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Solvothermal Synthesized Heterostructured Bi2S3–TiO2 Nanoparticles as Highly Selective Fluorescence Probe for Nitrobenzene 溶热合成异质结构 Bi2S3-TiO2 纳米粒子作为硝基苯的高选择性荧光探针
Pub Date : 2024-07-15 DOI: 10.1142/s2251237324400239
Abhinandan Syal, Aarti Sharma, Nidhi Gupta, D. Sud, Ritu Rai
This study describes a facile one-pot solvothermal method for the synthesis of heterostructured (HS) Bi2S3–TiO2 (BT) nanoparticles (NPs) and utilizes its potential for sensing the nitrobenzene (NB) as a fluorescent probe. The characterization of as-synthesized BT NPs endorses the mixed morphology with an average particle size of 14[Formula: see text]nm and the crystallography study depicted the orthorhombic Bi2S3 and tetragonal anatase TiO2 phases. The selectivity and sensitivity of BT NPs toward NB were examined by comparing the fluorescence quenching with a few other selected organic aromatic compounds. The appreciable quenching efficiency of 97% was achieved with NB. The visual response of the BT/NB mixture was noticed under UV light ([Formula: see text][Formula: see text]nm). The quenching parameters of the BT/NB system have been evaluated by modifying Stern–Volmer and double logarithmic equations. The results attribute the prevalence of dynamic quenching within the concentration range (0.4[Formula: see text]mM to 5[Formula: see text]mM) and beyond 5[Formula: see text]mM, both static and dynamic quenching coexist. Further, thermodynamic studies of the BT/NB system indicate the spontaneous hydrophobic interaction. Moreover, a reliable outcome has been demonstrated in the sensing application of BT NPs in real water samples.
本研究介绍了一种简单的一锅溶热法合成异质结构(HS)Bi2S3-TiO2(BT)纳米粒子(NPs),并利用其作为荧光探针感测硝基苯(NB)的潜力。合成的 BT NPs 具有混合形态,平均粒径为 14[式中:见正文]nm。通过比较 BT NPs 与其他几种选定的有机芳香化合物的荧光淬灭效果,考察了 BT NPs 对 NB 的选择性和灵敏度。对 NB 的淬灭效率高达 97%。在紫外光下([式中:见正文][式中:见正文]nm),BT/NB 混合物出现了视觉反应。通过修改斯特恩-沃尔默方程和双对数方程,对 BT/NB 系统的淬灭参数进行了评估。结果表明,在浓度范围(0.4[式:见正文]毫摩尔至 5[式:见正文]毫摩尔)内,动态淬火普遍存在,而当浓度超过 5[式:见正文]毫摩尔时,静态淬火和动态淬火并存。此外,BT/NB 系统的热力学研究表明存在自发的疏水相互作用。此外,BT NPs 在实际水样中的传感应用也证明了其可靠的结果。
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引用次数: 0
Investigation of High-entropy Alloys with Rare Element Additions Undergoing Phase Transformation at Cryogenic Temperatures 研究在低温下发生相变的添加稀有元素的高熵合金
Pub Date : 2024-07-12 DOI: 10.1142/s225123732450014x
Abdulkarim Omar Alfitouri, Harun Cuo, B. Cicek, M. Erden, Hakan Gungunep, Salih Birhanu Ahmed, Rajab Elkilani
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引用次数: 0
A comprehensive review on low-cost MEMS accelerometers for vibration measurement: types, novel designs, performance evaluation, and applications 全面评述用于振动测量的低成本 MEMS 加速计:类型、新型设计、性能评估和应用
Pub Date : 2024-03-28 DOI: 10.1142/s225123732430002x
Rüstem Binali, H. Demirpolat, Mustafa Kuntoglu, Mayur A. Makhesana, Saeed Yaghoubi, B. Kul
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引用次数: 0
X-ray Crystallographic Analysis of Pr modified BaTiO3 Ceramics with a Theoretical Perspective for Potential Applications in Microelectronics 从理论角度分析镨修饰的 BaTiO3 陶瓷在微电子学中的潜在应用的 X 射线晶体学分析
Pub Date : 2024-03-28 DOI: 10.1142/s2251237324400161
M. Panigrahi
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引用次数: 0
Effect of Rare-Earth Compounds on the Photocatalytic Performance of ZnIn2S4: A Review 稀土化合物对 ZnIn2S4 光催化性能的影响:综述
Pub Date : 2024-03-19 DOI: 10.1142/s2251237324300018
Dongsheng Jia, Ying Li
Semiconductor photocatalysis is considered one of the efficient and clean environmental technologies in the treatment of organic dye wastewater. Indium zinc sulfide (ZnIn2S4) is favored among many photocatalysts because of its narrow-forbidden bandwidth, good visible light absorption properties, suitable conduction and valence band positions, high chemical stability, low cost, easy preparation and low toxicity. However, indium zinc sulfide (ZnIn2S4) still faces the disadvantages of low visible light utilization and high photogenerated carrier complexation rate. In this paper, we introduce rare-earth ion doping and heterojunction of rare-earth oxides with ZnIn2S4 to improve photocatalytic efficiency, and we also review the current research status and development prospects of indium zinc sulfide in recent years.
半导体光催化技术被认为是处理有机染料废水的高效清洁环保技术之一。在众多光催化剂中,硫化铟锌(ZnIn2S4)因其窄禁带宽、良好的可见光吸收特性、合适的导带和价带位置、高化学稳定性、低成本、易制备和低毒性而备受青睐。然而,硫化铟锌(ZnIn2S4)仍然面临着可见光利用率低、光生载流子复合率高等缺点。本文介绍了稀土离子掺杂、稀土氧化物与 ZnIn2S4 异质结等提高光催化效率的方法,并综述了近年来硫化铟锌的研究现状和发展前景。
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引用次数: 0
A Comprehensive Literature Review on Efficient Synthetic Approaches and Polymorphism of Pazopanib (votrient), A Tyrosine Kinase Inhibitor 关于酪氨酸激酶抑制剂帕唑帕尼(votrient)的高效合成方法和多态性的全面文献综述
Pub Date : 2024-03-18 DOI: 10.1142/s225123732440015x
Onkar Chand, Lalita Chopra, Shashi Kant Tiwari
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引用次数: 0
Machining Performance Analysis of Ti6-Al-4V in Powder-Mixed EDM using Green Dielectric Oil 使用绿色介电油的粉末混合电火花加工 Ti6-Al-4V 的加工性能分析
Pub Date : 2024-02-29 DOI: 10.1142/s2251237324500072
Manas Ranjan Pal, K. Debnath, R. N. Mahapatra
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引用次数: 0
Quantifying Actinide HEA Superconducting Secrets: A Compositional Odyssey 量化锕系元素 HEA 超导秘密:成分奥德赛
Pub Date : 2024-02-28 DOI: 10.1142/s2251237324500060
Sudesh Jaiswal, Bijay Kumar, Ashwani Kumar
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引用次数: 0
A state of the art on sustainable metal working fluids in machining applications 可持续金属加工液在机械加工中的应用现状
Pub Date : 2024-02-16 DOI: 10.1142/s2251237324400136
Hakan Yurtkuran, Mustafa Gunay, Ritu Rai
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引用次数: 0
High Potential Electrochemical Synthesis of Thermally Reduced Graphene Nanomaterial 高电位电化学合成热还原石墨烯纳米材料
Pub Date : 2024-02-09 DOI: 10.1142/s2251237324500059
Rohit Srivastava, Pradeep Kumar Singh, Pankaj Kumar Singh
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引用次数: 0
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