P. Pauliš, Libor Hrůzek, Oldřich Janeček, Z. Dolníček, Volker Betz, Luboš Vrtiška, Radana Malíková, Ondřej Pour, F. Fediuk
A new locality of zeolite minerals occurs on the NE edge of the Jedlka village, at the SE slope of the Hlídka hill, 2 km to W of Benešov nad Ploučnicí (northern Bohemia, Czech Republic). The mineralization is developed in Cenozoic analcime-nepheline tephrite. Ten zeolite mineral species (gmelinite-K, analcime, harmotome, chabazite-Ca, lévyne-Ca, mezolite, natrolite, offretite, phillipsite-K, thomsonite-Ca) were found in small amygdule cavities of tephrite. The most interesting is gmelinite-K, a rare zeolite worldwide, which forms clear, white or slightly yellowish, hexagonal lenticular crystals up to 7 mm, always intergrown with the chabazite-Ca. The unit-cell parameters of gmelinite-K, refined from the powder X-ray data, are a = 13.795 (19), c = 9.811(6) Å and V = 1616.8(3) Å3; its quantitative chemical analyses correspond to the empirical formula (K2.32Ca1.86Sr0.53Na0.20Ba0.19)Σ5.10(Al8.14Si16.01O48)·22H2O.
一个新的沸石矿物产地出现在Jedlka村的东北边缘，在Hlídka山的东南斜坡上，距离Benešov nad Ploučnicí(捷克共和国波希米亚北部)2公里。成矿发育于新生代钙霞石碧玉中。在软玉的小淀粉体孔洞中发现了10种沸石矿物(闪辉石- k、安钙石、调和石、辉辉石- ca、lsamvyne - ca、间沸石、钠沸石、offrite、phillipsite-K、thomsonite-Ca)。最有趣的是闪辉石- k，这是一种世界上罕见的沸石，它形成透明的，白色或微黄色的六角形透镜状晶体，高达7毫米，总是与辉石- ca共生。根据粉末x射线数据，得到gmelite - k的单位胞参数为a = 13.795 (19)， c = 9.811(6) Å， V = 1616.8(3) Å3;其定量化学分析符合实验式(K2.32Ca1.86Sr0.53Na0.20Ba0.19)Σ5.10(Al8.14Si16.01O48)·22H2O。
{"title":"Zeolitová mineralizace s gmelinitem-K z Jedlky u Benešova nad Ploučnicí (Česká republika)","authors":"P. Pauliš, Libor Hrůzek, Oldřich Janeček, Z. Dolníček, Volker Betz, Luboš Vrtiška, Radana Malíková, Ondřej Pour, F. Fediuk","doi":"10.46861/bmp.29.213","DOIUrl":"https://doi.org/10.46861/bmp.29.213","url":null,"abstract":"A new locality of zeolite minerals occurs on the NE edge of the Jedlka village, at the SE slope of the Hlídka hill, 2 km to W of Benešov nad Ploučnicí (northern Bohemia, Czech Republic). The mineralization is developed in Cenozoic analcime-nepheline tephrite. Ten zeolite mineral species (gmelinite-K, analcime, harmotome, chabazite-Ca, lévyne-Ca, mezolite, natrolite, offretite, phillipsite-K, thomsonite-Ca) were found in small amygdule cavities of tephrite. The most interesting is gmelinite-K, a rare zeolite worldwide, which forms clear, white or slightly yellowish, hexagonal lenticular crystals up to 7 mm, always intergrown with the chabazite-Ca. The unit-cell parameters of gmelinite-K, refined from the powder X-ray data, are a = 13.795 (19), c = 9.811(6) Å and V = 1616.8(3) Å3; its quantitative chemical analyses correspond to the empirical formula (K2.32Ca1.86Sr0.53Na0.20Ba0.19)Σ5.10(Al8.14Si16.01O48)·22H2O.","PeriodicalId":53145,"journal":{"name":"Bulletin Mineralogie Petrologie","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70599042","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The Pb-Sb mineralization with dominant stibnite and plagionite and associated semseyite and zinkenite was found in an archive material collected at the Antimonitová vein, Bohutín, Březové Hory ore district (Czech Republic). Plagionite forms subhedral aggregates up to 1 mm in size. The unit-cell parameters of plagionite for monoclinic space group C2/c refined from the X-ray powder data are: a 13.4890(17), b 11.8670(14), c 19.997(2) Å, β 107.199(8)° and V 3057.9(6) Å3. Its chemical composition (average of 26 analyses, based on 30 apfu) corresponds to the empirical formula Pb5.02Sb8.15S16.82. Associated zinkenite is forming subhedral crystals up to 1 mm in size. Its empirical formula can be expressed as (Cu0.25Ag0.02Fe0.01)Σ0.28Pb9.22Sb22.19S41.31 (average of 26 analyses, based on 73 apfu). Semseyite aggregates have the empirical formula (Pb8.72Fe0.14)8.86Sb8.42S20.73 (average of 11 analyses, based on 38 apfu).
在捷克霍里矿区(Bohutín, Březové)的一份档案资料中，发现了以辉锑矿和斜长石为主，并伴有半锡锑矿和锌锑矿的铅锌矿化。斜长石形成大小可达1毫米的半面体聚集体。单斜空间群C2/c斜长石的单位胞参数分别为:a 13.4890(17)， b 11.8670(14)， c 19.997(2) Å， β 107.199(8)°，V 3057.9(6) Å3。其化学成分(26次分析的平均值，基于30 apfu)对应于实验式Pb5.02Sb8.15S16.82。伴生锌矿正在形成尺寸达1毫米的半面体晶体。其经验公式为(Cu0.25Ag0.02Fe0.01)Σ0.28Pb9.22Sb22.19S41.31(26次分析的平均值，基于73 apfu)。Semseyite团聚体的经验公式为(Pb8.72Fe0.14)8.86Sb8.42S20.73(平均11次分析，基于38 apfu)。
{"title":"Pb-Sb zrudnění z Antimonitové žíly, důl Rudolf, Bohutín (Česká republika)","authors":"Pavel Škácha, J. Sejkora","doi":"10.46861/bmp.29.275","DOIUrl":"https://doi.org/10.46861/bmp.29.275","url":null,"abstract":"The Pb-Sb mineralization with dominant stibnite and plagionite and associated semseyite and zinkenite was found in an archive material collected at the Antimonitová vein, Bohutín, Březové Hory ore district (Czech Republic). Plagionite forms subhedral aggregates up to 1 mm in size. The unit-cell parameters of plagionite for monoclinic space group C2/c refined from the X-ray powder data are: a 13.4890(17), b 11.8670(14), c 19.997(2) Å, β 107.199(8)° and V 3057.9(6) Å3. Its chemical composition (average of 26 analyses, based on 30 apfu) corresponds to the empirical formula Pb5.02Sb8.15S16.82. Associated zinkenite is forming subhedral crystals up to 1 mm in size. Its empirical formula can be expressed as (Cu0.25Ag0.02Fe0.01)Σ0.28Pb9.22Sb22.19S41.31 (average of 26 analyses, based on 73 apfu). Semseyite aggregates have the empirical formula (Pb8.72Fe0.14)8.86Sb8.42S20.73 (average of 11 analyses, based on 38 apfu).","PeriodicalId":53145,"journal":{"name":"Bulletin Mineralogie Petrologie","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70599060","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The heavy mineral concentrate originating from Permian freshwater sandstones/arkoses from the Tismice site (northern part of the Blanice Furrow, Bohemian Massif, Czech Republic) was studied in terms of mineral composition and chemical composition of selected phases. Ilmenite, to various degree altered to a TiO2 phase and/or unidentified non-stoichiometric Fe-Ti (hydro)oxides, is the predominating constituent of heavy mineral fraction. Garnet, tourmaline, apatite and baryte are subordinate components. Garnet (with commonly etched “drusy” surface) belongs exclusively to almandine (Alm45-91Prp4-27Sps1-32Grs0-17Adr0-5). Tourmaline has variable chemical composition, but oxy-dravite prevails. Accessory phases include biotite, REE-rich goyazite (Goy45-59Flo29-43Cra11-17Gor0-1), zircon, pyrite, limonite, gahnite (Ghn57-68Hrc21-32Spl7-10Mgt1-2Gal1), staurolite, xenotime and monazite. Baryte and goyazite were likely formed during diagenesis of the host sediments or during later hydrothermal activity. Detrital garnet and tourmaline were probably sourced from the granulites, mica schists and migmatites of the Malín segment of the neighbouring Kutná Hora Crystalline Complex (KHCC). Surprisingly, amphibolites or serpentinites, frequently present in areas of the KHCC more proximal to the Permian sedimentary basin, did not contribute their garnets. We suggest that these areas were not exposed to erosion during the Permian period. Spectacular etching of surface of garnets and pervasive alteration of ilmenite were associated with burial diagenesis of the host sediments.
{"title":"Minerály těžké frakce arkózových pískovců z Tismic u Českého Brodu (perm blanické brázdy, Česká republika)","authors":"Z. Dolníček, Jana Ulmanová","doi":"10.46861/bmp.29.337","DOIUrl":"https://doi.org/10.46861/bmp.29.337","url":null,"abstract":"The heavy mineral concentrate originating from Permian freshwater sandstones/arkoses from the Tismice site (northern part of the Blanice Furrow, Bohemian Massif, Czech Republic) was studied in terms of mineral composition and chemical composition of selected phases. Ilmenite, to various degree altered to a TiO2 phase and/or unidentified non-stoichiometric Fe-Ti (hydro)oxides, is the predominating constituent of heavy mineral fraction. Garnet, tourmaline, apatite and baryte are subordinate components. Garnet (with commonly etched “drusy” surface) belongs exclusively to almandine (Alm45-91Prp4-27Sps1-32Grs0-17Adr0-5). Tourmaline has variable chemical composition, but oxy-dravite prevails. Accessory phases include biotite, REE-rich goyazite (Goy45-59Flo29-43Cra11-17Gor0-1), zircon, pyrite, limonite, gahnite (Ghn57-68Hrc21-32Spl7-10Mgt1-2Gal1), staurolite, xenotime and monazite. Baryte and goyazite were likely formed during diagenesis of the host sediments or during later hydrothermal activity. Detrital garnet and tourmaline were probably sourced from the granulites, mica schists and migmatites of the Malín segment of the neighbouring Kutná Hora Crystalline Complex (KHCC). Surprisingly, amphibolites or serpentinites, frequently present in areas of the KHCC more proximal to the Permian sedimentary basin, did not contribute their garnets. We suggest that these areas were not exposed to erosion during the Permian period. Spectacular etching of surface of garnets and pervasive alteration of ilmenite were associated with burial diagenesis of the host sediments.","PeriodicalId":53145,"journal":{"name":"Bulletin Mineralogie Petrologie","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70599573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Z. Dolníček, Jana Ulmanová, K. Malý, Jaroslav Havlíček, J. Sejkora
One xenolith of a contactly metamorphosed feldspar-hydroxyapophyllite hornfels from basaltic volcanite of the active quarry in Těchlovice village near-by the town of Děčín has been investigated. Its main components are represented by K-feldspar and hydroxyapophyllite-(K), which was hitherto reported from a single locality only in the territory of the Czech Republic. It forms grains up to 2 mm in size tightly associated with K-feldspar and subsidiary quartz, pyroxene (aegirine, enstatite-ferrosilite and diopside) and titanite. The unit cell parameters of hydroxyapophyllite-(K), derived from the powder X-ray data, are a = 8.975(4), c = 15.8371(3) Å and V = 1275.6(5) Å3. Chemical analyses correspond to the empirical formula K0.93Ca3.75Si7.87O20(OH0.96F0.04)·8 H2O. The xenolith originated by a comparatively weak contact metamorphic effect of the basaltic magma to a marly sediment under high partial pressure of H2O. Among xenoliths of North Bohemian Cainozoic volcanites the rock represents a rarity, which has not been known hitherto.
研究了Děčín镇附近特克罗维兹村活跃采石场玄武质火山岩中接触变质长石-羟基磷灰石角粒的捕虏体。其主要成分为钾长石和羟基磷灰石-(K)，迄今为止仅在捷克共和国境内的一个地方报道过。它的颗粒大小可达2毫米，与钾长石及其附属石英、辉石(绿辉石、顽辉石-硅铁石和透辉石)和钛矿紧密相关。羟基磷灰石-(K)的单位胞参数为a = 8.975(4)， c = 15.8371(3) Å， V = 1275.6(5) Å3。化学分析对应于实验式K0.93Ca3.75Si7.87O20(OH0.96F0.04)·8 H2O。该包体是在高分压水作用下，玄武岩岩浆与泥质沉积物发生较弱的接触变质作用形成的。在北波西米亚新生代火山岩的捕虏体中，这种岩石是罕见的，迄今为止还不为人所知。
{"title":"Hydroxyapofylit-(K) z kamenolomu Těchlovice u Děčína (Česká republika)","authors":"Z. Dolníček, Jana Ulmanová, K. Malý, Jaroslav Havlíček, J. Sejkora","doi":"10.46861/bmp.29.124","DOIUrl":"https://doi.org/10.46861/bmp.29.124","url":null,"abstract":"One xenolith of a contactly metamorphosed feldspar-hydroxyapophyllite hornfels from basaltic volcanite of the active quarry in Těchlovice village near-by the town of Děčín has been investigated. Its main components are represented by K-feldspar and hydroxyapophyllite-(K), which was hitherto reported from a single locality only in the territory of the Czech Republic. It forms grains up to 2 mm in size tightly associated with K-feldspar and subsidiary quartz, pyroxene (aegirine, enstatite-ferrosilite and diopside) and titanite. The unit cell parameters of hydroxyapophyllite-(K), derived from the powder X-ray data, are a = 8.975(4), c = 15.8371(3) Å and V = 1275.6(5) Å3. Chemical analyses correspond to the empirical formula K0.93Ca3.75Si7.87O20(OH0.96F0.04)·8 H2O. The xenolith originated by a comparatively weak contact metamorphic effect of the basaltic magma to a marly sediment under high partial pressure of H2O. Among xenoliths of North Bohemian Cainozoic volcanites the rock represents a rarity, which has not been known hitherto.","PeriodicalId":53145,"journal":{"name":"Bulletin Mineralogie Petrologie","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70598785","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. Sejkora, P. Pauliš, Roman Gramblička, Z. Dolníček, Jana Ulmanová, Ondřej Pour
An interesting copper mineralization has been discovered in fragments of hydrothermal quartz gangue found in dump material of the abandoned unnamed gallery 1.5 km S from Horní Halže (now part of the Měděnec village), the Krušné hory Mts., Czech Republic. The primary mineralization represented by fine-grained quartz, hematite, pyrite and probably also djurleite was intensively affected by supergene processes. Djurleite and pyrite are partly replaced by Cu sulphides - roxbyite, anilite, spionkopite and covellite. The origin of association bornite/half-bornite/anilite found in some samples can be analogous, although in this case it cannot be ruled out that it may be the result of decomposition of the original solid solution (against the ideal bornite clearly enriched in Cu) formed in the hydrothermal stage. The formation of other Cu minerals (malachite, brochantite, libethenite and pseudomalachite) and goethite is already clearly bound to supergene conditions, part of malachite and brochantite was then formed by (sub)recent weathering of Cu-sulphides in the mine dump material. The detailed descriptions, X-ray powder diffraction data, refined unit-cell parameters and quantitative chemical composition of individual studied mineral phases are presented.
在捷克共和国Krušné hory Mts. Horní Halže(现为m德涅克村的一部分)1.5公里处废弃的未命名画廊的堆料中发现了一个有趣的热液石英矸石碎片，其中发现了一个有趣的铜矿化。以细粒石英、赤铁矿、黄铁矿为代表的原生矿化受表生作用的强烈影响。珠闪岩和黄铁矿部分被硫化物铜取代——铁长石、硅长石、绢云母和银长石。在某些样品中发现的结合斑铜矿/半斑铜矿/闪铜矿的成因可以是类似的，尽管在这种情况下，不能排除它可能是热液阶段形成的原始固溶体(相对于明显富铜的理想斑铜矿)分解的结果。其他铜矿物(孔雀石、枝辉石、利辉石和假孔雀石)和针铁矿的形成已经明确地与表生条件相结合，部分孔雀石和枝辉石则是由(亚)近代矿山排土场中硫化物风化作用形成的。介绍了所研究矿物相的详细描述、x射线粉末衍射数据、精细化的单胞参数和定量化学组成。
{"title":"Měděná mineralizace z Horní Halže u Měděnce v Krušných horách (Česká republika)","authors":"J. Sejkora, P. Pauliš, Roman Gramblička, Z. Dolníček, Jana Ulmanová, Ondřej Pour","doi":"10.46861/bmp.29.351","DOIUrl":"https://doi.org/10.46861/bmp.29.351","url":null,"abstract":"An interesting copper mineralization has been discovered in fragments of hydrothermal quartz gangue found in dump material of the abandoned unnamed gallery 1.5 km S from Horní Halže (now part of the Měděnec village), the Krušné hory Mts., Czech Republic. The primary mineralization represented by fine-grained quartz, hematite, pyrite and probably also djurleite was intensively affected by supergene processes. Djurleite and pyrite are partly replaced by Cu sulphides - roxbyite, anilite, spionkopite and covellite. The origin of association bornite/half-bornite/anilite found in some samples can be analogous, although in this case it cannot be ruled out that it may be the result of decomposition of the original solid solution (against the ideal bornite clearly enriched in Cu) formed in the hydrothermal stage. The formation of other Cu minerals (malachite, brochantite, libethenite and pseudomalachite) and goethite is already clearly bound to supergene conditions, part of malachite and brochantite was then formed by (sub)recent weathering of Cu-sulphides in the mine dump material. The detailed descriptions, X-ray powder diffraction data, refined unit-cell parameters and quantitative chemical composition of individual studied mineral phases are presented.","PeriodicalId":53145,"journal":{"name":"Bulletin Mineralogie Petrologie","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70599690","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The crystals of significantly zonal tetrahedrite-tennantite were found in the mine dump material of the Grubenwall 42 mine, Kramolín, the Michalovy Hory ore district, western Bohemia (Czech Republic). Tetrahedrite-tennantite forms layer of tetrahedral, partly corroded crystals up to 1 mm in size on a crust of crystalline quartz in association with chalcopyrite and cerussite. Individual zones in oscillatory zoned crystals are represented by three members of tetrahedrite group minerals - tetrahedrite-(Zn), tennantite-(Zn) and rare tennantite-(Fe). The observed range of AsSb-1 substitution is unusual within a single crystal and indicates high variability of the As/Sb ratio in the hydrothermal fluids.
{"title":"Výrazně zonální tetraedrit-tennantit z Kramolína, rudní revír Michalovy Hory (Česká republika)","authors":"Luboš Vrtiška, J. Sejkora","doi":"10.46861/bmp.29.249","DOIUrl":"https://doi.org/10.46861/bmp.29.249","url":null,"abstract":"The crystals of significantly zonal tetrahedrite-tennantite were found in the mine dump material of the Grubenwall 42 mine, Kramolín, the Michalovy Hory ore district, western Bohemia (Czech Republic). Tetrahedrite-tennantite forms layer of tetrahedral, partly corroded crystals up to 1 mm in size on a crust of crystalline quartz in association with chalcopyrite and cerussite. Individual zones in oscillatory zoned crystals are represented by three members of tetrahedrite group minerals - tetrahedrite-(Zn), tennantite-(Zn) and rare tennantite-(Fe). The observed range of AsSb-1 substitution is unusual within a single crystal and indicates high variability of the As/Sb ratio in the hydrothermal fluids.","PeriodicalId":53145,"journal":{"name":"Bulletin Mineralogie Petrologie","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70599226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
P. Pauliš, Luboš Vrtiška, Z. Dolníček, Radana Malíková, Ondřej Pour
Along with the abundant pyromorphite, relatively frequent coronadite was found in the Řimbaba mine in Bohutín near Příbram (Czech Republic). Coronadite forms up to 5 mm thick black matt and greasy coatings and cavity fillings. The unit cell parameters of coronadite, refined from the powder X-ray diffraction data, are a 9.943(17), b 2.876(8), c 9.820(11) Å, β 90.4(5)° and V 280.8(9) Å3 (space group I2/m). Chemical analyses correspond to the empirical formula Pb1.53Sb0.07Zn0.02(Mn4+5.62Mn3+2.06)O16.
{"title":"Coronadit z dolu Řimbaba v Bohutíně u Příbrami (Česká republika)","authors":"P. Pauliš, Luboš Vrtiška, Z. Dolníček, Radana Malíková, Ondřej Pour","doi":"10.46861/bmp.29.281","DOIUrl":"https://doi.org/10.46861/bmp.29.281","url":null,"abstract":"Along with the abundant pyromorphite, relatively frequent coronadite was found in the Řimbaba mine in Bohutín near Příbram (Czech Republic). Coronadite forms up to 5 mm thick black matt and greasy coatings and cavity fillings. The unit cell parameters of coronadite, refined from the powder X-ray diffraction data, are a 9.943(17), b 2.876(8), c 9.820(11) Å, β 90.4(5)° and V 280.8(9) Å3 (space group I2/m). Chemical analyses correspond to the empirical formula Pb1.53Sb0.07Zn0.02(Mn4+5.62Mn3+2.06)O16.","PeriodicalId":53145,"journal":{"name":"Bulletin Mineralogie Petrologie","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70599253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Peter Ružička, Pavol Myšľan, Martin Števko, Sergii Kurylo
Atoll garnets in basalt metapyroclastics from the locality Čučma - Vincent (Slovak Republic) consist of relict cores and zonal rings. Research was focused on comparison of chemical changes in these garnet microstructures. Relict cores have composition Sps41.4-45.2Grs40.6-43.0Adr6.4-13.6 Alm1.9-6.1, inner BSE light zone in the rings has composition Grs38.2-44.9Sps39.6-43.7Alm6.3-12.4 Adr6.5-9.6 and outer BSE dark zone in the rings has composition Sps34.3-40.3Grs33.3-38.3Adr8.5-17.3 Alm12.7-17.1. The highest content of Mn2+ in the atoll garnets was observed in the relict cores (1.21 - 1.33 apfu) and subsequent decreasing trend in contents of Mn2+ from the inner parts of the rings (BSE dark zone; 1.16 - 1.29 apfu) to their edge (BSE light zone; 1.02 -1.20 apfu) is present. The opposite trend was observed for Fe2+ content. Inner parts of the garnets are replaced by actinolite and calcite with slightly higher content of Mn (Act up to 0.07 apfu; Cal up to 0.02 apfu). Matrix of basalt metapyroclastics was primarily formed by hedenbergite which was later replaced by actinolite.
{"title":"Atolové granáty v bazaltových metapyroklastikách z lokality Čučma - Vincent (Slovenská republika)","authors":"Peter Ružička, Pavol Myšľan, Martin Števko, Sergii Kurylo","doi":"10.46861/bmp.29.016","DOIUrl":"https://doi.org/10.46861/bmp.29.016","url":null,"abstract":"Atoll garnets in basalt metapyroclastics from the locality Čučma - Vincent (Slovak Republic) consist of relict cores and zonal rings. Research was focused on comparison of chemical changes in these garnet microstructures. Relict cores have composition Sps41.4-45.2Grs40.6-43.0Adr6.4-13.6 Alm1.9-6.1, inner BSE light zone in the rings has composition Grs38.2-44.9Sps39.6-43.7Alm6.3-12.4 Adr6.5-9.6 and outer BSE dark zone in the rings has composition Sps34.3-40.3Grs33.3-38.3Adr8.5-17.3 Alm12.7-17.1. The highest content of Mn2+ in the atoll garnets was observed in the relict cores (1.21 - 1.33 apfu) and subsequent decreasing trend in contents of Mn2+ from the inner parts of the rings (BSE dark zone; 1.16 - 1.29 apfu) to their edge (BSE light zone; 1.02 -1.20 apfu) is present. The opposite trend was observed for Fe2+ content. Inner parts of the garnets are replaced by actinolite and calcite with slightly higher content of Mn (Act up to 0.07 apfu; Cal up to 0.02 apfu). Matrix of basalt metapyroclastics was primarily formed by hedenbergite which was later replaced by actinolite.","PeriodicalId":53145,"journal":{"name":"Bulletin Mineralogie Petrologie","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70598025","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The chemical composition of three samples of minerals of the hidalgoite-philipsbornite series from the central part of the Guatomo mine pit was studied in detail by EMPA-WDS. They form yellowish-green, light green to pale blue microcrystalline crusts or hollow pseudomorphs after prismatic hexagonal crystals of mimetite in fractures of strongly altered granite or quartz. All studied samples show relatively strong, irregular to oscillatory chemical zoning in BSE, caused by S versus As substitution on T-site. Most of the zones are corresponding to hidalgoite, with only minor, outer zones represented by S-rich philipsbornite. Besides of dominant contents of Pb, Al, As and S also minor amounts of K (up to 0.11 apfu), Na (up to 0.05 apfu), Cu (up to 0.22 apfu), Fe (up to 0.09 apfu) and P (up to 0.04 apfu) were detected in studied samples.
{"title":"New data on minerals of the hidalgoite-philipsbornite series from the Guatomo mine near Tham Thalu, Yala Province (Thailand)","authors":"M. Števko, Z. Dolníček","doi":"10.46861/bmp.29.270","DOIUrl":"https://doi.org/10.46861/bmp.29.270","url":null,"abstract":"The chemical composition of three samples of minerals of the hidalgoite-philipsbornite series from the central part of the Guatomo mine pit was studied in detail by EMPA-WDS. They form yellowish-green, light green to pale blue microcrystalline crusts or hollow pseudomorphs after prismatic hexagonal crystals of mimetite in fractures of strongly altered granite or quartz. All studied samples show relatively strong, irregular to oscillatory chemical zoning in BSE, caused by S versus As substitution on T-site. Most of the zones are corresponding to hidalgoite, with only minor, outer zones represented by S-rich philipsbornite. Besides of dominant contents of Pb, Al, As and S also minor amounts of K (up to 0.11 apfu), Na (up to 0.05 apfu), Cu (up to 0.22 apfu), Fe (up to 0.09 apfu) and P (up to 0.04 apfu) were detected in studied samples.","PeriodicalId":53145,"journal":{"name":"Bulletin Mineralogie Petrologie","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70598883","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jaromír Tvrdý, Z. Dolníček, Jana Ulmanová, Ondřej Krátký, Michal Nekl
Alkaline metasomatites (fenites) originated by pervasive Na metasomatism of granitoids of the Čistá-Jesenice Pluton (belonging to the Teplá-Barrandian unit in the NW part of the Bohemian Massif) contain a rich association of REE-bearing minerals. The occurrence of REE carbonates (bastnäsite, parisite), monazite, rhabdophane, churchite, fergusonite and pyrochlore was found in relatively weakly altered rocks (typical fenites), whereas much richer assemblage was observed in rocks which underwent the strongest metasomatism (so called reomorphic cancrinite-nepheline syenites). Here, the mineral assemblage includes in addition to all above mentioned minerals also xenotime and REE silicates, including tritomite/melanocerite, allanite, perbøeite, gadolinite and a Mn-analogue of hingganite. A common mineral phase is zircon in these rocks, too. Cerium, yttrium, and to lesser extent also lanthanum are dominating cations in the studied REE phases. A total of 24 mineral species was identified, including three unnamed phases. In most of the studied phases, the level of fractionation of REEs is high, exceptionally even extreme. Chondrite-normalized REE patterns of some phases are characterized by a pronounced M-type tetrad effect. The results of microprobe analyses suggest that individual minerals originated during several episodes, characterized by different chemical composition of the mineral-forming medium (especially with contrasting concentrations of strong REE-complexing ligands and oxygen fugacity) and/or temperature. We did not find any significant differences in chemistry of individual minerals present in various rock types showing different levels of metasomatic alteration. The obtained data are consistent with hydrothermal origin of most (if not all) reported REE-bearing phases. The material source and genesis of the studied REE+Nb+Zr mineralization was in all probability associated with hydrothermal activity in the exocontact of a deep-seated hypothetical carbonatite intrusion, as was suggested already in earlier works dealing with these remarkable rocks.
{"title":"REE minerály fenitů čistecko-jesenického masivu (Česká republika)","authors":"Jaromír Tvrdý, Z. Dolníček, Jana Ulmanová, Ondřej Krátký, Michal Nekl","doi":"10.46861/bmp.29.297","DOIUrl":"https://doi.org/10.46861/bmp.29.297","url":null,"abstract":"Alkaline metasomatites (fenites) originated by pervasive Na metasomatism of granitoids of the Čistá-Jesenice Pluton (belonging to the Teplá-Barrandian unit in the NW part of the Bohemian Massif) contain a rich association of REE-bearing minerals. The occurrence of REE carbonates (bastnäsite, parisite), monazite, rhabdophane, churchite, fergusonite and pyrochlore was found in relatively weakly altered rocks (typical fenites), whereas much richer assemblage was observed in rocks which underwent the strongest metasomatism (so called reomorphic cancrinite-nepheline syenites). Here, the mineral assemblage includes in addition to all above mentioned minerals also xenotime and REE silicates, including tritomite/melanocerite, allanite, perbøeite, gadolinite and a Mn-analogue of hingganite. A common mineral phase is zircon in these rocks, too. Cerium, yttrium, and to lesser extent also lanthanum are dominating cations in the studied REE phases. A total of 24 mineral species was identified, including three unnamed phases. In most of the studied phases, the level of fractionation of REEs is high, exceptionally even extreme. Chondrite-normalized REE patterns of some phases are characterized by a pronounced M-type tetrad effect. The results of microprobe analyses suggest that individual minerals originated during several episodes, characterized by different chemical composition of the mineral-forming medium (especially with contrasting concentrations of strong REE-complexing ligands and oxygen fugacity) and/or temperature. We did not find any significant differences in chemistry of individual minerals present in various rock types showing different levels of metasomatic alteration. The obtained data are consistent with hydrothermal origin of most (if not all) reported REE-bearing phases. The material source and genesis of the studied REE+Nb+Zr mineralization was in all probability associated with hydrothermal activity in the exocontact of a deep-seated hypothetical carbonatite intrusion, as was suggested already in earlier works dealing with these remarkable rocks.","PeriodicalId":53145,"journal":{"name":"Bulletin Mineralogie Petrologie","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70598904","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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