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Dental Implants with Electrochemical Nanopattern Formation to Increase Osseointegration. 利用纳米电化学模式形成牙种植体以增加骨整合。
Pub Date : 2021-11-22 DOI: 10.21203/rs.3.rs-1062416/v1
W. Kim, Y. C. Shin, Sung-Ho Lee, Moon-Sung Kang, Jong Ho Lee, J. Wie, Min-Sun Lee, Jang-Sik Lee, Dongwook Han, Bongju Kim
Nowadays, The coming acceleration of global population ageing. When people get older, the importance of implants is emphasized. Dental implants have a crucial effect on life satisfaction. Many techniques have already been developed it. However, those still required many procedures. Shin et al suggested the new model based on MA. The electrochemical nanopattern formation (ENF) model takes out lots of steps when it is made. It is very simple because it only removes TiO2 NT layers. Interestingly, we investigated many studies, this simple model did not distinguish the other commercial models. Surface modification by ENF process improved the osteogenic differentiation in cells. It did not limit the cells. In vivo study, ENF also promoted the bone to implant connectivity. The ENF technique used for the new substitute.
如今,全球人口老龄化即将加速。当人们变老时,植入物的重要性被强调。植牙对生活满意度有至关重要的影响。许多技术已经被开发出来。然而,这些仍然需要许多程序。Shin等人提出了基于MA的新模型。电化学纳米图案形成(ENF)模型在制作过程中需要经过许多步骤。它非常简单,因为它只去除二氧化钛NT层。有趣的是,我们调查了许多研究,这个简单的模型并没有区分其他商业模型。ENF表面修饰促进了细胞成骨分化。它没有限制细胞。在体内研究中,ENF还促进了骨与种植体的连通性。用于新替代品的ENF技术。
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引用次数: 0
Effect of Phenolic Acids on Temperature-sensitive Property of Self-assembly of Ionic Pair of Poly(ethylene imine)/(phenylthio)Acetic Acid 酚酸对聚(乙烯亚胺)/(苯基硫)乙酸离子对自组装温敏性能的影响
Pub Date : 2021-09-22 DOI: 10.21203/rs.3.rs-907833/v1
Fanyu Zhao, Jin-Chul Kim
The ionic pair self-assembly (IPSAM) composed of poly(ethyleneimine) (PEI) and (phenylthio)acetic acid (PTA) was prepared and the effect of phenolic acids (PAs) (e.g. cinnamic acid (CA), hydroxycinnamic acid (HCA), and dihydroxycinnamic acid (DHCA)) on the upper critical solution temperature (UCST) and the temperature-responsive releasing property of IPSAM were investigated. PEI/PTA ionic pair showed a UCST behavior and the PAs decreased the UCST effective in the order of DHCA > HCA > CA. The PAs were thought to attach to the PEI chain of PEI/PTA ionic pair as pendants. According to the interfacial tensiometry, PEI/PTA(3/7) ionic pair was found to be air/water interface-active due to their amphiphilic property. CA had little effect on the interfacial activity of the ionic pair. HCA and HDCA significantly decreased the interfacial activity possibly because they are more polar than CA thus the hydrophilic and lipophilic balance of PEI/PTA ionic pair could be broken by their attachment to PEI chains. IPSAM was found as nanoparticles whose diameter was tens of nanometer and PAs had little effect on the shape and the size of IPSAM, once the UCST of PEI/PTA/PA ionic pair was above room temperature where the TEM micrographs were taken. If the UCST of PEI/PTA/PA ionic pair was below room temperature, no particulate matters were found on the TEM micrographs. The release degree of cargo loaded in IPSAM increased slowly with time lapse below UCST. Whereas, the release degree increased rapidly with time lapse above UCST, possibly because of the thermally-induced disintegration of IPSAM.
制备了由聚乙亚胺(PEI)和苯基硫代乙酸(PTA)组成的离子对自组装体(IPSAM),考察了酚酸(CA)、羟基肉桂酸(HCA)和二羟基肉桂酸(DHCA)等酚酸(PAs)对IPSAM上临界溶液温度(UCST)和温度响应释放性能的影响。PEI/PTA离子对表现出UCST行为,PAs降低UCST效果的顺序为DHCA > HCA > CA,认为PAs作为挂件附着在PEI/PTA离子对的PEI链上。通过界面张力测定,发现PEI/PTA(3/7)离子对由于其两亲性而具有空气/水界面活性。CA对离子对的界面活性影响不大。HCA和HDCA明显降低了界面活性,这可能是因为它们比CA极性更强,因此PEI/PTA离子对的亲水亲脂平衡可能被它们附着在PEI链上而被打破。当PEI/PTA/PA离子对的UCST高于室温(TEM显微图)时,发现IPSAM为直径为几十纳米的纳米颗粒,PAs对IPSAM的形状和尺寸影响不大。当PEI/PTA/PA离子对的UCST低于室温时,TEM显微图上未发现颗粒物质。在UCST以下,随时间的推移,IPSAM所载货物的释放程度缓慢增加。而在温度以上,随着时间的推移,释放度迅速增加,这可能是由于IPSAM的热崩解所致。
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引用次数: 0
Preparation of high performance ZSM-5 zeolite membranes for CO2/H2 separation ZSM-5型高效CO2/H2分离沸石膜的制备
Pub Date : 2020-09-10 DOI: 10.22541/au.159969837.71192895
S. Mirfendereski, T. Mazaheri
Abstract High-quality zeolite ZSM-5 zeolite membranes were successfully synthesized on the outer surface of tubular α-alumina substrates by manipulating the microstructure of the zeolite layer using a new different-sized seeding (DSSM) in combination with a variable-temperature/time (VTT) methods. In this method the defects/microcracks in the bottom seed layer, which are filled by smaller seeds, are effectively eliminated using a designed temperature/time profile, resulting in a significant increase in selectivity without scarifying permeance. The effects of number and combination of seed layers, seed particle size, and the synthesis temperature-time profile on the microstructure, N2/SF6 gas permeation, and H2/CO2 separation performance of membranes are evaluated in detail. The synthesized ZSM-5 zeolite membranes show the microstructure of thin, fully inter-grown, and densified zeolite layer that is responsible for high selectivity without any negative effect on the permeance. The best synthesized defect-free ZSM-5 zeolite membranes on alumina supports exhibited a very low H2/CO2 selectivity of 0.1 with CO2 permeance of 3 × 10−5 mol m−2 s−1 Pa−1.
摘要:采用新型不同尺寸的种子(DSSM)和变温/时间(VTT)方法对沸石层的微观结构进行调控,在管状α-氧化铝衬底表面成功合成了高质量的沸石ZSM-5沸石膜。在这种方法中,使用设计的温度/时间分布,可以有效地消除由较小种子填充的底层种子层中的缺陷/微裂纹,从而显著提高选择性,而不会破坏渗透。考察了种子层数和组合、种子粒径、合成温度-时间分布对膜的微观结构、N2/SF6气体渗透性和H2/CO2分离性能的影响。所合成的ZSM-5沸石膜具有较薄、完全互生、致密的沸石层结构,具有较高的选择性,且对渗透性能没有负面影响。在氧化铝载体上合成的最佳无缺陷ZSM-5沸石膜的H2/CO2选择性非常低,为0.1,CO2透过率为3 × 10−5 mol m−2 s−1 Pa−1。
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引用次数: 8
The intrinsic relationship between color variation and performances of the deteriorated aviation lubrication oil 变质航空润滑油颜色变化与性能的内在关系
Pub Date : 2020-06-02 DOI: 10.22541/au.159112183.34918439
Jun Ma, S. Ruan, Jianqiang Hu, Yuanbao Sun, Y. Fei, X. Jiang, Shibao Dong, Teng Chen, N. Wu
Abstract Dose the blackened lubrication oil needs to be replaced for flying safety? Since there is very limited room for inaccurate assessment of oil quality due to strict flying safety standards, much aviation lubrication oil is disposed in advance long before their service life. More important, aircrafts still face the fatal challenges from unpredictable lubrication oil deterioration. Color change is surely a significant signal to diagnose the quality of lubrication oils. Based on the colorimeter, the color numbers of the testing lubrication oils are measured in this paper to identify the color variation degree of the oxidized lubrication oils. Then the molecular structures of the oxidized lubrication oils are investigated to find the intrinsic relationship between the oxidation products and color numbers. Based on key performances of the oxidized oil samples, the oil quality is undoubtfully deteriorated which is coincident with the variation of color number. The color numbers of the used aviation lubrication oils could provide an alternative way to readily and quickly measure the decline degree and residual lifetime.
为了飞行安全,是否需要更换变黑的润滑油?由于严格的飞行安全标准,对油品质量的不准确评估空间非常有限,许多航空润滑油在使用寿命之前就被提前处理掉了。更重要的是,飞机仍然面临着不可预测的润滑油变质的致命挑战。润滑油颜色变化是诊断润滑油质量的重要信号。本文利用比色计对试验润滑油的色号进行测定,以鉴别氧化润滑油的变色程度。然后对氧化润滑油的分子结构进行了研究,找出了氧化产物与颜色数之间的内在关系。从氧化油样的主要性能来看,油品质量无疑是恶化的,这与色数的变化是一致的。使用过的航空润滑油的色号可以提供一种简便、快速地测定其衰退程度和剩余寿命的方法。
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引用次数: 5
Comparative Tests of Chemical Glassware. 化学玻璃器皿的比较试验。
Pub Date : 2018-03-19 DOI: 10.1021/ie50096a009
P. H. Walker, F. Smither
These results indicate that all the American-made wares tested are superior to Kavalier and equal or superior to Jena ware for general chemical laboratory use.
这些结果表明,所有美国制造的器皿测试优于卡瓦利尔和等于或优于耶拿器皿一般化学实验室使用。
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引用次数: 3
Deterioration and Spontaneous Heating of Coal in Storage. 煤在贮存中的变质与自热。
Pub Date : 2017-11-10 DOI: 10.1021/IE50037A003
H. C. Porter, F. K. Ovitz
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引用次数: 5
Chlorinated breakdown products formed during oxidation of adsorbed phenol by electrochemical regeneration of a graphite intercalation compound 石墨插层化合物电化学再生吸附苯酚氧化过程中形成的氯化分解产物
Pub Date : 2015-10-25 DOI: 10.1016/J.JIEC.2015.05.024
S. N. Hussain, H. Asghar, H. Sattar, N. Brown, E. Roberts
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引用次数: 8
Comparative study between liquid–liquid extraction and bulk liquid membrane for the removal and recovery of methylene blue from wastewater 液-液萃取法与散装液膜法去除回收废水中亚甲基蓝的比较研究
Pub Date : 2015-10-25 DOI: 10.1016/J.JIEC.2015.05.032
M. Soniya, G. Muthuraman
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引用次数: 67
Optimization of extractive desulfurization of Malaysian diesel fuel using response surface methodology/Box–Behnken design 响应面法/ Box-Behnken设计优化马来西亚柴油萃取脱硫
Pub Date : 2015-10-25 DOI: 10.1016/J.JIEC.2015.05.033
W. Mokhtar, W. A. Bakar, R. Ali, A. Kadir
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引用次数: 23
Improved performance of cerium conversion coatings on steel with zinc phosphate post-treatment 磷酸锌后处理提高钢铈转化涂层性能
Pub Date : 2015-10-25 DOI: 10.1016/J.JIEC.2015.05.026
B. Ramezanzadeh, H. Vakili, R. Amini
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引用次数: 66
期刊
Journal of Industrial and Engineering Chemistry-Us
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