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The Beacon Heights “Tinguaite” (Phonolite): A recrystallised agpaitic ignimbrite in the Mesoproterozoic Pilanesberg alkaline complex, South Africa Beacon Heights“Tinguaite”(phonite):产于南非中元古代Pilanesberg碱性杂岩中的一种重结晶无灰质烟灰岩
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2023-08-26 DOI: 10.25131/sajg.126.0017
J. U. Akoh, M. Elburg, T. Andersen
An extrusive rock unit in the Mesoproterozoic Pilanesberg alkaline complex that has been referred to as the “Beacon Heights Tinguaite” since the work of Shand (1928) has been reexamined in the field and studied by petrographic microscopy, scanning electron microscopy, and whole-rock major and trace element analysis. The new observations indicate that the unit (here informally renamed the “Beacon Heights Phonolite” to comply with current petrographical nomenclature) is a laminated, volcanic rock in which mafic layers rich in sodic pyroxene alternate on any scale with discontinous, felsic layers consisting of alkali feldspar, nepheline, sodalite and their alteration products natrolite and analcime. Highly strontian apatite, fluorite, a manganiferous pectolite-group mineral, sphalerite and pyrrhotite are minor to accessory minerals. In addition, the rock carries indicator minerals typical of agpaitic rocks (including lamprophyllite and eudialyte-group minerals and their replacement products). The rock contains abundant crystal fragments of felsic minerals (alkali feldspar, nepheline and sodalite), fragments and elongated lenses of nepheline syenite, some of which contain primary magmatic lamprophyllite, and rare armoured lapilli. The overall structure of the rock is that of a welded ashflow tuff (igmimbrite) affected by post-magmatic recrystallisation processes. Whole-rock major and trace element compositions suggest a compositional affinity with members of the agpaitic, intrusive Green Foyaite Suite of the Pilanesberg Complex, and probably also a genetic relationship. The Beacon Heights Phonolite is a rare, possibly unique, example of an ashflow deposit of agpaitic, highly silica-undersaturated composition.
自Shand(1928)工作以来,中元古代Pilanesberg碱性杂岩中的一个喷出岩单元被称为“Beacon Heights Tinguaite”,已在野外进行了重新检查,并通过岩相显微镜、扫描电子显微镜、全岩主元素和微量元素分析进行了研究。新的观测结果表明,该单元(此处非正式地更名为“Beacon Heights Phonolite”,以符合当前的岩石学命名法)是一种层状火山岩,其中富含钠辉石的镁铁质层与由碱长石、霞石、方钠石及其蚀变产物钠长石和方沸石组成的不连续长英质层在任何规模上交替。高锶磷灰石、萤石、一种含锰的果胶矿族矿物、闪锌矿和磁黄铁矿是次要的副矿物。此外,岩石中还含有典型的指示矿物(包括煌斑岩和透绿石群矿物及其替代品)。岩石中含有丰富的长英质矿物(碱长石、霞石和方钠石)的晶体碎片、霞石正长岩的碎片和细长透镜体,其中一些含有原生岩浆煌斑岩和罕见的装甲蓝柱石。岩石的整体结构是受岩浆后再结晶过程影响的焊接灰流凝灰岩(igmimbrite)。全岩主要元素和微量元素的组成表明,它们与Pilanesberg杂岩的银白色侵入性Green Foyaite岩组的成员具有组成亲和力,可能还有遗传关系。Beacon Heights Phonolite是一个罕见的,可能是独特的,由高度二氧化硅不饱和组成的灰流矿床。
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引用次数: 0
Okorusu tailings – Part II: REE mineralisation, and oxygen and carbon isotope variations Okorusu尾矿——第二部分:REE矿化以及氧和碳同位素变化
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2023-08-18 DOI: 10.25131/sajg.126.0015
S. Lohmeier, J. Machleidt, R. Klemd, R. Ellmies
The Okorusu carbonatite complex and the mine’s tailings dump constitute a potential resource of rare earth elements meaning lanthanides and yttrium (REY). Small (≤100 μm), hydrothermal REE fluorcarbonates (bastnäsite, parisite, röntgenite and synchysite) are the principal light REE carriers while the heavy REE and Y are primarily hosted in magmatic apatite, magmatic-hydrothermal carbonates (calcite, dolomite, ankerite) and hydrothermal fluorite. Bastnäsite and röntgenite occur as individual, liberated crystals in the tailings albeit syntaxial intergrowths of acicular parisite-synchysite-röntgenite are more common. There is a clear trend of decreasing REY contents in the magmatic carbonates over the early hydrothermal carbonates to the late hydrothermal carbonates. The lower total REY abundance in the hydrothermal carbonates is interpreted to be mainly a consequence of their limited redistribution during hydrothermal activity following the breakdown of the primary magmatic minerals and precipitation of REE fluorcarbonates. During this process hydrothermal fluids changed the isotopic composition of the Okorusu carbonatites by shifting δ13C-δ18O pairs of magmatic carbonatite (δ13C: -6.5‰ to -5.4‰; δ18O: +6.4‰ to +11.2‰) to higher values of hydrothermally modified carbonatite (δ13C: -4.2 to -2.2; δ18O: +12.0‰ to +17.5‰). The preferential presence of REY in the magmatic carbonates and to a minor degree in the hydrothermal carbonates in the Okorusu carbonatite and tailings is an important exploration tool for primary magmatic REY mineralisations. The recovery of REE fluorcarbonates can be considered in the development of the flowsheet for the planned recycling of the tailings material as a potential REY by-product.
Okorusu碳酸岩杂岩和矿山尾矿堆构成了稀土元素的潜在资源,即镧系元素和钇(REY)。小型(≤100μm)热液REE氟碳酸盐岩(氟碳石、方沸石、röntgrante和同步硅岩)是主要的轻REE载体,而重REE和Y主要存在于岩浆磷灰石、岩浆热液碳酸盐岩(方解石、白云石、铁白云石)和热液萤石中。Bastnäsite和röntgrante作为单独的、释放的晶体出现在尾矿中,尽管针状方沸石-方沸石-rörtgrante的同轴共生更为常见。从早期热液碳酸盐到晚期热液碳酸盐,岩浆碳酸盐中REY含量有明显的下降趋势。热液碳酸盐中较低的总REY丰度被解释为主要是由于它们在原始岩浆矿物分解和REE氟碳酸盐沉淀后的热液活动中的有限再分配。在这一过程中,热液流体通过将岩浆碳酸岩的δ13C-δ18O对(δ13C:-6.5‰至-5.4‰;δ18O:+6.4‰至+11.2‰)转移到更高的水热改性碳酸岩值(δ13C:-4.2‰至-2.2;δ18O:+12.0‰至+17.5‰)来改变Okorusu碳酸岩的同位素组成Okorusu碳酸盐岩和尾矿中热液碳酸盐的程度是原始岩浆REY矿化的重要勘探工具。REE氟碳酸盐的回收可以在制定尾矿材料作为潜在REY副产品的计划回收流程时考虑。
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引用次数: 0
Okorusu tailings – Part I: General characterisation of superficial tailings Okorusu尾矿——第一部分:浅表尾矿的一般特征
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2023-08-18 DOI: 10.25131/sajg.126.0014
S. Lohmeier, R. Ellmies, T. Adolffs, S. Sindern
Former open-pit fluorite mining and processing at the Okorusu carbonatite deposit, Namibia, resulted in a large tailings dump comprising an old (~553 kt) and a new tailings part (~3.8 Mt). We characterise dump tailings mineralogically and geochemically in order to evaluate the potential for processing of relict fluorite and recovery of other commodities of interest. The tailings comprise largely quartz, K-feldspar, different carbonates (ankerite, calcite, dolomite, siderite and manganese carbonates), fluorite, apatite, pyroxenes, hornblende and Fe (hydro)oxides, whereas all other mineral phases such as baryte, pyrite, pyrochlore and REE fluorcarbonates occur in traces. The largest proportional difference between samples from the surface of the new and old tailings pertains to fluorite (average old dump: ~12 vol.%; average new dump: ~5 vol.%) and apatite proportions (average old dump: ~8 vol.%; average new dump: ~5 vol.%). Mineralogical contrasts between both tailings parts result largely from fluorite, apatite, quartz and Fe (hydro)oxides being more abundant in old tailings and carbonates being more abundant in new tailings. Geochemically, these contrasts are reflected in the major element composition, while variances in trace element compositions are mostly small. The mineral proportions clearly point out considerable fluorite (≥804 kt) and apatite (≥742 kt) resources, with potential by-products of Nb and REE based on drilling data. The readily available material in combination with a high proportion (about 80%) of liberated fluorite are favourable for re-processing by locally available flotation technology. Therefore, the tailings dump can be considered a valuable resource for the critical raw material fluorite and the fertiliser raw material apatite, which are wanted materials on international and national markets.
纳米比亚Okorusu碳酸岩矿床以前的露天萤石开采和加工形成了一个大型尾矿库,包括一个旧尾矿库(~553kt)和一个新尾矿库(~3.8Mt)。我们对尾矿库的矿物和地球化学特征进行了表征,以评估残余萤石加工和其他感兴趣商品回收的潜力。尾矿主要包括石英、钾长石、不同的碳酸盐(铁白云石、方解石、白云石、菱铁矿和碳酸锰)、萤石、磷灰石、辉石、角闪石和铁(水)氧化物,而所有其他矿物相,如重晶石、黄铁矿、烧绿石和REE氟碳酸盐,都存在微量。新尾矿和旧尾矿表面样品之间的最大比例差异属于萤石(平均旧尾矿堆:~12 vol.%;平均新尾矿堆:~5 vol.%)和磷灰石比例(平均旧渣堆:~8 vol.%,石英和铁(水)氧化物在旧尾矿中更为丰富,碳酸盐在新尾矿中更丰富。在地球化学上,这些对比反映在主元素组成中,而微量元素组成的差异大多很小。根据钻探数据,矿物比例清楚地表明了大量的萤石(≥804 kt)和磷灰石(≥742 kt)资源,以及Nb和REE的潜在副产品。容易获得的材料与高比例(约80%)的游离萤石相结合,有利于通过当地可用的浮选技术进行再加工。因此,尾矿堆可以被视为关键原料萤石和化肥原料磷灰石的宝贵资源,这是国际和国内市场上需要的材料。
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引用次数: 0
Review of the thermo-tectonic evolution of the Central Zone of the Limpopo Complex with implications for conflicting published geodynamic models 林波波杂岩中央区热构造演化综述及其对已发表的地球动力学模型的影响
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2023-06-14 DOI: 10.25131/sajg.126.0010
D. van REENEN, M. Clark, C. Smit, T. Tsunogae, O. Safonov
This paper addresses the credibility of published data utilised to underpin conflicting models recently proposed for the geodynamic evolution of the Limpopo Complex (LC), Southern Africa, in the Neoarchaean and Palaeoproterozoic. We are mainly focused on the tectonic and metamorphic processes that affected the Central Zone (CZ) of the LC, but also consider the significance of the timing of the thermo-tectonic interaction of the Southern Marginal Zone (SMZ) of the LC with the granite-greenstone terrane of the Kaapvaal Craton (KVC) at the position of the steep north-dipping Hout River Shear Zone (HRSZ). HRSZ-linked tectonism at the contact with the KVC is expressed as a narrow “hot-iron zone” directly dated at 2.72 to 2.69 Ga and developed in the footwall of the north-dipping HRSZ. HRSZ-linked tectonic activity intermittently continued up to 2.65 to 2.62 Ga with no structural-metamorphic or geochronological evidence that the SMZ and the rest of the KVC were affected by regional thermo-tectonic (orogenic) activity after ca. 2.68 Ga. The complementary evolution of the CZ at 2.72 to 2.62 Ga prior to emplacement at 2.612 Ga of the Bulai granitic pluton is expressed by two thermo-tectonic events, at 2.72 to 2.66 Ga and 2.65 to 2.62 Ga, respectively. The early 2.72 to 2.66 Ga event was associated with near-vertical exhumation of the CZ from a rising crustal-scale granulite diapir, accompanied by emplacement of steeply-dipping isoclinal folded and granoblastic-textured CZ granulites at the mid-crustal level (20 km depth). A moderately (~45°) northeast-directed shear deformational event, accompanied by extensive granitic diapirism, controlled the final emplacement of the CZ in the Neoarchaean at 2.65 to 2.62 Ga prior to intrusion of the 2.612 Ga Bulai pluton. This second tectono-thermal event is expressed by major sheared structural features that include mega-closed folds, mega-north-south trending folds, and the 29 km-wide southwest-northeast-trending and moderately southeast-dipping and northeast-verging Tshipise Straightening Zone (TSZ) that bounds the CZ in the south. The CZ was finally exhumed and emplaced at the upper crustal level 600 Myr later (at ca. 2.02 Ga) during a regional high-temperature Palaeoproterozoic thermal event associated with major near-vertical strike-slip shear zones that overprint Neoarchaean oblique slip shear zones that bound the CZ. Thermo-tectonic activity in the CZ that is associated with this mainly thermal event is recognised as discrete steeply-dipping narrow fabric-parallel shear zones dated at ca. 2.02 Ga that overprint older structures. A gravity-driven crustal-scale diapiric model is utilised to explain the evolution of the SMZ and CZ of the LC at 2.72 to 2.62 Ga during the Limpopo Orogeny. Data presented and discussed contradict alternative published models that propose a continent-continent collisional orogeny at 2.65 to 2.62 Ga involving the SMZ and KVC, followed 600 Myr later at 2.02 Ga by a transpressional orog
本文讨论了用于支持最近提出的非洲南部林波波复合体(LC)在新太古代和古元古代地球动力学演化的相互矛盾模型的已发表数据的可信度。本文主要讨论了影响陆相中央带(CZ)的构造和变质作用过程,同时也考虑了陆相南缘带(SMZ)与Kaapvaal克拉通(KVC)花岗岩-绿岩地体在陡峭北倾的侯特河剪切带(HRSZ)位置的热构造相互作用时间的意义。在与KVC接触处,与HRSZ相关的构造活动表现为一个狭窄的“热铁带”,其直接年代为2.72 ~ 2.69 Ga,发育于北倾的HRSZ下盘。与hrsz相关的构造活动间歇性地持续到2.65 ~ 2.62 Ga,没有构造变质或年代学证据表明SMZ和KVC的其余部分在约2.68 Ga之后受到区域热构造(造山)活动的影响。布来花岗岩体在2.612 Ga侵位前2.72 ~ 2.62 Ga CZ的互补演化分别表现为2.72 ~ 2.66 Ga和2.65 ~ 2.62 Ga两个热构造事件。早2.72 ~ 2.66 Ga事件与CZ从上升的地壳尺度麻粒岩底辟中近垂直掘出有关,并伴随着在地壳中(20 km深度)陡倾等斜褶皱和麻粒母粒结构的CZ麻粒岩侵位。在2.65 ~ 2.62 Ga的新太古代,一个中等(~45°)的东北方向剪切变形事件,伴随着广泛的花岗质底辟作用,控制了CZ在2.612 Ga布莱岩体侵入之前的最终侵位。第二次构造-热事件表现为主要的剪切构造特征,包括巨型封闭褶皱、巨型南北走向褶皱和宽29 km的西南-东北走向、适度东南倾、东北向外延的Tshipise矫直带(TSZ)。CZ最终在600 Myr后(约2.02 Ga)的区域性高温古元古代热事件中被挖掘出来并位于地壳上层,该热事件与主要的近垂直走滑剪切带重叠在新太古代斜滑剪切带上。与这一主要热事件相关的CZ热构造活动被认为是大约2.02 Ga的离散陡倾狭窄织物平行剪切带,覆盖了较旧的构造。利用重力驱动的地壳尺度底辟模型解释了林波波造山运动2.72 ~ 2.62 Ga时期LC的SMZ和CZ的演化。所提出和讨论的数据与其他已发表的模型相矛盾,这些模型提出了2.65至2.62 Ga的大陆-大陆碰撞造山运动,涉及SMZ和KVC,随后在600 Myr之后的2.02 Ga发生了与近水平逆冲构造相关的跨洋造山运动。
{"title":"Review of the thermo-tectonic evolution of the Central Zone of the Limpopo Complex with implications for conflicting published geodynamic models","authors":"D. van REENEN, M. Clark, C. Smit, T. Tsunogae, O. Safonov","doi":"10.25131/sajg.126.0010","DOIUrl":"https://doi.org/10.25131/sajg.126.0010","url":null,"abstract":"\u0000 This paper addresses the credibility of published data utilised to underpin conflicting models recently proposed for the geodynamic evolution of the Limpopo Complex (LC), Southern Africa, in the Neoarchaean and Palaeoproterozoic. We are mainly focused on the tectonic and metamorphic processes that affected the Central Zone (CZ) of the LC, but also consider the significance of the timing of the thermo-tectonic interaction of the Southern Marginal Zone (SMZ) of the LC with the granite-greenstone terrane of the Kaapvaal Craton (KVC) at the position of the steep north-dipping Hout River Shear Zone (HRSZ). HRSZ-linked tectonism at the contact with the KVC is expressed as a narrow “hot-iron zone” directly dated at 2.72 to 2.69 Ga and developed in the footwall of the north-dipping HRSZ. HRSZ-linked tectonic activity intermittently continued up to 2.65 to 2.62 Ga with no structural-metamorphic or geochronological evidence that the SMZ and the rest of the KVC were affected by regional thermo-tectonic (orogenic) activity after ca. 2.68 Ga. The complementary evolution of the CZ at 2.72 to 2.62 Ga prior to emplacement at 2.612 Ga of the Bulai granitic pluton is expressed by two thermo-tectonic events, at 2.72 to 2.66 Ga and 2.65 to 2.62 Ga, respectively. The early 2.72 to 2.66 Ga event was associated with near-vertical exhumation of the CZ from a rising crustal-scale granulite diapir, accompanied by emplacement of steeply-dipping isoclinal folded and granoblastic-textured CZ granulites at the mid-crustal level (20 km depth). A moderately (~45°) northeast-directed shear deformational event, accompanied by extensive granitic diapirism, controlled the final emplacement of the CZ in the Neoarchaean at 2.65 to 2.62 Ga prior to intrusion of the 2.612 Ga Bulai pluton. This second tectono-thermal event is expressed by major sheared structural features that include mega-closed folds, mega-north-south trending folds, and the 29 km-wide southwest-northeast-trending and moderately southeast-dipping and northeast-verging Tshipise Straightening Zone (TSZ) that bounds the CZ in the south. The CZ was finally exhumed and emplaced at the upper crustal level 600 Myr later (at ca. 2.02 Ga) during a regional high-temperature Palaeoproterozoic thermal event associated with major near-vertical strike-slip shear zones that overprint Neoarchaean oblique slip shear zones that bound the CZ. Thermo-tectonic activity in the CZ that is associated with this mainly thermal event is recognised as discrete steeply-dipping narrow fabric-parallel shear zones dated at ca. 2.02 Ga that overprint older structures. A gravity-driven crustal-scale diapiric model is utilised to explain the evolution of the SMZ and CZ of the LC at 2.72 to 2.62 Ga during the Limpopo Orogeny. Data presented and discussed contradict alternative published models that propose a continent-continent collisional orogeny at 2.65 to 2.62 Ga involving the SMZ and KVC, followed 600 Myr later at 2.02 Ga by a transpressional orog","PeriodicalId":49494,"journal":{"name":"South African Journal of Geology","volume":" ","pages":""},"PeriodicalIF":1.8,"publicationDate":"2023-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46331958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Timing of the Cenozoic magmatic intrusions in the offshore Tanga Basin, Tanzania: correlation to age equivalent deposits in the Eyasi-Wembere Basin and their implications for petroleum potential 坦桑尼亚坦加盆地近海新生代岩浆侵入的时间:与Eyasi Wembere盆地年龄当量矿床的相关性及其对石油潜力的影响
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2023-06-01 DOI: 10.25131/sajg.126.0013
B. N. Mvile, E. B. Kiswaka, O. O. Osinowo, E. Mshiu, V. E. Mboya
The offshore Tanga Basin of north-eastern Tanzania contains Cenozoic sedimentary successions that have been poorly studied. The basin development was due to an interplay of multiple factors including periods of active fault movement linked to the East African Rift system (EARs) which influenced the Cenozoic development of the offshore Tanga Basin. The EARs recorded several discrete tectonic episodes that were associated with magmatic activities and massive volcanism. However, there is no report on the possible presence of magmatic intrusions indicative of magmatic activities and volcanism in the history of the Tanga Basin. Timing of occurrence and distribution of magmatic intrusions are among the key components needed to evaluate the petroleum potential of the basin. A detailed 2D qualitative seismic interpretation, coupled with core logging data and analysis of elemental proxies, has been employed to evaluate the petroleum potential of the Cenozoic successions of the offshore Tanga Basin considering the presence and timing of occurrence of the magmatic intrusions. These used data and the associated interpretation techniques have not been used before to meet similar objectives. Both core logging and elemental proxies are newly collected information used in this study. Results suggest that the Tanga Basin has been variedly intruded by magmatic sills and dikes. Seismic well tie and correlation to age-equivalent deposits across the onshore successions in the EWB revealed that the volcanic events occurred during tectonic episodes that influenced the development of the East African Rift basins. Seismic interpretation also suggests that these tectonic episodes occurred possibly during the Miocene, Pleistocene and Holocene periods when magmatic intrusions are believed to have promoted source rock maturation and facilitated the formation of structural elements for petroleum preservation.
坦桑尼亚东北部的近海坦加盆地包含新生代沉积序列,但研究较少。盆地的发展是由多种因素相互作用造成的,包括与东非裂谷系(EARs)有关的活动断层运动期,这影响了近海坦加盆地的新生代发展。EAR记录了几个与岩浆活动和大规模火山活动有关的离散构造事件。然而,没有关于坦噶盆地历史上可能存在岩浆活动和火山活动的岩浆侵入体的报告。岩浆侵入体的发生时间和分布是评估盆地石油潜力所需的关键组成部分。考虑到岩浆侵入体的存在和发生时间,采用了详细的2D定性地震解释,结合岩心测井数据和元素代理分析,来评估近海坦加盆地新生代序列的石油潜力。这些使用过的数据和相关的解释技术以前从未用于实现类似的目标。岩心测井和元素代理都是本研究中新收集的信息。结果表明,坦噶盆地受到岩浆岩床和岩墙的不同侵入。EWB陆上序列的地震井联系和与年龄等效矿床的相关性表明,火山事件发生在影响东非裂谷盆地发展的构造期。地震解释还表明,这些构造事件可能发生在中新世、更新世和全新世时期,当时岩浆侵入被认为促进了烃源岩的成熟,并促进了石油保存结构元素的形成。
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引用次数: 0
Syn-Bushveld “granite sheets” associated with the Molopo Farms Complex intruding into Transvaal Supergroup strata in southern Botswana 与Molopo农场复合体有关的Syn-Bushveld“花岗岩片”侵入博茨瓦纳南部的德兰士瓦超群地层
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2023-06-01 DOI: 10.25131/sajg.126.0012
R. Mapeo, R.M. Key (MBE), A. Moore, J. Mulder, N. Gardiner, L. Robb
LA-ICPMS U-Pb isotope analyses are presented for zircons from a thin granite sheet intersected in a borehole drilled into the upper Transvaal Supergroup wall rocks to the Molopo Farms Complex in southern Botswana. Many of the zircons have irregular or angular grain margins, and some have rounded cores. Approximately half of the analysed grains yielded concordant 207Pb/206Pb ages ranging between 2 282 ± 29 and 2 113 ± 16 Ma. Assuming that these grains were inherited from the surrounding upper Transvaal Supergroup sedimentary strata, the youngest zircon age provides a maximum depositional age for these sediments. Importantly, these zircon ages coincide with dates from detrital zircons in upper Transvaal Supergroup strata in the eastern Kaapvaal Craton and in the Magondi Supergroup in western Zimbabwe. Hf isotope analyses of the rounded zircons suggest that these grains were sourced from a variable mixture of an old basement and more juvenile material. A younger age of 2 060 ± 12 Ma was obtained from a single subhedral zircon grain from the granite sheet. This is interpreted as the granite’s emplacement age, making it coeval with the adjacent Molopo Farms Complex that forms part of the Bushveld Large Igneous Province.
本文介绍了LA-ICPMS U-Pb同位素分析,这些锆石来自于在博茨瓦纳南部德兰士瓦超群(Transvaal Supergroup)上部岩壁中钻孔相交的花岗岩薄片。许多锆石具有不规则或棱角分明的颗粒边缘,有些则具有圆形的岩心。大约一半的分析颗粒产生一致的207Pb/206Pb年龄,范围在2 282±29和2 113±16 Ma之间。假设这些颗粒来自周围的上德兰士瓦超群沉积地层,最年轻的锆石年龄为这些沉积物提供了最大沉积年龄。重要的是,这些锆石年龄与东部Kaapvaal克拉通上德兰士瓦超群地层和津巴布韦西部Magondi超群地层的碎屑锆石年龄一致。圆形锆石的Hf同位素分析表明,这些颗粒来自一个古老的基底和更年轻的物质的可变混合物。花岗岩单粒半面体锆石年龄为2060±12 Ma。这被解释为花岗岩的就位年龄,使其与相邻的Molopo农场综合体(形成Bushveld大火成岩省的一部分)相同。
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引用次数: 0
Andrieslombaardite, RhSbS, a new platinum-group mineral from the platiniferous Onverwacht Pipe, Republic of South Africa Andrieslombaardite,RhSbS,一种来自南非共和国Onverwacht管道的新铂族矿物
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2023-05-09 DOI: 10.25131/sajg.126.0011
L. Cabri, A. McDonald, T. Oberthür, N. Tamura, A. Vymazalová, K. C. Ross, F. Melcher
A hundred years after the discovery of the Merensky Reef in 1924, it is appropriate to present the new mineral andrieslombaardite in honour of Andries Frederik Lombaard who was instrumental in its discovery. Andrieslombaardite, RhSbS, was first described as an unknown mineral from placer deposits associated with the Tulameen Alaskan-Uralian type complex, British Colombia, Canada (Raicevic and Cabri, 1976) but has since been reported from several other deposits including the platiniferous Driekop, Mooihoek, and Onverwacht pipes in the eastern Bushveld Complex, South Africa. The mineral and the name were approved by the Commission on New Minerals Nomenclature and Classification (CNMNC) of the International Mineralogical Association (IMA no. 2022-076) based on data in the co-type samples from Onverwacht and a co-type sample from the Yubdo stream, Birbir River, Ethiopia. Andrieslombaardite in the Onverwacht sample is a single 8 x 20 μm grain attached to laurite in a matrix of altered silicate and Fe-oxyhydroxide minerals. In the Yubdo samples, there are many grains of pale brownish gray andrieslombaardite up to 25 x 55 μm in size, included in Pt-Fe alloys, some associated with erlichmanite, and others attached to bornite and chalcopyrite. The reflectance values (R%) measured in air and in oil at the COM wavelengths are 48.3 and 33.0 (470 nm), 49.3 and 34.0 (546 nm), 51.0 and 35.9 (589 nm), and 51.8 and 36.7 (650 nm). The colour values x, y, Y, λd, and Pe in air are 0.317, 0.322, 50.3, 580, and 3.2, and in oil are 0.319, 0.324, 35.6, 579, and 4.5. The composition of andrieslombaardite is ideally RhSbS, but it contains variable amounts of Fe, Pt, Pd, and Ir that may substitute for Rh. The mineral is cubic with unit-cell dimensions of a = 6.0278(4) Å, V = 219.01(6) Å3 and Z = 4. It was synthesised at 400 and 550°C using stoichiometric elemental amounts. It is a member of the cobaltite group. The mineralisation of the intrusive dunite pipes was probably introduced at high temperatures, under magmatic conditions. The primary assemblages were to a certain degree overprinted and redistributed by low-temperature hydrothermal fluids. The Pt-Fe alloys from Yubdo containing PGM inclusions such as andrieslombaardite in the Yubdo-Alaskan-type complex were formed at some post-magmatic stage owing to PGE remobilisation during hydrothermal or metamorphic episodes.
1924年梅伦斯基礁被发现一百年后,为了纪念在其发现过程中发挥重要作用的安德里斯·弗雷德里克·隆巴德,我们可以将新矿物安德里斯·隆巴德(andrieslombaardite)赠送给大家。Andrieslombaardite,RhSbS,最初被描述为一种未知矿物,来自加拿大不列颠哥伦比亚省Tulameen Alaskan Uralian型杂岩的砂矿(Raicevic和Cabri,1976),但后来又被报道来自其他几个矿床,包括南非Bushveld杂岩东部的含铂Driekop、Mooihoek和Onverwacht管道。该矿物和名称由国际矿物学协会新矿物命名和分类委员会(CNMNC)(IMA编号:2022-076)根据Onverwacht的同型样品和埃塞俄比亚Birbir河Yubdo河的同型样本中的数据批准。Onverwacht样品中的Andrieslombaardite是一个8 x 20μm的颗粒,附着在蚀变硅酸盐和氧化铁矿物基质中的月桂石上。在Yubdo样品中,Pt-Fe合金中含有许多大小达25 x 55μm的浅棕灰色安德里斯洛姆巴rdite颗粒,其中一些与伊利石有关,另一些与斑铜矿和黄铜矿有关。在空气和油中测得的COM波长的反射率值(R%)分别为48.3和33.0(470 nm)、49.3和34.0(546 nm)、51.0和35.9(589 nm)以及51.8和36.7(650 nm)。在空气中的色值x、y、y、λd和Pe分别为0.317、0.322、50.3、580和3.2,在油中分别为0.319、0.324、35.6、579和4.5。andrieslombaardite的组成理想地为RhSbS,但它含有可替代Rh的可变量的Fe、Pt、Pd和Ir。该矿物为立方体,晶胞尺寸为a=6.0278(4)Å,V=219.01(6)Å3和Z=4。它是在400和550°C下使用化学计量元素量合成的。它是钴矿群的一员。侵入性纯橄榄岩管道的矿化作用可能是在高温、岩浆条件下引入的。初级组合在一定程度上被低温水热流体叠加和重新分布。Yubdo-Alaskan型杂岩中来自Yubdo的含有PGM包裹体的Pt-Fe合金,如andrieslombaardite,是在热液或变质过程中由于PGE的再活化而在岩浆后期形成的。
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引用次数: 0
Petrographic and geochemical evidence of calc-silicate xenolith – magma interaction in the western Bushveld Complex, South Africa 南非Bushveld杂岩西部钙硅酸盐捕虏体-岩浆相互作用的岩石学和地球化学证据
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2023-04-21 DOI: 10.25131/sajg.126.0008
B. Koovarjee, R. Gibson, P. Nex
Underground workings at Rowland Shaft, Lonmin Platinum, near Marikana have exposed a large (>7 x 5 m) calc-silicate xenolith in mottled anorthosite ~20 m below the UG 1 chromitite of the upper Critical Zone. The xenolith comprises a monticellite + forsterite + spinel assemblage that is consistent with a metamorphic Tmax of ≥975°C being reached at P ~1 kbar and XCO2 ~1. Internal variations in the modal proportions of these phases are interpreted as an artefact of sedimentary layering in the xenolith. The xenolith is flanked by a 20 to 30 cm wide magmatic skarn that contains several small, cm- to dm-scale, calc-silicate fragments displaying the same peak assemblage as the main xenolith, as well as a dm-scale chromitite autolith and mm- to dm-scale lenses and stringer-like masses of fine-grained uvarovite. The skarn matrix is mineralogically zoned, with an up to 10 cm wide clinopyroxenite layer proximal to the xenolith contact and calc-silicate fragments grading outwards into a gabbroic, plagioclase-clinopyroxene assemblage in which plagioclase becomes progressively more dominant distally. Notwithstanding its pseudo-ophitic texture, the distal skarn matrix displays a range of features consistent with crystallisation of magma contaminated by Ca from the decomposing xenolith under elevated fO2 conditions, including: (a) the unusual mineral compositions (zoned aluminian-ferrian diopside and anorthite, An>99), (b) the presence of calcite as inclusions in plagioclase and as a minor interstitial phase, (c) corroded wollastonite inclusions in clinopyroxene, and (d) thin grossular reaction rims between clinopyroxene and plagioclase. This chemical evolution is further substantiated by zoned spinel grains comprising Cr-rich cores and Al-enriched rims, which are, in turn, enclosed in garnet aggregates that grade outwards from uvarovite to grossular. Local development of grossular-vesuvianite symplectite indicates limited retrograde hydrous (XCO2 <0.1) fluid influx under subsolidus conditions (T <750°C). Bedding in the xenolith displays a steep westerly dip, approximately orthogonal to the magmatic layering. This, together with evidence in the skarn of both plastic shear strain and out-of-sequence magmatic autoliths, suggests that the xenolith underwent density-driven foundering within the RLS magma from an initial location above the UG 1 chromitite layer.
在Marikana附近的Lonmin Platinum的Rowland竖井的地下工作中,在上临界带ug1铬铁矿下方约20 m的斑驳斜长岩中暴露出一个巨大的(bb70 x 5 m)钙硅酸盐捕虏体。捕虏体由monticellite + forsterite +尖晶石组合组成,在P ~1 kbar和XCO2 ~1条件下达到≥975℃的变质Tmax。这些相的模态比例的内部变化被解释为捕虏体中沉积分层的人工产物。捕虏体两侧为20 - 30厘米宽的岩浆矽卡岩,其中包含若干厘米至厘米尺度的钙硅酸盐小块,与主捕虏体具有相同的峰组合,以及一个厘米尺度的铬铁矿自长体、毫米至厘米尺度的透镜体和细粒uvaroite的细条纹状团块。矽卡岩基质在矿物学上是分带的,在捕虏体接触点附近有一个宽达10厘米的斜辉石岩层,钙硅酸盐碎片向外分级为辉长岩、斜长石-斜辉石组合,其中斜长石在远端逐渐占主导地位。远端矽卡岩基质虽然具有伪蛇绿的结构,但其显示的一系列特征与fO2升高条件下分解捕虏岩中受Ca污染的岩浆结晶一致,包括:(a)不寻常的矿物组成(带状铝铁透辉石和钙长石,An bbb99), (b)方解石作为斜长石包裹体的存在,并作为一个小的间隙相,(c)斜辉石中腐蚀的硅灰石包裹体,(d)斜辉石和斜长石之间的细粗反应环。这种化学演化进一步得到了尖晶石颗粒的证实,尖晶石颗粒由富cr的核心和富al的边缘组成,而尖晶石颗粒又被包裹在石榴石聚集体中,从长云母向外分级到粗晶岩。粗硫-维苏岩共长岩的局部发育表明,在亚固体条件下(T <750℃),有少量逆行含水(XCO2 <0.1)流体流入。捕虏体层理呈陡峭的西风倾角,与岩浆层理大致正交。结合夕卡岩中塑性剪切应变和序外岩浆自岩体的证据,表明该包体从ug1铬铁矿层上方的初始位置开始,在RLS岩浆中经历了密度驱动的沉降过程。
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引用次数: 0
Zircon xenocrysts obscured the zircon date for the lower Koras Group, southern Africa 锆石异晶掩盖了非洲南部科拉斯群下部的锆石日期
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2023-04-10 DOI: 10.25131/sajg.126.0009
D. Cornell, M. Harris, D. Frei, B. Mapani, T. Malobela, A. Jonsson, C. Lundell, M. Kristoffersen
The Koras Group is a bimodal volcanosedimentary group located in post-tectonic grabens in a foreland thrust complex in the Kaaien Terrane of the Mesoproterozoic Namaqua-Natal Province of southern Africa. It contains two sequences of mafic and felsic volcanic rocks with an unconformity between them, only the lower sequence being slightly folded. The Koras Group was long regarded as having formed at the end of the 1 210 to 1 000 Ma Namaqua Orogeny, because it lacks the severe deformation and metamorphism of the underlying rocks, with igneous minerals preserved in many samples. Following years of unsuccessful attempts to precisely date the volcanic rocks, the first two ion probe U-Pb zircon studies both reported ages of ~1 172 Ma for the Swartkopsleegte Formation felsic lava in the slightly folded lower sequence (based on relatively few dated zircons) and ~1 100 Ma for the Leeuwdraai Formation rhyolite in the undeformed upper sequence. Thus a major 70 m.y. hiatus seemed apparent between the lower and upper sequences despite their similar geochemistry and rift-related setting. This gave rise to models which envisaged the Kaaien Terrane being unaffected by the syn- to late-tectonic deformation, migmatisation and granite intrusions, documented between 1 200 and 1 150 Ma in the adjoining Namaqua-Natal terranes to the west. A high-pressure (10 kbar) metamorphic event, recognised in the Kaaien Terrane basement just south of hardly-deformed Koras Group exposures and dated at 1 150 Ma, is inconsistent with such models. A re-investigation and microbeam dating campaign on the Koras Group confirms the 1 101 ± 2 Ma (n = 6) age for felsic volcanic rocks of the upper sequence, but establishes a new reliable age of 1 114 ± 4 Ma for the lower one (n = 2). The 1 170 ages obtained in the earlier two studies were revisited and are now considered to reflect the age of zircon xenocrysts from the source rocks, which dominate the zircon population of some Swartkopsleegte Formation samples. Several criteria to distinguish autocrystic (magmatic) from antecrystic (age-overlappping xenocrystic) data points were investigated. One sample had high Th levels in only the younger zircons, but histograms of sufficiently precise 207Pb/206Pb ages provided the main criterion. Calculations of zircon crystallisation temperature intervals were not useful in predicting the abundance or proportions of magmatic and antecryst zircons. A multi-episode model of magmatic generation and crystallisation events is probably appropriate. In cases when felsic volcanic samples yield few zircons, care must be taken to avoid the problem exposed in this study. The Koras Group sediments have similar detrital zircon U/Pb age distributions to those of the Rehoboth Basement Inlier. This supports the concept that the Kaaien Terrane originated as the southern part of the Rehoboth Province.
Koras群是一个双峰火山沉积群,位于非洲南部纳马夸-纳塔尔省中元古代Kaaien Terrane的前陆冲断复合体中的构造后地堑中。它包含两个镁铁质和长英质火山岩序列,它们之间不整合,只有较低的序列轻微褶皱。长期以来,Koras群被认为是在1210至1000 Ma Namaqua造山运动末期形成的,因为它缺乏下伏岩石的严重变形和变质作用,许多样品中保存着火成矿物。经过多年来对火山岩精确测年的失败尝试,前两次离子探针U-Pb锆石研究都报告了轻微褶皱的下部序列中Swartkopsleegte组长英质熔岩的年龄为~1172Ma(基于相对较少的测年锆石),未变形的上部序列中Leeuwdrai组流纹岩的年龄为~100Ma。因此,尽管它们的地球化学和裂谷相关背景相似,但下部和上部层序之间似乎明显存在70 m.y.的主要间断。这产生了一些模型,这些模型设想Kaaien Terrane不受同期至晚期构造变形、混合岩化和花岗岩侵入的影响,在西面毗邻的Namaqua-Natal地体中记录了1200至150 Ma之间的情况。在几乎不变形的Koras群暴露以南的Kaaien Terrane基底中发现的高压(10kbar)变质事件,其年代为1150 Ma,与此类模型不一致。对Koras群的重新调查和微束测年活动证实了上部序列长英质火山岩的年龄为1011±2Ma(n=6),但为下部序列(n=2)确定了新的可靠年龄为1144±4Ma。对前两项研究中获得的1170个年龄进行了重新研究,现在认为这些年龄反映了源岩中锆石捕虏晶的年龄,这些捕虏晶在一些Swartkopsleegte组样品的锆石种群中占主导地位。研究了区分自成岩(岩浆)和前成岩(年龄覆盖的捕虏晶)数据点的几个标准。一个样本仅在较年轻的锆石中具有高Th水平,但足够精确的207Pb/206Pb年龄的直方图提供了主要标准。锆石结晶温度区间的计算对于预测岩浆锆石和前锆石的丰度或比例没有用处。岩浆生成和结晶事件的多期模型可能是合适的。如果长英质火山样品产生的锆石很少,则必须小心避免本研究中暴露的问题。Koras群沉积物具有与Rehoboth基底Inlier相似的碎屑锆石U/Pb年龄分布。这支持了Kaaien Terrane起源于Rehoboth省南部的概念。
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引用次数: 0
Late Cretaceous to Early Cenozoic initiation of rifting of the Windhoek Graben, Namibia 纳米比亚温得和克地堑晚白垩世至早新生代的起裂作用
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2023-03-20 DOI: 10.25131/sajg.126.0007
R. Waren, J. Cartwright, M. Daly, R. Swart
The Windhoek Graben is a north-south trending rift in central Namibia that forms a prominent topographic feature bisecting an area of plateau uplift. It occupies a potentially crucial role in the propagation of the Late Cenozoic Southwest African Rift system regarding a possible continuation to the west of the Eiseb Rift. It is an unusual example of intra-continental rifting because it has no significant sediment fill associated with the period of active rifting, and hence the timing of rift activity and its tectonic relevance has not hitherto been established. To constrain the age of the Windhoek Graben we examine its regional geomorphic context and its relationship to four sites of igneous activity in the central Namibian Highlands. Two of these consist of clusters of eroded phonolitic tholoid bodies that have yielded 40Ar/39Ar dates of 32 Ma and 52 Ma, respectively, that we use to bracket the age of formation of a prominent remnant land surface, termed here the P52 Surface. From previous mapping of older intrusive igneous bodies, we argue that an even older land surface is partially preserved on the highest features in the area, and this surface (termed PRS) defines an initial domally uplifted surface from which initial drainage radiated, and onto which the earliest volcanic products associated with the Graben were erupted. In particular, the strong similarity in dyke and fault orientations is used to argue for a causal connection between the earliest magmatic activity and the onset of rifting. Long range correlation of PRS into the adjacent Aranos Basin strongly suggests a Late Cretaceous age for this earliest magmatic activity and the onset of rifting, but we cannot exclude a younger origin, any time up to the Early Eocene.
温得和克地堑是纳米比亚中部一个南北走向的裂谷,形成了一个突出的地形特征,将高原隆起地区一分为二。它在晚新生代西南非洲裂谷系统的传播中扮演着潜在的关键角色,可能延续到艾塞布裂谷的西部。这是一个不寻常的大陆内裂谷作用的例子,因为它没有与活跃裂谷作用时期相关的重要沉积物填充,因此裂谷活动的时间及其构造相关性迄今尚未确定。为了限制温得和克地堑的年龄,我们研究了它的区域地貌背景及其与纳米比亚中部高地四个火成岩活动地点的关系。其中两个由侵蚀的声母岩类体组成,它们分别产生了32 Ma和52 Ma的40Ar/39Ar年代,我们用它来表示一个突出的残余地表的形成年龄,这里称为P52地表。从之前对更古老的侵入火成岩的制图中,我们认为在该地区的最高特征上部分保留了一个更古老的陆地表面,这个表面(称为PRS)定义了一个最初的穹窿隆起表面,从这个表面上辐射出最初的排水,并在这个表面上爆发了与地堑相关的最早的火山产物。特别是,岩脉和断层方向的强烈相似性被用来论证最早的岩浆活动与裂陷的发生之间的因果关系。与邻近的Aranos盆地的PRS的长期对比强烈表明,最早的岩浆活动和裂谷的开始时间为晚白垩世,但我们不能排除一个更年轻的起源,任何时候都可以追溯到早始新世。
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South African Journal of Geology
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