球的挥发性元素相对较少(例如,约2ppm的氮,而原始陨石中的氮含量为数百ppm),碳的自然通量比当前人类活动排放的碳通量低两个数量级。太空任务记录了原太阳星云和外太阳系的组成,进一步深入了解了地球挥发物的起源。关于大气层和海洋起源的共识正在不断演变,尽管最近开始出现一个总体情况。在太阳系诞生之初,构成我们大气层和海洋大部分的挥发性形成元素(H、C、N、稀有气体)被困在固体尘埃相中(主要存在于雪线外的冰和各处的有机物中)。这些相是从原太阳星云气体中凝结而来的,和/或是从星际介质中继承而来的。在接下来的几百万年里,这些星子聚集在一起,形成了第一批星子,其中一些星子很早就经历了分化。挥发物的同位素特征也很早就固定下来,甚至可能早在第一次凝结和吸积之前。在地球吸积的整个过程中,挥发性元素是由内部(干燥、挥发性差)和外部(挥发性丰富)太阳系的物质输送的。这种输送伴随着形成地球大部分的金属和硅酸盐。在遥远的外太阳系形成的天体的贡献可能非常有限,该地区现在有彗星居住。从这个意义上说,在整个地球吸积过程中,挥发性元素不断地从太阳系内部的储层中产生,这些储层也提供了内行星的硅酸盐和金属构件。在吸积之后,地球的大气层和海洋可能需要数亿年才能稳定下来。幸运的是,我们能够通过分析太古代热液石英中捕获的古大气流体,获得早期大气和海洋的成分记录。从这些分析来看,地球表面的储层似乎是由于早期太阳和大气层顶部之间的相互作用以及早期生物圈的发展而进化的,该生物圈逐渐改变了其化学性质。
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引用次数: 7
Geology, Policy and Wine – The Intersection of Science and Life 地质学、政策与葡萄酒——科学与生活的交集
IF 3.8 3区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2020-04-01 DOI: 10.7185/geochempersp.9.1
L. Meinert
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引用次数: 2
My Stable Isotope Journey in Biogeochemistry, Geoecology, and Astrobiology 我的生物地球化学、地质生态学和天体生物学稳定同位素之旅
IF 3.8 3区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2019-10-01 DOI: 10.7185/geochempersp.8.2
M. Fogel
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引用次数: 1
CO2: Earth’s Climate Driver 二氧化碳:地球的气候驱动因素
IF 3.8 3区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2018-10-01 DOI: 10.7185/GEOCHEMPERSP.7.2
W. Broecker
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引用次数: 16
Big-Picture Geochemistry from Microanalyses – My Four-Decade Odyssey in Sims 宏观地球化学从微观分析-我的四十年奥德赛在模拟人生
IF 3.8 3区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2018-04-01 DOI: 10.7185/GEOCHEMPERSP.8.1
N. Shimizu
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引用次数: 1
Cosmochemistry Along The Rhine 莱茵河沿岸的宇宙化学
IF 3.8 3区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2018-04-01 DOI: 10.7185/GEOCHEMPERSP.7.1
H. Palme
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引用次数: 2
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