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Valorization of peanut shells through biochar production using slow and fast pyrolysis and its detailed physicochemical characterization 通过慢速和快速热解生产生物炭实现花生壳的增值及其详细的物理化学特性分析
Pub Date : 2024-07-25 DOI: 10.3389/frsus.2024.1417207
Gajanan Sawargaonkar, Rajesh Pasumarthi, Santosh Kale, Pushpajeet L. Choudhari, S. Rakesh, Srikanth Mutnuri, Ajay Singh, Harikishan Sudini, Manasa Ramaraju, Ramesh Singh, A. K. Padhee, M.L. Jat
Valorization of peanut shells has recently gained prominence in the context of thermally converting agricultural waste into biochar, a carbon-rich byproduct with significant potential as a soil amendment. The present study delves into understanding the influence of slow (450°C and 500°C) and fast (550°C and 600°C) pyrolysis temperatures with a resident time of 60 and 30 minutes, respectively, on the physico-chemical properties of peanut shell biochar produced in a low-cost kiln. Results of the Scanning Electron Microscopy analysis revealed that increased pyrolysis temperature increased porosity and surface roughness with crystalline deposits. Thermogravimetric analysis showed that increased temperatures contributed to enhanced thermal stability but reduced biochar yield. Pyrolysis temperatures of 450, 500, 550, and 600°C exhibited 32.19, 29.13, 21.8, and 19.43 percent conversion efficiency with organic carbon content of 11.57, 6.48, 8.64, and 7.76 percent, respectively. The intensities of functional groups (C-H and C-O) declined, whereas the intensity of C=C and stable carbon content increased with the rise in temperatures. The concentrations of heavy metals in all biochar samples were below permissible limits outlined by international biochar initiatives. The study concluded that slow pyrolysis at 450°C for 60 minutes resident time is an ideal pyrolytic condition for producing peanut shell biochar in terms of qualitative and quantitative characteristics.
最近,在将农业废弃物热转化为生物炭的背景下,花生壳的价值得到了凸显,生物炭是一种富含碳的副产品,具有作为土壤改良剂的巨大潜力。本研究旨在了解慢速(450°C 和 500°C)和快速(550°C 和 600°C)热解温度(驻留时间分别为 60 分钟和 30 分钟)对低成本窑炉生产的花生壳生物炭的物理化学特性的影响。扫描电子显微镜分析结果表明,热解温度升高会增加孔隙率和表面粗糙度,并出现结晶沉积。热重分析表明,温度升高有助于提高热稳定性,但会降低生物炭产量。热解温度为 450、500、550 和 600°C 时,转化效率分别为 32.19%、29.13%、21.8% 和 19.43%,有机碳含量分别为 11.57%、6.48%、8.64% 和 7.76%。随着温度的升高,官能团(C-H 和 C-O)的强度下降,而 C=C 和稳定碳含量的强度上升。所有生物炭样品中的重金属浓度均低于国际生物炭倡议规定的允许限值。研究得出结论,就质量和数量特征而言,450°C、60 分钟驻留时间的缓慢热解是生产花生壳生物炭的理想热解条件。
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引用次数: 0
From waste to wealth: a study of concrete recycling in Jordan 从废物到财富:约旦混凝土再循环研究
Pub Date : 2024-07-18 DOI: 10.3389/frsus.2024.1398918
Mutasem Al-Sharif, Bob Geldermans, Mario Rinke
The construction industry in Jordan plays a pivotal role in the national economy but also generates a significant amount of concrete waste, leading to environmental and health challenges. Current waste management practices involve landfill use and unregulated disposal, demonstrating the country's infrastructural shortcomings in concrete waste handling. Despite the recognized importance of the construction sector and the challenges of concrete waste management, more comprehensive studies need to focus on the practicality and benefits of recycling concrete within a circular economy framework in Jordan. This gap hinders the development of effective strategies that could mitigate environmental impacts, promote sustainability, and leverage economic and social benefits in the construction industry. Given the accelerating urbanization, increasing environmental awareness, and the pressing need for sustainable development goals, the timing for this study is critical. It aims to catalyze a timely shift toward more sustainable waste management practices that align with global sustainability trends and national priorities. This study aims to fill the knowledge gap regarding the practicality of recycling concrete within a circular economy context in Jordan and explore the hypothesis that adopting circular economy principles can enhance resource efficiency, reduce waste, lower greenhouse gas emissions, foster economic benefits, and create job opportunities within the sector. Methodologically, this research comprises an analysis based on literature, international comparisons, and technical, economic, and ecological explorations of concrete recycling in Jordan. The literature study establishes a foundational understanding of the current waste management landscape, the anticipated benefits of concrete recycling, and the challenges to its implementation. Furthermore, a technical analysis evaluates the quality and applicability of recycled concrete. The in-depth examination of Jordan's concrete waste problem highlights the urbanization challenges, regulatory gaps, and environmental, social, and economic impacts. Barriers, solutions, and recommendations are discussed through an interdisciplinary lens. This integrated approach supports the transition toward a sustainable, environmentally responsible, and economically viable construction sector. The findings could contribute to policy-making and the advancement of industry practices, ultimately promoting sustainable development in Jordan.
约旦的建筑业在国民经济中发挥着举足轻重的作用,但同时也产生了大量的混凝土废物,给环境和健康带来了挑战。目前的废物管理做法包括垃圾填埋和无序处置,这表明约旦在混凝土废物处理方面存在基础设施缺陷。尽管建筑行业的重要性和混凝土废物管理面临的挑战已得到公认,但约旦仍需开展更全面的研究,重点关注在循环经济框架内回收混凝土的实用性和益处。这一空白阻碍了有效战略的制定,而这些战略可以减轻对环境的影响,促进可持续性,并在建筑业中发挥经济和社会效益。鉴于城市化进程的加快、环境意识的增强以及实现可持续发展目标的迫切需要,本研究的时机至关重要。本研究旨在促进及时转向更可持续的废物管理实践,使其与全球可持续发展的趋势和国家优先事项保持一致。本研究旨在填补约旦在循环经济背景下回收混凝土的实用性方面的知识空白,并探讨采用循环经济原则可以提高资源效率、减少废物、降低温室气体排放、促进经济效益并在该行业创造就业机会的假设。在方法上,本研究包括基于文献的分析、国际比较以及对约旦混凝土循环利用的技术、经济和生态探索。文献研究为了解当前的废物管理状况、混凝土回收利用的预期效益以及实施过程中面临的挑战奠定了基础。此外,技术分析还对再生混凝土的质量和适用性进行了评估。对约旦混凝土废物问题的深入研究突出了城市化挑战、监管漏洞以及环境、社会和经济影响。通过跨学科视角讨论了障碍、解决方案和建议。这种综合方法有助于向可持续、对环境负责、经济上可行的建筑行业过渡。研究结果有助于制定政策和推动行业实践,最终促进约旦的可持续发展。
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引用次数: 0
Implementing concepts from green logistics in the turkey production supply chain 在火鸡生产供应链中实施绿色物流理念
Pub Date : 2024-07-10 DOI: 10.3389/frsus.2024.1416964
Griffin Wilson, Bazyl Horsey, Richard Stone
The global turkey market represents a sector of increasing growth in the previous decade, and projections for the next decade reflect the probable continuation of this growth. Industry trends also indicate the globalization of turkey meat production, as the loci of production has continually shifted from one dominated by the United States to one with an increasing number of production units globally. In contrast with other popular meat products, comparatively fewer resources have been devoted to academic research concerning the growth, production, distribution, and sale of turkey and turkey products. This lack of research is particularly notable in the area of supply chain management and environmental sustainability. Given the increasing volume of turkey production and lower volume of academic interest, it stands to reason that there remain many opportunities for improvement across the value chain in this industry.In this paper, we take a “green logistics” approach and use data provided by one of the largest turkey producers in the United States to formulate a mixed-integer program aimed at minimizing the environmental impact of turkey products in a segment of the product supply chain.Implementation of the resulting brooder-finisher farm assignments developed by the model would yield an average 50% decrease (184 metric ton) in greenhouse gas emissions at the operation under investigation while also addressing other areas of significant vulnerability for the industry (production costs, biosecurity risk, and animal wellbeing).As consolidated turkey meat production systems continue to expand globally, we argue that a similar approach could readily be deployed by these growing and emerging production systems.
全球火鸡市场是上一个十年不断增长的行业,对下一个十年的预测反映了这种增长可能会继续下去。行业趋势也表明火鸡肉生产的全球化,因为生产地点已从以美国为主不断转变为全球生产单位数量不断增加。与其他受欢迎的肉类产品相比,有关火鸡和火鸡产品的生长、生产、分销和销售的学术研究投入的资源相对较少。这种研究的缺乏在供应链管理和环境可持续性领域尤为明显。在本文中,我们采用 "绿色物流 "方法,利用美国最大的火鸡生产商之一提供的数据,制定了一个混合整数方案,旨在最大限度地减少火鸡产品在产品供应链中对环境的影响。通过实施该模型制定的育雏-雏鸡养殖场分配方案,受调查企业的温室气体排放量将平均减少 50%(184 公吨),同时还能解决该行业的其他重大薄弱环节(生产成本、生物安全风险和动物福利)。
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引用次数: 0
Interdisciplinary perspectives on sustainability in higher education: a sustainability competence support model 高等教育可持续性的跨学科视角:可持续性能力支持模式
Pub Date : 2024-07-10 DOI: 10.3389/frsus.2024.1416498
Alice Annelin, Gert-Olof Boström
After several decades of work toward elevating sustainability education, many have called for a transformation of the education system to create timely action. Teachers, students, organizational leaders, and many other stakeholders have voiced their dissatisfaction with their experience of sustainability education. Some say we can do more to create real action for sustainable futures. We investigate what, how and why lectures across disciplines at universities in different countries work with sustainability education. We conduct interviews and dialogs with teachers across disciplines to uncover interdisciplinary perspectives on sustainability education and how to move forward. The emerging reflections provide insights about transformations in the strategies and systems, and how to implement sustainability education. There is also a call for reuniting diverse intrapersonal and values thinking between stakeholders to support transformations in sustainability education. Furthermore, participants imagined the future as a creative space where collaboration across disciplines facilitates a student-centred transdisciplinary experience with real-world practice. This study provides insights into the mindset of teachers across disciplines and countries. A sustainability competence-based support model about the current sustainability education discourse is developed.
经过几十年提升可持续发展教育的努力,许多人呼吁改革教育系统,及时采取行动。教师、学生、组织领导者和许多其他利益相关者都表达了他们对可持续发展教育经历的不满。有些人说,我们可以做得更多,为可持续未来创造真正的行动。我们调查了不同国家的大学跨学科讲授可持续发展教育的内容、方式和原因。我们与不同学科的教师进行了访谈和对话,以揭示可持续发展教育的跨学科视角以及如何向前迈进。新出现的思考为战略和系统的转型以及如何实施可持续发展教育提供了启示。此外,还呼吁利益相关者重新整合不同的人际和价值观思维,以支持可持续发展教育的转型。此外,参与者将未来想象为一个创造性的空间,通过跨学科合作,促进以学生为中心的跨学科体验和现实世界的实践。这项研究为了解不同学科、不同国家教师的思维模式提供了启示。针对当前的可持续发展教育论述,开发了一个以可持续发展能力为基础的支持模型。
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引用次数: 0
Editorial: Case studies in circular economy 社论:循环经济案例研究
Pub Date : 2024-07-09 DOI: 10.3389/frsus.2024.1436950
Claudio Sassanelli
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引用次数: 0
Word-of-mouth in agent-based simulation model of reverse logistics 基于代理的逆向物流模拟模型中的口碑传播
Pub Date : 2024-07-05 DOI: 10.3389/frsus.2024.1264461
Alexandre Labelle, J. Frayret
Agent-based modeling and simulation is a method well suited for studying individual behavior and interactions among members of a population connected by social networks. Although the development of such simulation models can be relatively complex, it is even more challenging to develop models that are empirically valid. In the case of reverse logistics, the sophisticated and difficult-to-predict behavior of consumers must be modeled. In this paper, an agent-based simulation model of consumer behavior and interactions was configured to conduct a case study of the voluntary deposit collection program for wine bottles in the Val-Saint-François region of Quebec. As this collection program was officially launched in 2019, two empirical samples were obtained to test the validity of the model and study how social interactions such as word of mouth contributes to the success of the collection program. The first sample represents the amount of glass collected during the last 26 weeks of 2019, while the second sample covers the first 13 weeks of 2020. Having observed an increase in collection rates between 2019 and 2020, word of mouth was introduced into the model to explain this phenomenon. Statistical tests show that the model is indeed valid with the inclusion of diffusion of awareness, as the simulation results are significantly consistent with the empirical data. The validation of the model demonstrates the viability of using multiple heterogeneous data-sources to configure a simulation model based on the Theory of Planned Behavior without using Structural Equation Modeling.
基于代理的建模和模拟是一种非常适合研究个体行为和通过社会网络连接的群体成员之间互动的方法。虽然这种模拟模型的开发相对复杂,但要开发出经验上有效的模型则更具挑战性。就逆向物流而言,必须对消费者复杂且难以预测的行为进行建模。本文针对魁北克 Val-Saint-François 地区的葡萄酒瓶自愿押金收集计划进行了案例研究,并配置了一个基于代理的消费者行为和互动模拟模型。由于该收集计划于 2019 年正式启动,因此获得了两个经验样本,以检验模型的有效性,并研究口碑等社会互动如何促进收集计划的成功。第一个样本代表了 2019 年最后 26 周的玻璃收集量,第二个样本涵盖了 2020 年的前 13 周。观察到收集率在 2019 年和 2020 年之间有所上升,因此将口碑引入模型来解释这一现象。统计测试表明,模型在引入口碑传播后确实有效,因为模拟结果与经验数据明显一致。模型的验证表明,在不使用结构方程建模的情况下,使用多种异构数据源配置基于计划行为理论的模拟模型是可行的。
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引用次数: 0
Consequential life cycle assessment of demolition waste management in Germany 德国拆除废物管理的后果生命周期评估
Pub Date : 2024-07-03 DOI: 10.3389/frsus.2024.1417637
Christian Dierks, Tabea Hagedorn, Theresa Mack, Vanessa Zeller
Bulk mineral waste materials such as construction and demolition waste are Germany’s largest waste stream. Despite the availability of high-quality recycling pathways such as road base layers, waste concrete is predominantly recycled into lower-quality recycling pathways like earthworks or unbound road construction. This is due to low demand for recycled aggregates in road base layers and frost protection layers, especially in public procurement.This study assesses the environmental consequences of increasing high-quality recycling of waste concrete in the near future to provide decision support for public procurement in Germany. The focus lies on climate change due to its importance for decision-makers. However, 17 other impact categories were assessed to avoid problem shifting.Life cycle assessment (LCA) is applied with background data from ecoinvent 3.9.1. Impact assessment was conducted at midpoint level using IPCC 2021 and ReCiPe Midpoint (H). Foreground data were taken from literature and expert interviews. In line with the goal of this LCA, a consequential modeling approach was followed to account for changes in the material flow system. Substitution creates a cascade effect previously omitted in consequential LCA studies, in which lower quality recycling materials replace higher quality recycling materials in their respective utilization pathways.Increasing the high-quality recycling of waste concrete into road base layers causes a reduction in environmental impacts for all 18 impact categories, as it replaces natural aggregate and avoids backfilling of mixed mineral waste and excavated earth through substitution effects. Transport distances and ferrous metal recovery were identified as hot spots. Sensitivity analyses show that only transport is a significant issue.Increasing the high-quality recycling of waste concrete in Germany is recommended in terms of environmental impacts. Lower-quality recycling is environmentally feasible only in cases where the avoided transport distances for natural aggregates and backfilling are significantly lower than the additional transport distances for high-quality recycling.
散装矿物废料(如建筑和拆除废料)是德国最大的废物流。尽管有路基层等高质量的回收途径,但废弃混凝土主要被回收到土方工程或无约束道路建设等低质量的回收途径中。本研究评估了在不久的将来增加废弃混凝土高质量回收利用的环境影响,为德国的公共采购提供决策支持。由于气候变化对决策者的重要性,本研究重点关注气候变化。生命周期评估(LCA)的背景数据来自 ecoinvent 3.9.1。使用 IPCC 2021 和 ReCiPe Midpoint (H) 在中点水平上进行影响评估。前景数据来自文献和专家访谈。根据本项生命周期评估的目标,我们采用了后果建模法来考虑材料流动系统的变化。提高废弃混凝土在路基层中的回收利用质量可减少所有 18 个影响类别的环境影响,因为它取代了天然骨料,并通过替代效应避免了混合矿物废料和挖掘土的回填。运输距离和黑色金属回收被确定为热点。敏感性分析表明,只有运输是一个重要问题。就环境影响而言,建议德国提高废弃混凝土的回收质量。只有在避免天然骨料和回填的运输距离大大低于高质量回收的额外运输距离的情况下,低质量回收在环境上才是可行的。
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引用次数: 0
Perceived satisfaction and household fuel transition: evidence from Ugandan households 感知满意度与家庭燃料过渡:来自乌干达家庭的证据
Pub Date : 2024-07-01 DOI: 10.3389/frsus.2024.1404806
Joseph Elasu, Joseph M. Ntayi, M. Adaramola, Faisal Buyinza, Ronnette Atukunda, Muhamad Ngoma
The dominance of biomass for cooking has implications for the country. For instance, biomass conversion using traditional technologies (three stone) in poorly ventilated kitchens produce smoke that influences the reproductive health outcomes for expectant mother. Beyond health outcomes, uncontrollable harvesting of biomass for cooking contributes to environmental degradation. Unfortunately, biomass in form of firewood, charcoal, plant and animal wastes is widely consumed by more than 94% of Ugandan households for cooking. This paper examined whether perceived satisfaction plays a significant role in household energy transition in Uganda.The study adopted a panel data methodology employing an ordered logit model with random effects to estimate the effect of perceived satisfaction on household fuel transition from high to low pollutant cooking fuels in Uganda. The data used was obtained from Uganda Bureau of Statistics (UBoS) which is mandated by an Act of parliament to develop and maintain a national statistics system to ensure collection, analysis and publication of integrated, relevant, reliable and timely statistical information.Our findings demonstrate that perceived satisfaction influences household fuel transition decisions in Uganda. The study concluded by suggesting policy recommendations for government action.
生物质能在烹饪中的主导地位对该国产生了影响。例如,在通风不良的厨房使用传统技术(三块石头)进行生物质转换会产生烟雾,影响孕妇的生殖健康。除了对健康造成影响外,不加控制地采集生物质用于烹饪还会导致环境退化。遗憾的是,94% 以上的乌干达家庭广泛使用木柴、木炭、动植物废料等生物质做饭。该研究采用了面板数据方法,利用随机效应有序对数模型来估算满意度对乌干达家庭从高污染烹饪燃料向低污染烹饪燃料过渡的影响。所使用的数据来自乌干达统计局(UBoS),根据议会法案,该局负责开发和维护国家统计系统,以确保收集、分析和发布综合、相关、可靠和及时的统计信息。研究最后为政府行动提出了政策建议。
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引用次数: 0
How do individual-level factors influence the adoption of low-carbon technology? Proposing and validating the bioeconomy technology acceptance model in the context of Africa 个人层面的因素如何影响低碳技术的采用?在非洲提出并验证生物经济技术接受模型
Pub Date : 2023-12-22 DOI: 10.3389/frsus.2023.1148001
O. Oguntuase, Oluwatosin B. Adu, O. S. Obayori
The bioeconomy seeks to efficiently transform biomaterials into value-added products to achieve circularity. A circular bioeconomy is a circular carbon economy based on bio-based resources. There is a dearth of information in the literature about how psychological factors affect public acceptance of the bioeconomy, especially in Africa, where the adoption of bioeconomy is scant. Addressing this gap, this study characterized bioeconomy as a low-carbon bio-based technological innovation to combat climate change and developed the Bioeconomy Technology Acceptance Model (BTAM) to explain the effects of individual-level factors on public acceptance of bioeconomy and investigated it in a survey (N = 465) using questionnaires that were carried out in Lagos, Nigeria, in 2022. The respondents were chosen by proportional stratified random sampling, and descriptive statistics, Pearson’s correlation coefficient, and structural equation modeling were used to analyze the data obtained. The strong influence of perceived usefulness from bioeconomy and intention to accept bioeconomy in BTAM suggests that the Technology Acceptance Model (TAM) is suitable for predicting public acceptance of bioeconomy. Considering the strong influence of belief about climate change on the perceived usefulness of bioeconomy and intention to accept it in this study, it is imperative to promote climate change education among Africans to accelerate acceptance of bioeconomy on the continent. The identified psychological factors provide a reference for scholars, policymakers, and manufacturers to effectively develop individual-oriented intervention strategies and promotion schemes to enhance acceptance of bioeconomy in Africa in particular and other climes where there is not yet widespread acceptance of circular bioeconomy.
生物经济旨在有效地将生物材料转化为高附加值产品,以实现循环。循环生物经济是以生物资源为基础的循环碳经济。关于心理因素如何影响公众对生物经济的接受程度的文献资料十分匮乏,尤其是在非洲,因为那里采用生物经济的人很少。针对这一空白,本研究将生物经济定性为应对气候变化的低碳生物技术创新,并建立了生物经济技术接受模型(BTAM)来解释个人层面的因素对公众接受生物经济的影响,并于 2022 年在尼日利亚拉各斯进行了问卷调查(N = 465)。调查对象采用比例分层随机抽样法,并使用描述性统计、皮尔逊相关系数和结构方程模型对所获得的数据进行分析。在 BTAM 中,生物经济的感知有用性和接受生物经济的意向具有很强的影响,这表明技术接受模型(TAM)适用于预测公众对生物经济的接受程度。考虑到本研究中气候变化信念对生物经济的感知有用性和接受生物经济的意向有很大影响,因此必须在非洲人中推广气候变化教育,以加速非洲大陆对生物经济的接受。所发现的心理因素为学者、政策制定者和制造商提供了参考,以有效地制定以个人为导向的干预策略和推广计划,从而提高人们对生物经济的接受程度,尤其是在非洲和其他尚未广泛接受循环生物经济的地区。
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引用次数: 0
Engaging “unusual suspects” in climate action: cultural affordances for diverse competences and improvised identities 让 "不寻常的嫌疑人 "参与气候行动:不同能力和即兴身份的文化承受力
Pub Date : 2023-11-30 DOI: 10.3389/frsus.2023.1197885
Eva Heiskanen
The demonstrated urgency of the climate crisis would require mobilization by a larger and more diverse set of participants than those usually recognized as environmental activists. Hence this article asks: (1) What conditions enable unlikely participants (such as men working in manual occupations) to engage in and identify with a climate movement? And (2) what is it about the relationship between participants’ biographies, the practices of the climate movement and the interaction between them that allows – or affords – such identification to occur? I draw on an approach to identity formation as situated practice, i.e., as occurring in situations where social relations are enacted while drawing on the individual experience and shared understandings that participants bring to the situation. Based on fieldwork in Finnish municipalities that have committed to climate neutrality, I find that the conditions for engagement depend on socio-cultural affordances for engaging in climate action, which (1) accept and welcome participants’ life histories and lifestyles (2) build on and respect participants’ competences and multiple forms of expertise, (3) engage participants in practices that are familiar enough not to produce anxiety but stimulating enough to be fun, and (4) produce small but visible achievements that are acknowledged as such by both participants and onlookers. The current study contributes to previous research arguing for a more populist approach to climate policy by emphasizing existing competences and embodied practices as an avenue for engagement in climate action.
气候危机的紧迫性要求动员更多和更多样化的参与者,而不是那些通常被认为是环保活动家的人。因此,本文提出了以下问题:(1) 是什么条件使不太可能参与的参与者(如从事体力劳动的男性)参与并认同气候运动?(2) 参与者的履历、气候运动的实践以及它们之间的互动之间的关系是什么使得--或者说允许--这种认同发生?我借鉴了一种将身份认同的形成视为情景实践的方法,即身份认同是在社会关系发生的情景中形成的,同时借鉴了参与者的个人经历和对情景的共同理解。基于在芬兰致力于气候中和的城市开展的实地调查,我发现参与的条件取决于参与气候行动的社会文化承受力,这些承受力(1)接受并欢迎参与者的生活历史和生活方式(2)建立在并尊重参与者的能力和多种形式的专业知识之上(3)让参与者参与到既熟悉又不会产生焦虑,但又足够刺激有趣的实践中,以及(4)产生微小但可见的成就,并得到参与者和旁观者的认可。目前的研究强调现有能力和体现性实践是参与气候行动的途径,从而为之前的研究做出了贡献,这些研究主张对气候政策采取更加平民化的方法。
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