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Functionalization of Technical Textiles with Chitosan 用壳聚糖对技术纺织品进行功能化处理
Pub Date : 2024-02-15 DOI: 10.3390/textiles4010006
Kristina Klinkhammer, Hanna Hohenbild, Mohammad Toufiqul Hoque, Laura Elze, Helen Teshay, B. Mahltig
Textiles are used for many different applications and require a variety of properties. Wet functionalization improve textiles’ properties, such as hydrophilicity or antimicrobial activity. Chitosan is a bio-based polymer widely investigated in the textile industry for this purpose. A weaving comprising a cotton/polyester mix and a pure-polyester weaving was functionalized with different concentrations of chitosan to determine the most robust method for chitosan detection in both cotton- and polyester-containing materials. Additionally, mixtures of chitosan with 3-glycidyloxypropyltriethoxy silane (GLYEO) or 3-aminopropyltriethoxy silane (AMEO) were applied in a one-step or two-step procedure on the same fabrics. Scanning electron microscopy (SEM) combined with energy-dispersive X-ray spectroscopy (EDS) and dyeing with Remazol Brilliant Red F3B demonstrated the presence of chitosan and silanes on the textiles’ surfaces. While non-functionalized textiles were not stained, the dependency of the dyeing depths on the chitosan concentrations enabled us to infer the efficacy of the very short processing time and a mild dyeing temperature. The one-step application of AMEO and chitosan resulted in the highest presence of silicon on the textile and the greatest color intensity. The functionalization with GLYEO reduced the water sink-in time of polyester, while chitosan-containing solutions increased the hydrophobicity of the material. Washing experiments demonstrated the increasing hydrophilicity of the cotton/polyester samples, independent of the type of functionalization. These experiments show that chitosan-containing recipes can be used as part of a useful method, and the type of functionalization can be used to adjust the hydrophilic properties of polyester and cotton/polyester textiles. Via this first step, in the future, new combinations of bio-based polymers with inorganic binder systems can be developed, ultimately leading to sustainable antimicrobial materials with modified hydrophilic properties.
纺织品用途广泛,需要具备各种特性。湿功能化可改善纺织品的特性,如亲水性或抗菌活性。壳聚糖是纺织业为此广泛研究的一种生物基聚合物。我们用不同浓度的壳聚糖对棉/涤混合织物和纯涤纶织物进行了功能化处理,以确定在含棉和涤纶的材料中检测壳聚糖的最可靠方法。此外,壳聚糖与 3-缩水甘油氧基丙基三乙氧基硅烷(GLYEO)或 3-氨丙基三乙氧基硅烷(AMEO)的混合物以一步法或两步法应用于相同的织物。扫描电子显微镜(SEM)与能量色散 X 射线光谱(EDS)相结合,并用雷马索尔艳红 F3B 进行染色,结果表明纺织品表面存在壳聚糖和硅烷。虽然未功能化的纺织品未被染色,但染色深度与壳聚糖浓度的关系使我们能够推断出极短的加工时间和温和的染色温度的功效。一步施用 AMEO 和壳聚糖后,纺织品上的硅含量最高,颜色也最深。用 GLYEO 进行功能化可缩短涤纶的沉水时间,而含壳聚糖的溶液则可增加材料的疏水性。洗涤实验表明,棉/涤纶样品的亲水性不断增强,与官能化类型无关。这些实验表明,含壳聚糖的配方可作为有用方法的一部分,而官能化类型可用于调节聚酯和棉/涤纶纺织品的亲水性能。通过这第一步,未来可以开发出生物基聚合物与无机粘合剂系统的新组合,最终生产出具有改良亲水性能的可持续抗菌材料。
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引用次数: 0
OLEDs on Down-Converting Fabric by Using a High Scalable Planarization Process and a Transparent Polymeric Electrode 利用高可扩展性平面化工艺和透明聚合物电极在下转换织物上制造有机发光二极管
Pub Date : 2024-02-15 DOI: 10.3390/textiles4010007
C. T. Prontera, M. Pugliese, F. Mariano, D. Taurino, R. Giannuzzi, Vitantonio Primiceri, Marco Esposito, Antonio Andretta, Giuseppe Gigli, V. Maiorano
Textile-based electronics represents a key technology for the development of wearable devices. Light-emitting textiles based on OLED architecture are particularly promising due to their intrinsic flexibility and possibility to be fabricated on large areas using scalable processes. Fabric planarization is one of the most critical issues in their fabrication. Here we report a fast, simple, and industrially scalable planarization method based on the transfer of surface morphological properties from silicon to fabric. A liquid resin is used as a planarization layer, and by exploiting the low roughness of a ‘guide substrate’ it is possible to replicate the smooth and uniform surface from the silicon to the planarization layer. The result is a fabric with a flat and homogeneous polymer layer on its surface, suitable for OLED fabrication. In particular, the effect of resin viscosity on the surface morphology was evaluated to obtain the best planarization layer. The best device shows high luminance and current efficiency values, even after 1000 bending cycles. We also explored the possibility of tuning the color emitted by the device by using a fluorescent fabric as a down-converting layer. Thanks to this approach, it is in principle possible to achieve white emission from a very simple device architecture.
基于纺织品的电子技术是开发可穿戴设备的关键技术。基于 OLED 结构的发光纺织品因其固有的灵活性和使用可扩展工艺进行大面积制造的可能性而特别具有发展前景。织物平面化是其制造过程中最关键的问题之一。在此,我们报告了一种快速、简单、可工业化扩展的平面化方法,该方法基于从硅到织物的表面形态特性转移。液态树脂被用作平面化层,利用 "导向基底 "的低粗糙度,可以复制从硅到平面化层的光滑均匀表面。结果,织物表面形成了平整均匀的聚合物层,适用于制造有机发光二极管。为了获得最佳的平面化层,还特别评估了树脂粘度对表面形态的影响。最好的器件即使在经过 1000 次弯曲循环后,也能显示出较高的亮度和电流效率值。我们还探索了通过使用荧光织物作为下转换层来调整器件发射颜色的可能性。由于采用了这种方法,原则上可以通过非常简单的器件结构实现白光发射。
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引用次数: 0
OLEDs on Down-Converting Fabric by Using a High Scalable Planarization Process and a Transparent Polymeric Electrode 利用高可扩展性平面化工艺和透明聚合物电极在下转换织物上制造有机发光二极管
Pub Date : 2024-02-15 DOI: 10.3390/textiles4010007
C. T. Prontera, M. Pugliese, F. Mariano, D. Taurino, R. Giannuzzi, Vitantonio Primiceri, Marco Esposito, Antonio Andretta, Giuseppe Gigli, V. Maiorano
Textile-based electronics represents a key technology for the development of wearable devices. Light-emitting textiles based on OLED architecture are particularly promising due to their intrinsic flexibility and possibility to be fabricated on large areas using scalable processes. Fabric planarization is one of the most critical issues in their fabrication. Here we report a fast, simple, and industrially scalable planarization method based on the transfer of surface morphological properties from silicon to fabric. A liquid resin is used as a planarization layer, and by exploiting the low roughness of a ‘guide substrate’ it is possible to replicate the smooth and uniform surface from the silicon to the planarization layer. The result is a fabric with a flat and homogeneous polymer layer on its surface, suitable for OLED fabrication. In particular, the effect of resin viscosity on the surface morphology was evaluated to obtain the best planarization layer. The best device shows high luminance and current efficiency values, even after 1000 bending cycles. We also explored the possibility of tuning the color emitted by the device by using a fluorescent fabric as a down-converting layer. Thanks to this approach, it is in principle possible to achieve white emission from a very simple device architecture.
基于纺织品的电子技术是开发可穿戴设备的关键技术。基于 OLED 结构的发光纺织品因其固有的灵活性和使用可扩展工艺进行大面积制造的可能性而特别具有发展前景。织物平面化是其制造过程中最关键的问题之一。在此,我们报告了一种快速、简单、可工业化扩展的平面化方法,该方法基于从硅到织物的表面形态特性转移。液态树脂被用作平面化层,利用 "导向基底 "的低粗糙度,可以复制从硅到平面化层的光滑均匀表面。结果,织物表面形成了平整均匀的聚合物层,适用于制造有机发光二极管。为了获得最佳的平面化层,还特别评估了树脂粘度对表面形态的影响。最好的器件即使在经过 1000 次弯曲循环后,也能显示出较高的亮度和电流效率值。我们还探索了通过使用荧光织物作为下转换层来调整器件发射颜色的可能性。由于采用了这种方法,原则上可以通过非常简单的器件结构实现白光发射。
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引用次数: 0
Comparative Analysis of Electrokinetic Properties of Periodate- and TEMPO-Oxidized Regenerated Cellulose Fabric Functionalized with Chitosan 壳聚糖功能化的高活性和 TEMPO 氧化再生纤维素织物的电动特性对比分析
Pub Date : 2024-02-08 DOI: 10.3390/textiles4010005
A. Kramar, Matea Korica, Mirjana Kostić
The electrokinetic properties of materials give useful insight into the behavior of surfaces in contact with liquids and other compounds and their quantification is a powerful tool to predict their behavior during further processing and application, especially in textile materials. In this work, we perform a comparative analysis of influence of the two most common selective oxidative protocols for viscose (regenerated cellulose) fabrics on subsequent functionalization with chitosan, and cellulose fabrics’ electrokinetic properties, zeta potential in a pH range of approx. 3–10, and isoelectric point (IEP). For oxidation before deposition of chitosan, sodium periodate and 2,2,6,6-tetramethylpiperidine-1-oxy radical (TEMPO) were used. The content of functional groups in oxidized cellulose fabric (carboxyl and carbonyl groups) was determined by titration methods, while amino functional groups’ availability in samples with chitosan was determined using the CI acid orange 7 dye absorption method. This study reveals that the periodate oxidation (PO) of cellulose is more effective for binding chitosan onto material, which gave rise to higher availability of amino groups onto cellulose/chitosan material, which also influenced the shift in zeta potential curve towards positive values at a pH below 5. Analysis of a relationship between zeta potential increase at pH 4.4 and amino groups’ amount measured using absorption of CI acid orange 7 dye at pH 4.4 revealed dependency that can be fitted linearly or exponentially, with the latter providing the better fit (R2 = 0.75).
材料的电动特性有助于人们深入了解表面与液体和其他化合物接触时的行为,对其进行量化是预测其在进一步加工和应用过程中的行为的有力工具,尤其是在纺织材料中。在这项工作中,我们比较分析了两种最常见的粘胶(再生纤维素)织物选择性氧化方案对壳聚糖后续功能化的影响,以及纤维素织物的电动特性、pH 值范围约为 3-10 的 zeta 电位和等电点 (IEP) 的影响。在壳聚糖沉积前的氧化过程中,使用了高碘酸钠和 2,2,6,6-四甲基哌啶-1-氧自由基(TEMPO)。氧化纤维素织物中官能团(羧基和羰基)的含量采用滴定法测定,而壳聚糖样品中氨基官能团的含量则采用 CI 酸性橙 7 染料吸收法测定。这项研究表明,纤维素的高碘酸盐氧化(PO)能更有效地将壳聚糖结合到材料上,从而提高了纤维素/壳聚糖材料中氨基的可用性,这也影响了 zeta 电位曲线在 pH 值低于 5 时向正值移动。利用 CI 酸性橙 7 染料在 pH 值为 4.4 时的吸收情况,分析了 pH 值为 4.4 时 zeta 电位的增加与氨基基团数量之间的关系,发现两者之间的关系可按线性或指数拟合,后者的拟合效果更好(R2 = 0.75)。
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引用次数: 0
Effect of Number of Layers on Tensile and Flexural Behavior of Cementitious Composites Reinforced with a New Sisal Fabric 层数对用新型剑麻织物增强的水泥基复合材料拉伸和挠曲行为的影响
Pub Date : 2024-02-01 DOI: 10.3390/textiles4010004
Adilson Brito de Arruda Filho, P. L. Lima, Ricardo Fernandes Carvalho, Otávio da Fonseca Martins Gomes, R. D. T. Filho
The use of fabric in reinforcing cement-based materials expands their applications for various types of construction elements. Additionally, employing renewable sources of plant-based fabrics contributes to reducing the environmental impact of the construction industry. However, the variability in the properties of plant fibers and fabrics necessitates prior studies to confirm their effectiveness as reinforcement materials. In this study, a new sisal fabric was produced and utilized as reinforcement in cement-based matrix composites. The sisal fibers, yarns, and fabrics produced were tested under direct tension. Five composites were manufactured by manual lamination, with reinforcement ranging from one to five layers, and were subjected to direct tension and flexural testing. The results indicate that, while the fiber shows brittle failure, the yarn and fabric exhibit a gradual loss of strength after reaching the maximum tension. All composites display strain-hardening and deflection-hardening behavior, with multiple cracking and an increase in tension and deformation before rupture. The mechanical properties exhibited improvement with an increase in the number of layers, and composites with four and five layers displayed distinct behavior, demonstrating increased stiffness after the occurrence of multiple cracking and a better mechanical performance, qualifying them for use as a construction element.
在水泥基加固材料中使用织物,扩大了其在各类建筑构件中的应用。此外,使用可再生的植物纤维织物还有助于减少建筑业对环境的影响。然而,由于植物纤维和织物的特性各不相同,因此有必要对其进行预先研究,以确认其作为加固材料的有效性。在这项研究中,生产了一种新型剑麻织物,并将其用作水泥基复合材料的加固材料。所生产的剑麻纤维、纱线和织物在直接拉力下进行了测试。五种复合材料是通过手工层压制造的,加固层从一层到五层不等,并进行了直接拉伸和弯曲测试。结果表明,纤维呈现脆性破坏,而纱线和织物在达到最大拉力后会逐渐失去强度。所有复合材料都表现出应变硬化和挠曲硬化行为,在断裂前会出现多次开裂以及拉力和变形的增加。随着层数的增加,复合材料的机械性能也有所改善,四层和五层的复合材料表现出不同的行为,在出现多重开裂后刚度增加,机械性能更好,可用作建筑构件。
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引用次数: 0
Mechanical Property Characterization of Architectural Coated Woven Fabrics Subjected to Freeze–Thaw Cycles 受冻融循环影响的建筑涂层机织物的机械特性表征
Pub Date : 2024-01-11 DOI: 10.3390/textiles4010003
H. Asadi, J. Uhlemann, N. Stranghoener, Mathias Ulbricht
This paper presents experimental investigations into the freeze–thaw response of two common architectural coated woven fabrics. Strip specimens for the tensile tests were exposed to −20 °C for three hours followed by three hours of thaw at ambient temperatures. This was repeated for a maximum of 100 cycles. Afterwards, the residual tensile strength was measured and compared to results achieved for test specimens without prior freeze–thaw cycles. Maximum mean tensile strength reductions of approximately 21% (warp direction) and 19% (weft direction) for probed polytetrafluoroethylene (PTFE)-coated woven glass fiber fabrics were identified, while no remarkable tensile strength deterioration rate was observed for the investigated polyvinyl chloride-coated woven polyethylene terephthalate materials. Overall, the results indicate that freeze–thaw cycles can have a significant deteriorating impact on the mechanical properties of glass-PTFE fabrics.
本文介绍了对两种常见建筑涂层编织物冻融反应的实验研究。用于拉伸测试的带状试样在零下 20 °C 的环境中暴露三小时,然后在环境温度下解冻三小时。如此反复进行,最多循环 100 次。之后,测量残余拉伸强度,并将其与未进行冻融循环的试样结果进行比较。结果表明,聚四氟乙烯(PTFE)涂层玻璃纤维编织物的最大平均拉伸强度降低了约 21%(经线方向)和 19%(纬线方向),而聚氯乙烯涂层聚对苯二甲酸乙二醇酯编织物的拉伸强度没有明显下降。总之,研究结果表明,冻融循环会对玻璃-聚四氟乙烯织物的机械性能产生明显的恶化影响。
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引用次数: 0
Sensory Considerations for Emerging Textile Applications 新兴纺织品应用的感官考虑因素
Pub Date : 2024-01-04 DOI: 10.3390/textiles4010002
Emma Kay, Jessica Levick, Tawanda Machingura, Stephen Bird
Textiles are increasingly playing a role as a therapeutic medium in the disability field as well as in everyday life. This paper aims to review the literature on the relationship between textiles and sensory integration or sensory preferences in the general population. A brief literature review was conducted using PubMed (MEDLINE), SCOPUS, and Google Scholar. The review of the current literature highlights some key themes in the literature, including the indication that adaptive and sensory clothing design requires consideration of the textiles and fabrics being used, the functionality and appearance of garments, and affordability and access. The evidence suggests that clothing design should utilize soft fabrics which are seamless, have limited external tags, support social participation and functional engagement in daily activities, and are accessible.
在残疾领域和日常生活中,纺织品越来越多地扮演着治疗媒介的角色。本文旨在回顾有关纺织品与普通人群感觉统合或感觉偏好之间关系的文献。我们使用 PubMed (MEDLINE)、SCOPUS 和 Google Scholar 进行了简要的文献综述。对现有文献的回顾突出了文献中的一些关键主题,包括适应性和感官服装设计需要考虑所使用的纺织品和面料、服装的功能性和外观,以及可负担性和可获得性。有证据表明,服装设计应使用无缝、外部标签有限、支持社会参与和日常活动功能性参与以及方便获取的柔软织物。
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引用次数: 0
State of the Art in Textile Waste Management: A Review 纺织废物管理的最新技术:综述
Pub Date : 2023-12-18 DOI: 10.3390/textiles3040027
K. Tang
Textile waste constitutes a significant fraction of municipal solid waste sent to landfill or incinerated. Its innovative management is important to enhance sustainability and circularity. This review aims to present the latest policies and the state-of-the-art technologies in the collection, sorting and recycling of textile waste. Policies at global and regional levels are increasingly made to address the sustainability of the textile industry and integrate the concept of circular economy. They are crucial to driving changes and innovations in current textile waste management. The Internet of Things, big data, blockchain and smart contracts have been proposed to improve transparency, traceability and accountability in the textile waste collection process. They optimize collection routes, and transactions and agreements among stakeholders. The sorting of textile waste using near-infrared spectroscopy, optical sorting and artificial intelligence enables its separation based on composition, color and quality. The mechanical recycling of textiles regenerates fibers with the same or different applications from those of the original fabrics. Fibers have been used for making building and slope protection materials. Chemical recycling depolymerizes waste textiles using chemicals to produce monomers for new textiles or other materials, while biological recycling uses enzymes and microorganisms for this purpose instead of chemicals. Thermal recycling recovers energy and fuels from textile waste through pyrolysis, gasification and hydrothermal liquefaction. These innovations may have the drawbacks of high cost and scalability. This review contributes to decision making by synthesizing the strengths and weaknesses of the innovations in textile waste management.
在送往垃圾填埋场或焚化的城市固体废物中,纺织废物占了很大一部分。创新管理对于提高可持续性和循环性非常重要。本综述旨在介绍纺织废物收集、分类和回收利用方面的最新政策和先进技术。全球和地区层面的政策越来越多地涉及纺织业的可持续性和循环经济概念。这些政策对于推动当前纺织废物管理的变革和创新至关重要。有人提出利用物联网、大数据、区块链和智能合约来提高纺织废物收集过程的透明度、可追溯性和问责制。它们优化了收集路线以及利益相关者之间的交易和协议。利用近红外光谱、光学分拣和人工智能对纺织废物进行分拣,可根据成分、颜色和质量对其进行分类。纺织品的机械再循环使纤维再生,其用途与原织物相同或不同。纤维已被用于制造建筑和护坡材料。化学回收利用化学品对废弃纺织品进行解聚,生产出新纺织品或其他材料的单体,而生物回收则利用酶和微生物来代替化学品。热回收利用通过热解、气化和水热液化从纺织废料中回收能源和燃料。这些创新技术可能存在成本高和可扩展性差的缺点。本综述总结了纺织废物管理创新的优缺点,有助于决策。
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引用次数: 0
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Textiles
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