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A comprehensive analysis of uncertainties in warm rain parameterizations in climate models based on in situ measurements 基于现场测量结果的气候模型暖雨参数化不确定性综合分析
Pub Date : 2024-05-13 DOI: 10.1175/jas-d-23-0198.1
Zhibo Zhang, D. Mechem, J. C. Chiu, J. Covert
Because of the coarse grid size of Earth system models (ESM), representing warm-rain processes in ESMs is a challenging task involving multiple sources of uncertainty. Previous studies evaluated warm-rain parameterizations mainly according to their performance in emulating collision-coalescence rates for local droplet populations over a short period of a few seconds. The representativeness of these local process rates comes into question when applied in ESMs for grid sizes on the order of 100 kilometers and time steps on the order of 20-30 minutes. We evaluate several widely used warm-rain parameterizations in ESM application scenarios. In the comparison of local and instantaneous autoconversion rates, the two parameterization schemes based on numerical fitting to stochastic collection equation (SCE) results perform best. However, because of Jessen’s inequality, their performance deteriorates when grid-mean, instead of locally-resolved, cloud properties are used in their simulations. In contrast, the effect of Jessen’s inequality partly cancels the overestimation problem of two semi-analytical schemes, leading to an improvement in the ESM-like comparison. In the assessment of uncertainty due to the large time step of ESMs, it is found that the rain-water tendency simulated by the SCE is roughly linear for time steps smaller than 10 minutes, but the nonlinearity effect becomes significant for larger time steps, leading to errors up to a factor of 4 for a time step of 20 minutes. After considering all uncertainties, the grid-mean and time-averaged rain-water tendency based on the parameterization schemes are mostly within a factor of 4 of the local benchmark results simulated by SCE.
由于地球系统模式的网格尺寸较粗,在地球系统模式中表示暖雨过程是一项具有挑战性的任务,涉及多种不确定性来源。以往的研究主要根据暖雨参数在几秒钟的短时间内模拟局部水滴群碰撞凝聚率的性能来评估暖雨参数。如果将这些局部过程率应用于网格大小约为 100 公里、时间步长约为 20-30 分钟的 ESM,其代表性就会受到质疑。我们评估了在 ESM 应用场景中广泛使用的几种暖雨参数。在局部和瞬时自动转换率的比较中,基于随机集合方程(SCE)结果数值拟合的两种参数化方案表现最佳。然而,由于杰森不等式的存在,当模拟中使用网格均值而非局部分辨的云特性时,它们的性能就会下降。相比之下,杰森不等式的影响部分消除了两个半解析方案的高估问题,从而改善了类似 ESM 的比较。在评估 ESM 大时间步长引起的不确定性时,发现 SCE 模拟的雨水趋势在时间步长小于 10 分钟时大致呈线性,但在时间步长较大时,非线性效应变得显著,导致时间步长为 20 分钟时误差高达 4 倍。在考虑所有不确定因素后,基于参数化方案的网格平均雨水倾向和时间平均雨水倾向与 SCE 模拟的本地基准结果的误差大多在 4 倍以内。
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引用次数: 0
Kelvin Helmholtz Instability “Tube” and “Knot” Dynamics, Part III: Extension of Elevated Turbulence and Energy Dissipation into Increasingly Viscous Flows 开尔文亥姆霍兹不稳定性 "管 "和 "结 "动力学,第三部分:将升高湍流和能量消耗扩展到粘性增加的流动中
Pub Date : 2024-05-06 DOI: 10.1175/jas-d-23-0085.1
D. Fritts, Ling Wang, Thomas S. Lund, Marvin A. Geller
A companion paper by Fritts et al. (2023) reviews extensive evidence for Kelvin-Helmholtz instability (KHI) “tube” and “knot” (T&K) dynamics at multiple altitudes in the atmosphere and in the oceans that reveal these dynamics to be widespread. A second companion paper by Fritts and Wang (2023) reveals KHI T&K events at larger and smaller scales to arise on multiple highly-stratified sheets in a direct numerical simulation (DNS) of idealized, multi-scale gravity wave – fine structure interactions. These studies reveal the diverse environments in which KHI T&K dynamics arise and suggest their potentially ubiquitous occurrence throughout the atmosphere and oceans. This paper describes DNS of multiple KHI evolutions in wide and narrow domains enabling and excluding T&K dynamics. These DNS employ common initial conditions, but are performed for decreasing Reynolds numbers, Re, to explore whether T&K dynamics enable enhanced KHI-induced turbulence where it would be weaker or not otherwise occur. The major results are that KHI T&K dynamics extend elevated turbulence intensities and energy dissipation rates, ε, to smaller Re. We expect these results to have important implications for improving parameterizations of KHI-induced turbulence in the atmosphere and oceans.
Fritts 等人(2023 年)的另一篇论文回顾了开尔文-赫尔姆霍兹不稳定性(KHI)"管 "和 "结"(T&K)动力学在大气和海洋多个高度的广泛证据,揭示了这些动力学的广泛性。Fritts 和 Wang(2023 年)的第二篇论文揭示了在理想化、多尺度重力波-精细结构相互作用的直接数值模拟(DNS)中,在多个高度分层的板块上出现了较大尺度和较小尺度的 KHI T&K 事件。这些研究揭示了 KHI T&K 动力学产生的不同环境,并表明它们可能在大气和海洋中无处不在。本文描述了在宽域和窄域中产生和排除 T&K 动力的多种 KHI 演变的 DNS。这些 DNS 采用了共同的初始条件,但在雷诺数 Re 不断减小的情况下进行,以探索 T&K 动力是否会在 KHI 诱导湍流较弱或不会发生湍流的地方增强 KHI 诱导湍流。主要结果是 KHI T&K 动力学将升高的湍流强度和能量耗散率 ε 扩展到更小的 Re。我们希望这些结果对改进 KHI 引起的大气和海洋湍流的参数化有重要意义。
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引用次数: 0
Reinterpretation of the Thorpe Length Scale 重新解释索普长度标尺
Pub Date : 2024-05-02 DOI: 10.1175/jas-d-23-0137.1
Lakshmi Kantha
In 1977, S. A. Thorpe proposed a method to estimate the dissipation rate ε of turbulence kinetic energy (TKE) in an overturning turbulent layer in a lake, by sorting the observed (unstable) density profile to render it stable and thus deriving a length scale LT named after him, from the resulting vertical displacements of water parcels. By further proposing that this purely empirical scale (with no a priori physical basis, unlike many other turbulence length scales) is proportional to the Ozmidov scale LO, definable only for stably (not unstably or neutrally) stratified flows, he was able to extract ε. The simplicity of the approach that requires nothing but CTD (Conductivity, Temperature and Depth) casts in water bodies, including lakes and oceans, made it attractive, until microstructure profilers were developed and perfected in later decades to actually make in-situ measurements of ε. Since equivalent microstructure devices are not available for the atmosphere, Thorpe technique has been resurrected in recent years for application to the atmosphere, using potential temperature profiles obtained from high vertical resolution radiosondes. Its popularity and utility have increased lately, in spite of unresolved issues related to the validity of assuming LT is proportional to LO. In this study, we touch upon these issues and offer an alternative interpretation of the Thorpe length scale as indicative of the turbulence velocity scale σK, which allows Thorpe sorting technique to be applied to all turbulent flows, including those generated by convection.
1977 年,索普(S. A. Thorpe)提出了一种估算湖泊翻转湍流层中湍流动能(TKE)耗散率 ε 的方法,即对观测到的(不稳定的)密度剖面进行排序,使其趋于稳定,从而根据由此产生的水团垂直位移推导出以他的名字命名的长度尺度 LT。通过进一步提出这一纯粹的经验尺度(与许多其他湍流长度尺度不同,它没有先验的物理基础)与奥兹米多夫尺度 LO 成比例,该尺度只适用于稳定(而非不稳定或中性)分层流,他就能够提取出 ε。这种方法很简单,只需要在水体(包括湖泊和海洋)中进行 CTD(电导率、温度和深度)测量,因此很有吸引力,直到后来几十年微结构剖面仪的发展和完善,才能真正对 ε 进行原位测量。尽管假定 LT 与 LO 成正比的有效性问题尚未解决,但该技术的受欢迎程度和实用性近来有所提高。在本研究中,我们探讨了这些问题,并提出了将索普长度尺度解释为湍流速度尺度σK的替代方案,从而使索普分选技术能够应用于所有湍流,包括由对流产生的湍流。
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引用次数: 0
Effect of Turbulence on the Collision Rate between Settling Ice Crystals and Droplets 湍流对沉降冰晶和水滴碰撞率的影响
Pub Date : 2024-05-01 DOI: 10.1175/jas-d-23-0119.1
M. Z. Sheikh, K. Gustavsson, E. Lévêque, B. Mehlig, A. Pumir, A. Naso
In mixed-phase clouds, graupel forms by riming, a process whereby ice crystals and supercooled water droplets settling through a turbulent flow collide and aggregate. We consider here the early stage of the collision process of small ice crystals with water droplets and determine numerically the geometric collision kernel in turbulent flows (therefore neglecting all interactions between the particles and assuming a collision efficiency equal to unity), over a range of energy dissipation rate 1–250 cm2 s−3 relevant to cloud microphysics. We take into account the effect of small, but nonzero fluid inertia, which is essential since it favors a biased orientation of the crystals with their broad side down. Since water droplets and ice crystals have different masses and shapes, they generally settle with different velocities. Turbulence does not play any significant role on the collision kernel when the difference between the settling velocities of the two sets of particles is larger than a few millimeters per second. The situation is completely different when the settling speeds of droplets and crystals are comparable, in which case turbulence is the main cause of collisions. Our results are compatible with those of recent experiments according to which turbulence does not clearly increase the growth rate of tethered graupel in a flow transporting water droplets.
在混相云中,灰凝胶是通过镶边形成的,这是冰晶和过冷水滴在湍流中沉降碰撞和聚集的过程。在此,我们考虑了小冰晶与水滴碰撞过程的早期阶段,并在与云微观物理相关的能量耗散率 1-250 cm2 s-3 的范围内,数值确定了湍流中的几何碰撞核(因此忽略了颗粒之间的所有相互作用,并假设碰撞效率等于统一)。我们考虑了较小但不为零的流体惯性的影响,这一点至关重要,因为它有利于晶体宽面朝下的偏向。由于水滴和冰晶的质量和形状不同,它们的沉降速度通常也不同。当两组颗粒的沉降速度相差大于每秒几毫米时,湍流对碰撞内核的影响不大。当液滴和晶体的沉降速度相当时,情况就完全不同了,在这种情况下,湍流是碰撞的主要原因。我们的研究结果与最近的实验结果一致,根据这些实验结果,湍流并不会明显增加水滴在流动过程中的生长速度。
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引用次数: 0
Toward Building a Virtual Laboratory to Investigate Rainfall Microphysics at Process Scales 建立虚拟实验室,研究过程尺度上的降雨微物理学
Pub Date : 2024-03-28 DOI: 10.1175/jas-d-23-0121.1
Lihui Ji, Ana P. Barros
A 3D numerical model was built to serve as a virtual microphysics laboratory (VML) to investigate rainfall microphysical processes. One key goal for the VML is to elucidate the physical basis of warm precipitation processes toward improving existing parameterizations beyond the constraints of past physical experiments. This manuscript presents results from VML simulations of classical tower experiments of raindrop collisional collection and breakup. The simulations capture large raindrop oscillations in shape and velocity in both horizontal and vertical planes and reveal that drop instability increases with diameter due to the weakening of the surface tension compared to the body force. Detailed evaluation against reference experimental data sets of binary collisions over a wide range of drop sizes shows that the VML reproduces collision outcomes well including coalescence, and disk, sheet, and filament breakups. Furthermore, the VML simulations captured spontaneous breakup, and secondary coalescence and breakup. The breakup type, fragment number, and size distribution are analyzed in the context of collision kinetic energy, diameter ratio, and relative position, with a view to capture the dynamic evolution of the vertical microstructure of rainfall in models and to interpret remote-sensing measurements.
建立了一个三维数值模型,作为研究降雨微物理过程的虚拟微物理实验室(VML)。虚拟微观物理实验室的一个关键目标是阐明暖降水过程的物理基础,从而超越过去物理实验的限制,改进现有的参数设置。本手稿介绍了 VML 模拟雨滴碰撞收集和破裂的经典塔式实验的结果。模拟捕捉到了雨滴在水平和垂直平面上的形状和速度的大幅振荡,并揭示了由于表面张力相对于体力的减弱,雨滴的不稳定性随直径的增加而增加。根据各种雨滴大小的二元碰撞参考实验数据集进行的详细评估表明,VML 很好地再现了碰撞结果,包括凝聚、盘状、片状和丝状破裂。此外,VML 模拟还捕捉到了自发破裂以及二次凝聚和破裂。在碰撞动能、直径比和相对位置的背景下,对破裂类型、碎片数量和大小分布进行了分析,以期在模型中捕捉降雨垂直微观结构的动态演变,并解释遥感测量结果。
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引用次数: 0
Characteristics of Generating Cells in Wintertime Orographic Clouds 冬季睛云中发电单元的特征
Pub Date : 2024-02-28 DOI: 10.1175/jas-d-23-0029.1
S. Tessendorf, Kyoko Ikeda, Roy M. Rasmussen, Jeffrey R. French, R. Rauber, Alexei Korolev, L. Xue, D. Blestrud, Nicholas Dawson, Melinda Meadows, M. Kunkel, S. Parkinson
During the Seeded and Natural Orographic Wintertime clouds: the Idaho Experiment (SNOWIE) field campaign, cloud-top generating cells were frequently observed in the very high-resolution W-band airborne cloud radar data. This study examines multiple flight segments from three SNOWIE cases that exhibited cloud-top generating cells structures, focusing on the in-situ measurements inside and outside these cells to characterize the microphysics of these cells. The observed generating cells in these three cases occurred in cloud tops of −15 to −30 °C, with and without overlying cloud layers, but always with shallow layers of atmospheric instability observed at cloud top. The results also indicate that liquid water content, vertical velocity, and drizzle and ice crystal concentrations are greater inside the generating cells compared to the adjacent portions of the cloud. The generating cells were predominantly < 500 m in horizontal width and frequently exhibited drizzle drops coexisting with ice. The particle imagery indicates that ice particle habits included plates, columns, and rimed and irregular crystals, likely formed via primary ice nucleation mechanisms. Understanding the sources of natural ice formation is important to understanding precipitation formation in winter orographic clouds, and is especially relevant for clouds that may be targeted for glaciogenic cloud seeding as well as to improve model representation of these clouds.
在 "冬季播种和自然地貌云:爱达荷州实验(SNOWIE)"实地活动期间,在分辨率极高的 W 波段机载云雷达数据中经常观测到云顶生成细胞。本研究考察了三个 SNOWIE 案例中呈现云顶生成细胞结构的多个飞行片段,重点是这些细胞内外的原位测量,以描述这些细胞的微物理特性。在这三个案例中观测到的生成单元发生在-15 到 -30 °C的云顶,有上覆云层和无上覆云层,但在云顶始终观测到浅层大气不稳定。结果还表明,与云的邻近部分相比,生成单元内的液态水含量、垂直速度、细雨和冰晶浓度更高。生成单元的水平宽度主要小于 500 米,并经常出现雨滴与冰共存的现象。颗粒图像显示,冰颗粒的习性包括板状、柱状以及边缘和不规则晶体,很可能是通过原生冰核机制形成的。了解天然冰形成的来源对于了解冬季地貌云中降水的形成非常重要,特别是对于可能成为冰川成因云播种目标的云以及改进这些云的模型表示法来说更是如此。
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引用次数: 0
The Energetics of the Lagrangian Evolution of Tropical Convective Systems 热带对流系统的拉格朗日演化能量学
Pub Date : 2024-02-28 DOI: 10.1175/jas-d-23-0141.1
H. Masunaga, Hanii Takahashi
Convective lifecycle is often conceptualized to progress from congestus to deep convection and develop further to stratiform anvil clouds, accompanied by a systematic change in the vertical structure of vertical motion. This archetype scenario has been developed largely from the Eulerian viewpoint, and has yet to be explored whether or not the same lifecycle emerges itself in a moving system tracked in the Lagrangian manner. To address this question, Lagrangian tracking is applied to tropical convective systems in combination with a thermodynamic budget analysis forced by satellite-retrieved precipitation and radiation. A new method is devised to characterize the vertical motion profiles in terms of the column import or export of moisture and moist static energy (MSE). The Bottom-heavy, Mid-heavy, and Top-heavy regimes are identified for every one-square-degree grid pixel accompanying tracked precipitation systems, making use of the diagnosed column export/import of moisture and MSE. Major findings are as follows. The Lagrangian evolution of convective systems is dominated by a state of dynamic equilibrium among different convective regimes rather than a monotonic progress from one regime to the next. The transition from the Bottom-heavy to Mid-heavy regimes is fed with intensifying precipitation presumably owing to a negative gross moist stability (GMS) of the Bottom-heavy regime, whereas the transition from the Mid-heavy to Top-heavy regimes dissipates the system. The Bottom-heavy to Mid-heavy transition takes a relaxation time of about 5 h in the equilibrating processes, whereas the relaxation time is estimated as roughly 20 h concerning the Mid-heavy to Top-heavy transition.
对流生命周期的概念通常是从稠密对流发展到深对流,再进一步发展到层状砧云,并伴随着垂直运动结构的系统性变化。这种原型方案主要是从欧拉角度开发的,至于以拉格朗日方式跟踪的移动系统是否也会出现同样的生命周期,还有待探讨。为了解决这个问题,拉格朗日跟踪技术被应用于热带对流系统,并结合由卫星检索的降水和辐射强迫进行的热力学预算分析。设计了一种新方法,根据水汽和湿静态能量(MSE)的柱状输入或输出来描述垂直运动剖面。利用诊断出的水汽和 MSE 柱进出口,确定了伴随跟踪降水系统的每个一平方度网格像素的底重、中重和顶重系统。主要发现如下对流系统的拉格朗日演化主要是不同对流系统之间的动态平衡状态,而不是从一种系统到另一种系统的单调演化。从底层重型对流系统过渡到中层重型对流系统时,降水会增强,这可能是由于底层重型对流系统的负湿润稳定性(GMS),而从中层重型对流系统过渡到顶层重型对流系统时,系统会消散。在平衡过程中,底重型向中重型过渡的弛豫时间约为 5 小时,而中重型向顶重型过渡的弛豫时间估计约为 20 小时。
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引用次数: 0
A parametrization scheme accounting for non-hydrostatic effects on the momentum flux of vertically-propagating orographic gravity waves: Formulae and preliminary tests in the Model for Prediction Across Scales (MPAS) 考虑到垂直传播的地心引力波动量通量的非静水效应的参数化方案:跨尺度预测模型(MPAS)中的公式和初步测试
Pub Date : 2024-02-26 DOI: 10.1175/jas-d-23-0020.1
Xin Xu, Rongrong Zhang, Miguel A. C. Teixeira, Annelize van Niekerk, Ming Xue, Yixiong Lu, Haile Xue, Runqiu Li, Yuan Wang
The momentum transport by orographic gravity waves (OGWs) plays an important role in driving the large-scale circulation throughout the atmosphere and is subject to parameterization in numerical models. Current parameterization schemes, which were originally developed for coarse-resolution models, commonly assume that unresolved OGWs are hydrostatic. With the increase in the horizontal resolution of state-of-the-art numerical models, unresolved OGWs are of smaller horizontal scale and more influenced by nonhydrostatic effects (NHE), thus challenging use of the hydrostatic assumption. Based on the analytical formulae for nonhydrostatic OGWs derived in our recent study, the orographic gravity wave drag (OGWD) parameterization scheme in the Model for Prediction Across Scales is revised by accounting for NHE. Global simulations with 30-km horizontal resolution are conducted to investigate NHE on the momentum transport of OGWs and their impacts on the large-scale circulation in boreal winter. NHE are evident in regions of complex terrain such as the Tibetan Plateau, Rocky Mountains, Southern Andes and Eastern Antarctica. The parameterized surface wave momentum flux can be either reduced or enhanced depending on the relative importance of NHE and model physics-dynamics interactions. The NHE corrections to the OGWD scheme significantly reduce the easterly biases in the polar stratosphere of the Northern Hemisphere, due to both weakened OGWD in the upper troposphere and lower stratosphere and suppressed upward propagation of resolved waves into the stratosphere. However, the revised OGWD scheme only has a weak influence on the large-scale circulation in the Southern Hemisphere during boreal winter.
地貌重力波(OGWs)的动量传输在驱动整个大气层的大尺度环流方面起着重要作用,需要在数值模式中进行参数化。目前的参数化方案最初是为粗分辨率模式开发的,通常假定未解决的 OGW 是静力学的。随着最新数值模式水平分辨率的提高,未解决的 OGW 水平尺度更小,受非静水效应(NHE)的影响更大,因此对使用静水假设提出了挑战。根据我们最近研究得出的非静水 OGW 分析公式,通过考虑非静水效应,对跨尺度预测模式中的地形重力波阻力(OGWD)参数化方案进行了修订。进行了水平分辨率为 30 千米的全球模拟,以研究 NHE 对 OGWs 动量传输的影响及其对北方冬季大尺度环流的影响。在青藏高原、落基山脉、南安第斯山脉和南极洲东部等地形复杂的地区,NHE 非常明显。参数化的表面波动量通量可以减少或增加,这取决于 NHE 和模型物理-动力相互作用的相对重要性。由于对流层上部和平流层下部的 OGWD 被削弱,以及解析波向平流层的向上传播被抑制,对 OGWD 方案的 NHE 修正大大减少了北半球极地平流层的偏东现象。然而,修订后的 OGWD 方案仅对寒冬期间南半球的大尺度环流产生微弱影响。
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引用次数: 0
The stochastic spin-up of vorticity in spontaneous tropical cyclogenesis 自发热带气旋生成过程中涡度的随机旋升
Pub Date : 2024-02-19 DOI: 10.1175/jas-d-23-0186.1
Hao Fu, Morgan O’Neill
Cloud-permitting simulations have shown that tropical cyclones (TCs) can form spontaneously in a quiescent environment with uniform sea surface temperature. While several mesoscale feedbacks are known to amplify an existing midlevel vortex, how the noisy deep convection produces the initial midlevel vortex remains unclear. This paper develops a theoretical framework to understand the evolution of the midlevel mesoscale vorticity’s histogram in the first two days of spontaneous tropical cyclogenesis, which we call the “stochastic spin-up stage”. The mesoscale vorticity is produced by two random processes related to deep convection: the random stretching of planetary vorticity (f) and the tilting of random vertical shear. The mesoscale vorticity is modeled as the sum of three independent normal distributions, which include the cyclones produced by stretching, cyclones produced by tilting, and anticyclones produced by tilting. Their collective effect is calculated with the central limit theorem. The theory predicts that the standard deviation of the midlevel mesoscale vorticity is universally proportional to the square root of the domain-averaged accumulated rainfall, agreeing with simulations. The theory predicts a critical latitude below which tilting is dominant in producing mesoscale vorticity. Treating the magnitude of random vertical shear as a fitting parameter, the critical latitude is shown to be around 12°N. Because the magnitude of vertical shear should be larger in the real atmosphere, this result suggests tilting is an important source of mesoscale vorticity fluctuation in the tropics.
云许可模拟显示,热带气旋(TC)可以在海面温度均匀的静止环境中自发形成。虽然已知有几种中尺度反馈会放大现有的中层涡旋,但嘈杂的深对流如何产生初始中层涡旋仍不清楚。本文建立了一个理论框架,以理解自发热带气旋生成的头两天中层中尺度涡度柱状图的演变,我们称之为 "随机旋升阶段"。中尺度涡度是由两个与深对流有关的随机过程产生的:行星涡度(f)的随机拉伸和随机垂直切变的倾斜。中尺度涡度被模拟为三个独立正态分布的总和,其中包括拉伸产生的气旋、倾斜产生的气旋和倾斜产生的反气旋。它们的集体效应是通过中心极限定理计算得出的。该理论预测,中层中尺度涡度的标准偏差普遍与域平均累积降雨量的平方根成正比,这与模拟结果一致。该理论预测了一个临界纬度,在该纬度以下,倾斜在产生中尺度涡度方面占主导地位。将随机垂直切变的大小作为一个拟合参数,结果表明临界纬度在北纬 12°左右。由于真实大气中的垂直切变幅度应该更大,这一结果表明倾斜是热带中尺度涡度波动的一个重要来源。
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引用次数: 0
An Approximate Criterion for Morphological Transformations in Small Vapor Grown Ice Crystals 小型蒸汽生长冰晶体形态变化的近似标准
Pub Date : 2024-02-01 DOI: 10.1175/jas-d-23-0131.1
J. Y. Harrington, G. Pokrifka
Observations and measurements show that crystals remain relatively compact at low ice supersaturations, but become increasingly hollowed and complex as the ice supersaturation rises. Prior measurements at temperatures >−25°C indicate that the transition from compact, solid ice to morphologically complex crystals occurs when the excess vapor density exceeds a threshold value of about 0.05 g m−3. A comparable threshold is not available at low temperatures. A temperature-dependent criterion for the excess vapor density threshold (Δρthr) that defines morphological transformations to complex ice is derived from laboratory measurements of vapor grown ice at temperatures below −40°C. This criterion depends on the difference between the equilibrium vapor density of liquid () and ice (ρei) multiplied by a measurement-determined constant, . The new criterion is consistent with prior laboratory measurements, theoretical estimates, and it reproduces the classical result of about 0.05 g m−3 above −25°C. Since Δρthr defines the excess vapor density above which crystals transition to a morphologically complex (lower density) growth mode, we can estimate the critical supersaturation (scrit) for step nucleation during vapor growth. The derived values of scrit are consistent with previous measurements at temperatures above −20°C. No direct measurements of scrit are available for temperatures below −40°C; however, our derived values suggest some measurement-based estimates may be too high while estimates from molecular dynamics simulations may be too low.
观察和测量结果表明,在低冰过饱和度时,晶体保持相对紧凑,但随着冰过饱和度的升高,晶体变得越来越空洞和复杂。之前在温度大于 25°C 时进行的测量表明,当过量蒸汽密度超过约 0.05 g m-3 的临界值时,就会从紧密的实心冰转变为形态复杂的晶体。在低温条件下,还没有可比的临界值。过剩蒸汽密度阈值 (Δρthr)随温度变化的标准定义了向复杂冰的形态转变,该标准是通过对温度低于 -40°C 的蒸汽生长冰进行实验室测量得出的。该标准取决于液体()和冰的平衡蒸气密度(ρei)之间的差值乘以一个测量确定的常数,即 。新标准与之前的实验室测量结果和理论估计值一致,并且重现了-25°C 以上约 0.05 g m-3 的经典结果。由于 Δρthr 定义了晶体过渡到形态复杂(密度较低)生长模式的过高蒸汽密度,因此我们可以估算出蒸汽生长过程中阶跃成核的临界过饱和度 (scrit)。得出的 scrit 值与之前在 -20°C 以上温度条件下的测量值一致。然而,我们的推导值表明,一些基于测量的估计值可能过高,而分子动力学模拟的估计值可能过低。
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引用次数: 0
期刊
Journal of the Atmospheric Sciences
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