This study investigates the fracture mechanics of notched P3HB specimens subjected to monotonic tensile loading under different average strain rates, from 0.14·10−3 s−1 to 14·10−3 s−1, and tested 24, 168, and 720 h after manufacturing to capture changes due to natural aging. Flat specimens were weakened with double-sided V-notches of various root radii to analyse stress concentration effects. Force response, elongation, and fracture surface morphology were examined to identify mechanisms governing crack initiation and propagation. Natural aging increased Young's modulus by 15–20 % and reduced elongation at break by 30–40 %, indicating embrittlement over time. In contrast, higher strain rates promoted up to 25 % greater maximum force and elongation to fracture, likely due to strain-induced mesophase formation. In all cases, fracture initiated at the notch root, with a larger notch radius reducing stress concentration and delaying crack initiation. A progressive shift toward brittle fracture behaviour was observed with aging duration and strain rate. The predictive capability of two classical brittle-fracture criteria-Maximum Tangential Stress (MTS) and Mean Stress (MS) – was evaluated. Significant discrepancies between predicted and experimental critical loads were found, with errors of approximately 49–56 %. These results demonstrate that existing criteria do not adequately capture local deformation mechanisms in P3HB. Reliable fracture prediction therefore requires models incorporating evolving plastic strain fields and experimentally derived hardening behaviour, providing a foundation for improved failure criteria for aging-sensitive polymers. When critical parameters were calibrated using experimental data within the Theory of Critical Distances framework, the prediction error was reduced to below 7 % (MTS), demonstrating that the proposed approach provides quantitative predictive capability for notched P3HB specimens across different aging times and strain rates.
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