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Structure of the Hydrothermal System of Thermal Fields Inferred from Geological-Geophysical Modeling: A Case Study of the Kambalny Volcanic Ridge (Kamchatka) 地质地球物理模型推断的热田热液系统结构:坎巴尔尼火山脊(堪察加半岛)案例研究
Pub Date : 2024-04-19 DOI: 10.2113/rgg20234608
I. Nuzhdaev, S. Rychagov, S. Feofilaktov, Y. Bukatov
––Based on integrated structural and geophysical studies and generalization of geophysical, hydrogeological, mineralogical, geochemical and other data, it is shown that the southern cluster of thermal fields of the Kambalny volcanic ridge (South Kamchatka) is included in the modern hydrothermal system. New data on the structure of the steam hydrotherm discharge area investigated to a depth of about 300 m have been obtained. The structural and hydrodynamic connection between two thermal fields from this group has been established. The Kambalny Ridge geothermal system embracing all major clusters of thermal fields is assumed to have a single deep-seated source of heat supply.
--根据对结构和地球物理的综合研究以及对地球物理、水文地质、矿物学、地球化学和其他数据的归纳,表明坎巴尔尼火山脊(南堪察加半岛)南部的热田群包括在现代热液系统中。研究还获得了深度约为 300 米的蒸汽热液排放区结构的新数据。该组中两个热区之间的结构和流体力学联系已经确定。康巴尔内山脊地热系统包括所有主要的热田群,被假定为只有一个深层热源。
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引用次数: 0
Behavior of Gold Nanoparticles at the Interphase Boundary of Quartz–Selenide Copper and Iron at a Temperature of 450 °C and Different Selenium Activity 在 450 °C 温度和不同硒活性条件下,金纳米粒子在石英-硒化铜-铁相间边界的行为
Pub Date : 2024-04-12 DOI: 10.2113/rgg20244691
V.V. Akimov, D. Babkin, O. Belozerova
—In this work, based on structural and phase analysis data, we consider the behavior of Au nanoparticles (NP) during the formation of interphase boundaries between quartz and copper and iron selenides upon annealing at 450 °C and different selenium activities: lgfSe2=−2.4 with a melted selenium buffer and lgfSe2=−3.15 according to the indications of the indicator mineral mixture γ–Fe1–xSe and δ–Fe1–xSe. In two series of experiments, contrasting textural features (nano- and microstates) of the initial metal phases were used, which made it possible to construct 2D and 3D models of interphase boundaries. In the first case, thin layers of gold NPs (~30 nm thick), iron (~50 nm thick), and copper (~50 nm thick) were deposited onto quartz crystals less than 40 μm in size by magnetron sputtering, i.e., all metals were in a nanosized state. In the second case, iron, copper, and selenium (in eskebornite stoichiometry – CuFeSe2) were introduced into the system in the form of micron-sized powder materials (1–10 microns). Gold still remained in the form of NPs on the quartz surface. The thermal annealing products were studied by X-ray diffraction (XRD) and scanning electron microscopy (SEM) analyses, and X-ray photoelectron spectroscopy (XPS). The study showed that, regardless of the activity of selenium, annealing of Au NPs leads to partial enlargement of particles (up to submicron sizes) based on the self-assembly mechanism (the size distribution of Au particles corresponds to a lognormal law with a maximum shifted towards smaller sizes), and gold remains in the metallic state. The 2D model of the interphase boundary is a mineral mixture of copper selenides (Cu2Se), iron (γ–Fe1–xSe) and islands of submicron gold particles formed on the surface of quartz. The 3D model of the interphase boundary is characterized by the fact that Au particles are concentrated mainly in eskebornite, and not on the quartz surface. Moreover, NPs are localized in the pores of mesoporous eskebornite, and submicron particles with a size of ~ 200 nm or more are displaced to the surface of eskebornite particles. Based on the data obtained, typomorphic features of the presence of Au NPs in the ore-forming processes of the formation and development of gold ore deposits are formulated.
-在这项工作中,我们基于结构和相分析数据,考虑了在 450 °C 退火和不同硒活度条件下石英与铜硒化物和铁硒化物之间形成相间边界过程中金纳米粒子(NP)的行为:熔融硒缓冲液 lgfSe2=-2.4 和根据指示矿物混合物 γ-Fe1-xSe 和 δ-Fe1-xSe 的指示 lgfSe2=-3.15。在两个系列的实验中,使用了初始金属相的对比纹理特征(纳米和微观状态),从而构建了相间边界的二维和三维模型。在第一种情况下,通过磁控溅射将金(约 30 纳米厚)、铁(约 50 纳米厚)和铜(约 50 纳米厚)的薄层沉积到尺寸小于 40 微米的石英晶体上,即所有金属都处于纳米状态。在第二种情况中,铁、铜和硒(按照埃斯基邦尼特的化学计量法 - CuFeSe2)以微米级粉末材料(1-10 微米)的形式被引入到系统中。金仍然以 NPs 的形式留在石英表面。通过 X 射线衍射 (XRD) 和扫描电子显微镜 (SEM) 分析以及 X 射线光电子能谱 (XPS) 对热退火产物进行了研究。研究表明,无论硒的活性如何,基于自组装机制,金纳米粒子的退火都会导致粒子的部分增大(达到亚微米级)(金粒子的尺寸分布符合对数正态分布规律,最大值向更小尺寸移动),而金则保持金属态。相间边界的二维模型是在石英表面形成的铜硒化物(Cu2Se)、铁(γ-Fe1-xSe)和亚微米金颗粒岛屿的矿物混合物。相间边界三维模型的特点是金颗粒主要集中在埃斯基伯恩岩中,而不是石英表面。此外,NPs 定位于介孔埃斯基波恩石的孔隙中,尺寸约为 200 nm 或更大的亚微米颗粒被移至埃斯基波恩石颗粒的表面。根据所获得的数据,提出了在金矿床形成和发展的成矿过程中存在 Au NPs 的典型特征。
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引用次数: 0
Localization of High-Titanium Dolerites in Kimberlite Fields: Possible Causes and a New Criterion for Kimberlite Search 金伯利岩田中高钛辉长岩的定位:金伯利岩搜索的可能原因和新标准
Pub Date : 2024-04-12 DOI: 10.2113/rgg20244680
М.D. Тomshin, N. Pokhilenko, S. Gogoleva, A.L. Zemnukhov
––The generalized chemical composition data on the studied dolerites from the Vilyui–Markha dike swarm (Vilyui paleorift) allowed detecting geochemically anomalous areas among them. It has been found that percentage of TiO2 and a number of heavy rare-earth elements (Th, Ta, Hf, Y, Nd) in the dolerites of dikes located within the kimberlite fields show almost twofold increase compared to the normal content for these elements in the Vilyui–Markha dolerites. Similar behavior of these elements is also observed in the dolerite dikes near the Kuoika kimberlite field (the Molodo dike swarm, Olenek paleorift). It is inferred that there is a connection between the increase in abundances of titanium and rare-earth elements in the dolerites and that the latter occur within the lithosphere blocks hosting kimberlite fields. The areas of lithospheric mantle roots linked with the formation of proto-kimberlites may have had bearing on the composition of tholeiite melt both in the processes of its generation and during its ascent to the Earth’s surface, which led to its local enrichment in titanium and a number of other elements. While the processes of the alignment of the geochemical composition between the high-titanium basites and the rest of the melt beyond the contours of the lithospheric blocks with kimberlite fields were weakly pronounced, they were responsible for appearance of zones enriched in titanium. Kimberlite fields that formed before or after basite magmas intrusion overlap with placements of high-titanium dolerite dikes. Thus, high-titanium dolerites in dike swarms (belts) can be used as one of the criteria for kimberlite searches. In view of the above, two new potential zones (Tenkelyakh and Kyulenke areas) for kimberlite exploration have been identified within the Vilyui–Markha dike swarm.
--所研究的维柳伊-马尔卡辉长岩群(维柳伊古漂移)中的辉长岩的一般化学成分数据有助于发现其中的地球化学异常区域。研究发现,位于金伯利岩岩场内的辉长岩中二氧化钛和一些重稀土元素(Th、Ta、Hf、Y、Nd)的含量与维柳伊-马尔卡辉长岩中这些元素的正常含量相比几乎增加了两倍。在 Kuoika 金伯利岩场附近的辉长岩中(奥利尼克古漂移区的莫洛多辉长岩群)也观察到了这些元素的类似情况。据此推断,辉绿岩中钛元素和稀土元素丰度的增加与后者出现在容纳金伯利岩场的岩石圈区块中有关。与原金伯利岩形成有关的岩石圈地幔根区域可能在托勒密岩熔体的生成过程中以及在其上升到地球表面的过程中对其成分产生了影响,从而导致其钛和其他一些元素在局部富集。虽然高钛基性岩和岩石圈块轮廓线以外的熔体与金伯利岩场之间的地球化学成分排列过程并不明显,但它们是出现钛元素富集区的原因。在玄武岩岩浆侵入之前或之后形成的金伯利岩场与高钛辉长岩岩峰的位置重叠。因此,尖晶石群(带)中的高钛辉长岩可作为寻找金伯利岩的标准之一。有鉴于此,在 Vilyui-Markha 长堤群中确定了两个新的潜在金伯利岩勘探区(Tenkelyakh 和 Kyulenke 地区)。
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引用次数: 0
Bio-, Lithostratigraphic and Geochemical Markers of Global Events in the Upper Devonian of the South of Western Siberia and their Value for Inter-regional Correlations 西西伯利亚南部上泥盆统全球事件的生物、岩石地层和地球化学标志及其对区域间相关性的价值
Pub Date : 2024-04-11 DOI: 10.2113/rgg20244634
O. Izokh, N. Izokh, B.M. Popov, S. V. Saraev
—Upper Devonian carbonate reef complexes have been studied on the territory of the Kolyvan-Tom’ Folded Area in sections in the right bank of Tom’ River. Facies analysis of the exposed part of the reef complex indicates the predominance of fore-reef and continental margin depositional environments of a tectonically active margin. The identified conodont associations are represented by cosmopolitan representatives of the genera Ancyrodella, Ancyrolepis, Icriodus, Mehlina, Palmatolepis, Polygnathus and “Polylophodonta” suggesting a correlation with the punctata–jamieae, rhenana–linguiformis, triangularis and Lower crepida conodont zones. The largest conodont diversity occurs at the triangularis/crepida boundary. Biofacies analysis of ostracod distribution has led to identification of characteristic associations and their restriction to certain parts of the palaeobasin. Substage boundaries yielded ostracods with both smooth and ornamented shells. In the lower part of the substages, smooth forms predominate, whereas the middle and upper parts of the substages are characterised by forms with tuberculate and reticulated surface. Hollinella valentinae Beds were traced in the Upper Frasnian Solomino Formation, and Acratia granuliformis Beds were traced in the Lower Famennian Kosoy Utyos and lower Mitikha members. Isotope geochemistry of the Upper Devonian sections of the south of Western Siberia reveals Frasnian global events – the Middlesex/punctata and the Upper Kellwasser, their stratigraphic position confirmed by palaeontological data, as well as by the globally expressed negative carbon isotope anomaly. These boundaries are marked by changes in depositional regime reflecting sea-level eustatic fluctuations, which are complemented with faunal changes.
-在科利万-托姆褶皱区的领土上,对托姆河右岸的上泥盆纪碳酸盐岩礁石群进行了分段研究。对礁石群暴露部分的地貌分析表明,构造活跃的边缘地区的前礁和大陆边缘沉积环境占主导地位。已确定的锥齿动物群由 Ancyrodella 属、Ancyrolepis 属、Icriodus 属、Mehlina 属、Palmatolepis 属、Polygnathus 属和 "Polylophodonta "属的世界性代表组成,表明与 punctata-jamieae、henana-linguiformis、triangularis 和 Lower crepida 锥齿动物区相关。三角龙/绉褶龙界线处的锥齿动物种类最为丰富。通过对浮游动物分布的生物构成进行分析,可以确定其特征组合,并将其局限于古盆地的某些部分。在亚阶段的分界线上,浮游动物既有光滑的贝壳,也有装饰性的贝壳。在亚层的下部,光滑的贝壳占多数,而在亚层的中部和上部,贝壳表面有瘤和网纹。在上弗拉斯年索洛米诺地层中发现了 Hollinella valentinae 床,在下法门年的 Kosoy Utyos 和下米提哈岩层中发现了 Acratia granuliformis 床。西西伯利亚南部上泥盆统地段的同位素地球化学研究揭示了弗拉斯年的全球性事件--米德尔塞克斯/蓬塔和上凯尔瓦瑟,古生物学数据以及全球性的负碳同位素异常证实了它们的地层位置。这些边界以沉积体系的变化为标志,反映了海平面的震荡起伏,并与动物群的变化相辅相成。
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引用次数: 0
Biomarker Hydrocarbons and Carbon Isotopes of Individual n-Alkanes in Paraffin Oils and Bitumens of the Middle Devonian–Lower Frasnian Terrigenous Complex of the Timan–Pechora Basin 铁曼-伯朝拉盆地中泥盆纪-下弗拉斯年土著复合体石蜡油和沥青中的生物标志碳氢化合物和单个正烷烃的碳同位素
Pub Date : 2024-04-11 DOI: 10.2113/rgg20234674
D. Bushnev, A. Ilchenko, L. V. Ogdanets, N. S. Burdel’naya
––The objects of study were bitumens of sedimentary rocks and paraffin oils of the Middle Devonian–lower Frasnian terrigenous complex of the Timan–Pechora basin. We studied the composition of biomarker hydrocarbons and the carbon isotope composition of individual n-alkanes of bitumens from the cores of the wells of the Omra–Lyzha saddle. The results were compared with similar data on the composition of paraffin oils from the south of the Pechora–Kozhva megaswell. The generation potential and thermal maturity of organic matter were studied by the Rock-Eval pyrolysis method. The maturity of organic matter in the rocks of the studied complex in the Omra–Lyzha saddle and the Pechora–Kozhva megaswell corresponds to the oil window. Data on the carbon isotopy of n-alkanes and on the composition of biomarker hydrocarbons do not contradict the possible genetic relationship between paraffin oils and the organic matter of the host sedimentary complex. Both the studied paraffin oils and the rock bitumens contain early eluting rearranged hopanes atypical of oils of other petroliferous complexes and show high contents of n-alkanes relative to iso-alkanes and polycyclic biomarkers. The content of 13C tends to decrease with an increase in the number of carbon atoms in the n-alkane molecule in both oils and bitumen rocks.
--研究对象是蒂曼-佩乔拉盆地中泥盆世-下弗拉斯年地层复合体的沉积岩沥青质和石蜡油。我们研究了奥姆拉-利扎鞍部井芯中沥青质的生物标志烃组成和单个正构烷烃的碳同位素组成。研究结果与佩乔拉-科日瓦巨型油井南部石蜡油成分的类似数据进行了比较。采用岩石-评价热解方法研究了有机物的生成潜力和热成熟度。所研究的奥姆拉-利扎鞍部和佩乔拉-科日瓦巨型油井复合体岩石中有机物的成熟度与石油窗口相对应。关于正构烷烃碳同位素和生物标志烃组成的数据与石蜡油和主沉积岩群有机质之间可能存在的遗传关系并不矛盾。所研究的石蜡油和岩石沥青都含有早期洗脱的重排烷烃,这与其他含石油复合物的油类不同,而且正构烷烃的含量高于异构烷烃和多环生物标志物。在石油和沥青岩中,随着正构烷烃分子中碳原子数量的增加,13C 含量呈下降趋势。
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引用次数: 0
Influence of Magnetic Polarization on Diagrams of Inductive and Electromagnetic Logs 磁极化对电感和电磁测井曲线图的影响
Pub Date : 2024-04-09 DOI: 10.2113/rgg20234671
E.I. Shtanko, D.A. Arkhipov, M. Epov
––We present the results of the study of the effect of induced magnetic polarization of clay beds under the influence of an external harmonic electromagnetic field (frequencies 70 and 875 kHz). A two-stage numerical modeling procedure is proposed. At the first stage we determine the effective relative magnetic permeability of a synthetic sample with inclusions of clay particles. In this case a 3D heterogeneous mesh sample is generated. Then we numerically model a spatial distribution of an electric field. The electromotive force (EMF) induced in the measuring coil is calculated from this distribution. Relative magnetic permeability is determined by comparison with EMF of homogeneous samples with different values of magnetic permeability. It has been found that during the electric field excitation by an alternating current coil, the effect of induced magnetic polarization appears in the sample with clay particles. Its manifestation is that the effective magnetic permeability becomes complex. At the second stage we calculate the EMF diagram of the three-coil logging probe in the macro-model ‘clay cap – reservoir’. Magnetic permeability of the clay cap is given by a complex value. In the generated logs, extremes appear in the vicinity of the bottom of the clay cap; they do not correspond to the distribution of electrical conductivity and magnetic permeability in the given model. They can be incorrectly interpreted when analyzing real logs into individual formations. Numerical modeling at all stages is performed by the Vector Finite Element Method on a consistent adaptive tetrahedral partition and the first-order Webb vector basis.
--我们介绍了在外部谐波电磁场(频率为 70 和 875 kHz)影响下粘土层诱导磁极化效应的研究结果。我们提出了一个两阶段的数值建模程序。在第一阶段,我们确定了含有粘土颗粒夹杂物的合成样品的有效相对磁导率。在这种情况下,会生成一个三维异质网格样本。然后,我们对电场的空间分布进行数值建模。测量线圈中感应的电动势(EMF)就是根据这一分布计算出来的。通过与具有不同磁导率值的均质样品的 EMF 进行比较,确定相对磁导率。研究发现,在交流线圈的电场激励下,含有粘土颗粒的样品会出现感应磁极化效应。其表现为有效磁导率变得复杂。第二阶段,我们在宏观模型 "粘土帽-储层 "中计算三线圈测井探头的电磁场图。粘土盖的磁导率由一个复杂值给出。在生成的测井曲线中,粘土帽底部附近会出现极端值;这些极端值与给定模型中的导电率和磁导率分布不符。在分析各个地层的实际测井时,可能会对它们进行错误的解释。所有阶段的数值建模都是通过矢量有限元法在一致的自适应四面体分区和一阶韦伯矢量基础上进行的。
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引用次数: 0
Biogeography and Paleogeography of Taxonomic Diversity of Coniacian–Santonian Dinocysts of the Northern Hemisphere 北半球康尼阿世-山口组恐龙囊分类多样性的生物地理学和古地理学
Pub Date : 2024-04-09 DOI: 10.2113/rgg20244717
N. Lebedeva
––Dinocyst assemblages are subjected to taxonomic typification based on a qualitative and quantitative assessment of their generic composition for the Northern Hemisphere during the Coniacian–Santonian time in order to identify correlation taxa. The typification is carried out using a cluster analysis according to the Jacquard calculation model (BioDiversity Professional, 1997). Three types of dinocyst assemblages have been identified in the Coniacian. As compared to the Turonian, the relatively cold-water West Siberian basin is characterized by a decrease in the number of cosmopolitan taxa and an increase in species endemism. The only taxa identified at present are those allowing for intrabasin correlations. Three types of dinocyst assemblages have also been established for the Santonian. Free interbasin connections in the Northern Hemisphere contribute to the equalization of the generic composition between the three identified types and to the identification of characteristic taxa that allow for interregional correlation.
--根据对北半球科尼阿克-山童时期的类群组成进行的定性和定量评估,对丁囊虫集合体进行了分类分型,以确定相关类群。根据 Jacquard 计算模型(BioDiversity Professional,1997 年),采用聚类分析法进行分类。在科尼阿克纪发现了三种类型的恐龙囊集合体。与都龙纪相比,相对冷水的西西伯利亚盆地的特点是世界性类群数量减少,物种地方性增加。目前唯一确定的类群是可以进行流域内相关性研究的类群。此外,还为山顿纪确定了三种类型的二叠体组合。北半球自由的流域间联系有助于使已确定的三种类型之间的类群组成趋于平衡,并有助于确定可进行区域间相关性研究的特征类群。
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引用次数: 0
New Oil and Gas Plays in the Cis-Urals 顺式-乌拉尔地区的新油气藏
Pub Date : 2024-04-09 DOI: 10.2113/rgg20234652
K.O. Sobornov
––The search for oil and gas in folded zones and in the foredeep of the cis-Uralian region for many decades was reduced to testing of easy-to-find closures and reefs located at shallow depths. Many important discoveries were made as a result, but the overall performance of the work remained relatively low. On the one hand, this was due to the poor subsurface imaging of the data for reliable preparation of structures in regions of complex structure. On the other hand, the peculiarities of the development of oil and gas systems in these regions were ignored during the assessment of prospecting sites. In comparison with traditional production hubs centers in the platform regions of the Volga–Ural and Timan–Pechora basins, this distinguishing feature was caused by a thicker sedimentary cover, the variability of its composition and structure, and multiple phases of structural development. Many failures were due to the formation of traps after the passage of the primary migration flow of oil and gas, low capacity of reservoirs, and their fracturing by faults. As shown by interpretation of new geodata using modern knowledge about the oil and gas potential of regions of similar structure, the cis-Uralian region contains poorly studied oil and gas accumulation zones that can contain large deposits. These include blind thrust regions, subsalt traps in development zones of dislocated diapirs, and also stratigraphic and combined traps associated with unconformities and facies changes. The utmost attention is paid to new prospecting objects in the Timan–Pechora basin in which the thickness of the Paleozoic cover has increased. The preparation of new promising objects in these zones has become possible due to new knowledge and better geophysical data.
--几十年来,在顺乌拉尔地区的褶皱带和前深海中寻找石油和天然气的工作仅限于对浅海中容易发现的闭合区和暗礁进行测试。因此,虽然发现了许多重要的油气资源,但总体工作成效仍然相对较低。一方面,这是由于地下成像数据不佳,无法在结构复杂的区域可靠地准备结构。另一方面,在对勘探地点进行评估时,忽略了这些地区油气系统开发的特殊性。与伏尔加-乌拉尔盆地和季曼-伯朝拉盆地台地地区的传统生产中心相比,这一显著特征是由较厚的沉积覆盖层、其组成和结构的多变性以及结构发展的多个阶段造成的。许多失败是由于石油和天然气原生迁移流通过后形成的陷阱、储油层容量低以及断层断裂造成的。正如利用有关类似构造地区石油和天然气潜力的现代知识对新的地质数据进行解释所显示的那样,顺乌地区包含的石油和天然气积聚区研究不足,可能蕴藏着大量矿藏。这些区域包括推力盲区、错位斜长岩发育区的盐下陷落带,以及与不整合和地貌变化相关的地层和组合陷落带。在古生代覆盖层厚度增加的 Timan-Pechora 盆地,对新的勘探对象给予了极大关注。由于有了新的知识和更好的地球物理数据,在这些区域准备新的有前景的目标成为可能。
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引用次数: 0
Formation Conditions of Ignimbrites of the Khangar Volcano (Kamchatka) 堪察加半岛汉加尔火山点燃岩的形成条件
Pub Date : 2024-04-02 DOI: 10.2113/rgg20234566
V. Simonov, A. Kotlyarov, A.A. Kotov, A. Perepelov, N. Karmanov, A. Borovikov
—The study of minerals, melt inclusions, as well as natural glasses showed that two different melts contributed to the formation of ignimbrites of the Khangar Volcano. The first, providing the information on melt inclusions in plagioclase and quartz phenocrysts, represents the state of magma in a deep source. The other type of melt is responsible for the formation of glasses and microcrystals of feldspars in fiamme. Experimental and analytical studies of melt inclusions showed that crystallization of most plagioclase and quartz phenocrysts from ignimbrites of the Khangar Volcano occurred at temperatures of 840–960 °C and pressures up to 1.1 kbar, from the melt with water contents up to 3.23 wt.%, under the conditions of magma chamber. The presence of syngenetic primary melt and fluid inclusions in plagioclase and quartz phenocrysts from ignimbrites of the Khangar Volcano indicates phase separation (“boiling”) of the melt with mass formation of СО2 microbubbles in magma. The other type of melt is secondary relative to magmatic systems of the Khangar Volcano and is formed by sintering and melting of tuffogenic volcanoclastic material. This melt contributed to the formation of fiamme in the examined ignimbrites. Based on the study of glasses and microcrystals of feldspars in fiamme, it was found that crystallization of oligoclase occurred at temperatures of 770–840 °C in the melt between the spherules (with water content up to 2.91 wt.%). Sanidine crystals grew over spherules at lower temperatures, 680–760 °C.
-对矿物、熔体包裹体以及天然玻璃的研究表明,有两种不同的熔体促成了康加尔火山火成岩的形成。第一种熔体提供了斜长石和石英表晶中熔体包裹体的信息,代表了深源岩浆的状态。另一类熔体是岩浆中玻璃和长石微晶形成的原因。对熔体包裹体的实验和分析研究表明,在岩浆室条件下,康加尔火山火成岩中大部分斜长石和石英表晶的结晶发生在温度为 840-960 °C、压力高达 1.1 千巴的条件下,来自含水量高达 3.23 wt.%的熔体。在康加尔火山火成岩的斜长石和石英表晶中存在共生原生熔体和流体包裹体,这表明熔体相分离("沸腾"),在岩浆中大量形成СО2微气泡。另一种熔体相对于康卡尔火山的岩浆系统是次生的,是由凝灰岩成因的火山碎屑物质烧结熔化形成的。这种熔体在所考察的火成岩中促成了火成岩的形成。根据对 fiamme 中的玻璃和长石微晶的研究,发现在球粒(含水量高达 2.91 wt.%)之间的熔体中,低闪长岩的结晶温度为 770-840 ℃。在较低温度(680-760 °C)下,赛尼丁晶体生长在球状体上。
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引用次数: 0
Alterations of High-Carbon (Shungite) Rocks by the Lake Onega Waters: Mineralogy and Geochemistry of the Process 奥涅加湖湖水对高碳(霰石)岩石的改造:矿物学和地球化学过程
Pub Date : 2024-03-21 DOI: 10.2113/rgg20234690
V. Malov, V. Strakhovenko, D. Subetto, E. Ovdina, M. Potakhin, N. Belkina, G. Malov
––Carbonaceous (shungite) rocks have high contents of trace elements, which can get to the environment through natural weathering. Shungite rocks are a group of Precambrian carbonaceous rocks of volcanic and sedimentary genesis in Karelia. In this work we present results of studying the mineral and geochemical compositions of shungite rocks at their outcrops on the shoreline of Lake Onega. The interaction of the Onega waters with shungite rocks led to: (1) the removal of most elements, except for K, Mn, Ba, and Mg, whose contents in the rocks increased; (2) the formation of an assemblage of secondary minerals, such as hematite, jarosite, goethite, chalcocite, anglesite, brookite, and Mn hydroxides. Based on the results obtained, we propose a model of the transformation of high-carbon (shungite) rocks by the Onega waters.
--碳质(霰石)岩石的微量元素含量很高,可通过自然风化进入环境。霰岩石是卡累利阿地区火山和沉积成因的前寒武纪碳质岩石群。在这项研究中,我们介绍了对奥涅加湖沿岸出露的霰岩石的矿物和地球化学成分的研究结果。奥涅加湖水与霰岩石的相互作用导致了以下结果(1) 除 K、Mn、Ba 和 Mg 外,大部分元素被移除,这些元素在岩石中的含量增加了;(2) 形成了一系列次生矿物,如赤铁矿、绿泥石、鹅卵石、方解石、角闪石、褐铁矿和锰氢氧化物。根据所获得的结果,我们提出了奥涅加水体对高碳(霰石)岩石的转化模型。
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Russian Geology and Geophysics
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