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Physics and Chemistry of Glasses-European Journal of Glass Science and Technology Part B最新文献

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A 11B and 31P MAS NMR study of the impact of Ca2+ and Sr2+ network modifying cations on the structure of borate and borophosphate glasses A - 11B和31P MAS NMR研究Ca2+和Sr2+网络修饰阳离子对硼酸盐和硼磷酸盐玻璃结构的影响
IF 0.6 4区 材料科学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2018-08-06 DOI: 10.13036/17533562.59.4.048
Tony Jin, G. Bernard, M. Miskolzie, V. Terskikh, V. Michaelis
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引用次数: 6
Structural behaviour of vanadium ions in alkali borosilicate glass for nuclear waste storage 核废料贮存用碱硼硅酸盐玻璃中钒离子的结构行为
IF 0.6 4区 材料科学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2018-08-06 DOI: 10.13036/17533562.59.4.027
Masanori Suzuki, N. Umesaki, Toshihiro Tanaka, T. Ohkubo, T. Kakihara, Hidenori Kawashima, T. Hashimoto
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引用次数: 11
Steve Feller: a life in borates 史蒂夫·费勒:生活在硼酸盐中
IF 0.6 4区 材料科学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2018-08-06 DOI: 10.13036/17533562.59.4.025
M. Affatigato
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引用次数: 0
Optical and structural properties of d0 ion-doped silicate glasses for photovoltaic applications 用于光伏应用的离子掺杂硅酸盐玻璃的光学和结构特性
IF 0.6 4区 材料科学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2018-08-06 DOI: 10.13036/17533562.59.4.003
B. Allsopp, G. Christopoulou, Adam Brookfield, S. Forder, P. Bingham
Optical and structural properties of float-type soda lime silicate (SLS) glasses doped with 0.2 mol % TiO2, ZrO2, HfO2, Nb2O5, Ta2O5, MoO3 or WO3 have been studied. Under UV excitation all d0 doped glasses exhibit broadband visible emission centred between 19,000 cm-1 and 25,000 cm-1 (400nm – 525nm) due to a transition from the 2p orbital of O2- to the metal d0 orbital. Dopant additions lead to shifts in the UV absorption edge to lower energies, with doped glasses having an absorption edge 2,000 cm-1 (~20nm), and in the case of MoO3, 4,000 cm-1 (~40nm), lower than the corresponding undoped glass. Combined UV-Vis absorption and X-band EPR spectroscopy analyses confirm that dopant cations occur in the studied glasses in the expected oxidation states of Ti4+, Zr4+, Hf4+, Nb5+, Ta5+, Mo6+ and W6+, although very low levels of Mo5+ are also observed, as demonstrated by the EPR resonance at g=1.92 (3.7T). The incorporation of the studied dopants into SLS glasses may find applications as cover glasses in photovoltaic (PV) applications, providing UV protection of polymers and solar cell materials in PV units whilst enhancing solar cell efficiency through downconversion / fluorescence of absorbed UV photons with re-emission as visible photons, available for absorption and conversion by the solar cell material.
研究了掺杂0.2 mol % TiO2、ZrO2、HfO2、Nb2O5、Ta2O5、MoO3或WO3的浮子型钠钙硅酸盐玻璃(SLS)的光学和结构性能。在紫外激发下,由于O2-的2p轨道跃迁到金属d0轨道,所有掺杂d0的玻璃都表现出集中在19,000 cm-1和25,000 cm-1 (400nm - 525nm)之间的宽带可见发射。掺杂导致紫外吸收边沿向较低能量偏移,掺杂玻璃的吸收边沿为2000 cm-1 (~20nm), MoO3的吸收边沿为4000 cm-1 (~40nm),低于相应的未掺杂玻璃。紫外-可见吸收和x波段EPR光谱分析证实,在所研究的玻璃中,Ti4+、Zr4+、Hf4+、Nb5+、Ta5+、Mo6+和W6+的氧化态出现了掺杂阳离子,尽管在g=1.92 (3.7T)处也观察到极低水平的Mo5+。将所研究的掺杂剂掺入SLS玻璃中,可能会在光伏(PV)应用中作为覆盖玻璃应用,为光伏单元中的聚合物和太阳能电池材料提供紫外线防护,同时通过吸收的紫外线光子的下转换/荧光再发射为可见光子,提高太阳能电池的效率,可用于太阳能电池材料的吸收和转换。
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引用次数: 11
Electrical conductivity of lithium phosphate glass-ceramics precipitated with nanocrystalline BaTiO3 纳米晶BaTiO3沉淀的磷酸锂微晶玻璃的导电性
IF 0.6 4区 材料科学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2018-06-01 DOI: 10.13036/17533562.59.3.003
Shyam Sunder Gandi, S. Gandi, N. Katari, M. S. S. Babu
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引用次数: 1
Excitation power dependence of Eu3+ photoluminescence in barium borate glass 硼酸钡玻璃中Eu3+光致发光的激发功率依赖性
IF 0.6 4区 材料科学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2018-06-01 DOI: 10.13036/17533562.59.3.033
F. Steudel, Systems Imws, B. Ahrens, S. Schweizer
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引用次数: 3
A bond topological approach to borate minerals: A brief review 硼酸盐矿物的键拓扑方法:简要综述
IF 0.6 4区 材料科学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2018-06-01 DOI: 10.13036/17533562.59.3.023
F. Hawthorne
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引用次数: 2
Investigations on structural, optical and magnetic features of vanadyl ions in PbO–CaO–ZnO–B2O3 glasses PbO-CaO-ZnO-B2O3玻璃中钒基离子的结构、光学和磁性研究
IF 0.6 4区 材料科学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2018-06-01 DOI: 10.13036/17533562.59.3.055
V. Padmini, K. V. Babu, Sandhya Cole
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引用次数: 2
Structural and optical properties of Dy3+-doped lithium borate glass 掺Dy3+硼酸锂玻璃的结构和光学性质
IF 0.6 4区 材料科学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2018-04-16 DOI: 10.13036/17533562.59.2.027
A. C. Rimbach, F. Steudel, B. Ahrens, S. Schweizer
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引用次数: 6
A new factor for predicting the acoustical properties of oxide glasses 预测氧化玻璃声学性能的新因素
IF 0.6 4区 材料科学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2018-04-16 DOI: 10.13036/17533562.59.2.022
A. A. El-Moneim, H. Alfifi
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引用次数: 15
期刊
Physics and Chemistry of Glasses-European Journal of Glass Science and Technology Part B
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