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An experimental ultrasonic method to determine a scattering quality factor, with application to earth's inner core 一种测定散射品质因子的实验超声方法,并应用于地核
IF 1.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-01 Epub Date: 2025-09-24 DOI: 10.1016/j.pepi.2025.107456
Ming Gong , Michael I. Bergman
<div><div>Seismic attenuation can be intrinsic or due to scattering. The relative role of each for Earth's inner core is uncertain. Whereas intrinsic attenuation depends primarily on the material, temperature, and pressure, scattering is primarily a function of microstructure, that is, grain size, shape, texture, as well as single-crystal elastic anisotropy. Here we studied experimentally scattering of ultrasonic compressional waves in a hexagonal close-packed (hcp) Zn-rich Sn alloy, for two microstructures that are likely relevant to the inner core: textured, large columnar dendritic crystals typical of directional solidification, and untextured, equiaxed, ‘fine-grained’ crystals that can result from diffusion creep. We also studied the wavelength/grain size dependence of scattering for these two microstructures. We used a Zn-rich Sn alloy not because we expect it to have intrinsic attenuation similar to Fe under inner core conditions, but because its hcp crystal structure is the likely phase of the Fe alloy in the inner core, making it suitable for understanding the role of microstructure on scattering in the inner core. For the purpose of scaling the experiments to the inner core, pressure and temperature affect scattering primarily through their effects on the elastic constants of Fe and inner core growth dynamics, both of which we account for.</div><div>We developed an algorithm using the pulse-echo technique to experimentally determine a scattering quality factor <em>Q</em><sub><em>Z</em></sub>. We set criteria to determine, and measured, the energy per cycle in the first echo <em>T</em><sub><em>1</em></sub>, which is a measure of the transmitted energy, and the energy per cycle that is reflected before the first echo <em>R</em><sub><em>1</em></sub>, which represents the scattered energy. In order to facilitate comparison with seismic quality factors we defined a scattering quality factor <em>Q</em><sub><em>Z</em></sub> <em>= (R</em><sub><em>1</em></sub> <em>+ T</em><sub><em>1</em></sub><em>)/R</em><sub><em>1</em></sub>. Scaling <em>Q</em><sub><em>Z</em></sub> from the laboratory experiments to the inner core depends on the magnitude of the single-crystal wave speed anisotropy, which is known for Zn, but uncertain for Fe under inner core conditions, so we scaled the experimental results for single-crystal Fe elastic anisotropy between 5 and 20 %.</div><div>As expected, we found a directionally solidified microstructure has a highly anisotropic <em>Q</em><sub><em>Z</em></sub>, showing almost no scattering in the growth direction, whereas in the transverse directions scattering attenuation in the inner core may be comparable to intrinsic attenuation. Taking into account the anisotropy factor for scattering in polycrystalline, anisotropic material, our results predict randomly oriented, equiaxed 10 km-sized grains in the inner core would exhibit more scattering attenuation that the total inferred seismic attenuation, ruling out such a microstr
地震衰减可以是固有的,也可以是由于散射引起的。它们对地球内核的相对作用是不确定的。虽然本征衰减主要取决于材料、温度和压力,但散射主要是微观结构的函数,即晶粒尺寸、形状、织构以及单晶弹性各向异性。在这里,我们实验研究了超声波纵波在六方紧密堆积(hcp)富锌锡合金中的散射,研究了两种可能与内核相关的微观结构:典型定向凝固的织构大柱状枝晶,以及可能由扩散蠕变产生的非织构等轴细晶。我们还研究了这两种微结构散射与波长/晶粒尺寸的关系。我们使用富锌的Sn合金并不是因为我们期望它在内核条件下具有类似于Fe的固有衰减,而是因为它的hcp晶体结构是内核中Fe合金的可能相,这使得它适合于理解微观结构对内核散射的作用。为了将实验扩展到内核,压力和温度主要通过对铁的弹性常数和内核生长动力学的影响来影响散射,我们解释了这两者。我们开发了一种利用脉冲回波技术实验确定散射品质因子QZ的算法。我们设定准则来确定和测量第一回波T1中每周期的能量,这是透射能量的度量,而在第一回波R1之前每周期的反射能量,这是散射能量。为了便于与地震质量因子进行比较,我们定义了散射质量因子QZ = (R1 + T1)/R1。从实验室实验到内核的QZ缩放取决于单晶波速各向异性的大小,这对于Zn是已知的,但对于Fe在内核条件下不确定,因此我们将单晶Fe弹性各向异性的实验结果缩放在5%到20%之间。正如预期的那样,我们发现定向凝固组织具有高度各向异性的QZ,在生长方向上几乎没有散射,而在横向方向上,内核的散射衰减可以与本征衰减相媲美。考虑到多晶、各向异性材料中散射的各向异性因素,我们的研究结果预测内核中随机定向、等轴10公里大小的颗粒将表现出比推断的总地震衰减更多的散射衰减,从而排除了这种微观结构。然而,在小于10 km的随机取向等轴粒度下,QZ迅速增加,这表明地震质量因子QP的大横向变化最有可能是由于0.1 ~ 0.10 km范围内的粒度变化。在我们确定QZ的算法中,最大的不确定性是在第一次回波之后到达的散射能量,我们试图量化它。
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引用次数: 0
Geomagnetic field and the growth of the Earth’s inner core: Past, present and future 地磁场和地球内核的成长:过去、现在和未来
IF 1.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-01 Epub Date: 2025-10-22 DOI: 10.1016/j.pepi.2025.107460
Ján Šimkanin
Changes in the geomagnetic field corresponding to the Earth’s inner core growth are numerically investigated. The Geodynamo is driven by thermochemical convection in the Earth’s outer core, with the codensity gradient serving as the primary driving force. Simulations begin with a small inner core (‘Past’), which progressively enlarges until reaching a stage where the inner core becomes dominant (‘Future’). During the ’Past’ stage, the Geodynamo model generates a multipolar geomagnetic field, which gradually transitions into a predominantly dipolar field as the inner core grows. These transitions are also accompanied by shifts between weak-field and strong-field dynamos and vice versa. The ratio of magnetic to kinetic energy emerges as a more reliable parameter for controlling the transition from multipolar to dipolar dynamos. The dipole component for a small inner core proves unstable, with frequent polarity reversals. As the inner core grows, the frequency of these reversals decreases until the ‘Present’ case, where polarity reversals cease entirely. It is important to note that during the ‘Past’, fluctuations in dipole polarity are observed even in a dipole-dominated magnetic field. In the ‘Future’ stage, representing a potential scenario for the Earth’s geomagnetic field, the hydromagnetic dynamo produces a dipole-dominated magnetic field without polarity reversals. However, if the Earth’s liquid outer core becomes exceedingly small, convection diminishes, causing the Geodynamo to fail. This leads to a slow decay of the magnetic field due to magnetic diffusion. During the ’Future’ stage, the emergence of subcritical dynamos is observed. It is important to note that the results of the present analysis are more strongly influenced by the supercriticality of the flow than by the inner core size, as the latter is determined by the selected solution parameters.
用数值方法研究了与地球内核生长相对应的地磁场变化。地球发电机由地球外核的热化学对流驱动,密度梯度是主要驱动力。模拟从一个小内核(“过去”)开始,逐渐扩大,直到内核成为主导(“未来”)。在“过去”阶段,地球发电机模型产生了一个多极地磁场,随着内核的增长,它逐渐转变为一个主要的偶极场。这些转变也伴随着弱场和强场发电机之间的转变,反之亦然。磁动能比成为控制多极发电机向偶极发电机转变的更可靠的参数。一个小内核的偶极子成分被证明是不稳定的,具有频繁的极性反转。随着内核的增长,这些反转的频率减少,直到“现在”的情况,极性反转完全停止。重要的是要注意,在“过去”期间,即使在偶极子主导的磁场中也观察到偶极子极性的波动。在“未来”阶段,代表了地球地磁场的潜在情景,磁流体发电机产生一个偶极子主导的磁场,没有极性反转。然而,如果地球的液体外核变得非常小,对流就会减弱,导致地球发电机失效。这导致磁场由于磁扩散而缓慢衰减。在“未来”阶段,观察到亚临界发电机的出现。值得注意的是,当前分析的结果受流体超临界的影响比受内核尺寸的影响更大,因为内核尺寸是由所选的溶液参数决定的。
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引用次数: 0
Evidence for lowermost mantle anisotropy from discrepant splitting intensity of XKS and SKKS phases recorded in India 印度记录的XKS和SKKS相分裂强度的差异证明了地幔最下层各向异性
IF 1.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-01 Epub Date: 2025-09-20 DOI: 10.1016/j.pepi.2025.107439
Sunil K. Roy, M. Ravi Kumar
This study comprehensively examines the shear wave splitting measurements of XKS (SKS and PKS) - SKKS pairs on the same seismograms recorded at 357 broadband stations spanning India, to characterize anisotropy in the lowermost mantle. This resulted in the identification of 104 XKS-SKKS pairs at 62 stations, of which 27 pairs were found to be discrepant, based on the difference in splitting intensity of XKS and the corresponding SKKS phases. These discrepant pairs dominantly sample a portion of the lowermost mantle beneath Southeast Asia and the Indian Ocean. The majority of these pairs represent null-split and split-split cases, with the delay time of SKKS being larger than that of XKS for the latter. This suggests that the XKS phases primarily sample the isotropic (weakly anisotropic) or anisotropic regions with a cancelling effect in the lowermost mantle, while the corresponding SKKS phases sample the anisotropic region of the D layer. In addition, there are three discrepant pairs in the split-null category, suggesting anisotropy in the vicinity of southern Tibet, where discrepant pairs from other cases are not observed. This implies an apparent change in the anisotropy of the D layer for the regions sampled by XKS and SKKS, although they are associated with high-velocity anomalies. In these regions, the fast polarization azimuths of the discrepant pairs are in the NE-SW and ENE-WSW, and NNE-SSW directions, respectively. These do not coincide with the trend of mantle flow in the lowermost mantle, suggesting an association with paleo-subducted slabs. The observed deformation is probably due to phase transformation of bridgmanite to a more stable post-perovskite, causing Crystallographic Preferred Orientation of the lowermost mantle, which is the candidate mechanism for lowermost mantle anisotropy beneath Southeast Asia and the Indian Ocean.
本研究综合考察了在印度357个宽带站记录的相同地震记录上的XKS (SKS和PKS) - SKKS对剪切波分裂测量结果,以表征最下层地幔的各向异性。结果在62个站点鉴定了104对XKS-SKKS,根据XKS分裂强度和相应SKKS阶段的差异,发现27对XKS-SKKS存在差异。这些差异对主要是在东南亚和印度洋下的最下层地幔的一部分取样。这些对大多数代表null-split和split-split情况,其中SKKS的延迟时间大于XKS的延迟时间。这表明XKS相主要对各向同性(弱各向异性)或各向异性区域进行采样,并在最下层地幔中起到抵消作用,而对应的SKKS相则对D″层的各向异性区域进行采样。这意味着在XKS和SKKS取样的区域,D″层的各向异性发生了明显变化,尽管它们与高速异常有关。在这些区域,差值对的快速极化方位角分别在NE-SW和ENE-WSW方向,以及NNE-SSW方向。这些与最底地幔的地幔流动趋势不一致,表明与古俯冲板块有关。观测到的变形可能是由桥菱矿向更稳定的后钙钛矿相变引起的,导致了最下层地幔的晶体优先取向,这是东南亚和印度洋最下层地幔各向异性的候选机制。
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引用次数: 0
Accounting for correlated data errors in geomagnetic field modeling using Swarm magnetic observations 利用群磁观测计算地磁场模拟相关数据误差
IF 1.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-01 Epub Date: 2025-10-08 DOI: 10.1016/j.pepi.2025.107459
Clemens Kloss
Studies of Earth’s magnetic field and its sources rely on accurate geomagnetic field models derived from ground and satellite-based magnetic data. During the field model estimation, data errors are usually assumed to be uncorrelated in time and independent of position. However, limitations in the field model parameterization, especially regarding ionospheric and magnetospheric fields, lead to data errors that are not only larger than the expected measurement noise but are also correlated in time and vary with position. As a result, the obtained model uncertainties are often underestimated, making it more challenging to evaluate the reliability of recovered signals in the field models.
This study investigates the effect of including correlated data errors in field modeling. The approach involves building a stochastic data error model to treat correlated errors due to unmodeled magnetospheric fields within the CHAOS geomagnetic field modeling framework. The error model parameters are estimated using empirical covariances computed from vector residuals between the satellite magnetic observations made by the Swarm satellites and the CHAOS geomagnetic field model. Field modeling experiments are performed with and without including the data error covariances described in the stochastic error model.
The inclusion of data error covariances due to unmodeled magnetospheric fields leads to only small changes in the estimated internal field, but also a noticeable increase in model uncertainty for the sectoral coefficients. This highlights the significant impact of unmodeled magnetospheric fields and the importance of accurately defining data errors, including the covariances between observations, for interpreting the retrieved magnetic signals in geomagnetic field modeling.
对地球磁场及其来源的研究依赖于从地面和卫星磁数据中得出的精确地磁场模型。在现场模型估计中,通常假设数据误差在时间上不相关,与位置无关。然而,由于磁场模型参数化的局限性,特别是对电离层和磁层磁场的参数化,导致数据误差不仅大于预期的测量噪声,而且随时间和位置的变化而变化。因此,得到的模型不确定性往往被低估,这使得评估现场模型中恢复信号的可靠性更具挑战性。本研究探讨了在现场建模中纳入相关数据误差的影响。该方法涉及建立随机数据误差模型,以处理混沌地磁场建模框架内未建模的磁层场引起的相关误差。利用Swarm卫星的卫星磁观测与CHAOS地磁场模型之间的矢量残差计算经验协方差来估计误差模型参数。现场建模实验包括和不包括随机误差模型中描述的数据误差协方差。由于未模拟的磁层场而包含的数据误差协方差导致估计的内部场只有很小的变化,但也显著增加了部门系数的模式不确定性。这突出了未模拟的磁层磁场的重大影响,以及准确定义数据误差(包括观测之间的协方差)对于解释地磁场模拟中检索到的磁信号的重要性。
{"title":"Accounting for correlated data errors in geomagnetic field modeling using Swarm magnetic observations","authors":"Clemens Kloss","doi":"10.1016/j.pepi.2025.107459","DOIUrl":"10.1016/j.pepi.2025.107459","url":null,"abstract":"<div><div>Studies of Earth’s magnetic field and its sources rely on accurate geomagnetic field models derived from ground and satellite-based magnetic data. During the field model estimation, data errors are usually assumed to be uncorrelated in time and independent of position. However, limitations in the field model parameterization, especially regarding ionospheric and magnetospheric fields, lead to data errors that are not only larger than the expected measurement noise but are also correlated in time and vary with position. As a result, the obtained model uncertainties are often underestimated, making it more challenging to evaluate the reliability of recovered signals in the field models.</div><div>This study investigates the effect of including correlated data errors in field modeling. The approach involves building a stochastic data error model to treat correlated errors due to unmodeled magnetospheric fields within the CHAOS geomagnetic field modeling framework. The error model parameters are estimated using empirical covariances computed from vector residuals between the satellite magnetic observations made by the <em>Swarm</em> satellites and the CHAOS geomagnetic field model. Field modeling experiments are performed with and without including the data error covariances described in the stochastic error model.</div><div>The inclusion of data error covariances due to unmodeled magnetospheric fields leads to only small changes in the estimated internal field, but also a noticeable increase in model uncertainty for the sectoral coefficients. This highlights the significant impact of unmodeled magnetospheric fields and the importance of accurately defining data errors, including the covariances between observations, for interpreting the retrieved magnetic signals in geomagnetic field modeling.</div></div>","PeriodicalId":54614,"journal":{"name":"Physics of the Earth and Planetary Interiors","volume":"368 ","pages":"Article 107459"},"PeriodicalIF":1.9,"publicationDate":"2025-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145416691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Seismic reflectors in the mid-lower mantle beneath central Pacific: The relationship with the Pacific LLSVP 中太平洋下中下地幔地震反射体:与太平洋LLSVP的关系
IF 1.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-01 Epub Date: 2025-08-22 DOI: 10.1016/j.pepi.2025.107437
Satoshi Kaneshima
Seismic signals in P coda originating from deep mantle heterogeneity have not yet been investigated extensively, except for the observations of the waves reflected presumably at the top of the D″ layer. We show in this study that array processing of seismograms of deep earthquakes at Tonga-Fiji and Solomon Islands recorded by seismograph networks at southern California reveals strong off-great circle arrivals in P coda 5 to 10 s after direct P waves. We also show that the large arrivals observed for the Tonga-Fiji events are P-to-P reflected waves at a dipping interface in the mid-lower mantle beneath central Pacific. The reflector is located south-southeast of Hawaii around 2000 km depth and dips down to southeast by nearly 35°. The observed amplitude and polarity of the reflected waves could be explained if the Vp of the underlying side of the reflector is 1 to 2 % faster than the overlying side. The small Vp anomaly may not necessarily contradict the absence of a noticeable Vp anomaly in previous seismic tomography models at the site of the reflector. We also find that the reflected wave is approximately concomitant with a weaker arrival from a mid-mantle scattering object located nearly 1000 km closer to the hypocenters. The heterogeneous object causing the anomalous arrivals for the Solomon Islands events, although the properties of the object are less well constrained than the Tonga-Fiji reflector, also likely represents another dipping reflector at 2400 km located approximately below the Hawaiian hotspot. As in the Tonga-Fiji case the signals are occasionally followed by a weaker signal from a mid-mantle scattering object located nearer to the hypocenters. The mid-mantle reflection/scattering objects do not indicate the presence of a global discontinuity but must represent localized strong heterogeneities. It is notable that the localized heterogeneities are all located near the edges of a large low Vs body (the Pacific LLSVP) resolved by global tomography, up to 500 km above the LLSVP itself. The relation between the locations of the reflector/scatterers and the large scale Vp structure is unclear, probably reflecting poorer tomography images of Vp structure associated with the LLSVP. We discuss possible tectonic implications of these mid-mantle heterogeneities on the structure and evolution of the LLSVP.
P尾区的地震信号来源于深部地幔非均质性,除了推测在D″层顶部反射的波外,尚未得到广泛的研究。我们在本研究中表明,对南加州地震仪台网记录的汤加-斐济和所罗门群岛深地震的地震图进行阵列处理后发现,在直接P波后5至10秒,P波尾强烈的非大圆到达。我们还表明,汤加-斐济事件观测到的大到达波是太平洋中部下地幔倾斜界面上的P-to-P反射波。反射面位于夏威夷东南偏南,深度约2000公里,向东南方向倾斜近35°。如果反射器下侧的Vp比上侧快1 ~ 2%,就可以解释反射波的振幅和极性。小的Vp异常不一定与以前的地震层析成像模型在反射器位置没有明显的Vp异常相矛盾。我们还发现,反射波与靠近震源近1000公里的中地幔散射物体的较弱到达近似伴随。引起所罗门群岛事件异常到达的异质物体,虽然其性质不像汤加-斐济反射器那样受到很好的约束,但也可能代表位于夏威夷热点大约下方2400公里处的另一个倾斜反射器。就像汤加-斐济的情况一样,在这些信号之后,偶尔会有来自靠近震源的中地幔散射物体的较弱信号。中地幔反射/散射对象不能表明全球不连续性的存在,而必须代表局部强非均质性。值得注意的是,局部非均质分布都位于全球层析成像分辨出的一个大型低v体(太平洋LLSVP)的边缘附近,距离LLSVP本身高达500 km。反射体/散射体的位置与大尺度Vp结构之间的关系尚不清楚,可能反映了与LLSVP相关的Vp结构较差的断层扫描图像。我们讨论了这些中地幔非均质性对LLSVP构造和演化的可能的构造意义。
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引用次数: 0
Viscosity measurements of aqueous magnesium sulfate solutions under high pressure: Implications for subsurface fluids in large icy satellites 高压下硫酸镁水溶液的粘度测量:对大型冰冻卫星地下流体的影响
IF 1.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-01 Epub Date: 2025-09-17 DOI: 10.1016/j.pepi.2025.107450
Shunsuke Nozaki , Seiji Kamada , Shin Ozawa , Akio Suzuki
Subsurface oceans and brines beneath the thick icy crust of large icy satellites such as Europa, Ganymede, Callisto, and Titan are among the most promising targets for exploring potential habitability. The physical properties of these liquids, particularly viscosity, play a fundamental role in governing fluid dynamics, as well as material and heat transport occurring within high-pressure environments. Although magnesium sulfate (MgSO4) is likely one of the primary dissolved salts in these extra-terrestrial oceans, its viscosity under high-pressure conditions remains poorly understood. In this study, a falling-sphere viscometer was developed with a diamond anvil cell (DAC) to measure the viscosity of 10 wt% MgSO4 solutions at pressures up to 1100 MPa and temperatures ranging from 263 to 313 K. Our results showed that MgSO4 solutions exhibited viscosities more than 1.5 times as high as that of pure water at the same pressure and temperature conditions. At low temperature, the viscosity of MgSO4 solutions increased monotonically with pressure, whereas pure water exhibited a minimum viscosity at ∼200 MPa. This difference reflects the strong ionic effects on the disruption of water structure and construction of hydration shell by Mg2+ and SO42− ions. By extrapolating our findings to subsurface ocean conditions, we estimated that 10 wt% aqueous MgSO4 oceans/brines in icy satellites would have viscosities between 1 and 13 mPa·s at pressures below 700 MPa. This finding suggests that aqueous MgSO4 fluids potentially present in icy satellites can exhibit higher viscosities compared with pure water, whose viscosities are typically limited to the narrow range of 1–2 mPa·s.
木卫二、木卫三、木卫四和土卫六等大型冰冻卫星厚厚的冰壳下的地下海洋和盐水是探索潜在宜居性的最有希望的目标之一。这些液体的物理性质,特别是粘度,在控制流体动力学以及高压环境中发生的物质和热传输中起着重要作用。虽然硫酸镁(MgSO4)可能是这些地外海洋中的主要溶解盐之一,但其在高压条件下的粘度仍然知之甚少。在这项研究中,开发了一种带有金刚石砧细胞(DAC)的落球粘度计,用于测量压力高达1100 MPa,温度范围为263至313 K的10 wt% MgSO4溶液的粘度。我们的研究结果表明,在相同压力和温度条件下,MgSO4溶液的粘度是纯水的1.5倍以上。在低温下,MgSO4溶液的粘度随压力单调增加,而纯水在~ 200 MPa时粘度最小。这种差异反映了Mg2+和SO42−离子对水结构破坏和水化壳构建的强离子效应。通过将我们的发现外推到地下海洋条件,我们估计在压力低于700 mPa时,冰冻卫星中10%的含水MgSO4海洋/盐水的粘度在1至13 mPa·s之间。这一发现表明,与纯水相比,冰卫星中可能存在的含水MgSO4流体具有更高的粘度,纯水的粘度通常限制在1-2 mPa·s的狭窄范围内。
{"title":"Viscosity measurements of aqueous magnesium sulfate solutions under high pressure: Implications for subsurface fluids in large icy satellites","authors":"Shunsuke Nozaki ,&nbsp;Seiji Kamada ,&nbsp;Shin Ozawa ,&nbsp;Akio Suzuki","doi":"10.1016/j.pepi.2025.107450","DOIUrl":"10.1016/j.pepi.2025.107450","url":null,"abstract":"<div><div>Subsurface oceans and brines beneath the thick icy crust of large icy satellites such as Europa, Ganymede, Callisto, and Titan are among the most promising targets for exploring potential habitability. The physical properties of these liquids, particularly viscosity, play a fundamental role in governing fluid dynamics, as well as material and heat transport occurring within high-pressure environments. Although magnesium sulfate (MgSO<sub>4</sub>) is likely one of the primary dissolved salts in these extra-terrestrial oceans, its viscosity under high-pressure conditions remains poorly understood. In this study, a falling-sphere viscometer was developed with a diamond anvil cell (DAC) to measure the viscosity of 10 wt% MgSO<sub>4</sub> solutions at pressures up to 1100 MPa and temperatures ranging from 263 to 313 K. Our results showed that MgSO<sub>4</sub> solutions exhibited viscosities more than 1.5 times as high as that of pure water at the same pressure and temperature conditions. At low temperature, the viscosity of MgSO<sub>4</sub> solutions increased monotonically with pressure, whereas pure water exhibited a minimum viscosity at ∼200 MPa. This difference reflects the strong ionic effects on the disruption of water structure and construction of hydration shell by Mg<sup>2+</sup> and SO<sub>4</sub><sup>2−</sup> ions. By extrapolating our findings to subsurface ocean conditions, we estimated that 10 wt% aqueous MgSO<sub>4</sub> oceans/brines in icy satellites would have viscosities between 1 and 13 mPa·s at pressures below 700 MPa. This finding suggests that aqueous MgSO<sub>4</sub> fluids potentially present in icy satellites can exhibit higher viscosities compared with pure water, whose viscosities are typically limited to the narrow range of 1–2 mPa·s.</div></div>","PeriodicalId":54614,"journal":{"name":"Physics of the Earth and Planetary Interiors","volume":"368 ","pages":"Article 107450"},"PeriodicalIF":1.9,"publicationDate":"2025-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145120913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unraveling the lithospheric magnetic field masked by the Earth’s main field by estimating the magnetization and magnetic crustal thickness using a statistical approach 利用统计方法估算磁化强度和磁性地壳厚度,揭示被地球主磁场掩盖的岩石圈磁场
IF 1.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-10-01 Epub Date: 2025-08-25 DOI: 10.1016/j.pepi.2025.107421
Erwan Thébault , Gauthier Hulot
Detailed mapping of Earth’s lithospheric magnetic field provides important insights into the composition, dynamics, and geological history of the crust. This field can be modeled using satellite and near-surface magnetic measurements. However, structures larger than approximately 2500 km in scale are obscured by the dominant magnetic signal generated by the Earth’s core. The superposition of core and crustal magnetic fields introduces ambiguities in both geodynamo and crustal magnetic source studies. Previous efforts to address this issue have included statistical estimates of upper and lower bounds on the long-wavelength components of the crustal field, as well as more deterministic predictions based on geophysical priors such as crustal magnetization and seismic Moho depth models. These approaches, however, have often produced contradictory results. In this study, we adopt a two-step strategy. The first step involves a series of regional spherical spectral analysis of the World Digital Magnetic Anomaly Grid (WDMAM2.2), without relying on any prior information from seismic or magnetization models. This approach, applied to the 5 km × 5 km WDMAM2.2 grid across 6000 regions uniformly distributed over the Earth’s surface, allows us to estimate the probability distributions of three key parameters statistically characterizing crustal magnetization in each of the 6000 regions: magnetization amplitude, magnetic layer thickness, and a power-law exponent. The resulting world map of magnetic layer thickness differs from existing Moho depth models but indicates that, statistically, there is no significant evidence of magnetic sources located below the Moho at the studied length scales. In the second step, the ensemble of regional magnetization models is used to generate a set of large-scale spherical harmonic models of the lithospheric magnetic field (degrees 1 to 50). This set allows us to quantify the extent to which the lithospheric field contaminates both the static and time-varying components of the core magnetic field. We find that this contamination is substantial between spherical harmonic degrees 12 and 15 for the static core field, and from degree 21 onward for the secular variation.
地球岩石圈磁场的详细地图为了解地壳的组成、动力学和地质历史提供了重要的见解。这个磁场可以用卫星和近地表磁场测量来模拟。然而,规模超过2500公里的结构被地核产生的主要磁信号所掩盖。地核和地壳磁场的叠加给地球动力学和地壳磁源研究带来了模糊性。以前解决这一问题的努力包括对地壳场长波分量的上下限的统计估计,以及基于地球物理先验(如地壳磁化和地震莫霍深度模型)的更确定的预测。然而,这些方法往往产生相互矛盾的结果。在本研究中,我们采用两步策略。第一步涉及世界数字磁异常网格(WDMAM2.2)的一系列区域球面谱分析,而不依赖于任何来自地震或磁化模型的先验信息。该方法应用于分布在地球表面均匀分布的6000个区域的5km × 5km WDMAM2.2网格,使我们能够估计6000个区域中每个区域中统计表征地壳磁化的三个关键参数的概率分布:磁化幅度、磁层厚度和幂律指数。由此得到的磁层厚度世界图与现有的莫霍深度模型有所不同,但从统计上看,在研究的长度尺度上,莫霍以下没有明显的磁源证据。第二步,利用区域磁化模型集合生成一组大尺度(1 ~ 50度)的岩石圈磁场球谐模型。这组数据使我们能够量化岩石圈磁场对地核磁场静态和时变分量的污染程度。我们发现这种污染在静态核心场的球谐度12和15之间是实质性的,并且从21度以后的长期变化。
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引用次数: 0
Local flow estimation at the top of the Earth’s core using Physics Informed Neural Networks 利用物理信息神经网络估算地核顶部的局部流量
IF 1.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-10-01 Epub Date: 2025-08-26 DOI: 10.1016/j.pepi.2025.107424
Naomi Shakespeare-Rees , Philip W. Livermore , Christopher J. Davies , Hannah F. Rogers , William J. Brown , Ciarán D. Beggan , Christopher C. Finlay
The Earth’s main geomagnetic field arises from the constant motion of the fluid outer core. By assuming that the field changes are advection-dominated, and that diffusion only plays a minor role, the fluid motion at the core surface can be related to the secular variation of the geomagnetic field, providing an observational approach to understanding the motions in the deep Earth. The majority of existing core flow models are global, showing features such as an eccentric planetary gyre, with some evidence of rapid regional changes. By construction, the flow defined at any location by such a model depends on all magnetic field variations across the entire core–mantle boundary: because of this nonlocal dependence of the flow on the magnetic field, it is very challenging to interpret local structures in the flow as due to specific local changes in magnetic field. Here we present an alternative strategy in which we construct regional flow models that rely only on local secular changes. We use a novel technique based on machine learning termed Physics-Informed Neural Networks (PINNs), in which we seek a regional flow model that simultaneously fits both the local magnetic field variation and dynamical conditions assumed satisfied by the flow. Although we present results using the Tangentially Geostrophic flow constraint, we set out a modelling framework for which the physics constraint can be easily changed by altering a single line of code. After validating the PINN-based method on synthetic flows, we apply our method to the CHAOS-8.1 geomagnetic field model, itself based on data from Swarm. Constructing a global mosaic of regional flows, we reproduce the planetary gyre, providing independent evidence that the strong secular changes at high latitude and in equatorial regions are part of the same global feature. Our models also corroborate regional changes in core flows over the last decade. In our models, we find that the azimuthal flow under South America has changed sign quasi-periodically, with a recent sign change in 2022. Furthermore, our models endorse the existence of a dynamic high latitude jet, which began accelerating around 2005 but has been weakening since 2017.
地球的主要地磁场是由流体外核的不断运动产生的。假设磁场变化以平流为主,扩散只起次要作用,那么地核表面的流体运动可以与地磁场的长期变化联系起来,为了解地球深部的运动提供了一种观测方法。现有的大多数地核流模型都是全球性的,显示出偏心行星环流等特征,并有一些证据表明存在快速的区域变化。通过构造,这种模型在任何位置定义的流动取决于整个核心-地幔边界上的所有磁场变化:由于流动对磁场的非局部依赖,将流动中的局部结构解释为由于特定的局部磁场变化而非常具有挑战性。在这里,我们提出了一种替代策略,其中我们构建仅依赖于局部长期变化的区域流量模型。我们使用了一种基于机器学习的新技术,称为物理信息神经网络(pinn),在该技术中,我们寻求一个区域流模型,该模型同时适合局部磁场变化和假定流满足的动态条件。虽然我们使用切向地转流约束呈现结果,但我们设置了一个建模框架,其中物理约束可以通过更改一行代码轻松更改。在对基于pass的方法进行综合流验证后,我们将该方法应用于基于Swarm数据的chaoos -8.1地磁场模型。通过构建区域流的全球马赛克,我们重现了行星环流,为高纬度和赤道地区强烈的长期变化是同一全球特征的一部分提供了独立的证据。我们的模型也证实了过去十年核心流动的区域变化。在我们的模型中,我们发现南美洲的方位流是准周期性地改变符号的,最近的符号变化是在2022年。此外,我们的模型证实了动态高纬度急流的存在,该急流在2005年左右开始加速,但自2017年以来一直在减弱。
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引用次数: 0
A two-and-a-half-dimensional flexing-drip model of lithospheric instabilities and proto-subduction (with two-phase grain-damage) 岩石圈不稳定性和原俯冲(含两相颗粒损伤)的二维半弯曲-滴流模型
IF 1.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-10-01 Epub Date: 2025-06-18 DOI: 10.1016/j.pepi.2025.107403
David Bercovici, Jennifer Girard
The emergence of plate tectonics on the early Earth likely first requires subduction to initiate motion and to harness the mantle's convective gravitational energy as a power source. Whether such proto-subduction initiated as lithospheric drips (Rayleigh-Taylor like instabilities), or was triggered by mantle plumes (or even bolide impacts) remains a mystery. To infer whether drip instabilities and intermittent downwellings are possible causes of subduction initiation, we have developed a relatively simple two-and-a-half-dimensional (2.5-D) model of lithospheric instabilities. We specifically use this model to examine whether such instabilities, coupled to shear-localizing mechanisms like two-phase grain damage, can lead to subduction-like features, as well as semi-permanent weak zones that can be reactivated later to make new plate boundaries. Our model couples the physics of drip instabilities of amplitude h in a horizontal 2-D layer with 2-D viscous lithospheric flexure (bending and folding) of amplitude w. The flexure model is generalized from the Biot's classical 1-D thin-plate theory by accounting for all bending and twisting torques, as well as complex rheology. The drip and flexure models are coupled in that the drips act as a load on the bending lithosphere, while vertical flexure affects the heat transport and pressure gradients governing drip growth. The coupled model predicts least stable mode selection of drip and flexure instabilities, in some cases bimodal instabilities wherein one mode is oscillatory, thus predicting intermittent downwellings. With two-phase grain damage, drips localize into narrow features, often organizing into strings of drips, which induce lineated or arcuate weak zones suggestive of dormant and inheritable plate boundaries.
早期地球板块构造的出现可能首先需要俯冲来启动运动,并利用地幔的对流重力能量作为动力来源。这种原始俯冲是由岩石圈滴流(瑞利-泰勒式的不稳定性)引发的,还是由地幔柱(甚至是火流星撞击)引发的,仍然是一个谜。为了推断滴水不稳定性和间歇性下沉是否是俯冲起始的可能原因,我们开发了一个相对简单的2.5维岩石圈不稳定性模型。我们特别使用这个模型来研究这种不稳定性,加上剪切局部机制,如两相颗粒损伤,是否会导致类似俯冲的特征,以及半永久性的薄弱带,这些薄弱带可以在以后重新激活以形成新的板块边界。我们的模型将水平二维层中振幅为h的水滴不稳定性与振幅为w的二维粘性岩石圈挠曲(弯曲和折叠)耦合在一起。挠曲模型是由Biot经典的一维薄板理论推广而来,考虑了所有的弯曲和扭转力矩以及复杂的流变学。液滴和弯曲模型是耦合的,液滴在弯曲的岩石圈上起载荷作用,而垂直弯曲影响控制液滴生长的热传递和压力梯度。耦合模型预测滴流和弯曲不稳定的最不稳定模式选择,在某些情况下双峰不稳定,其中一个模式是振荡的,因此预测间歇性下降。随着两相颗粒的破坏,液滴局部化为狭窄的特征,经常组织成串状的液滴,形成线状或弓形的弱带,暗示着休眠和可继承的板块边界。
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引用次数: 0
Complex deformation mechanisms of the Qinling orogenic belt lithosphere and clockwise rotation of the Yangtze craton crust: Insights from Rayleigh wave azimuthally anisotropic tomography 秦岭造山带岩石圈复杂变形机制与扬子克拉通地壳顺时针旋转——来自Rayleigh波方位各向异性层析成像的启示
IF 1.9 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-10-01 Epub Date: 2025-08-21 DOI: 10.1016/j.pepi.2025.107436
Tengfei Wu , Shuangxi Zhang , Meng Chen
The collision and convergence between the Yangtze Craton (YZC) and North China Craton (NCC) beneath the Qinling orogenic belt (QOB) have resulted in complex lithospheric deformation, the mechanisms of which remain unclear. In this study, we extracted 10–60 s Rayleigh-wave dispersion curves using the two-station method from vertical-component waveform data of 1087 teleseismic events, recorded at 110 seismic stations across the QOB and adjacent regions. Subsequently, anisotropic tomography was employed to reconstruct high-resolution isotropic and anisotropic phase velocity models of the crust and upper mantle beneath the QOB and surrounding regions. We focused on analyzing deformation patterns in four key subregions of the QOB. Our results demonstrated that crustal deformation is affected by multiple geological factors. Major tectonic activities, such as island arc collisions, oceanic basin closure, and orogenic events, have fundamentally shaped the regional structural framework. Building on this, crustal lithological features, thrust tectonic movements, and the strike of fault systems, which together control present-day deformation. Furthermore, our anisotropic model, in combination with previous geodetic and seismological observations, suggests that the clockwise rotation of the YZC during its convergence with the NCC plays a significant role in influencing crustal deformation. Upper mantle deformation is primarily driven by absolute plate motion, with additional influences from the northeastward escape of material in the Tibetan Plateau and mantle flow. Notably, our anisotropic model provides new seismological evidence supporting the clockwise rotation of the YZC crust, which is closely related to the tectonic development of the Sichuan basin and the formation of the Dabashan arcuate structure. Integrating with previous studies, we propose a conceptual model to explain the formation mechanism of the Dabashan arcuate structure, which we attribute to the combined effects of the clockwise rotation of the YZC crust during the Middle to Late Triassic and the ongoing convergence between the YZC and the NCC. These findings provide new insights into the lithospheric dynamic processes of the QOB.
秦岭造山带下扬子克拉通与华北克拉通的碰撞辐合导致了复杂的岩石圈变形,其机制尚不清楚。本文采用双站法,从QOB及邻近地区110个地震台站记录的1087次远震事件的垂直分量波形数据中提取了10 ~ 60s的瑞利波频散曲线。随后,利用各向异性层析成像技术重建了QOB及其周围区域地壳和上地幔各向同性和各向异性的高分辨率相速度模型。我们重点分析了QOB的四个关键子区域的变形模式。结果表明,地壳变形受多种地质因素的影响。岛弧碰撞、洋盆闭合、造山活动等主要构造活动从根本上塑造了区域构造格局。在此基础上,地壳岩性特征、逆冲构造运动和断层系统的走向共同控制着当今的变形。此外,我们的各向异性模型结合以往的大地测量和地震观测结果表明,YZC在与NCC辐合期间的顺时针旋转对地壳变形有重要影响。值得注意的是,我们的各向异性模型为YZC地壳的顺时针旋转提供了新的地震证据,这与四川盆地的构造发育和大巴山弧形构造的形成密切相关。结合前人的研究成果,提出了大巴山弧形构造形成机制的概念模型,认为大巴山弧形构造的形成是中-晚三叠世中生代地壳顺时针旋转和中生代与北陆的持续辐合共同作用的结果。这些发现为QOB岩石圈动力学过程提供了新的认识。
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引用次数: 0
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Physics of the Earth and Planetary Interiors
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