Pub Date : 2018-08-06DOI: 10.13036/17533562.59.4.048
Tony Jin, G. Bernard, M. Miskolzie, V. Terskikh, V. Michaelis
{"title":"A 11B and 31P MAS NMR study of the impact of Ca2+ and Sr2+ network modifying cations on the structure of borate and borophosphate glasses","authors":"Tony Jin, G. Bernard, M. Miskolzie, V. Terskikh, V. Michaelis","doi":"10.13036/17533562.59.4.048","DOIUrl":"https://doi.org/10.13036/17533562.59.4.048","url":null,"abstract":"","PeriodicalId":49696,"journal":{"name":"Physics and Chemistry of Glasses-European Journal of Glass Science and Technology Part B","volume":"6 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2018-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84536835","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-08-06DOI: 10.13036/17533562.59.4.027
Masanori Suzuki, N. Umesaki, Toshihiro Tanaka, T. Ohkubo, T. Kakihara, Hidenori Kawashima, T. Hashimoto
{"title":"Structural behaviour of vanadium ions in alkali borosilicate glass for nuclear waste storage","authors":"Masanori Suzuki, N. Umesaki, Toshihiro Tanaka, T. Ohkubo, T. Kakihara, Hidenori Kawashima, T. Hashimoto","doi":"10.13036/17533562.59.4.027","DOIUrl":"https://doi.org/10.13036/17533562.59.4.027","url":null,"abstract":"","PeriodicalId":49696,"journal":{"name":"Physics and Chemistry of Glasses-European Journal of Glass Science and Technology Part B","volume":"15 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2018-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84861304","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-08-06DOI: 10.13036/17533562.59.4.025
M. Affatigato
{"title":"Steve Feller: a life in borates","authors":"M. Affatigato","doi":"10.13036/17533562.59.4.025","DOIUrl":"https://doi.org/10.13036/17533562.59.4.025","url":null,"abstract":"","PeriodicalId":49696,"journal":{"name":"Physics and Chemistry of Glasses-European Journal of Glass Science and Technology Part B","volume":"33 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2018-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87600890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-08-06DOI: 10.13036/17533562.59.4.003
B. Allsopp, G. Christopoulou, Adam Brookfield, S. Forder, P. Bingham
Optical and structural properties of float-type soda lime silicate (SLS) glasses doped with 0.2 mol % TiO2, ZrO2, HfO2, Nb2O5, Ta2O5, MoO3 or WO3 have been studied. Under UV excitation all d0 doped glasses exhibit broadband visible emission centred between 19,000 cm-1 and 25,000 cm-1 (400nm – 525nm) due to a transition from the 2p orbital of O2- to the metal d0 orbital. Dopant additions lead to shifts in the UV absorption edge to lower energies, with doped glasses having an absorption edge 2,000 cm-1 (~20nm), and in the case of MoO3, 4,000 cm-1 (~40nm), lower than the corresponding undoped glass. Combined UV-Vis absorption and X-band EPR spectroscopy analyses confirm that dopant cations occur in the studied glasses in the expected oxidation states of Ti4+, Zr4+, Hf4+, Nb5+, Ta5+, Mo6+ and W6+, although very low levels of Mo5+ are also observed, as demonstrated by the EPR resonance at g=1.92 (3.7T). The incorporation of the studied dopants into SLS glasses may find applications as cover glasses in photovoltaic (PV) applications, providing UV protection of polymers and solar cell materials in PV units whilst enhancing solar cell efficiency through downconversion / fluorescence of absorbed UV photons with re-emission as visible photons, available for absorption and conversion by the solar cell material.
{"title":"Optical and structural properties of d0 ion-doped silicate glasses for photovoltaic applications","authors":"B. Allsopp, G. Christopoulou, Adam Brookfield, S. Forder, P. Bingham","doi":"10.13036/17533562.59.4.003","DOIUrl":"https://doi.org/10.13036/17533562.59.4.003","url":null,"abstract":"Optical and structural properties of float-type soda lime silicate (SLS) glasses doped with 0.2 mol % TiO2, ZrO2, HfO2, Nb2O5, Ta2O5, MoO3 or WO3 have been studied. Under UV excitation all d0 doped glasses exhibit broadband visible emission centred between 19,000 cm-1 and 25,000 cm-1 (400nm – 525nm) due to a transition from the 2p orbital of O2- to the metal d0 orbital. Dopant additions lead to shifts in the UV absorption edge to lower energies, with doped glasses having an absorption edge 2,000 cm-1 (~20nm), and in the case of MoO3, 4,000 cm-1 (~40nm), lower than the corresponding undoped glass. Combined UV-Vis absorption and X-band EPR spectroscopy analyses confirm that dopant cations occur in the studied glasses in the expected oxidation states of Ti4+, Zr4+, Hf4+, Nb5+, Ta5+, Mo6+ and W6+, although very low levels of Mo5+ are also observed, as demonstrated by the EPR resonance at g=1.92 (3.7T). The incorporation of the studied dopants into SLS glasses may find applications as cover glasses in photovoltaic (PV) applications, providing UV protection of polymers and solar cell materials in PV units whilst enhancing solar cell efficiency through downconversion / fluorescence of absorbed UV photons with re-emission as visible photons, available for absorption and conversion by the solar cell material.","PeriodicalId":49696,"journal":{"name":"Physics and Chemistry of Glasses-European Journal of Glass Science and Technology Part B","volume":"17 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2018-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83940562","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-06-01DOI: 10.13036/17533562.59.3.003
Shyam Sunder Gandi, S. Gandi, N. Katari, M. S. S. Babu
{"title":"Electrical conductivity of lithium phosphate glass-ceramics precipitated with nanocrystalline BaTiO3","authors":"Shyam Sunder Gandi, S. Gandi, N. Katari, M. S. S. Babu","doi":"10.13036/17533562.59.3.003","DOIUrl":"https://doi.org/10.13036/17533562.59.3.003","url":null,"abstract":"","PeriodicalId":49696,"journal":{"name":"Physics and Chemistry of Glasses-European Journal of Glass Science and Technology Part B","volume":"5 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89899179","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-06-01DOI: 10.13036/17533562.59.3.033
F. Steudel, Systems Imws, B. Ahrens, S. Schweizer
{"title":"Excitation power dependence of Eu3+ photoluminescence in barium borate glass","authors":"F. Steudel, Systems Imws, B. Ahrens, S. Schweizer","doi":"10.13036/17533562.59.3.033","DOIUrl":"https://doi.org/10.13036/17533562.59.3.033","url":null,"abstract":"","PeriodicalId":49696,"journal":{"name":"Physics and Chemistry of Glasses-European Journal of Glass Science and Technology Part B","volume":"67 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74107878","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-06-01DOI: 10.13036/17533562.59.3.023
F. Hawthorne
{"title":"A bond topological approach to borate minerals: A brief review","authors":"F. Hawthorne","doi":"10.13036/17533562.59.3.023","DOIUrl":"https://doi.org/10.13036/17533562.59.3.023","url":null,"abstract":"","PeriodicalId":49696,"journal":{"name":"Physics and Chemistry of Glasses-European Journal of Glass Science and Technology Part B","volume":"26 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74896618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-06-01DOI: 10.13036/17533562.59.3.055
V. Padmini, K. V. Babu, Sandhya Cole
{"title":"Investigations on structural, optical and magnetic features of vanadyl ions in PbO–CaO–ZnO–B2O3 glasses","authors":"V. Padmini, K. V. Babu, Sandhya Cole","doi":"10.13036/17533562.59.3.055","DOIUrl":"https://doi.org/10.13036/17533562.59.3.055","url":null,"abstract":"","PeriodicalId":49696,"journal":{"name":"Physics and Chemistry of Glasses-European Journal of Glass Science and Technology Part B","volume":"22 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81298048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-04-16DOI: 10.13036/17533562.59.2.027
A. C. Rimbach, F. Steudel, B. Ahrens, S. Schweizer
{"title":"Structural and optical properties of Dy3+-doped lithium borate glass","authors":"A. C. Rimbach, F. Steudel, B. Ahrens, S. Schweizer","doi":"10.13036/17533562.59.2.027","DOIUrl":"https://doi.org/10.13036/17533562.59.2.027","url":null,"abstract":"","PeriodicalId":49696,"journal":{"name":"Physics and Chemistry of Glasses-European Journal of Glass Science and Technology Part B","volume":"62 1","pages":"93-96"},"PeriodicalIF":0.6,"publicationDate":"2018-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83933406","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-04-16DOI: 10.13036/17533562.59.2.022
A. A. El-Moneim, H. Alfifi
{"title":"A new factor for predicting the acoustical properties of oxide glasses","authors":"A. A. El-Moneim, H. Alfifi","doi":"10.13036/17533562.59.2.022","DOIUrl":"https://doi.org/10.13036/17533562.59.2.022","url":null,"abstract":"","PeriodicalId":49696,"journal":{"name":"Physics and Chemistry of Glasses-European Journal of Glass Science and Technology Part B","volume":"26 1","pages":"97-104"},"PeriodicalIF":0.6,"publicationDate":"2018-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89524605","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}