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Spectroscopic and Thermal Investigations on Methyl Methacrylate – co – Methacrylic Acid Copolymer 甲基丙烯酸甲酯-甲基丙烯酸共聚物的光谱和热学研究
Pub Date : 2023-11-29 DOI: 10.32802/asmscj.2023.1457
D. Shireesh, N. Srinivasa Rao, S. Kalahasti, B. Sanjeeva Rao
Gamma irradiation effects on methyl methacrylate (MMA) – methacrylic acid (MAA) copolymer were investigated by spectroscopic (ESR, FTIR) and thermal (DSC) methods. Electron spin resonance (ESR) spectra of the irradiated copolymer are analysed to be caused by different component spectra from the free radicals (~ CH2 – CH – CH2 ~ and – COOH or – COOCH3) as per computer simulation analysis. The ESR signals could be annealed near the transition temperature of the copolymer, and the free radicals formed irradiation might react to form stable structures at transition temperatures. Fourier transform infrared (FTIR) studies suggested that the 3380 cm-1 absorption band (due to COOH groups and or hydrogen bonding) and 1734 cm-1 absorption band (due to carbonyl groups) were mostly affected by irradiation. Differential scanning calorimeter (DSC) thermogram indicated that the copolymer is a two-phase system (PMMA and PMAA), and transition temperatures are influenced by gamma irradiation. The dosimetric application of copolymer is tested by the ESR technique, and it was found suitable for dosimetry.
通过光谱(ESR、FTIR)和热(DSC)方法研究了伽马辐照对甲基丙烯酸甲酯(MMA)-甲基丙烯酸(MAA)共聚物的影响。根据计算机模拟分析,辐照共聚物的电子自旋共振(ESR)光谱是由自由基(~ CH2 - CH - CH2 ~ 和 - COOH 或 - COOCH3)的不同成分光谱引起的。ESR 信号可能是在共聚物的转变温度附近退火,辐照形成的自由基可能在转变温度下反应形成稳定的结构。傅立叶变换红外(FTIR)研究表明,3380 cm-1 吸收带(由 COOH 基团和氢键引起)和 1734 cm-1 吸收带(由羰基引起)主要受到辐照的影响。差示扫描量热仪(DSC)热图表明,共聚物是一个两相体系(PMMA 和 PMAA),过渡温度受伽马辐照的影响。利用 ESR 技术对共聚物的剂量测定应用进行了测试,结果表明共聚物适用于剂量测定。
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引用次数: 0
Physical and Chemical Components Characteristics of Liquid Smoke Redistillation from Different Biomass Sources 不同生物质来源的液态烟再蒸馏的物理和化学成分特征
Pub Date : 2023-11-28 DOI: 10.32802/asmscj.2023.1442
B. Piluharto, Adi Kurniawan Efendi, D. Indarti, A. Asnawati, Agus Wedi Pratama
In this study, liquid smoke from coconut shells, sengon wood, and corn cobs has been produced and redistilled. The change of colour, pH value, and chemical components of liquid smoke (LS) and redistilled liquid smoke (r-LS) have been studied. Redistillation was carried out at about 100–105 °C for 3 hours. The results show that the colour of r-LS from the three biomass sources is lighter than LS. The pH values slightly decreased for coconut shell, sengon wood, and corn cobs, from 3.63 to 3.40, 4.42 to 3.39, and 3.53 to 3.36, respectively. This result is caused by the evaporation of volatile compounds. Meanwhile, the results of the analysis of the chemical components showed that all the main components of liquid smoke decreased after redistillation, except for the esters component, which increased in coconut shell and corn cobs, from 2.98% to 64.36% and 2.98% to 8.07%, respectively.
在这项研究中,从椰子壳、森贡木和玉米芯中生产并重新蒸馏出了液态烟雾。研究了液体烟雾(LS)和再蒸馏液体烟雾(r-LS)的颜色、pH 值和化学成分的变化。再蒸馏在约 100-105 °C 的温度下进行 3 小时。结果表明,三种生物质来源的再蒸馏烟液颜色比烟液浅。椰子壳、仙人木和玉米芯的 pH 值略有下降,分别从 3.63 降至 3.40、4.42 降至 3.39 和 3.53 降至 3.36。造成这一结果的原因是挥发性化合物的蒸发。同时,化学成分分析结果表明,除了酯类成分在椰壳和玉米芯中有所增加(分别从 2.98% 增加到 64.36%和从 2.98% 增加到 8.07%),其他主要成分在再蒸馏后都有所减少。
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引用次数: 0
A Blood Substitute for Blood Pattern Analysis of Low-Velocity Passive Stains – Its Implications in the Examination of Crime Scenes 用于低速被动污迹血型分析的血液替代物--其在犯罪现场检查中的意义
Pub Date : 2023-11-24 DOI: 10.32802/asmscj.2023.1374
Nisha Ng, Prabitha V.G, Lekshmi G
In forensic blood pattern analysis, the conventional trajectory reconstruction methods are based on trigonometric principles. Most of these approaches do not take into account the fluid properties of blood, a non-Newtonian fluid, leading to enormous uncertainties. For perpendicular impact blood stains, simple mathematical models based on fluid dynamics are used to determine the spreading factor and number of spines. We evaluate some of the mathematical models in this study with experimental data obtained as a function of impact height using a blood substitute. A blood substitute, which has comparable fluid properties as human blood, was preferred because using human blood for laboratory purpose has many ethical issues. The study shows that the spreading pattern and number of spines obtained from the low-velocity drip stains of circular shape using the blood substitute improves the prediction accuracy of the blood source’s vertical height from target surface. We also conducted a qualitative analysis of its spreading mechanism on different substrates with regard to surface roughness. The results indicate that a reconstructional analysis for the drip stains is possible using the suggested blood substitute. More research has to be done for evaluating its performance in all velocity ranges and all impact angles.
在法医血型分析中,传统的轨迹重建方法以三角函数原理为基础。这些方法大多没有考虑血液这种非牛顿流体的流体特性,从而导致巨大的不确定性。对于垂直撞击血迹,基于流体动力学的简单数学模型可用于确定扩散因子和刺的数量。在本研究中,我们利用使用血液替代品获得的与撞击高度相关的实验数据对部分数学模型进行了评估。由于在实验室中使用人体血液存在许多道德问题,因此我们选择了与人体血液具有相似流体特性的血液替代品。研究表明,使用血液替代品从圆形低速滴渍中获得的扩散模式和刺的数量提高了对血源距目标表面垂直高度的预测精度。我们还根据表面粗糙度对其在不同基底上的扩散机制进行了定性分析。结果表明,使用建议的血液替代物可以对滴落污渍进行重建分析。还需要进行更多的研究,以评估其在所有速度范围和所有撞击角度下的性能。
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引用次数: 0
The Specificity and Efficacy of Alternating Electric Fields as a Prospective Cancer Treatment 交变电场作为前瞻性癌症治疗方法的特异性和有效性
Pub Date : 2023-11-23 DOI: 10.32802/asmscj.2023.1588
E. S. Palupi, Bambang Retnoaji, Pudji Astuti, F. Alamsyah, R. Pratiwi
An external electric field is still debatable for cancer treatment, although many study results proved its capacity. Cancer involves complex mechanisms, including how the cancer cells arise and grow. Thus, this disease is known to have many hallmarks. This condition complicates precise and accurate treatment. The study proved that an external electric field has prospects to become an effective cancer treatment, demonstrated by its ability to inhibit cancer growth through anti-proliferative and pro-apoptotic capacities. Several devices generating electric fields for cancer treatment were Tumour Treating Fields (TTFields), nanosecond Pulsed Electric Fields (nsPEF), picosecond Pulsed Electric Fields (psPEF), and Electro-Capacitive Cancer Therapy (ECCT). This article will compare those devices’ efficacy, safety, treatment methods, and research progress, including the advantages and disadvantages of static electric field devices and future research prospects. More attention will be focused on ECCT, which has been closely and profoundly investigated in breast cancer treatment.
尽管许多研究结果证明了外部电场的治疗能力,但它在癌症治疗中的作用仍有待商榷。癌症涉及复杂的机制,包括癌细胞如何产生和生长。因此,众所周知,这种疾病有许多特征。这种情况使得精确治疗变得复杂。研究证明,外部电场通过抗增殖和促凋亡能力抑制癌症生长,有望成为一种有效的癌症治疗方法。用于治疗癌症的几种产生电场的装置包括肿瘤治疗场(TTFields)、纳秒脉冲电场(nsPEF)、皮秒脉冲电场(psPEF)和电容式癌症疗法(ECCT)。本文将比较这些设备的疗效、安全性、治疗方法和研究进展,包括静态电场设备的优缺点和未来研究前景。ECCT 在乳腺癌治疗中得到了密切而深入的研究,将受到更多关注。
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引用次数: 0
The Nature of Gender Difference in The Effectiveness of GeoGebra GeoGebra 效果中的性别差异性质
Pub Date : 2023-11-23 DOI: 10.32802/asmscj.2023.1044
Ziham Zawawi Mazlan, Hutkemri Zulnaidi
GeoGebra is a type of Dynamic Geometric Software (DGS) that has been widely used to teach Mathematics. A substantial research study was done to investigate the effectiveness of GeoGebra to enhance students’ learning in mathematics from varied dimensions. In this research, a systematic review of the effectiveness of GeoGebra to enhance students’ learning in mathematics from varied dimensions was conducted using PRISMA’s procedure. The use of GeoGebra as one of STEM education instrument has yet to be discovered. Thus, the further study of its effectiveness is needed. 11 articles between 2011-2020 have been analysed. The distribution of the accessed articles over the years were up and down by heading to its declining trend from 2011 to 2020. The distribution of origin in the accessed articles by country of origin shows that Asia dominated this study with six articles (55%), while Africa with three articles (27%) and North America and Europe, respectively produced one paper (9%). All accessed articles conclusively stated that GeoGebra can improve students and pupils cognitive and affective dimensions. In terms of gender difference, the conclusive findings show no gender difference on the effectiveness of GeoGebra in the teaching and learning of mathematics.
GeoGebra 是一种动态几何软件(DGS),已被广泛用于数学教学。为从不同维度调查 GeoGebra 在促进学生数学学习方面的有效性,我们进行了大量的研究。本研究采用 PRISMA 程序,对 GeoGebra 从不同维度促进学生数学学习的有效性进行了系统综述。作为 STEM 教育工具之一的 GeoGebra 的使用还有待探索。因此,需要进一步研究其有效性。对 2011-2020 年间的 11 篇文章进行了分析。从 2011 年到 2020 年,被访问文章的分布呈上升和下降趋势。按来源国划分的文章来源地分布显示,亚洲在本研究中占主导地位,有六篇文章(55%),非洲有三篇文章(27%),北美和欧洲分别有一篇论文(9%)。所有文章都明确指出,GeoGebra 可以提高学生的认知和情感水平。在性别差异方面,研究结果表明,GeoGebra 在数学教学中的有效性没有性别差异。
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引用次数: 0
An Empirical Analysis of The Impact of Money Attitudes on Retirement Savings Behaviour in Malaysia 马来西亚货币态度对退休储蓄行为影响的实证分析
Pub Date : 2023-11-22 DOI: 10.32802/asmscj.2023.1038
Nurul Sima Mohamad Shariff, Anis Hanani Azhar, Muhammad Safwan Ibrahim
Saving for the future, especially for life after retirement, is a critical issue often debated. Early savings planning needs to be paid serious attention to ensure a good and comfortable life after retirement. However, behaviour towards savings for retirement is related to money attitude as it is how an individual behaves or reacts to money. Each person is believed to have different views and behaviours towards money and income, especially regarding retirement savings. As such, this study aims to investigate the effect of money attitudes on retirement savings behaviour. The survey approach was employed and conducted using questionnaires developed by adopting several studies and then randomly distributed via an online platform. A total of 160 respondents from 250 targeted respondents successfully answered the questionnaire and were used for further analysis. The collected sample suggested a successful response rate of 64%, more than enough to allow for population-wide generalisation of the findings. The analyses conducted were the pilot test for the initial screening of the items in the questionnaire, descriptive statistics, multicollinearity test, and the ordered Probit model. This study revealed mixed findings on the relationship between the type of money attitudes and retirement savings behaviour, indicating that people with different attitudes towards money will have different perceptions of savings for retirement.
为未来储蓄,尤其是为退休后的生活储蓄,是一个经常被争论的关键问题。为了确保退休后过上舒适的美好生活,需要认真关注早期储蓄规划。然而,退休储蓄行为与金钱态度有关,因为金钱态度是指个人对金钱的行为或反应。相信每个人对金钱和收入都有不同的看法和行为,尤其是在退休储蓄方面。因此,本研究旨在调查金钱态度对退休储蓄行为的影响。本研究采用了调查方法,并使用了通过采纳多项研究而编制的问卷,然后通过在线平台随机分发。在 250 名目标受访者中,共有 160 名受访者成功回答了问卷,并被用于进一步分析。收集到的样本表明,成功回复率为 64%,足以将研究结果推广到整个人群。所进行的分析包括初步筛选问卷项目的试点测试、描述性统计、多重共线性测试和有序 Probit 模型。这项研究揭示了金钱态度类型与退休储蓄行为之间的关系,结果不一,表明对金钱持不同态度的人对退休储蓄会有不同的看法。
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引用次数: 0
Role of Microglia in 3, 4 Methylenedioxymethamphetamine (MDMA) -Induced Neurotoxicity: A Mini Review 小胶质细胞在 3、4 亚甲二氧基甲基苯丙胺(MDMA)诱导的神经毒性中的作用:微型综述
Pub Date : 2023-11-17 DOI: 10.32802/asmscj.2023.1455
Nor Suliana Mustafa, Mohd Nazri Mohd Daud, Nor Hidayah Abu Bakar, Liyana Hazwani Mohd Adnan, N. Mohamad, Nor Hidayah Abu Bakar, Nelbon Giloi
MDMA (3, 4 Methylenedioxymethamphetamine) is a psychoactive drug under the amphetamine-type stimulant group. While the modulatory effects of MDMA on serotonin neurotransmission and its neurotoxicity in the central nervous system are well studied, MDMA’s effects on modulating microglial neuroimmune functions have attracted considerable attention. Resident glial cells, including microglia in the brain, are implicated in contributing to MDMA-induced neurotoxicity. In their response to the disturbances around neurons, microglia can take on the role of the first line of defence against pathogens by the production of a variety of inflammatory mediators such as tumour necrosis factor-alpha (TNF-α), interleukin (IL) 1β, IL-6, nitric oxide (NO), and reactive oxygen species (ROS). They also can act as anti-inflammatory mediators to initiate recovery from an insult. Hence, the current review illuminates MDMA-induced neurotoxicity by summarising studies reporting microglial activation after MDMA exposure in vitro and in vivo. A modulation between cytotoxic states to a neuroprotective state of microglia probably can make up an important strategy to reduce the negative impairments made by MDMA on neuronal cells by targeting microglial cells.
亚甲二氧基甲基苯丙胺(3, 4 Methylenedioxymethamphetamine)是苯丙胺类兴奋剂中的一种精神活性药物。虽然亚甲二氧基甲基苯丙胺对血清素神经传递的调节作用及其在中枢神经系统中的神经毒性已被充分研究,但亚甲二氧基甲基苯丙胺对小胶质细胞神经免疫功能的调节作用也引起了广泛关注。驻留的神经胶质细胞,包括大脑中的小胶质细胞,与亚甲二氧基甲基苯丙胺诱导的神经毒性有牵连。在对神经元周围的紊乱做出反应时,小胶质细胞可通过产生多种炎症介质(如肿瘤坏死因子-α(TNF-α)、白细胞介素(IL)1β、IL-6、一氧化氮(NO)和活性氧(ROS)),发挥抵御病原体的第一道防线的作用。它们还可以作为抗炎介质,启动损伤后的恢复。因此,本综述通过总结有关亚甲二氧基甲基苯丙胺体外和体内暴露后小胶质细胞活化的研究,阐明了亚甲二氧基甲基苯丙胺诱导的神经毒性。小胶质细胞的细胞毒性状态与神经保护状态之间的调节可能是一种重要的策略,可通过针对小胶质细胞来减少亚甲二氧基甲基苯丙胺对神经细胞造成的负面损伤。
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引用次数: 0
Concentration of Indoor Air Chemical Parameters at Different Ship Conditions and Engine Sequences 不同船况和发动机序列下的室内空气化学参数浓度
Pub Date : 2023-11-16 DOI: 10.32802/asmscj.2023.1015
Nur Sarah Fatihah Tamsi, Maryam Zahaba, Amirul Faiz Kamaruddin, Norhidayah Abdull, Arman Ariffin, Mohammad Naufal Mohammad Sharif
Good indoor air quality (IAQ) is crucial for navy crew due to longer periods onboard, especially during pandemic. Increased frequency of the ship’s operations is required to prevent trespassing and illegal border crossings. This study aims to determine and compare the indoor air chemical parameters; carbon dioxide (CO₂), carbon monoxide (CO), and total volatile organic compounds (TVOC) at different ship conditions (alongside and sailing) and engine sequences (idling, cruising, full ahead and slowing down). The parameters were measured in four compartments, following the Industry Code of Practice on Indoor Air Quality 2010 (ICOP IAQ 2010). At different ship conditions, there were significant differences of indoor air chemical parameters in the common room, electrical room, and accommodation area 2. However, no trend of higher or lower concentrations was observed between the conditions due to ship operation, human activities, and occupancy. The engine sequences affect the indoor air chemical parameters, where the CO concentrations were recorded higher in all compartments, especially when the engine was running at 1000 rpm. In conclusion, the navy crew could be exposed to unacceptable IAQ conditions regardless of ship conditions and engine sequences. It is good to highlight that good ventilation is crucial to dilute the air pollutants onboard.
由于海军船员在船上的时间较长,尤其是在大流行病期间,良好的室内空气质量(IAQ)对他们至关重要。为了防止非法入侵和非法越境,需要增加舰艇的运行频率。本研究旨在确定和比较不同舰船条件(靠岸和航行)和发动机顺序(怠速、巡航、全速前进和减速)下的室内空气化学参数:二氧化碳 (CO₂)、一氧化碳 (CO) 和总挥发性有机化合物 (TVOC)。按照《2010 年室内空气质量行业规范》(ICOP IAQ 2010),在四个舱室测量了这些参数。在不同的船舶条件下,公共休息室、电气室和 2 号住宿区的室内空气化学参数存在显著差异。然而,由于船舶运行、人类活动和占用等原因,不同条件下的室内空气化学参数并没有呈现出高或低的趋势。发动机序列会影响室内空气化学参数,所有舱室的一氧化碳浓度都较高,尤其是当发动机以 1000 rpm 运行时。总之,无论船舶状况和发动机顺序如何,海军船员都可能暴露在不可接受的室内空气质量条件下。值得强调的是,良好的通风对稀释舰上空气污染物至关重要。
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引用次数: 0
Mortality Index Simulation for Forecasting Malaysian Mortality Rates 用于预测马来西亚死亡率的模拟死亡率指数
Pub Date : 2023-11-16 DOI: 10.32802/asmscj.2023.1465
N. Redzwan, Rozita Ramli, Pavitra Sivasundaram
Mortality studies are very important in demography and actuarial areas because they assist policymakers and life insurers in managing longevity and mortality risks. In recent decades, many extrapolative mortality models have been developed following the Lee-Carter model. Despite the widely used Lee-Carter model for projecting mortality rates, the literature that has a thorough explanation of it is limited. In this study, we aim to provide a comprehensive explanation of the model with a focus on its fitting and simulation forecasting techniques. We fitted the mortality rates of the Malaysian population for the years 1991 to 2012 using the Lee-Carter model. We then projected the mortality rates for the years 2013 to 2018 using an autoregressive integrated moving average (ARIMA) (0,1,0) model by using a simulation of the mortality index. Findings showed that the Lee-Carter model performs well for this dataset based on the computed standard accuracy measures. The estimated age parameters exhibited a high mortality rate in the age group of 0-4 years, while the estimated time-varying parameter indicated a decreasing trend. This study presents a thorough interpretation of the Lee-Carter model and a detailed simulation of the ARIMA (0,1,0) model and hence provides a comprehensive reference for beginners in mortality studies.
死亡率研究在人口学和精算学领域非常重要,因为它有助于决策者和人寿保险公司管理长寿和死亡率风险。近几十年来,许多推断死亡率的模型都是按照 Lee-Carter 模型开发的。尽管 Lee-Carter 模型被广泛用于预测死亡率,但对其进行深入解释的文献却很有限。在本研究中,我们旨在全面解释该模型,重点是其拟合和模拟预测技术。我们使用 Lee-Carter 模型拟合了 1991 年至 2012 年马来西亚人口的死亡率。然后,我们通过模拟死亡率指数,使用自回归综合移动平均(ARIMA)(0,1,0)模型预测了 2013 年至 2018 年的死亡率。研究结果表明,根据计算的标准精确度,Lee-Carter 模型在该数据集上表现良好。估计的年龄参数显示 0-4 岁年龄组的死亡率较高,而估计的时变参数显示出下降趋势。本研究对 Lee-Carter 模型进行了深入解读,并对 ARIMA (0,1,0) 模型进行了详细模拟,从而为死亡率研究的初学者提供了全面的参考。
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引用次数: 0
Flexible Feedstock Analysis of Biomass Gasification Process for Carbon-Negative Energy Technology via Aspen Plus Simulation 通过 Aspen Plus 仿真对用于负碳能源技术的生物质气化工艺进行灵活的原料分析
Pub Date : 2023-11-16 DOI: 10.32802/asmscj.2023.873
N. A. Manaf, Z. F. Mohd Shadzalli, Nursyuhada’ Kamarulzaman
The escalating concern over greenhouse gas (GHG) emissions from solid waste treatment and fossil fuel power plants has garnered global attention, including in Malaysia. Abundant agricultural waste (AW) and organic municipal solid waste (MSW) in this region hold promise as potential replacements for fossil fuels, offering a pathway to generate electricity while reducing GHG emissions. The innovative gasification approach, particularly the combined heat and power (CHP) system, emerges as a viable solution to address these challenges. However, the operational design of conventional gasification processes typically using a single type of fuel from various discarded resources, such as agricultural waste (e.g., woodchips and coconut shells) and organic MSW, remains controversial. To address these concerns, the present study investigates the power pallet system's capability and reliability to generate electricity from diverse mixed ratios of organic MSW to agricultural waste via a simulation approach. The results demonstrated that power generation remained above 20kW for all mix ratios. It was observed that as the ratio of MSW increased, the composition of hydrogen and carbon monoxide decreased. These trends suggest that power generation is influenced by the syngas yield, which correlates with the quality of the feedstock.
固体废物处理和化石燃料发电厂产生的温室气体(GHG)排放问题日益引起全球关注,马来西亚也不例外。该地区丰富的农业废弃物(AW)和城市有机固体废弃物(MSW)有望成为化石燃料的潜在替代品,为发电同时减少温室气体排放提供了途径。创新的气化方法,特别是热电联产(CHP)系统,成为应对这些挑战的可行解决方案。然而,传统气化工艺通常使用来自各种废弃资源(如农业废弃物(如木屑和椰子壳)和有机都市固体废弃物)的单一类型燃料,其操作设计仍存在争议。为了解决这些问题,本研究通过模拟方法研究了动力托盘系统利用不同比例的有机城市固体废弃物和农业废弃物发电的能力和可靠性。结果表明,所有混合比例的发电量都保持在 20 千瓦以上。据观察,随着 MSW 比例的增加,氢气和一氧化碳的成分减少。这些趋势表明,发电量受合成气产量的影响,而合成气产量与原料质量相关。
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引用次数: 0
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