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Crystal structure of nesquehonite, MgCO3·3H(D)2O by neutron diffraction and effect of pH on structural formulas of nesquehonite 中子衍射法研究钠铝石MgCO3·3H(D)2O的晶体结构及pH对钠铝石结构式的影响
IF 0.7 4区 地球科学 Q4 MINERALOGY Pub Date : 2021-04-27 DOI: 10.2465/JMPS.200117
Gen–ichiro Yamamoto, A. Kyono, J. Abe, A. Sano‐Furukawa, T. Hattori
Neutron di ff raction, Raman spectroscopy, and thermal analysis were performed to investigate the composition, structure, and formation conditions of the magnesium carbonate hydrate nesquehonite. The crystal structure of deuterated nesquehonite was analyzed by Rietveld re fi nement of the time – of – fl ight neutron powder di ff raction pattern. The crystal structure possessed the monoclinic space group P 2 1 / n with lattice parameters of a = 7.72100(12) Å, b = 5.37518(7) Å, c = 12.1430(3) Å, β = 90.165(4)°, and V = 503.956(13) Å 3 . The re fi nement with a fi nal crystal structure model of deuterated nesquehonite converged to wRp = 4.22% and Rp = 3.50%. The result of structure re fi nement showed that two deuterium atoms are coordinated to the O1, O2, and O6 atoms as a water molecule in the nesquehonite. The fact that the three water molecules were included in the structure suggests the structural formula of the nesquehonite obtained in the study should be written as MgCO 3 ·3H 2 O not Mg(HCO 3 )(OH)·2H 2 O.
进行了中子衍射、拉曼光谱和热分析,以研究碳酸镁水合物钠石的组成、结构和形成条件。通过Rietveld对轻中子粉末衍射时间模式的分析,分析了氘核钠石的晶体结构。晶体结构具有单斜空间群P2 1/n,晶格参数为a=7.72100(12)Å,b=5.37518(7)Å、c=12.1430(3)Å和β=90.165(4)°,V=503.956(13)Å3。用氘化钠石的最终晶体结构模型进行的研究收敛到wRp=4.22%和Rp=3.50%。结构研究结果表明,两个氘原子作为水分子与钠石中的O1、O2和O6原子配位。三种水分子都包含在该结构中,这表明本研究中获得的nesquehonite的结构式应写成MgCO3·3H2O,而不是Mg(HCO3)(OH)·2H2O。
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引用次数: 3
Zircon U–Pb ages and whole–rock geochemistry from the Hida granites: implications for the geotectonic history and the origin of Mesozoic granites in the Hida belt, Japan 日本飞驒花岗岩锆石U-Pb年龄及全岩地球化学:对日本飞驒带中生代花岗岩构造史及成因的启示
IF 0.7 4区 地球科学 Q4 MINERALOGY Pub Date : 2021-02-25 DOI: 10.2465/JMPS.201125
Raiki Yamada, H. Sawada, Shinnosuke Aoyama, Wataru Ouchi, S. Niki, M. Nagata, Toshiro Takahashi, T. Hirata
The Hida granites, classi fi ed into the pre – Jurassic and Jurassic plutons in this study, are important components of the Hida belt, which is a Paleozoic – Mesozoic basement of the Japan arc and underwent Permian to Triassic metamorphism during the collision between the North and South China blocks. This study performed zircon U – Pb dating and whole – rock geochemical analyses for the Hida granites from the major plutonic bodies to reveal the geotectonic history and the origin of the Hida belt. Obtained 238 U – 206 Pb weighted mean ages exhibit 239.1 – 238.3 Ma for the Katakaigawa body (augen granite) and 200.5 – 180.9 Ma for the other bodies (non – deformed granitoids), and these ages can be correlated to the pre – Jurassic and Jurassic plutons, respectively. Geochronological results suggest that the mylonitization forming augen granites of the pre – Jurassic plutons occurred during its intrusion and indicate that the Jurassic plutons are distributed widely in the Japan Sea side of the Hida belt. Meanwhile, geochemical characteristics of whole – rock major and trace element compositions indicate that the pre – Jurassic and Jurassic plutons seem di ffi cult to distinguished geochemically and suggest that both of them are adakitic and non – adakitic granites generated in subduction zone.
Hida花岗岩在本研究中被分为前侏罗纪和侏罗纪深成岩体,是Hida带的重要组成部分,Hida带是日本弧的古生代-中生代基底,在华北和华南地块碰撞期间经历了二叠纪至三叠纪的变质作用。本研究对主要深成岩体中的Hida花岗岩进行了锆石U-Pb定年和全岩地球化学分析,揭示了Hida带的大地构造史和起源。获得的238 U–206 Pb加权平均年龄Katakaigawa岩体(眼球状花岗岩)为239.1–238.3 Ma,其他岩体(非变形花岗岩)为200.5–180.9 Ma,这些年龄可分别与前侏罗纪和侏罗纪深成岩体相关。地质年代学结果表明,前侏罗纪深成岩体的糜棱岩化形成眼球状花岗岩是在其侵入过程中发生的,并表明侏罗纪深成岩广泛分布于Hida带的日本海一侧。同时,全岩主元素和微量元素组成的地球化学特征表明,前侏罗纪和侏罗纪深成岩体似乎难以从地球化学上区分,并表明它们都是俯冲带中生成的阿达克花岗岩和非阿达克花岗岩。
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引用次数: 5
Ore and skarn mineralogy of the Eboshi deposit of the Naganobori copper mine, Yamaguchi, Japan 日本山口长野博里铜矿埃布石矿床的矿石和矽卡岩矿物学
IF 0.7 4区 地球科学 Q4 MINERALOGY Pub Date : 2021-02-10 DOI: 10.2465/JMPS.200818
M. Nagashima, Y. Morishita, Yuji Imoto, T. Imaoka
Mineral assemblages and chemical compositions of ore minerals from the Eboshi deposit, the historical Naganobori copper mine, Yamaguchi Prefecture, Japan were investigated in order to clarify its characteristics as a skarn deposit. Some Bi – , Ag – , and Te – bearing minerals are newly identi fi ed, which contribute updating the mineralization sequence of this deposit. Samples collected from the mine dump are one massive magnetite ore, and copper ores associated with skarn gangue minerals. Skarns are categorized as clinopyroxene skarn, garnet skarn, and wollastonite skarn, and the clinopyroxene skarn is the most dominant. The major ore minerals are chalcopyrite, cobaltite, and early – stage pyrite (Py – I) and later stage pyrite (Py – II). Py – II is enriched in arsenic (~ 5.19 As wt%). The Bi – , Ag – , and Te – bearing minerals, such as native bismuth, bismuthinite, wittichenite, emplectite, tsumoite, kawazulite, hessite, and matildite are minor ore minerals. Based on the mineral assemblages and textures of the specimens examined, four ore mineralization stages were recognized; the ore mineralization stage I is characterized by the major ore minerals such as chalcopyrite, bornite, pyrrhotite, sphalerite, and Py – I. The stage II is de fi ned by the mineralization of cobaltite, Py – II, and Bi( – Cu) – bearing sul fi des such as native bismuth, bismuthinite, and wittichenite. The mineralization stage III is characterized by the Ag – and/or Te – bearing ore minerals such as matildite, kawazulite, tsumoite, and hessite. The stage IV is characterized by chalcopyrite veins cutting the main skarn masses and the host limestone. The mineralogical properties and mineralization process of the Eboshi deposit is similar to those of the skarn deposits in the Yamato mine and the Tsumo mine, and consistent with common skarn – type deposits associated with ilmenite – series granitoids in the San – yo Belt, which are characterized by the occurrence of minor Ag – and/or Te – bearing ore minerals.
为了阐明其矽卡岩型矿床的特征,对日本山口县历史悠久的长野原铜矿埃布石矿床的矿物组合和矿物化学成分进行了研究。一些含Bi、Ag和Te的矿物是新发现的,它们有助于更新该矿床的矿化序列。从矿山排土场采集的样品是一种块状磁铁矿,以及与矽卡岩脉石矿物有关的铜矿。矽卡岩分为单斜辉石矽卡岩、石榴石矽卡岩和硅灰石矽卡岩,其中以单斜辉石夕卡岩为主。主要矿石矿物为黄铜矿、钴矿、早期黄铁矿(Py–I)和晚期黄铁矿(Py-II)。Py–II富含砷(~5.19 As wt%)。含铋、Ag和Te的矿物,如天然铋、铋矿、硫铁镍矿、铁闪锌矿、铁云母、川流石、赤铁矿和钛铁矿,都是次要的矿石矿物。根据样品的矿物组合和结构,识别出四个成矿阶段;矿石矿化阶段I的特征是主要矿石矿物,如黄铜矿、斑铜矿、磁黄铁矿、闪锌矿和Py–I。阶段II的特征是钴矿、Py–II和含Bi(–Cu)硫化物的矿化,如天然铋、铋矿和硫铁矿。矿化阶段III的特征是含Ag和/或Te的矿石矿物,如钛铁矿、川流石、铁闪锌矿和赤铁矿。第四阶段的特征是黄铜矿矿脉切割了主要的矽卡岩块和主石灰岩。埃博希矿床的矿物学性质和矿化过程与大和矿和津磨矿的矽卡岩矿床相似,并与San–yo带中与钛铁矿-系列花岗质岩石相关的常见矽卡岩型矿床一致,其特征是出现少量含Ag和/或Te的矿石矿物。
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引用次数: 1
Chemical and lithium isotope characteristics of murakamiite and Li–rich pectolite from Iwagi Islet, Southwest Japan 日本西南部岩城岛村上岩和富锂果胶岩的化学和锂同位素特征
IF 0.7 4区 地球科学 Q4 MINERALOGY Pub Date : 2021-02-10 DOI: 10.2465/JMPS.200721
T. Imaoka, J. Kimura, Q. Chang, T. Ishikawa, M. Nagashima, N. Takeshita
We report in situ major and trace element and Li isotope analyses of murakamiite and Li – rich pectolite in an albitite and whole – rock analyses of the albitite and host granite from Iwagi Islet, SW Japan. The albitite forms small bodies that are several tens of centimeters to tens of meters in size, disseminated in a host granite of Late Cretaceous age. The studied murakamiite – bearing albitite contains albite, sugilite, aegirine – augite, quartz, murakamiite – Li – rich pectolite, microcline, katayamalite, and accessory minerals. It shows conspicuous strain – induced textures. The murakamiite and Li – rich pectolite form a solid solution with Li × 100/(Li + Na) atomic ratios ranging from 44.2 to 60.1, and the Na line pro fi les show a zoning structure in which Na decreases from core to rim. Major and trace element compositions of murakamiite – pectolite normalized to that of albitite in-dicate the enrichments of some elements, particularly in Mn, Ca, Li, Sr, and REEs, roughly on the same order of magnitude (~ 10 times). The albitite – normalized element concentrations vary systematically with ionic radius of the element; the normalized concentrations of cations with the same valence roughly form a simple convex parabolic curve when plot against the ionic radius. This indicates that the element partitioning of murakamiite and pectolite during metasomatism to form albitite took place under a strong control of crystal structure, quasi – equilibrated with metasomatic fl uids and coexisting minerals. The δ 7 Li values of murakamiite and Li – rich pectolite show a wide range from − 9.1 to +0.4 ‰ (average − 2.9 ‰ ), and no obvious correlation with Li contents was observed. These δ 7 Li values should have resulted from hydrothermal fl uid – rock interactions at the temperatures of 300 – 600 °C. The very low δ 7 Li values down to − 9.1 ‰ may have originated from intra – crystalline Li isotope di ff usion, or involvement of deep – seated, Li – Na – enriched subduction – zone fl uids with low δ 7 Li values. ,
我们报道了日本西南部岩城岛钠长岩中村神岩和富锂果胶岩的原位主元素、微量元素和锂同位素分析,以及钠长岩和寄主花岗岩的全岩分析。钠长石形成几十厘米到几十米大小的小型岩体,散布在白垩纪晚期的花岗岩中。所研究的含云纹岩的钠长石包含钠长石、苏铁榴石、赤铁矿-辉石、石英、富云纹岩-富锂果胶岩、微斜长石、方钠石和副矿物。它显示出明显的应变诱导纹理。Murakamite和富含Li的pectolite形成了Li×100/(Li+Na)原子比为44.2~60.1的固溶体,Na线颗粒显示出Na从核心到边缘减少的分区结构。与钠长石标准化后的村安岩-镜铁矿的主元素和微量元素组成表明,一些元素的富集程度大致相同(约10倍),特别是Mn、Ca、Li、Sr和REE。钠长石-归一化元素浓度随元素离子半径的变化而系统变化;具有相同化合价的阳离子的归一化浓度在相对于离子半径绘制时大致形成简单的凸抛物线。这表明,在交代形成钠长石的过程中,Murakamite和pectolite的元素分配是在晶体结构的强烈控制下进行的,与交代流体和共存矿物准平衡。村安岩和富锂果胶岩的δ7Li值范围较宽,为−9.1~+0.4‰(平均−2.9‰),与Li含量无明显相关性。这些δ7 Li值应该是300–600°C温度下热液-流体-岩石相互作用的结果。低至−9.1‰的非常低的δ7 Li值可能源于晶体内Li同位素的扩散,或参与了低δ7 Li的深层富集Li的俯冲带流动,
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引用次数: 6
Discovery of datolite in a high–pressure marble from the Sanbagawa metamorphic belt: Indication of B–rich fluid activity 三巴川变质带高压大理岩中datolite的发现:富b流体活动的指示
IF 0.7 4区 地球科学 Q4 MINERALOGY Pub Date : 2021-01-01 DOI: 10.2465/jmps.200730
Kenta Yoshida, S. Niki, H. Sawada, R. Oyanagi
Datolite [CaBSiO 4 (OH)] was discovered in an eclogite – facies calcite marble collected from the Eastern Iratsu body in the Sanbagawa metamorphic belt of central Shikoku. The marble was composed of calcite, diopside, and garnet that contained inclusions of omphacite. Enclosed in the marble is a pod composed mainly of quartz, with subordinate calcite, diopside, and garnet that has inclusions of datolite. The formation conditions of the datolite were estimated on the basis of mineral assemblage and the Raman elastic geobarometer to be approximately 400 – 650 °C and 0.8 – 1.3 GPa, which coincide with the conditions of the eclogite juxtaposition with the non – eclogite units in the Besshi district. Our study records the highest pressure – temperature conditions as the metamorphic datolite formation. Our fi ndings provide evidence for the occurrence of B – rich fl uid in fi ltration during the juxtaposition of eclogite unit with the non – eclogite unit in the Besshi district.
在四国中部三巴川变质带东伊拉苏体的榴辉岩相方解石大理岩中发现了[cabsio4 (OH)]。大理石由方解石、透辉石和石榴石组成,其中含有辉长石包裹体。包裹在大理石中的是一个主要由石英组成的荚果,辅之以方解石、透辉石和石榴石,石榴石含有英脱石包裹体。根据矿物组合和拉曼弹性地压估算,该datolite的形成条件约为400 ~ 650℃,0.8 ~ 1.3 GPa,与Besshi地区榴辉岩单元与非榴辉岩单元并置的条件相吻合。我们的研究记录了最高压力-温度条件下的变质datolite的形成。本研究结果为贝石地区榴辉岩单元与非榴辉岩单元并置时富B流体的发生提供了证据。
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引用次数: 2
Modulated structure of hemimorphite associated with pressure–induced phase transition 与压力诱导相变相关的半晶岩调制结构
IF 0.7 4区 地球科学 Q4 MINERALOGY Pub Date : 2021-01-01 DOI: 10.2465/jmps.210731
K. Okamoto, T. Kuribayashi, T. Nagase
In situ high – pressure single – crystal X – ray di ff raction experiments on natural hemimorphite, ideally Zn 4 [Si 2 O 7 ](OH) 2 ·H 2 O, up to 4.7 GPa were conducted to investigate its pressure response property associated with pressure – induced phase transition. After the phase transition con fi rmed between 2.46 and 3.01 GPa, pairs of satellite re fl ections were newly found at certain Bragg re fl ections. The modulation vector q of the satellites was approximately [0, 1/8.4, 0]. The results of the re fi nements on the averaged structure indicated that the modulation arose from displacements of atomic sites associated with the mechanism of the phase transition, i.e., the rotation of the secondary building unit (SBU). The lower rotation angle of the SBU ( Φ ) than the value estimated from the non – modulated structure meant that the high – pressure phase contained anti – phase boundaries (APBs) resulting from the opposite direction of the SBU rotation and that the coherency was held across the APBs. Within the coherent domain, the APB ’ s intervals were distributed along the b – axis with a mean value of 8.4 b ≈ 90 Å, where the displacement of each site η ( y ) was approximated as the fi rst – harmonic. The distribution of the direction of SBU rotation was initially considered to be inhomogeneous, but the elimination of the APBs had proceeded anisotropically and had been aborted below 3.01 GPa.
采用原位高压X射线衍射实验,研究了天然半非晶zn4 [si2o7](OH) 2·h2o在高达4.7 GPa的条件下的压力响应特性。在2.46 ~ 3.01 GPa之间确认相变后,在某些Bragg反射区发现了卫星反射对。卫星的调制矢量q近似为[0,1 /8.4,0]。对平均结构的修正结果表明,调制是由与相变机制有关的原子位的位移引起的,即次级结构单元(SBU)的旋转。SBU的旋转角度(Φ)比非调制结构估计的值小,这意味着高压相包含由SBU旋转方向相反引起的反相边界(apb),并且在apb之间保持了相干性。在相干域中,APB的间隔沿b轴方向分布,平均值为8.4 b≈90 Å,其中各点的位移η (y)近似为一次谐波。SBU旋转方向的分布最初被认为是不均匀的,但apb的消除是各向异性的,并在3.01 GPa以下中止。
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引用次数: 0
Zircon U–Pb ages of the pegmatites in the Kontum massif, central Vietnam and their quality evaluation for ceramic industry 越南中部孔图姆地块伟晶岩锆石U-Pb年龄及其陶瓷工业用质量评价
IF 0.7 4区 地球科学 Q4 MINERALOGY Pub Date : 2021-01-01 DOI: 10.2465/jmps.210911
Truong Chi Cuong, P. T. Hieu, Pham Quang Nhat Minh, Kenta Kawaguchi, Nong T. Q. Anh, K. Hung
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引用次数: 1
Evolution of supracrustal rocks of the Indochina Block: Evidence from new detrital zircon U–Pb ages of the Kontum Massif, Central Vietnam
IF 0.7 4区 地球科学 Q4 MINERALOGY Pub Date : 2021-01-01 DOI: 10.2465/JMPS.200916
Kenta Kawaguchi, P. Minh, P. T. Hieu, Truong Chi Cuong, K. Das
*Department of Earth and Environmental Sciences, Jeonbuk National University, Jeonju 54896, Republic of Korea **Department of Earth and Planetary Systems Science, Graduate School of Science, Hiroshima University, Higashi–Hiroshima 739–8526, Japan ***Faculty of Geology, University of Science, Ho Chi Minh City, Vietnam Vietnam National University, Ho Chi Minh City, Vietnam ‡Hiroshima Institute of Plate Convergence Region Research, Higashi–Hiroshima 739–8526, Japan
*全北大学地球与环境科学系,全州54896 **广岛大学理学院地球与行星系统科学系,日本广岛739-8526 ***越南胡志明市理学院地质学系越南国立大学,越南胡志明市广岛板块辐合区研究所,日本广岛739-8526
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引用次数: 9
Structure changes of nanocrystalline mackinawite under hydrothermal conditions: formation of greigite and its structural properties 水热条件下纳米晶镁铁的结构变化:灰长岩的形成及其结构性质
IF 0.7 4区 地球科学 Q4 MINERALOGY Pub Date : 2021-01-01 DOI: 10.2465/jmps.210418
Y. Sano, A. Kyono
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引用次数: 0
Structure Refinement of Prehnite from Passaic County, New Jersey, USA 美国新泽西州帕塞克县普瑞尼特的结构改良
IF 0.7 4区 地球科学 Q4 MINERALOGY Pub Date : 2021-01-01 DOI: 10.2465/jmps.210318
K. Sugiyama, T. Kawamata, T. Kuribayashi
The crystal structure of prehnite Ca2(Al, Fe)(Si3AlO10)(OH)2 from Upper New Street Quarry, Paterson, Passaic County, New Jersey, USA was determined by single–crystal X–ray diffraction. The converged structural model in the space group P2cm [a = 4.63309(9) Å, b = 5.4839(1) Å, c = 18.5100(3) Å, Z = 2] allowed for the investigation of an ordered Si/Al distribution together with the feasible hydrogen positions inferred from the difference Fourier maps.
用单晶x射线衍射法测定了美国新泽西州帕塞克县帕特森Upper New Street采石场钙(Al, Fe)(Si3AlO10)(OH)2的晶体结构。空间群P2cm中的收敛结构模型[a = 4.63309(9) Å, b = 5.4839(1) Å, c = 18.5100(3) Å, Z = 2]允许研究有序的Si/Al分布以及由差分傅里叶映射推断的可行氢位置。
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引用次数: 1
期刊
Journal of Mineralogical and Petrological Sciences
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