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Optimizing bonding performance in CF/PEKK composites: The role of IR heating and press consolidation 优化 CF/PEKK 复合材料的粘合性能:红外加热和加压固化的作用
Pub Date : 2024-03-30 DOI: 10.1142/s0217984924410057
Kang-Min Kim, Sanjay Kumar, Yun-Hae Kim
Bonding performance of carbon fiber/polyetherketoneketone (CF/PEKK) laminates is closely related to crystallinity and is influenced by growth, formation, and density of spherulites. Press consolidation, with its ability to adjust pressure, exhibits superior quality compared to oven consolidation. However, bonding and production of CF/PEKK laminates using Press consolidation exhibit significant variations in quality depending on forming conditions. While research on producing CF/PEKK laminates using press consolidation is currently active, there is a lack of studies on co-consolidation for CF/PEKK laminates. Thus, in this study, establishment of forming process variables for press consolidation was conducted to achieve excellent bonding performance for CF/PEKK. Furthermore, IR heating-assisted surface heat treatment was employed to enhance bonding performance of CF/PEKK laminates by controlling crystallinity and spherulites. To analyze bonding performance, short bean shear testing was conducted to obtain interlaminar shear strength (ILSS). Results showed that surface modification through IR heating led to an increase in crystallinity and a noticeable growth in size of spherulites. In specific conditions, improved bonding performance was observed. This is judged to be primarily due to increase in spherulite size and crystallinity at bonding interface, attributed to specific conditions of both surface treatment through IR heating and Press consolidation.
碳纤维/聚醚醚酮酮(CF/PEKK)层压板的粘结性能与结晶度密切相关,并受球泡体的生长、形成和密度的影响。与烘箱固结相比,压力固结具有调节压力的能力,因此质量更优。然而,使用压制固结法粘合和生产 CF/PEKK 层压材料时,质量会因成型条件的不同而有很大差异。目前,使用压机固结法生产 CF/PEKK 层压板的研究十分活跃,但对 CF/PEKK 层压板的共固结研究却十分缺乏。因此,在本研究中,为实现 CF/PEKK 的优异粘合性能,对压机固结的成型工艺变量进行了确定。此外,还采用了红外加热辅助表面热处理,通过控制结晶度和球形颗粒来提高 CF/PEKK 层压材料的粘合性能。为了分析粘合性能,进行了短豆剪切试验,以获得层间剪切强度(ILSS)。结果表明,通过红外加热进行表面改性可提高结晶度,并明显增大球粒尺寸。在特定条件下,还观察到粘结性能得到改善。据判断,这主要是由于通过红外加热进行表面处理和加压固结的特定条件增加了粘合界面的球形颗粒尺寸和结晶度。
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引用次数: 0
Terahertz ultra-broadband and multi-frequency narrowband perfect absorber based on compound metamaterial 基于复合超材料的太赫兹超宽带和多频窄带完美吸收器
Pub Date : 2024-03-30 DOI: 10.1142/s0217984924503226
Ruihan Yang, Zhimin Liu, Xin Luo, Cheng Ji, Guangxin Yang, Yadong Xie
A perfect absorber in the terahertz band with ultra-broadband and triple narrowband is achieved, using Vanadium Dioxide (VO2) and patterned graphene hybrid metamaterials, which can be converted by adjusting the temperature. When only VO2 is present in the structure, the absorption spectrum shows broadband absorption in metallic phases of VO2. Adding graphene to metallic VO2, the absorption bandwidth over 95% is expanded to 5.5[Formula: see text]THz, which is 1.9 times broader compared to the absence of graphene, and the absorption bandwidth over 99% increases to 1.72[Formula: see text]THz. Adding graphene to insulating VO2, three narrowband absorptions appear with absorption rates approaching 100%. Polarization characteristics show that ultra-broadband is insensitive to polarization angle, while multi-frequency narrowband exhibits sensitivity. Therefore, the proposed tunable multifunctional absorber can greatly optimize the absorption capacity of ultra-broadband and multi-frequency narrow bands, demonstrating great potential in future practical applications.
利用二氧化钒(VO2)和图案化石墨烯混合超材料在太赫兹波段实现了具有超宽带和三重窄带的完美吸收器,并可通过调节温度进行转换。当结构中只有二氧化钒时,吸收光谱显示出二氧化钒金属相的宽带吸收。在金属 VO2 中加入石墨烯后,95% 以上的吸收带宽扩大到 5.5[式:见正文]太赫兹,是没有石墨烯时的 1.9 倍,99% 以上的吸收带宽增加到 1.72[式:见正文]太赫兹。在绝缘的 VO2 中加入石墨烯,会出现三个窄带吸收,吸收率接近 100%。偏振特性表明,超宽带对偏振角不敏感,而多频窄带则表现出敏感性。因此,所提出的可调谐多功能吸收器可以极大地优化超宽带和多频窄带的吸收能力,在未来的实际应用中展现出巨大的潜力。
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引用次数: 0
Flexural behavior of carbon/epoxy nanocomposite pipes with interleaved structure 具有交错结构的碳/环氧纳米复合材料管道的挠曲行为
Pub Date : 2024-03-30 DOI: 10.1142/s0217984924410100
Ye-Rim Park, Sanjay Kumar, Anam Naz, Yun-Hae Kim
The filament winding process used in this study mainly produces pipe-shaped structures. In this structure, there is an intersection of fiber bundles, which makes the fiber bundles overlapping with other fiber bundles wavy. In that area, the concentration of stress and deformation appears. Therefore, halloysite nanotubes were applied among nanoparticles to supplement this through the study. In the utilization of nanoparticles, the control of agglomeration phenomena and the ease of dispersion are pivotal factors. In consideration of this, general halloysite nanotubes were heat-treated at 1000∘C to produce amorphous halloysite nanotubes to reduce the surface energy of particles, making it easier to control agglomeration phenomena and the ease of dispersion, and it was intended to supplement and improve mechanical properties in local applications through interleaved structure design. In this study, each stacked structure was analyzed through an axial pipe bending test. The fracture pattern for each structure was observed through an optical microscope. As a result, A3 reinforced with A-HNT for all layers had the highest load value (4207N), and the flexural strength was also measured high accordingly. It shows a small degree of fracture compared to other structures. Following that, E2A1, whose innermost layer was reinforced with A-HNT, had the second-highest load value (3864N), and accordingly, the second-highest flexural strength was measured. The observed surface of the pipe was the outermost layer (E), and it was observed that the degree of fracture was more advanced than that of A3.
本研究采用的长丝缠绕工艺主要产生管状结构。在这种结构中,存在纤维束的交叉点,这使得与其他纤维束重叠的纤维束呈波浪状。在该区域,会出现应力集中和变形。因此,通过研究,在纳米粒子中应用了埃洛石纳米管作为补充。在利用纳米粒子时,控制团聚现象和易于分散是关键因素。有鉴于此,一般的埃洛石纳米管在1000∘C下进行热处理,生成无定形埃洛石纳米管,以降低颗粒的表面能,从而更容易控制团聚现象和分散的难易程度,并希望通过交错结构设计来补充和改善局部应用的力学性能。本研究通过轴向管道弯曲试验对每种堆叠结构进行了分析。通过光学显微镜观察了每种结构的断裂形态。结果表明,所有层都使用 A-HNT 增强的 A3 具有最高的载荷值(4207N),抗弯强度也相应较高。与其他结构相比,它的断裂程度较小。随后,最内层用 A-HNT 加固的 E2A1 的荷载值(3864N)位居第二,因此测得的抗弯强度也位居第二。观察到的管道表面是最外层(E),断裂程度比 A3 更深。
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引用次数: 0
Delamination mechanism in CF/EPOXY with open hole under mode II loading at different distances 带开孔的 CF/EPOXY 在不同距离的模式 II 载荷下的分层机理
Pub Date : 2024-03-30 DOI: 10.1142/s0217984924410136
Tae-Sun Bang, Sanjay Kumar, Yun-Hae Kim
This research addresses limitations in current aviation composite assembly techniques, often constrained by certification challenges. To enhance bonded composite components, open holes are frequently introduced, leading to increased vulnerability to delamination, a prominent failure mode in composite laminates. This study focuses on observing the impact of open holes on the mode II behavior of composites under various distances and hole diameter conditions. Results illustrate distinct load–displacement curves influenced by hole size, with shorter distances accelerating crack propagation, evidenced by reduced elastic regions and lower load values. Analyzing specimen appearances and crack patterns highlights stress concentration at the hole, influencing initiation and propagation. In the absence of a hole, cracks exhibit a zig-zag pattern near the loading point, while with a hole, they concentrate around it. Elastic region length varies with the pre-crack-to-hole distance, indicating accelerated crack propagation in shorter distances. This study underscores the direct influence of hole size on load values, emphasizing its pivotal role in determining composite mechanical properties. This research provides valuable insights into hole characteristics’ interplay with delamination behavior in carbon fiber-reinforced composites, essential for optimizing aerospace component design and structural integrity.
这项研究解决了当前航空复合材料组装技术的局限性,这些技术往往受到认证挑战的限制。为了增强粘合复合材料组件的性能,经常会引入开孔,从而导致复合材料层压板中一种突出的失效模式--分层的脆弱性增加。本研究的重点是观察在不同距离和孔径条件下,开孔对复合材料模式 II 行为的影响。结果表明,孔径大小会影响不同的载荷-位移曲线,较短的距离会加速裂纹扩展,表现为弹性区域减少和载荷值降低。对试样外观和裂纹模式的分析突出表明,应力集中在孔处,影响了裂纹的产生和扩展。在无孔的情况下,裂纹在加载点附近呈 "之 "字形分布,而在有孔的情况下,裂纹则集中在加载点周围。弹性区域的长度随裂纹前到孔的距离而变化,表明裂纹在较短的距离内加速扩展。这项研究强调了孔尺寸对载荷值的直接影响,突出了孔尺寸在决定复合材料机械性能方面的关键作用。这项研究为了解碳纤维增强复合材料中孔的特性与分层行为之间的相互作用提供了宝贵的见解,对于优化航空航天部件的设计和结构完整性至关重要。
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引用次数: 0
Synthesis of PANIHCl/ZnO conductive composite by in-situ polymerization and for humidity sensing application 通过原位聚合合成 PANIHCl/ZnO 导电复合材料并将其用于湿度传感应用
Pub Date : 2024-03-30 DOI: 10.1142/s0217984924410082
Cheng-Ho Chen, Jian-Fu Wu, Hung-Mao Lin
In this study, the conductive polyaniline doped by hydrochloric acid (PANIHCl)/zinc oxide (PANIHCl/ZnO) conductive composite was synthesized by in-situ polymerization. The conductive PANIHCl solution or PANIHCl/ZnO conductive composite solution was coated on an interdigital electrode (IDE) by drop coating to make a humidity sensor. The synthesis process, chemical structure, surface morphology, and humidity sensing characteristics of PANIHCl and PANIHCl/ZnO conductive composite were investigated. Field emission scanning electron microscope (FE-SEM) images suggested that the surface morphology of the PANIHCl/ZnO conductive composite is fibrous or rod-shaped, with a diameter of about 100 nm. The sensing responses of PANIHCl and PANIHCl/ZnO were 40% and 87%, respectively. The humidity sensing response of PANIHCl/ZnO as the sensing material was more than twice that of PANIHCl as the sensing material. The response time (Tres) is 13 s, and the recovery time (Trec) is 171 s. Research results showed that adding ZnO to PANIHCl can effectively improve the response of the sensor to humidity detection. Therefore, using PANIHCl/ZnO conductive composite as a sensing material will have great potential for application in humidity or other gas sensing devices.
本研究采用原位聚合法合成了掺盐酸(PANIHCl)/氧化锌(PANIHCl/ZnO)导电复合材料。将导电的 PANIHCl 溶液或 PANIHCl/ZnO 导电复合溶液通过滴涂的方法涂覆在数字间电极 (IDE) 上,制成了湿度传感器。研究了 PANIHCl 和 PANIHCl/ZnO 导电复合材料的合成过程、化学结构、表面形貌和湿度传感特性。场发射扫描电子显微镜(FE-SEM)图像表明,PANIHCl/ZnO导电复合材料的表面形态为纤维状或棒状,直径约为100 nm。PANIHCl 和 PANIHCl/ZnO 的传感响应分别为 40% 和 87%。PANIHCl/ZnO 作为传感材料的湿度传感响应是 PANIHCl 作为传感材料的两倍多。研究结果表明,在 PANIHCl 中添加氧化锌可有效提高传感器的湿度检测响应。因此,使用 PANIHCl/ZnO 导电复合材料作为传感材料在湿度或其他气体传感设备中的应用将大有可为。
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引用次数: 0
Temperature-dependent pinned joint tensile behavior and failure analysis of CF/PEKK composites CF/PEKK 复合材料随温度变化的销钉连接拉伸行为和失效分析
Pub Date : 2024-03-30 DOI: 10.1142/s0217984924410112
Xiaoqi Li, Sanjay Kumar, Dong-Wook Hwang, Yun-Hae Kim
The pinned joint tensile properties and failure behaviors of carbon-fiber-reinforced polyetherketoneketone (CF/PEKK) composites are sensitive to application temperatures. Herein, this study investigated the temperature-dependent mechanical behavior of CF/PEKK composites in a pinned joint configuration, emphasizing the impact on tensile behavior and bearing strength. Utilizing Solvay’s CF/PEKK prepreg with a quasi-isotropic stacking sequence, tensile tests were conducted at [Formula: see text]C and 230∘C. At [Formula: see text]C, increased load-pin displacement stiffness was observed, attributed to reduced polymer chain mobility, leading to increased peak load and concentrated bearing area around the pin contact region. Conversely, at 230∘C, a substantial reduction in stiffness and peak load was evident, emphasizing the severe deterioration of pin-load strength. Fracture analysis revealed distinct failure modes at different temperatures, highlighting localized compressive failure at [Formula: see text]C and severe permanent bearing failure at 230∘C. Understanding these temperature-dependent behaviors is critical for optimizing CF/PEKK composite applications in diverse industrial settings, providing insights for enhanced performance and reliability. The findings offer valuable information on the material’s behavior under extreme temperature conditions, contributing to the design and application of CF/PEKK composites in various industrial scenarios.
碳纤维增强聚醚酮酮(CF/PEKK)复合材料的销钉连接拉伸性能和失效行为对应用温度非常敏感。在此,本研究调查了销钉连接配置中 CF/PEKK 复合材料随温度变化的机械性能,重点研究了其对拉伸性能和承载强度的影响。利用索尔维的 CF/PEKK 预浸料和准各向同性堆叠顺序,在 [式中:见正文] C 和 230∘C 下进行了拉伸试验。在[式中:见正文]C 下,观察到载荷-插针位移刚度增加,这归因于聚合物链流动性降低,导致峰值载荷增加,插针接触区域周围的承载面积集中。相反,在 230∘C时,刚度和峰值载荷明显降低,突出表明销钉负载强度严重下降。断裂分析显示了不同温度下的不同失效模式,突出显示了在 [公式:见正文]C 时的局部压缩失效和在 230∘C 时的严重永久轴承失效。了解这些随温度变化的行为对于优化 CF/PEKK 复合材料在不同工业环境中的应用至关重要,可为提高性能和可靠性提供启示。研究结果为材料在极端温度条件下的行为提供了宝贵的信息,有助于 CF/PEKK 复合材料在各种工业场景中的设计和应用。
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引用次数: 0
Comparison of pin-loaded tensile behavior and failure behavior of thermosetting and thermoplastic composite 热固性和热塑性复合材料的针负载拉伸行为和破坏行为比较
Pub Date : 2024-03-30 DOI: 10.1142/s0217984924410148
Dong-Wook Hwang, Sanjay Kumar, Su-Min Jo, Xiaoqi Li, Yun-Hae Kim
This study investigated the pin-loaded tensile behavior, bearing strength, and failure mechanisms of thermosetting and thermoplastic composite materials. Specifically, the investigation focuses on carbon-fiber-reinforced polyetherketoneketone (CF/PEKK) and carbon-fiber-reinforced epoxy (CF/EPOXY). Notably, CF/PEKK exhibited a shear-out failure mode, surpassing CF/EPOXY with a 56.4% higher peak load. The absence of crack propagation in CF/EPOXY, attributed to the presence of yarn at a 90∘ angle, leads to bearing failure. In contrast, CF/PEKK demonstrates a significantly higher bearing strength, approximately 150[Formula: see text]MPa greater than CF/EPOXY. This discrepancy in performance suggests that CF/PEKK holds promise as a structural material for applications involving the fastening of thermoplastic composites, presenting a viable alternative to traditional thermosetting composites. The findings imply that the unique failure mechanisms and enhanced mechanical properties of CF/PEKK make it a compelling candidate for use in scenarios where thermosetting composites are conventionally applied. This study contributes valuable insights into the potential advancements and applications of thermoplastic composites in structural materials, paving the way for optimized and innovative engineering solutions.
本研究调查了热固性和热塑性复合材料的针负载拉伸行为、承载强度和失效机理。具体来说,研究重点是碳纤维增强聚醚酮酮(CF/PEKK)和碳纤维增强环氧树脂(CF/EPOXY)。值得注意的是,CF/PEKK 表现出一种剪切破坏模式,其峰值载荷比 CF/EPOXY 高出 56.4%。CF/EPOXY 中没有裂纹扩展,这是因为纱线呈 90∘ 角,导致轴承失效。相比之下,CF/PEKK 的轴承强度明显更高,比 CF/EPOXY 高出约 150[计算公式:见正文]兆帕。这种性能差异表明,CF/PEKK 有希望成为热塑性复合材料紧固应用的结构材料,成为传统热固性复合材料的可行替代品。研究结果表明,CF/PEKK 具有独特的失效机理和更强的机械性能,使其成为传统热固性复合材料应用领域的理想候选材料。这项研究为热塑性复合材料在结构材料中的潜在进步和应用提供了宝贵的见解,为优化和创新工程解决方案铺平了道路。
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引用次数: 0
Mechanical properties of CoCrFeNiV high-entropy alloys with different Cu element contents under different strain rates 不同应变速率下不同铜元素含量的 CoCrFeNiV 高熵合金的力学性能
Pub Date : 2024-03-30 DOI: 10.1142/s021798492441001x
Chi-Fan Liu, Shih-Chen Shi, Wei-Ming Huang, Tao-Hsing Chen
In this study, the alloys used contained Co, Cr, Fe, Ni, and V as the primary elements, while 6%–10% Cu was used as the added element. The high-entropy alloys (HEAs) were made in an electric-arc vacuum furnace from which specimens in the form of cylinders with a 5-mm diameter and 5-mm length were fabricated. An XRD analysis revealed that alloys with 6% and 8% Cu had a single-phase FCC structure, and a weak BCC peak only appeared in the (110) direction in alloys with 10% Cu. A universal testing machine was used for testing at the strain rates of [Formula: see text][Formula: see text]s[Formula: see text], [Formula: see text][Formula: see text]s[Formula: see text], and [Formula: see text][Formula: see text]s[Formula: see text], and the high strain rate was tested using a split Hopkinson pressure bar (SHPB) under strain at 3000[Formula: see text]s[Formula: see text], 4000[Formula: see text]s[Formula: see text], and 5000[Formula: see text]s[Formula: see text], respectively. The specimens did not fracture during the quasi-static compression and dynamic impact tests, which displayed better ductility. The surface of the three alloys had extensive dendrites and non-equiaxed crystal structures. In an EDS composition analysis, the Cr and V elements were more frequently observed in the intergranular region than in the interdendritic region.
在这项研究中,所用合金的主要元素包括钴、铬、铁、镍和钒,添加元素为 6%-10%的铜。高熵合金(HEA)是在电弧真空炉中制成的,并从中制作出直径为 5 毫米、长度为 5 毫米的圆柱体试样。XRD 分析表明,含 6% 和 8% 铜的合金具有单相 FCC 结构,而含 10% 铜的合金仅在 (110) 方向出现了微弱的 BCC 峰。使用万能试验机以[式:见正文][式:见正文]s[式:见正文]、[式:见正文][式:见正文]s[式:见正文]和[式:见正文]s[式:见正文]的应变速率进行测试:见正文],而高应变率则使用分体式霍普金森压力棒(SHPB)分别在 3000[式:见正文][式:见正文]、4000[式:见正文][式:见正文]和 5000[式:见正文][式:见正文]的应变下进行测试。在准静态压缩和动态冲击试验中,试样均未发生断裂,显示出较好的延展性。这三种合金的表面具有广泛的枝晶和非等轴晶结构。在 EDS 成分分析中,晶间区比树枝状晶间区更常观察到铬和钒元素。
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引用次数: 0
An investigation of structural, thermo-physical, and photoelectric properties of glassy As2Se3–Tl2Te3 alloys 玻璃状 As2Se3-Tl2Te3 合金的结构、热物理和光电特性研究
Pub Date : 2024-02-26 DOI: 10.1142/s0217984924502324
I. I. Aliyev, R. M. Rzayev, Kh. M. Hashimov, C. Ahmedova, T. Naghiyev
Glass formation and the nature of the chemical interaction in the As2Se3–Tl2Te3 system were studied by differential-thermal (DTA), X-ray phase (XRD), microstructural (MSA) analysis. Based on the performed experiments T-x phase diagram is constructed. It is established that the phase diagram of the system is a partially quasi-binary section of the quaternary system Tl,As//Se,Te. Eutectic equilibrium and peritectic transformation process occur in the system. When the ratio of As2Se3 and Tl2Te3 components is 1:1, a new quaternary compound Tl2As2Se3Te3 is formed. It has been established that the Tl2As2Se3Te3 compound melts with an open maximum at 568[Formula: see text]K and crystallizes in a hexagonal symmetry. In the system, under normal cooling, the glass formation area reaches −80[Formula: see text]mol.% Tl2Te3, and in the mode of quenching in liquid nitrogen up to −100[Formula: see text]mol.% T12Te3. The photoelectric properties of glassy alloys (As2Se[Formula: see text](Tl2Te[Formula: see text] ([Formula: see text]; 0.3; 0.05) have been studied. Depending on the Tl2Te3 concentration of the system, the observed changes in the photoelectric properties and calculated parameters are presented.
通过差热(DTA)、X 射线相(XRD)和微结构(MSA)分析,研究了 As2Se3-Tl2Te3 体系中玻璃的形成和化学作用的性质。根据所做实验构建了 T-x 相图。该体系的相图是四元体系 Tl、As//Se、Te 的部分准二元截面。体系中存在共晶平衡和包晶转变过程。当 As2Se3 和 Tl2Te3 的比例为 1:1 时,会形成新的四元化合物 Tl2As2Se3Te3。已经证实,Tl2As2Se3Te3 化合物在 568[式:见正文]K熔化,并形成六方对称晶体。在该体系中,正常冷却时,玻璃形成面积达到-80[式:见正文]摩尔%的 Tl2Te3,而在液氮淬火模式下,玻璃形成面积达到-100[式:见正文]摩尔%的 T12Te3。研究了玻璃合金(As2Se[式:见正文](Tl2Te[式:见正文]([式:见正文];0.3;0.05)的光电特性。根据体系中 Tl2Te3 浓度的不同,观察到的光电特性变化和计算参数也不同。
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引用次数: 0
Gravitational expansion and collapse of anisotropic cylindrical source with cosmological constant 具有宇宙常数的各向异性圆柱源的引力膨胀和坍缩
Pub Date : 2024-02-26 DOI: 10.1142/s0217984924502476
Junaid Khalid, S. Z. Abbas, H. H. Shah, J. El Ghoul, Mayeen Uddin Khandaker
This work presents an anisotropic cylindrical source’s gravitational expansion and collapse with the cosmological constant. For this purpose, we use the cylindrical symmetric metric and energy–momentum tensor to achieve Einstein’s field equation component. The mass function is also used to assess the state of the trapped surface. The parametric form of the auxiliary solution is discovered. These presumptions enable us to examine the parameter range at the positive and negative expansion scalar transitions. The generated solution produces expanding and collapsing solutions correspondingly for positive and negative parameter values. A dimensionless measure of anisotropy, pressures and energy density are utilized as physical quantities. The included parameters are shown graphically. The cosmological constant has impacted both the expansion and collapse solutions to phenomena.
本研究提出了各向异性圆柱源的引力膨胀和坍缩与宇宙学常数的关系。为此,我们使用圆柱对称度量和能动张量来实现爱因斯坦场方程分量。质量函数也用于评估被困表面的状态。我们发现了辅助解的参数形式。这些假设使我们能够检验正负膨胀标量转换时的参数范围。生成的解在正负参数值下会产生相应的膨胀和塌缩解。各向异性、压力和能量密度的无量纲测量值被用作物理量。包含的参数以图形显示。宇宙常数对膨胀和坍缩现象的解都有影响。
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引用次数: 0
期刊
Modern Physics Letters B
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