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Pedogenic and subaerial exposure microfabrics in a late Carboniferous-early Permian carbonate-volcanic lacustrine-palustrine system (San Ignacio Formation, Frontal Cordillera, Argentina) 晚石炭世-早二叠世碳酸盐岩-火山-湖泊-沼泽系统中的成地和陆上暴露微构造(阿根廷科迪勒拉前沿圣伊格纳西奥组)
IF 0.9 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2020-05-29 DOI: 10.5027/ANDGEOV47N2-3214
I. Méndez-Bedia, G. Gallastegui, P. Busquets, S. N. Césari, C. Limarino, E. Prats, R. Cardó, F. Colombo
In the Argentinian Andes (Frontal Cordillera) the upper part of the late Carboniferous-early Permian San Ignacio Formation is made up of lacustrine-palustrine microbial carbonates and interbedded volcanic deposits. In this lacustrine-palustrine environment a natural monospecific forest was developed. The deposits of this sedimentary-volcanic succession were repeatedly subjected to subaerial exposure and modified by pedogenesis to varying degrees giving rise to paleosoils development. Diagenetic microfabrics were well preserved in the carbonates and volcanic rocks. The carbonate microfabrics comprise a wide spectrum of features consisting of root marks and stumps-related structures (rhizoliths, alveolar texture, tunnel-like structures and coprolites of arthropods), pisoids, coated grains and pseudomicrokarst, cracking, brecciated and nodular fabrics, and grainification also occur corresponding to different stages in the pedogenic evolution. Meteoric dissolution and cementation processes are observed; examples are well identified by scanning electron microscope showing silica-filled voids in partially dissolved carbonates and growths of inorganic carbonate microcrystals or of microbial origin in voids. Other different types of cements can be seen such as discontinuous carbonate crusts, ribbon spar, cavities with silt infillings and pendant cements. The whole set of these microfabrics are indicative of wetting, desiccation and meteoric conditions (vadose and phreatic). The abundance of plant roots and associated micro-organisms mainly of bacterial origin (micro-rods, short rod-shapes, nano-fibres, filaments and nano-spheres) played an important role in the pedogenic and subaerial diagenetic processes affecting these deposits. The immature character of the paleosoils and absence of calcretes point out to short intervals of subaerial exposure due to oscillating fluctuations in water level, intermittent volcanic supply, tectonic subsidence and oscillating climatic conditions. The whole of the macro and microfabrics reveals that the prevailing weather could correspond to an intermediate between semi-arid to sub-humid, however the alternating wetting and drying conditions in which the fossil forest developed and the abundance and diversity of micro-organisms, suggest a transition to sub-humid climate conditions.
在阿根廷安第斯山脉(Frontal Cordilera),晚石炭世-早二叠世San Ignacio组的上部由湖相沼泽微生物碳酸盐岩和互层火山沉积物组成。在这种湖泊沼泽环境中,形成了一种天然的单特异性森林。该沉积火山序列的沉积物多次受到陆上暴露,并在不同程度上受到成土作用的改变,从而导致古土壤的发育。碳酸盐岩和火山岩中保存完好的成岩微构造。碳酸盐微组构包括广泛的特征,包括根痕和树桩相关结构(节肢动物的根状体、肺泡结构、隧道状结构和粪化石)、豆状物、涂层颗粒和假微岩溶、开裂、角砾化和结节状组构,颗粒化也对应于成土演化的不同阶段。观察到流星溶解和胶结过程;通过扫描电子显微镜很好地鉴定了实例,其显示在部分溶解的碳酸盐中二氧化硅填充的空隙以及空隙中无机碳酸盐微晶或微生物来源的生长。可以看到其他不同类型的胶结物,如不连续的碳酸盐结壳、带状晶石、带有淤泥填充物的空腔和悬垂胶结物。整套这些微组构表明了湿润、干燥和大气环境条件(渗流和潜水)。丰富的植物根系和主要由细菌来源的相关微生物(微棒、短棒形状、纳米纤维、细丝和纳米球体)在影响这些沉积物的成土和陆上成岩过程中发挥了重要作用。古土壤的不成熟特征和钙质混凝土的缺乏表明,由于水位的振荡波动、间歇性火山供应、构造沉降和振荡的气候条件,陆上暴露的时间间隔很短。整个宏观和微观构造表明,主要天气可能介于半干旱和亚湿润之间,但化石森林发育的干湿交替条件以及微生物的丰富性和多样性表明,气候条件已过渡到亚湿润。
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引用次数: 5
Fluvial deposits of the Diamante Formation as a record of the Late Cretaceous tectonic activity in the Southern Central Andes, Mendoza, Argentina 作为阿根廷门多萨安第斯山脉中南部晚白垩世构造活动记录的迪亚曼特组冲积层
IF 0.9 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2020-05-29 DOI: 10.5027/andgeov47n2-3218
Ricardo M. Gómez, Maísa A. Tunik, S. Casadío
The Upper Cretaceous nonmarine deposits of the Neuquén Basin have an important regional exposure. These deposits are included in the Neuquén Group, a well-studied unit in both the south and central part of the basin. However, the northernmost exposed between the Laguna del Diamante and the Atuel River-assigned to the Diamante Formation-have not been studied in detail. In the studied area, the Diamante Formation corresponds to a braided fluvial system with moderate sinuosity evolving through time towards an anastomosing fluvial system. Petrographic analyses indicate that sandstones belong to feldspatic litharenites and litharenites, while the source area indicates provenance from both a recycled orogen and a transitional arc. The latter could be linked to the exhumation of the Andean orogen located to the west and to the input from the north-eastern border of the Neuquén Basin, represented by the rocks currently exposed in the San Rafael Block. On a macroscopic scale, the presence of calcareous lithic fragments in the mid and upper part of the surveyed stratigraphic section, strongly suggest an input from the west. This indicates an important change in the polarity of the basin and the presence of a deformation front located to the west of the study area in accordance to previous proposals in equivalent deposits to the south of study area.
Neuquén盆地的上白垩纪非海相矿床具有重要的区域暴露。这些矿床包含在Neuquén群中,这是盆地南部和中部一个经过充分研究的单元。然而,尚未详细研究迪亚曼特组的Laguna del Diamante和Atuel河之间暴露的最北端。在研究区域,Diamante组对应于一个具有中等弯度的辫状河流系统,随着时间的推移,该系统逐渐演变为网状河流系统。岩石学分析表明,砂岩属于长石岩屑砂岩和岩屑砂岩,而源区表明来源于再循环造山带和过渡弧。后者可能与位于西部的安第斯造山带的剥露和来自Neuquén盆地东北边界的输入有关,以目前暴露在圣拉斐尔区块的岩石为代表。在宏观尺度上,所测地层剖面的中上部存在钙质岩屑,强烈表明有来自西方的输入。这表明盆地极性发生了重要变化,并且根据研究区域南部等效矿床的先前建议,研究区域西部存在变形锋。
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引用次数: 1
Unexpected coseismic surface uplift at Tirúa-Mocha Island area of south Chile before and during the Mw 8.8 Maule 2010 earthquake: a possible upper plate splay fault 2010年毛勒8.8级地震前后,智利南部蒂鲁阿莫查岛地区意外的同震地表隆起:可能的上盘扇断层
IF 0.9 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2020-05-29 DOI: 10.5027/andgeov47n2-3057
Jorge Quezada, E. Jaque, N. Catalán, A. Belmonte, A. Fernández, F. Isla
The Tirúa-Mocha Island area (38.2°-38.4° S) in southern Chile has been affected by two megaearthquakes in only 50 years: the 1960 Mw=9.5 Valdivia earthquake and 2010 Mw=8.8 Maule earthquake. We studied in the field the vertical ground movements occurred during the interseismic period between both earthquakes and the coseismic period of 2010 Maule earthquake and 2011 Mw=7.1 Araucanía earthquake. During the 1960 earthquake, vertical coseismic ground movements are typical of subduction related earthquakes with Mocha Island, located close to the trench, experienced bigger ground uplift (150 cm) than that occurred in Tirúa (-20 cm), place located in the continental margin at the latitude of Mocha Island. Then during the 1960-2010 interseismic period, the 1960 coseismic uplift remained at Mocha Island unlike the normal interseismic subsidence that occurred northward at Arauco Peninsula and Santa María Island. Also Tirúa experienced the biggest interseismic uplift (180 cm) in all the area affected later by 2010 Maule earthquake. Then during the 2010 Mw=8.8 Maule earthquake an anomalous vertical coseismic ground uplift occurred in the study area, opposite to that of 1960 since Mocha Island experienced lower (25 cm) ground uplift than Tirúa (90 cm). Subsequently, during the Araucanía 2011 earthquake a ground uplift in Mocha Island (50 cm) and subsidence at Tirúa (20 cm) occurred. These unexpected vertical ground movements can be explained by the existence of an upper plate splay fault located below the sea bottom between Tirúa and Mocha Island: the Tirúa-Mocha splay fault. Considering the last seismic cycle, the activity of this fault would have started after the 1960 Valdivia earthquake. During 2010 Maule earthquake, the main slip occurred at Tirúa Mocha splay fault. Finally during 2011 Araucanía earthquake, the slip occurred mainly at the updip of Wadati-Benioff plane with probable normal activity of Tirúa-Mocha splay fault. Simple elastic dislocation models considering the Wadati-Benioff plane and the Tirúa-Mocha splay fault activity, can account for all the vertical ground movements observed during 1960 earthquake, the 1960-2010 interseismic period, the 2010 Maule earthquake and the 2011 Araucanía earthquake.
智利南部的蒂鲁阿-莫查岛地区(38.2°-38.4°S)在短短50年内遭受了两次大地震的影响:1960年瓦尔迪维亚9.5级地震和2010年毛勒8.8级地震。我们在野外研究了两次地震之间的震间期以及2010年Maule地震和2011年Mw=7.1 Araucanía地震的同震期发生的垂直地面运动。在1960年的地震中,垂直同震地面运动是典型的俯冲相关地震,位于海沟附近的莫查岛经历了比位于莫查岛纬度大陆边缘的蒂鲁阿(-20厘米)更大的地面隆起(150厘米)。然后,在1960-2010年的震间期,1960年的同震隆升仍在莫查岛,这与阿劳科半岛和圣玛丽亚岛向北发生的正常震间沉降不同。此外,蒂鲁阿在受2010年毛勒地震影响的所有地区都经历了最大的震间隆起(180厘米)。然后,在2010年Mw=8.8 Maule地震期间,研究区域发生了异常的垂直同震地面隆起,与1960年相反,因为Mocha岛的地面隆起(25厘米)低于Tirúa(90厘米)。随后,在2011年阿劳卡尼亚地震期间,莫查岛发生了地面隆起(50厘米),蒂鲁阿发生了地面沉降(20厘米)。这些意想不到的垂直地面运动可以通过位于蒂鲁阿和莫查岛之间海底下方的上板块扇断层的存在来解释:蒂鲁阿-莫查扇断层。考虑到上一次地震周期,该断层的活动可能始于1960年瓦尔迪维亚地震之后。2010年Maule地震期间,主要滑动发生在Tirúa-Mocha扇断层。最后,在2011年阿劳卡尼亚地震期间,滑动主要发生在Wadati-Benioff平面的上升倾,Tirúa-Mocha扇断层可能正常活动。考虑到Wadati-Benioff平面和Tirúa-Mocha扇断层活动的简单弹性位错模型可以解释1960年地震、1960-2010年震间期、2010年Maule地震和2011年Araucanía地震期间观测到的所有垂直地面运动。
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引用次数: 4
Análisis de los procesos de regresión y restitución del monumento natural Puente del Inca, Andes Centrales, Provincia de Mendoza, Argentina 阿根廷门多萨省安第斯山脉中部印加古桥自然遗迹的回归与恢复过程分析
IF 0.9 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2020-05-29 DOI: 10.5027/andgeov47n2-3131
Esteban Lannutti, M. G. Lenzano, J. Barón, M. Durand, L. Lenzano
The Puente del Inca, next to the homonymous village, is a natural bridge located on the Cuevas River, at about 2,700 m above sea level in the Central Andes of the province of Mendoza, Argentina. Declared Provincial Natural Monument in 2005, since the beginning of the 20th century it has registered a continuous weakening, mainly related to erosive processes that cause detachments of part of the material that makes up its structure. The objective of this study is to determine the factors involved in the structural regression and restitution of the natural bridge. To achieve this, visual inspection, characterization of thermal springs, measurement of accretion-erosion rate of travertine deposits, testing of materials and the development of a structural numerical model by the Finite Element Method, were carried out. Results indicate that the deterioration is linked, mainly, with changes in the geobiological system that regulates the travertine deposition and to the heterogeneous structure of the bridge. Changes of the geobiological system are related to the activity of the thermal waters present in the area, whose discontinuity and/or fluctuations in the flow rate are influenced by both natural and anthropogenic factors. The heterogeneity of the structure conditions the stability of the monument due to the presence of a less resistant material in the lower part of the bridge arch. From the numerical simulation, safety factors between 1.5 and 3 were determined for the bridge, thus, we conclude the structure is stable against its own weight, as long as the bridge maintains the current conditions.
毗邻同名村庄的Puente del Inca是一座天然桥梁,位于阿根廷门多萨省安第斯山脉中部海拔约2700米的Cuevas河上。2005年被宣布为省级自然古迹,自20世纪初以来,它一直在持续弱化,主要与侵蚀过程有关,导致构成其结构的部分材料脱落。本研究的目的是确定影响天然桥梁结构回归和恢复的因素。为了实现这一目标,进行了目视检查,表征温泉,测量石灰华沉积物的吸积-侵蚀速率,材料测试以及通过有限元方法开发结构数值模型。结果表明,这种恶化主要与调节石灰华沉积的地球生物系统的变化和桥梁的非均质结构有关。地质生物系统的变化与该地区存在的热水的活动有关,其流量的不连续性和/或波动受到自然和人为因素的影响。结构的非均质性决定了纪念碑的稳定性,因为在桥拱的下部有一种阻力较小的材料。从数值模拟中,确定了该桥的安全系数在1.5到3之间,因此,我们得出结论,只要桥梁保持当前状态,结构在自重下是稳定的。
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引用次数: 0
Trace metal partitioning and potential mobility in the naturally acidic sediment of Lake Caviahue, Neuquén, Argentina 阿根廷Neuquén Caviahue湖天然酸性沉积物中微量金属的分配和潜在移动性
IF 0.9 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2020-01-31 DOI: 10.5027/andgeov47n1-3200
J. M. Cabrera, P. Temporetti, F. Pedrozo
Lake Caviahue, in Patagonia (Argentina), is a very acid water body (Patagonia, Argentina) due to the influx of volcanic fluids. Over the past 18 years, the lake has been progressively alkalinizing and pH is close to the ferric iron precipitation threshold (pH>3,0). Should iron precipitate, water and sediment composition will be altered. To set a baseline, trace metal partitioning (Cu, Cd, Cr, Pb, Zn and Mn) was studied for three sediment cores (0 to 16 cm depth) at three sampling stations using a sequential extraction procedure (SEP) and the acid volatile sulfide/simultaneously extracted metals (AVS/SEM) protocol. The total metals content of the sediments ranged between 0 to 408 μg g-1 of dry sediment, with Pb>Cr>Mn>Cu>Zn>Cd. No Cd was measured above the limit of detection. The sediment was richest in Mn and Cr, two non-toxic metals at the pH / Eh combination of the lake basin. Total Pb was at a moderate contamination level although it is associated with the most recalcitrant fraction and therefore has low mobility. The sediment fractions with higher metal content were the oxidizable and residual, the former commonly associated with labile organic matter and pyrite while the latter are related to recalcitrant organic matter and rock forming minerals. In addition, a high correlation was found between Cr, Pb and Mn,thus these metals may be subject to analogous precipitation processes and possibly to co-variation in the volcano effluents. Furthermore, no metals were detected in the exchangeable/carbonates fraction, which is the most labile of all the sediment fractions. The metal content in (SEM) was likewise below the toxicity thresholds of two international sediment quality guidelines and the ratio AVS/SEM was over one, indicative of non-toxicity. Both results indicate that metal mobility in the acidic sediments of lake Caviahue is very low.
由于火山流体的涌入,位于巴塔哥尼亚(阿根廷)的Caviahue湖是一个非常酸性的水体(阿根廷巴塔哥尼亚)。在过去的18年里,该湖一直在逐渐碱化,pH值接近三价铁沉淀阈值(pH>3.0)。如果铁沉淀,水和沉积物成分将发生变化。为了设定基线,使用顺序提取程序(SEP)和酸性挥发性硫化物/同时提取金属(AVS/SEM)方案,在三个采样站研究了三个沉积物岩芯(0至16cm深)的微量金属分配(Cu、Cd、Cr、Pb、Zn和Mn)。沉积物中的总金属含量在0~408μg~(-1)之间,其中Pb>Cr>Mn>Cu>Zn>Cd。未测得镉含量超过检测限。沉积物中Mn和Cr含量最丰富,这两种无毒金属在湖盆的pH/Eh组合下。总Pb处于中等污染水平,尽管它与最难降解的部分有关,因此具有低迁移率。金属含量较高的沉积物组分是可氧化的和残余的,前者通常与不稳定有机物和黄铁矿有关,而后者与难降解有机物和成岩矿物有关。此外,发现Cr、Pb和Mn之间存在高度相关性,因此这些金属可能会经历类似的沉淀过程,并可能在火山流出物中发生共同变化。此外,在所有沉积物组分中最不稳定的可交换/碳酸盐组分中未检测到金属。(SEM)中的金属含量同样低于两个国际沉积物质量指南的毒性阈值,AVS/SEM比值超过1,表明无毒。这两个结果都表明,Caviahue湖酸性沉积物中的金属迁移率很低。
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引用次数: 3
Late Pleistocene and Holocene geomorphologic evolution of Laguna Las Vueltas area, Tierra del Fuego (Argentina) 火地岛(阿根廷)拉古纳-拉斯拉帕斯地区晚更新世和全新世地貌演变
IF 0.9 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2020-01-31 DOI: 10.5027/andgeov47n1-3219
Alejandro Montes, Fernando Santiago, M. Salemme, R. López
Laguna Las Vueltas (LLV) area retains the morphology of a late Pleistocene watershed that was flooded during a mid-Holocene marine transgression. Sediments associated with a paleosol dated at 22,582 cal yr BP reflect subaerial exposure of the area prior to the submergence during the marine transgression. This transgression produced an extensive tidal flat near the mouth of the former LLV watershed by 7,477 cal yr BP. Subsequent decoupling of the Las Vueltas valley from the sea occurred through the growth of a baymouth barrier and a beach-ridge plain to the east. This decoupling turned the lagoon into a pan environment in which subsequent lake-level fluctuations were controlled by climate. A lunette dune developed at the pans in the former lagoon, providing a narrow corridor where humans trapped, killed and processed guanacos as early as 3,402 cal yr BP. Changes in aeolian sedimentation hint at increased aridity during the past 500 years.
Laguna Las Vueltas(LLV)地区保留了更新世晚期分水岭的形态,该分水岭在全新世中期海侵期间被淹没。与22582 cal yr BP的古土壤相关的沉积物反映了海侵期间淹没之前该地区的陆上暴露。这一海侵在7477 cal yr BP的前LLV分水岭河口附近形成了一片广阔的滩涂。随后,Las Vueltas山谷与大海脱钩,原因是海湾河口屏障和东部海滩山脊平原的生长。这种脱钩将泻湖变成了一个泛环境,随后的湖面波动受到气候的控制。早在3402年英国石油公司(BP),前泻湖的平底锅上就形成了一个新月形沙丘,为人类捕获、杀死和加工鸟粪提供了一条狭窄的走廊。风成沉积的变化表明,在过去500年中,干旱加剧。
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引用次数: 7
Primer registro de estromatolitos en el Maastrichtiano tardío del Grupo Chubut, Cuenca del Golfo San Jorge, Patagonia central, Argentina 阿根廷巴塔哥尼亚中部圣乔治湾盆地丘布特群晚期马斯特里赫特叠层石的首次记录
IF 0.9 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2020-01-31 DOI: 10.5027/ANDGEOV47N1-3177
Gabriel A. Casal, Patricia Vallati, L. Ibiricu, Andrea de Sosa Tomas, Nicolás Foix, José Óscar Alllard, R. Martínez
The presence of stromatolites from Cretaceous outcrops at the headwaters of the río Chico locality in the Golfo San Jorge Basin is reported for the first time. They are present in the uppermost part of the Lago Colhué Huapi Formation (Coniacian-Maastrichtian) of the Chubut Group. The presence of, up to now, four structures interpreted as stromatolites in this locality are not only important because it is the first record in the basin, but because it contributes to the knowledge of these bioconstructions in continental environments. The stromatolite called E1, which is characterized and discussed in detail, is associated with an abundant and diverse fossil record represented by palynomorphs, fragments of silicified trunks, dinosaur remains and eggshells. The study, integrated mainly with the recorded pollen and spores, is important for paleoenvironmental interpretations of the site and contributes to the paleoecological and paleoclimatic understanding of the most modern stratigraphic interval of the Chubut Group.
首次报道了Golfo San Jorge盆地río Chico地区源头白垩纪露头的叠层石的存在。它们存在于Chubut群的Lago-ColhuéHuapi组(Coniacian-Maastrichtian)的最上部。到目前为止,该地区存在四个被解释为叠层石的结构,这不仅很重要,因为这是该盆地的第一个记录,还因为它有助于了解大陆环境中的这些生物结构。被称为E1的叠层石,经过详细的表征和讨论,与丰富多样的化石记录有关,这些化石记录以坡缕石、硅化树干碎片、恐龙遗骸和蛋壳为代表。这项研究主要与记录的花粉和孢子相结合,对该遗址的古环境解释很重要,并有助于对楚布特群最现代地层间隔的古生态和古气候理解。
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引用次数: 3
Aportes a la metalogénesis del basamento proterozoico superior-cámbrico de las Sierras Pampeanas Orientales: mineralogía, termometría e isótopos de azufre del skarn Malagueño (Cu- Fe±Zn), Sierra Chica, Córdoba, Argentina 对东潘帕斯山脉上元古代-寒武纪基底成矿的贡献:马拉加夕卡岩(Cu-Fe±Zn)、塞拉·奇拉、科尔多瓦、阿根廷的矿物学、温度计和硫同位素
IF 0.9 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2020-01-31 DOI: 10.5027/andgeov47n1-3112
María José J. Espeche, R. Lira, Nicolás Antonio Viñas
On-going mining operations in a marble quarry (Cantera Centro) from Malagueno, Sierra Chica de Cordoba, Argentina, have unearthed veins, veinlets and lenses of sulfides (pyrrhotite>pyrite≅ chalcopyrite>>sphalerite). These veins and lenses are up to 0.3 m thick and 2-3 m long, although intermittently can extend about a hundred meters. They are associated with skarns. The metasedimentary host sequence, largely composed of gneisses, amphibolites and marbles, was intruded by amphibolic metagabbro and metadiorite dykes, metatonalite plutons and alkali-feldspar metagranites; the whole complex was metamorphosed into medium to high amphibolite facies and strongly deformed as a result of the a regional event M2-D2/D3 that affected the Neoproterozoic-Cambrian basement during the Pampean orogeny. Except for gneisses, all the other metamorphic lithologies register evidence of differential alteration into skarn, although the process was preferentially developed on marbles, amphibolites and metagranite, and to a lesser exten on mafic and mesosilicic dykes. The metasomatic rocks are characterized by a garnet>>pyroxene skarn (Grs27-48Adr22-34Alm15-27Sps9-21), formed after the replacement of the metagranite; a pyroxene-rich skarn (Hd42-63Di32-50Jo3-5) developed after para-amphibolite, and a garnet (Adr54-71Grs22-40Alm4-7Sps1-2) (±wollastonite) skarn that replaced a calcic marble. The dykes show poor metasomatic replacement and lack sulfides of metasomatichydrothermal origin. Retrograde mineral associations include hastingsite, ferroactinolite, epidote, clinozoisite, sericite, plagioclase (An18), chamosite and calcite. The sulfide mineralization is paragenetically associated with late-stage, infilling skarn-hydrothermal minerals that were sequentially deposited as: calcite→clinochlore→quartz→pyrite→pyrrhotite→chalcopyrite+sphalerite; these phases occur as veins and veinlets within the garnetpyroxene skarn, and as massive pyrrhotite lenses in the piroxene-rich skarn. Microthermometric data from fluid inclusions in sulfide related calcite, together with the geothermometric data from the Fe/Mg ratios in clinochlore and the phase equilibria data from intergrown high and low T oC pyrrhotite phases, all constrain the infilling gangue phases and sulfide crystallization temperature within the ~360 °C to 250 °C range; the gradual termal decrease is in agreement with the temporal depositional sequence of the infilling phases. Fluid inclusion petrographic data and salinity estimations suggest that sulfide precipitation was triggered by boiling, from a fluid of moderate to high salinity (~14.5 to 33.5 wt% eq. NaCl). Evidence that the fluid evolved under dominantly reducing conditions are the high Fe+2/(Fe+2+Fe+3) ratios and molar proportions of subcalcic garnet (Alm+Sps) in garnet-pyroxene skarn, the presence of fluid inclusion sulfide daughter crystals in calcite, the high H2S/SO42- ratios in the sulfide-bearing fluid and the presence of pyrrhotite among the sulfide phases.
在阿根廷科尔多瓦山脉马拉盖诺的大理石采石场(Cantera Centro)进行的采矿作业中,发现了硫化物的矿脉、细脉和透镜体(磁黄铁矿>黄铁矿>黄铜矿>>闪锌矿)。这些矿脉和透镜体厚达0.3米,长2-3米,尽管间歇性地可以延伸约100米。它们与矽卡岩有关。变质沉积宿主序列主要由片麻岩、角闪岩和大理岩组成,被角闪变辉长岩和变闪长岩脉、变英云闪长岩深成岩体和碱性长石变花岗岩侵入;整个杂岩变质为中高角闪岩相,并由于潘潘造山运动期间影响新元古代-寒武系基底的区域事件M2-D2/D3而强烈变形。除片麻岩外,所有其他变质岩都记录了矽卡岩差异蚀变的证据,尽管该过程优先在大理岩、角闪岩和变质花岗岩上发展,在镁铁质和中硅化岩脉上发展程度较小。交代岩的特征是变质花岗岩置换后形成的石榴石>>辉石矽卡岩(Grs27-48Dr22-34Alm15-27Ps9-21);富含辉石的矽卡岩(Hd42-63Di32-50Jo3-5)是在准角闪岩之后形成的,石榴石(Adr54-71Grs22-40Alm4-7Sps1-2)(±硅灰石)矽卡岩取代了钙质大理岩。岩脉交代交代交代作用差,缺乏交代交代热成因的硫化物。逆变质矿物组合包括辉长岩、铁阳起石、绿帘石、斜帘石、绢云母、斜长石(An18)、洋甘菊和方解石。硫化物矿化与晚期共生,充填矽卡岩热液矿物,这些矿物依次沉积为:方解石→斜绿泥石→石英→黄铁矿→磁黄铁矿→黄铜矿+闪锌矿;这些相在石榴石-辉石矽卡岩中以脉和细脉的形式出现,在富含吡洛西烯的矽卡岩内以块状磁黄铁矿透镜体的形式出现。硫化物相关方解石中流体包裹体的微温测量数据,以及斜绿石中Fe/Mg比率的地热测量数据和共生高温和低温磁黄铁矿相的相平衡数据,都将填充脉石相和硫化物结晶温度限制在~360°C至250°C范围内;充填期的逐渐递减与充填期的时间沉积序列相一致。流体包裹体岩相数据和盐度估计表明,硫化物沉淀是由中等至高盐度(约14.5至33.5wt%当量NaCl)的流体沸腾引发的。流体在主要还原条件下演化的证据是石榴石-辉石-矽卡岩中亚钙石榴石(Alm+Sps)的高Fe+2/(Fe+2+Fe+3)比和摩尔比,方解石中存在流体包裹体硫化物子晶体,含硫化物流体中的高H2S/SO42-比,以及硫化物相中存在磁黄铁矿。变质辉长岩闪长岩脉中散布的原生黄铜矿和黄铁矿(Cu~300ppm)以及角闪岩中的高铜含量(~900ppm)表明,这些原石器时代的岩性可能是金属(Cu>>Zn±Ag)的来源。在350-150℃的温度范围内,黄铁矿、磁黄铁矿和黄铜矿的分馏因子得出的δ34S∑流体值在~4至+1.4‰之间,表明硫的岩浆来源,可能是由变质辉长岩-闪长岩脉的原生硫化物浸出或脱硫提供的。交代热液循环后,这些岩脉和角闪岩提供的金属和硫会在矽卡岩中重新分布。矽卡岩体可能是由深交代流体的渗透和流体-岩石的相互作用形成的,这影响了上元古代-寒武纪变质基底的岩性。流体可能来自隐藏的寒武纪侵入岩,或来自周围的区域混合岩化,沿着岩性接触和断层/裂缝流动。Cantera Centro矽卡岩组合中硫化物矿化的野外环境、结构和矿物学证据表明,寒武纪与潘潘造山运动的后变形阶段有关。
{"title":"Aportes a la metalogénesis del basamento proterozoico superior-cámbrico de las Sierras Pampeanas Orientales: mineralogía, termometría e isótopos de azufre del skarn Malagueño (Cu- Fe±Zn), Sierra Chica, Córdoba, Argentina","authors":"María José J. Espeche, R. Lira, Nicolás Antonio Viñas","doi":"10.5027/andgeov47n1-3112","DOIUrl":"https://doi.org/10.5027/andgeov47n1-3112","url":null,"abstract":"On-going mining operations in a marble quarry (Cantera Centro) from Malagueno, Sierra Chica de Cordoba, Argentina, have unearthed veins, veinlets and lenses of sulfides (pyrrhotite>pyrite≅ \u0000chalcopyrite>>sphalerite). These veins and lenses are up to 0.3 m thick and 2-3 m long, although intermittently can extend about a hundred meters. They are associated with skarns. The metasedimentary host sequence, largely composed of gneisses, amphibolites and marbles, was intruded by amphibolic metagabbro and metadiorite dykes, metatonalite plutons and alkali-feldspar metagranites; the whole complex was metamorphosed into medium to high amphibolite facies and strongly deformed as a result of the a regional event M2-D2/D3 that affected the Neoproterozoic-Cambrian basement during the Pampean orogeny. Except for gneisses, all the other metamorphic lithologies register evidence of differential alteration into skarn, although the process was preferentially developed on marbles, amphibolites and metagranite, and to a lesser exten on mafic and mesosilicic dykes. The metasomatic rocks are characterized by a garnet>>pyroxene skarn (Grs27-48Adr22-34Alm15-27Sps9-21), formed after the replacement of the metagranite; a pyroxene-rich skarn (Hd42-63Di32-50Jo3-5) developed after para-amphibolite, and a garnet (Adr54-71Grs22-40Alm4-7Sps1-2) (±wollastonite) skarn that replaced a calcic marble. The dykes show poor metasomatic replacement and lack sulfides of metasomatichydrothermal origin. Retrograde mineral associations include hastingsite, ferroactinolite, epidote, clinozoisite, sericite, plagioclase (An18), chamosite and calcite. The sulfide mineralization is paragenetically associated with late-stage, infilling skarn-hydrothermal minerals that were sequentially deposited as: calcite→clinochlore→quartz→pyrite→pyrrhotite→chalcopyrite+sphalerite; these phases occur as veins and veinlets within the garnetpyroxene skarn, and as massive pyrrhotite lenses in the piroxene-rich skarn. Microthermometric data from fluid inclusions in sulfide related calcite, together with the geothermometric data from the Fe/Mg ratios in clinochlore and the phase equilibria data from intergrown high and low T oC pyrrhotite phases, all constrain the infilling gangue phases and sulfide crystallization temperature within the ~360 °C to 250 °C range; the gradual termal decrease is in agreement with the temporal depositional sequence of the infilling phases. Fluid inclusion petrographic data and salinity estimations suggest that sulfide precipitation was triggered by boiling, from a fluid of moderate to high salinity (~14.5 to 33.5 wt% eq. NaCl). Evidence that the fluid evolved under dominantly reducing conditions are the high Fe+2/(Fe+2+Fe+3) ratios and molar proportions of subcalcic garnet (Alm+Sps) in garnet-pyroxene skarn, the presence of fluid inclusion sulfide daughter crystals in calcite, the high H2S/SO42- ratios in the sulfide-bearing fluid and the presence of pyrrhotite among the sulfide phases.","PeriodicalId":49108,"journal":{"name":"Andean Geology","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2020-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49493481","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
El registro más austral de la Fauna Aseptella-Tuberculatella / Rhipidomella-Micraphelia (Serpukhoviano tardío-Bashkiriano) en la cuenca Calingasta-Uspallata, Argentina 阿根廷卡林加斯塔-乌斯帕拉塔盆地Aseptella-Tuberculatella/Rhipidomella-Micraphelia(晚期Serpukhovian-Bashkiriano)动物群的最南端记录
IF 0.9 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2020-01-31 DOI: 10.5027/andgeov47n1-3195
Andrea F. Sterren, G. A. Cisterna, O. López-Gamundí, M. M. Vergel
The Agua del Jaguel Formation crops out in the southernmost part of the Calingasta-Uspallata basin, in central western Argentina. The lower part of the unit is characterized by a glacigenic sequence with diamictites and mudstones with dropstones. In the latter, elements of the Aseptella-Tuberculatella/Rhipidomella-Micraphelia Fauna (AT/RM Fauna), such as the brachiopods Rhipidomella discreta Cisterna, Micraphelia indianae Simanauskas and Cisterna and Orbiculoidea? sp., the gastropods Murchisonia? sp., and Glabrocingulum (Stenozone)? sp., the bivalve Nuculanidae indet., rugose corals, and indeterminate fragments of nautiloids and hyolithids, have been identified. The importance of this fauna mainly resides in its paleoenvironmental and biostratigraphic implications. AT/RM Fauna is characteristic of restricted environments with relatively low concentrations of oxygen and nutrients in the seafloor, which is consistent with the glaciomarine sequences in fjord-type coasts suggested for the Agua del Jaguel Formation. The relatively low diversity of the fauna in this unit compared to that defined in the El Paso Formation, located further north in the basin, might suggest more restricted sectors for benthic colonization, related to the paleovalle’s isolation from oceanic waters. The postglacial mudstones with marine invertebrate faunas of late Serpukhovian-Bashkirian age would have been deposited in relatively restricted (palaeofjord) part of the Uspallata-Calingasta basin as well as in open shelf environments. The marine flooding over drastically different coast configurations and the availability of nutrient and oxygen in the water column would have propitiated the development of faunas with important differences in the taxonomic composition and the paleoecological structure (AT/RM and Levipustula Faunas) occurring at the same time interval. Radiometric data in Agua del Jaguel Formation and paleontological records in the glacial-postglacial sedimentary succession in the basin (marine invertebrate faunas, palynomorphs and plants) are the most important tools to adjust the timing of the postglacial transgression. This information herein presented complements the scheme proposed for the Carboniferous sequences throughout the central western of Gondwana but is not sufficient to assign a more precise age of the fauna studied within the late Serpukhovian-Bashkirian interval.
Agua del Jaguel组产于阿根廷中西部Calingasta Uspallata盆地的最南端。该单元的下部以含杂岩的冰川序列和含落石的泥岩为特征。在后者中,结核足类/小缝足类动物群(AT/RM动物群)的元素,如腕足类Rhipideomella discita Cisterna、小缝足属Simanauskas和Cisterna和Orbiculoidea?sp.,腹足类Murchisonia?sp.和Glabrocingulum(Stenozone)?sp.,双壳类裸藻科。,褶皱珊瑚,以及鹦鹉螺和舌骨类的不确定碎片已经被确认。该动物群的重要性主要在于其古环境和生物地层学意义。AT/RM动物群的特征是海底氧气和营养物质浓度相对较低的受限环境,这与Agua del Jaguel组所建议的峡湾型海岸的冰川海洋序列一致。与位于盆地北部的埃尔帕索组相比,该单元的动物群多样性相对较低,这可能表明与古河谷与海水隔离有关的底栖生物定殖区更受限制。Serpukhovian Bashkirian晚期的冰川后泥岩和海洋无脊椎动物群可能沉积在Uspallata Calingasta盆地相对受限的(古峡湾)部分以及开放陆架环境中。在截然不同的海岸结构和水柱中营养物质和氧气的可用性上发生的海洋洪水会促进动物群的发展,在同一时间间隔内,动物群在分类学组成和古生态结构(AT/RM和Levipustula动物群)上存在重要差异。Agua del Jaguel组的辐射数据和盆地冰后沉积序列的古生物记录(海洋无脊椎动物、坡缕菌和植物)是调整冰后海侵时间的最重要工具。本文提供的这些信息补充了针对整个冈瓦纳大陆中西部石炭系序列提出的方案,但不足以确定晚谢尔普霍夫阶-巴什基尔阶区间内研究的动物群的更精确年龄。
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引用次数: 3
Mallines en la Sierra de Comechingones, Sierras Pampeanas, Argentina. Caracterización geológico-geomorfológica y reconstrucción paleoambiental durante el Holoceno 阿根廷潘帕斯山脉科梅钦戈内斯山脉的马林斯。全新世地质地貌特征与古环境重建
IF 0.9 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2020-01-31 DOI: 10.5027/andgeov47n1-3138
M. J. Andreazzini, S. Degiovanni, A. Prieto, Alfonsina Tripaldi, M. Luque
Los mallines son humedales de alto valor ambiental y son frecuentes en diversas regiones de la Argentina, como la Patagonia, la Cordillera de los Andes y las Sierras Pampeanas. En particular en esta ultima region, los estudios sobre su funcionamiento y dinamica son aun insuficientes y parciales. En este trabajo, se analizan los factores geologico-geomorfologicos que influyeron en el origen, distribucion, morfometria y dinamica de mallines del sector sur de la Sierra de Comechingones (Sierras Pampeanas de Cordoba, Argentina) y se realiza una reconstruccion paleoambiental a partir del registro sedimentologico, polinico y diatomologico de uno de estos sistemas durante el Holoceno. El area de estudio forma parte de una paleosuperficie de erosion desarrollada sobre rocas de basamento igneo-metamorfico con anterioridad a la orogenia andina, la cual se preserva en el faldeo oriental de esta sierra y presenta distinto grado de incision fluvial. El mayor desarrollo de los mallines se asocia a ambientes geomorfologicos con baja actividad morfodinamica, preferentemente sobre rocas graniticas, y depositos loessicos/loessoides. La fuente principal de los materiales que forman los depositos de mallines es la removilizacion de las secuencias loessicas/loessoides cuaternarias situadas en el sector serrano. Los registros sedimentologico, polinico y diatomologico sugieren la persistencia de estos ambientes en los sectores altos de las Sierras de Comechingones durante gran parte del Holoceno, con contracciones y expansiones como respuesta a la variabilidad ambiental. Las condiciones climaticas fueron variables, con un periodo mas seco que el actual, al menos temporariamente, entre ca. 7.000 y 4.700 cal. anos AP (6.400 y 4.100 14C anos AP) y, a partir de los 4.700 cal. anos AP (4.326 14C anos AP) se habrian establecido condiciones climaticas semejantes a las actuales. Los procesos de incision e integracion de las redes de drenaje que ocurrieron en las ultimas centurias iniciaron la desactivacion y perdida de estos humedales, en especial a partir de la decada de 1970, por el incremento en las precipitaciones y, subordinadamente, los frecuentes incendios forestales.
马林是一种具有高环境价值的湿地,在阿根廷的各个地区都很常见,如巴塔哥尼亚、安第斯山脉和潘帕斯山脉。特别是在后一个地区,关于其运作和动态的研究仍然不足和部分。本文分析了影响Comechingones山脉(阿根廷科尔多瓦潘帕斯山脉)南段马林的起源、分布、形态和动力学的地质地貌因素,并根据全新世期间其中一个系统的沉积学、多项式和硅藻记录进行了古环境重建。研究区是安第斯造山前在火成岩-变质基底岩石上发育的侵蚀古表面的一部分,该侵蚀古表面保存在该山脉的东缘,具有不同程度的河流切割。马林的进一步发展与形态动力学活性较低的地貌环境有关,最好是在花岗岩和黄土/黄土矿床上。形成马林矿床的物质的主要来源是位于塞拉诺地区的第四纪黄土/黄土序列的再活化。沉积学、多项式和双生态学家的记录表明,这些环境在全新世的大部分时间里都在科梅钦戈斯山脉的上游持续存在,收缩和扩张是对环境变异性的反应。气候条件各不相同,比目前干燥的时期至少暂时在约7000至4700卡尔之间。AP年(6400至4100 14C年),从4700卡尔开始。AP年(4326 14C年)将建立类似于当前的气候条件。近几个世纪发生的排水网络的切割和整合过程开始使这些湿地失活和丧失,特别是从1970年代开始,原因是降雨量增加,其次是森林火灾频繁。
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引用次数: 3
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Andean Geology
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