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Deformation of the Northwestern Junggar Basin (Che-Guai Region, Northwest China) and Implications for Hydrocarbon Accumulation 准噶尔盆地西北部(车拐地区)的形变及其油气成藏意义
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2020-01-01 DOI: 10.1086/706263
Lin-jun Huang, Kongyou Wu, Yin Liu, Jian-guo Pan, Weijiang Yao, Bo Liu, Jian Cao
The Che-Guai region is located in the most strongly deformed area of the northwestern Junggar Basin (northwest China) and its deformation history is key to understanding the tectonic evolution of West Junggar and its associated hydrocarbon accumulation. However, the presence of complex multiphase structures makes it difficult to unravel the deformation history. In this study, we present comprehensive seismic and well log data, combined with geological observations from sedimentary and volcanic rocks, to reveal the structural deformation of the northwestern Junggar Basin. Based on our results, four zones of concentrated deformation are identified: (1) the Ke-Bai Fault Zone, (2) the Hongshanzui transition zone, (3) the Zhongguai uplifted zone, and (4) the Hong-Che Fault Zone. Based on the interpretation of seismic profiles, we suggest that Paleozoic strata were affected mainly by thrust faults, whereas Triassic and Jurassic strata of the Zhongguai uplifted zone were affected by strike-slip faults. Deformation in Cretaceous and Cenozoic strata is associated mainly with normal faults. Based on our results, the following tectonic history is proposed. The first stage involved initial basin formation during the Permian under the influence of northwestward subduction of the Junggar Ocean crust. The second stage, during the Triassic and Jurassic, involved transpressional deformation related to movement along the Darbute Fault. The third stage, during the Cretaceous and Cenozoic, involved moderate extensional deformation triggered by collision between the Indian and Eurasian plates. In the context of this tectonic history, hydrocarbon accumulation is proposed to be linked to fault terraces of the Hong-Che and Ke-Bai Fault Zones and the uplift of the Zhongguai Uplift.
车拐地区位于准噶尔盆地西北部变形最强烈的地区,其变形史是了解准噶尔西部构造演化及其油气聚集的关键。然而,复杂的多相结构的存在使得解开变形历史变得困难。在本研究中,我们提供了综合的地震和测井数据,并结合沉积岩和火山岩的地质观测,揭示了准噶尔盆地西北部的结构变形。根据研究结果,确定了四个集中变形带:(1)柯白断裂带、(2)红山嘴过渡带、(3)钟拐隆起带和(4)红车断裂带。根据地震剖面的解释,我们认为中拐隆起带的古生代地层主要受逆冲断层的影响,而三叠纪和侏罗系地层主要受走滑断层的影响。白垩纪和新生代地层的变形主要与正断层有关。基于我们的研究结果,提出了以下构造史。第一阶段是在准噶尔洋地壳西北俯冲的影响下,二叠纪的初始盆地形成。第二阶段,在三叠纪和侏罗纪期间,涉及与Darbute断层运动相关的转挤压变形。第三阶段,在白垩纪和新生代,涉及印度和欧亚板块碰撞引发的适度伸展变形。在这一构造史背景下,油气聚集与红车断裂带和柯白断裂带的断阶及钟拐隆起有关。
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引用次数: 0
Petrogenesis of Silicic Magmas in Iceland through Space and Time: The Isotopic Record Preserved in Zircon and Whole Rocks 冰岛硅质岩浆的时空成因:锆石和整块岩石中的同位素记录
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2020-01-01 DOI: 10.1086/706261
T. Carley, C. Miller, C. Fisher, J. Hanchar, J. Vervoort, A. Schmitt, R. Economos, B. Jordan, A. J. Padilla, Tenley J. Banik
Iceland exemplifies the potential for generation of abundant silicic magma in the absence of mature island arc or preexisting continental crust. Zircon ages (U-Th and U-Pb) and isotope compositions (Hf and O), combined with whole-rock isotope data (Nd, Hf, Pb), provide insight into the petrogenesis and mantle heritage of these silicic magmas. Zircon and whole-rock samples represent the past 15 Ma of Iceland’s geologic evolution, geographic extent (marginal fjordlands to neovolcanic zones), and modern tectonic settings (on-rift, propagating-rift, off-rift). The generation of Icelandic silicic magma has been influenced by hydrothermally altered crust, via assimilation and/or anatexis, throughout Iceland’s history. This is shown by consistently depleted O isotopes in zircon (median δ18O +3.1‰; >98% below +5.3‰), and silicic rocks. Zircon δ18O values appear to have become lower and more diverse since ca. 0.7 Ma (median +1.9‰). This decrease may reflect lower δ18O of meteoric waters involved in hydrothermal alteration during the Pleistocene and/or more volumetrically significant contributions from low δ18O altered crust. Zircon O compositions from historically active volcanoes confirm that the role of altered crust is greater in on-rift than in off-rift settings; diversity in δ18O at volcanoes in propagating rift settings suggests highly variable contributions from altered crust. The silicic record (whole-rock and zircon) exhibits a correlation between geographic position and isotope composition that seems to be independent of local tectonic setting. Silicic samples of all ages collected above 65° N have more radiogenic whole-rock Hf and Nd isotopic compositions, and less radiogenic Pb, than samples collected in southern Iceland; published isotopic data for basalts suggest a similar time-independent latitudinal trend. The persistence of this trend through time suggests that northern Iceland has been underlain by a more depleted mantle source than southern Iceland throughout the island’s history.
冰岛表明,在没有成熟岛弧或大陆地壳的情况下,有可能产生丰富的硅质岩浆。锆石年龄(U-Th和U-Pb)和同位素组成(Hf和O),结合全岩同位素数据(Nd、Hf、Pb),可以深入了解这些硅质岩浆的岩石成因和地幔遗产。锆石和全岩样品代表了冰岛过去15 Ma的地质演化、地理范围(边缘峡湾到新火山带)和现代构造环境(裂谷上、扩展裂谷上、裂谷外)。冰岛硅质岩浆的形成在整个冰岛历史上一直受到热液蚀变地壳的影响,通过同化和/或深熔作用。锆石中O同位素持续亏缺(δ18O +3.1‰;bbb98 % < +5.3‰)和硅质岩石。锆石δ18O值自约0.7 Ma(中位数+1.9‰)以来呈现出较低和多样化的特征。这种减少可能反映了更新世期间参与热液蚀变的大气水δ18O较低,或者低δ18O蚀变地壳在体积上的贡献更大。历史上活火山的锆石O组成证实了蚀变地壳在裂谷上的作用大于裂谷外;扩展裂谷环境下火山δ18O的多样性表明,蚀变地壳的贡献是高度可变的。硅记录(全岩和锆石)显示了地理位置和同位素组成之间的相关性,似乎与当地的构造背景无关。在65°N以上采集的所有年龄的硅样品比冰岛南部采集的样品具有更多的放射性全岩Hf和Nd同位素组成,而放射性Pb同位素组成较少;已公布的玄武岩同位素数据也显示出类似的与时间无关的纬度趋势。随着时间的推移,这种趋势的持续表明,在冰岛的整个历史中,冰岛北部比冰岛南部受到更枯竭的地幔源的影响。
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引用次数: 16
Geodynamic Implications of the Latest Chattian-Langhian Central-Western Peri-Mediterranean Volcano-Sedimentary Event: A Review 最新的查天-朗吉安中-西部环地中海火山-沉积事件地球动力学意义综述
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2020-01-01 DOI: 10.1086/706262
M. Martín-Martín, F. Guerrera, M. Tramontana
High amounts of Chattian-Langhian orogenic magmatism have generated volcaniclastic deposits that are interbedded within the penecontemporaneous sedimentary marine successions in several central-western peri-Mediterranean chains. These deposits are widespread in at least 41 units of different basins located in different geotectonic provinces: (1) the Africa-Adria continental margins (external units), (2) the basinal units resting on oceanic or thinned continental crust of the different branches of the western Tethys, (3) the European Margin (external units), and (4) the Western Sardinia zone (Sardinia Trough units). The emplacement of volcaniclastic material in marine basins was controlled by gravity flows (mainly turbidites; epiclastites) and fallout (pyroclastites). A third type comprises volcaniclastic grains mixed with marine deposits (mixed pyroclastic-epiclastic). Calc-alkaline magmatic activity is characterized by a medium- to high-potassium andesite-dacite-rhyolite suite and is linked to complex geodynamic processes that affected the central-western Mediterranean area in the ∼26 to 15 My range. The space/time distribution of volcaniclastites, together with a paleogeographic reconstructions, provide keys and constraints for a better reconstruction of some geodynamic events. Previous models of the central-western Mediterranean area were examined to compare their compatibility with main paleotectonic and paleogeographic constraints presented by the main results of the study. Despite the complexity of the topic, a preliminary evolutionary model based on the distribution of volcaniclastites and active volcanic systems is proposed.
大量的查天-朗吉造山岩浆活动产生了火山碎屑矿床,这些火山碎屑矿床在几个中西部环地中海链的准同生海相沉积序列中互层。这些矿床分布在位于不同大地构造省的不同盆地的至少41个单元中:(1)非洲-亚德里亚大陆边缘(外部单元),(2)位于西特提斯不同分支的海洋或薄大陆地壳上的盆地单元,(3)欧洲边缘(外部单元)和(4)西撒丁岛带(撒丁岛海槽单元)。海相盆地火山碎屑物质的侵位受重力流(主要是浊积岩)控制;辉长岩)和沉降物(火山碎屑岩)。第三种类型是火山碎屑颗粒与海相沉积物混合(混合火山碎屑-火山碎屑)。钙碱性岩浆活动以中至高钾安山岩-英安岩-流纹岩套件为特征,并与影响地中海中西部地区的复杂地球动力学过程有关。火山碎屑岩的时空分布和古地理重建为更好地重建一些地球动力学事件提供了关键和约束条件。对地中海中西部地区以往的模型进行了检验,比较了它们与主要古构造和古地理约束的配伍性。尽管这个问题很复杂,但我们还是提出了一个基于火山碎屑岩和活火山系统分布的初步演化模型。
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引用次数: 30
940 Ma Anatexis in 1726 Ma Orthogneiss in the Northern Margin of the Bhilwara Belt and Significance for the Precambrian Evolution in Northwest India 印度西北部Bhilwara带北缘1726 Ma正长片麻岩中940 Ma的Anatexis及其对前寒武纪演化的意义
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2019-10-14 DOI: 10.1086/705325
Ambik Kumar, A. Prakash, L. Saha, F. Corfu, A. Bhattacharya
The northwestern domains of India record Proterozoic orogenies that reflect global cycles of convergence and extension. A garnet-biotite migmatitic orthogneiss hosted within the Agucha-Kekri Shear Zone sandwiched between the Bhilwara Belt and the North Delhi Fold Belt (NDFB) has two zircon populations yielding U-Pb ages of 1726 and 938 Ma. The older age is correlated with the intrusion of the migmatite protolith, consistent with the partial melting event recorded in gneisses in the southern margin of the Bhilwara Belt. The younger age is interpreted as the age of partial melting and migmatization. Petrographical observations and pressure-temperature (PT) pseudosection analyses indicate incongruent melting of biotite and plagioclase in the gneiss-produced garnet, potash feldspar, and melt under water-fluxed conditions. The peak conditions of ~9 kbar and ≥700°C estimated for the partial melting are similar to those of coeval migmatization recorded at the northwestern margin of the Bhilwara Belt, but lower than those in the adjacent NDFB. This is interpreted to indicate formation of a migmatitic front along the northwestern margin of the Bhilwara Belt while this was being underthrust under the NDFB. Migmatization under similar PT conditions and, at the same time, estimated for the Central Indian Tectonic Zone implies the presence of several loci of crustal amalgamation leading to the final architecture of peninsular India during Rodinia formation.
印度西北地区记录了元古代造山运动,反映了全球收敛和伸展的周期。夹在Bhilwara带和北德里褶皱带(NDFB)之间的Agucha-Kekri剪切带内的石榴石-黑云母混合岩正片麻岩有两个锆石群,U-Pb年龄分别为1726和938Ma。较老的年龄与混合岩原岩的侵入有关,与Bhilwara带南缘片麻岩中记录的部分熔融事件一致。较年轻的年龄被解释为部分熔融和混合岩化的年龄。岩石学观察和压力-温度(PT)假剖面分析表明,片麻岩中黑云母和斜长石的熔融不协调,产生石榴石、钾长石,并在水通量条件下熔融。估计部分熔融的~9 kbar和≥700°C的峰值条件与Bhilwara带西北边缘记录的同时代混合岩化的峰值条件相似,但低于邻近NDFB的峰值条件。这被解释为表明,当Bhilwara带的西北边缘在NDFB下进行逆冲时,形成了一个混合岩化锋。在类似PT条件下的混合作用,同时,对印度中部构造带的估计表明,在罗迪尼亚形成期间,存在几个地壳拼合位点,导致印度半岛的最终构造。
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引用次数: 6
Nature, Occurrence, and Lithological Setup of Youngest Toba Tuff Volcanic Ash, Purna Alluvial Basin, Central India 印度中部普尔纳冲积盆地最年轻多巴凝灰岩火山灰的性质、产状和岩性设置
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2019-10-10 DOI: 10.1086/705326
A. Srivastava, Ajab Singh
Youngest Toba Tuff ashes in the Purna alluvial basin of central India have been encountered at various places and are represented by light-gray, yellowish-brown, grayish-orange-pink, loosely packed, fine-grained material. These are preserved as pockets, lenticles, and discontinuous beds of 0.5–3.0-m thickness in the arenoargillaceous sediments of fluvial environments. Based on color, thickness, and sedimentological features, this distal material is divisible into primary ash and reworked ash. Microscopically, the ashes consist predominantly of glass shards with bubble-wall morphologies, minor minerals, unidentifiable fine-grain admixture, and, rarely, channel sediments. The glass shards are colorless, transparent, angular, unfractured, and unaltered in nature. A total of six morphotypes have been identified: (1) uniradiate, or two-bubble-wall, shards, (2) Y-shaped, or triradiate, shards, (3) platy shards, (4) blocky shards, (5) shards with elongated vesicles, and (6) pumice shards. Facies architecture of various successions shows broadly low-energy fluviolacustrine depositional environments. Major-element analysis of the glass shards shows a high percentage of silica, followed by alumina, potassium, and sodium. In general, high percentages of major ions in the glass shards reflect rhyolitic magma composition. The minerals in the ash, though minor in quantity, are represented by quartz, feldspar, biotite, amphibole, pyroxene, olivine, allanites, and Fe-Ti oxides. Preservations of various paleoclimatic proxies are also recorded from pretephra successions and are represented by rhizoliths, rhizolith balls, rhizosphere, ant traces, and vertebrate remains.
印度中部Purna冲积盆地中最年轻的Toba Tuff灰在不同地方都有发现,其特征是浅灰色、黄褐色、灰橙粉色、松散堆积的细粒物质。它们以0.5–3.0m厚的口袋、小透镜体和不连续床的形式保存在河流环境的砂质沉积物中。根据颜色、厚度和沉积学特征,这种远端物质可分为原始灰和再加工灰。显微镜下,灰烬主要由具有气泡壁形态的玻璃碎片、次要矿物、无法识别的细粒混合物组成,很少有通道沉积物。玻璃碎片无色、透明、有棱角、未破裂,性质不变。共鉴定出六种形态类型:(1)单辐射状或两个泡壁碎片,(2)Y形或三辐射状碎片,(3)片状碎片,(4)块状碎片,(5)具有细长囊泡的碎片,以及(6)浮石碎片。不同序列的相结构显示出广泛的低能流体沉积环境。对玻璃碎片的主要元素分析显示,二氧化硅的比例很高,其次是氧化铝、钾和钠。一般来说,玻璃碎片中主要离子的高百分比反映了流纹岩岩浆的成分。灰中的矿物虽然数量较少,但以石英、长石、黑云母、角闪石、辉石、橄榄石、尿囊石和铁钛氧化物为代表。各种古气候替代物的保存也记录在胞前序列中,以根石、根石球、根际、蚂蚁痕迹和脊椎动物遗骸为代表。
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引用次数: 10
Geochemistry and Petrogenesis of Late Ediacaran Rare-Metal Albite Granite of the Nubian Shield: Case Study of Nuweibi Intrusion, Eastern Desert, Egypt 努比亚地盾晚埃迪卡拉纪稀有金属白云岩的地球化学和岩石成因——以埃及东部沙漠努韦比入侵为例
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2019-10-09 DOI: 10.1086/705328
M. Azer, Khaled M. Abdelfadil, A. A. Ramadan
The Nuweibi albite granite (NAG) is a postcollisional intrusion emplaced as a high-level magmatic cupola into metamorphic and syntectonic calc-alkaline country rocks. It consists of two cogenetic intrusive bodies: the western, nonporphyritic, albite granite was emplaced deeper than the eastern, fine-grained, porphyritic, albite granite. In places the nonporphyritic phase crosscuts the earlier porphyritic phase, but the occurrence of gradational contacts between the phases implies a near coincidence in time, with the nonporphyritic phase emplaced before crystallization of the porphyritic phase was complete. The steeply dipping slope of the western contact of the Nuweibi pluton against country rocks, in contrast to the gently dipping contacts above the eastern and northeastern parts, indicates the probable location of the cupola apex in the eastern part of the pluton. The NAG intrusion is highly evolved meta- to peraluminous leucocratic rare-metal albite granite. The NAG intrusion is chemically zoned, with upward increases of Al2O3, Na2O, Sr, Ga, and Ta concentrations, alongside upward decreases in SiO2, K2O, Rb, Nb, Zn, Zr, Th, Sn, and rare earth element concentrations. These trends are interrupted by a compositional gap with discontinuities in evolutionary trends of both compatible and incompatible elements, suggesting multiple pulses of intrusion. The NAG was generated via partial melting of a juvenile crust that had undergone extensive fractional crystallization combined with late-magmatic fluid overprint. Accumulation of residual volatile-rich melt and exsolved fluids in the apical part of the magmatic cupola produced stockscheider pegmatite, greisen, and quartz veins that cut the peripheries of the NAG pluton. Metasomatic activity by late- to postmagmatic fluids drove changes in the bulk composition of the cupola, removing K and driving the alkali feldspars toward pure albite.
Nuweibi钠长石花岗岩(NAG)是一种以高岩浆冲天炉侵入变质和同构造钙碱性岩石的碰撞后侵入岩体。它由两个同生岩体组成:西部的非斑岩钠长花岗岩比东部的细粒斑岩钠长花岗岩侵位更深。在某些地方,非斑岩相与早期的斑岩相交叉,但两相之间的级递进接触意味着在时间上几乎重合,非斑岩相在斑岩相结晶完成之前就位。nuwebi岩体西部触点对围岩的陡倾斜坡与东部和东北部触点的缓倾斜坡形成对比,表明冲天炉顶可能位于岩体东部。NAG侵入体为高度演化的偏铝-过铝质白闪质稀有金属钠长花岗岩。NAG侵入具有明显的化学分区特征,Al2O3、Na2O、Sr、Ga和Ta浓度呈上升趋势,SiO2、K2O、Rb、Nb、Zn、Zr、Th、Sn和稀土元素浓度呈上升趋势。这些趋势被组成间隙打断,相容元素和不相容元素的进化趋势不连续性,表明存在多次入侵脉冲。NAG是由经历了广泛的分离结晶和晚期岩浆流体叠印的幼年地壳的部分熔融作用产生的。岩浆冲天炉顶部富含挥发性残留物的熔体和溶解液的积累产生了大量伟晶岩、灰岩和石英脉,切断了NAG岩体的外围。岩浆晚期至岩浆后期流体的交代活动改变了冲天炉的主体成分,使钾元素被移走,碱长石向纯钠长石转变。
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引用次数: 20
New Zircon U-Pb Age and Its Restriction on the Warming Time of the Interglacial Paleoclimate during the Cryogenian in the Yangtze Block 新锆石U-Pb年龄及其对扬子地块低温期间冰期古气候变暖时间的限制
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2019-10-07 DOI: 10.1086/705327
Minglong Li, Jingchun Tian, Lin Chen, Hui Xu, Deshun Zheng, Weiqing Liu
The evolution of the paleoclimate and the duration of the two glacial periods during the Cryogenian in the Yangtze Block are of great geological significance for understanding “Snowball Earth.” We studied the evolution of the paleoclimate during the Cryogenian, using chemical weathering, and determined the warming time of the interglacial paleoclimate, using zircon U-Pb dating in the Yangtze region. A new laser ablation ICP-MS zircon U-Pb age of 659.9±3.2 Ma is reported from the middle Datangpo Formation. The chemical index of alteration (CIA) for the Cryogenian fine clastic rock samples from a drill core shows that the climate in the provenance area during the Gucheng and Nantuo glacial periods was dry and cold and that the chemical weathering was weak; the average CIA values were 63.3 and 64.2, respectively. In the early stage of the Datangpo period, the climate in the provenance area was still dry and cold, with a CIA average of 60.7, compatible with that in the two glacial periods; in the middle and late stages, the climate was warm and humid, chemical weathering was enhanced, and the average CIA rose to 77.4, compatible with the 76.9 of the Liantuo period before the Cryogenian. The evolution of other chemical weathering (paleoclimate) proxies, such as the chemical index of weathering, the plagioclase index of alteration, and Rb/Sr, is compatible with that of the CIA. The warming time of the interglacial paleoclimate during the Cryogenian in the Yangtze Block was ca. 660 Ma, roughly consistent with the ending time of the Sturtian in Australia and Mongolia, indicating that the lower part of the Datangpo Formation may still represent Sturtian glacial deposits, thus further suggesting the global consistency of the end of the Sturtian.
长江地块成冰纪古气候的演变和两个冰川期的持续时间对理解“雪球地球”具有重要的地质意义,利用长江地区锆石U-Pb测年。报道了一个新的激光烧蚀ICP-MS锆石U-Pb年龄为659.9±3.2Ma。钻孔岩芯中成冰纪细碎屑岩样品的化学蚀变指数(CIA)表明,故城、南陀冰川期物源区气候干燥寒冷,化学风化较弱;平均CIA值分别为63.3和64.2。在大塘坡期早期,物源区气候仍然干燥寒冷,CIA平均值为60.7,与两次冰川期相适应;中后期气候温暖湿润,化学风化作用增强,平均CIA上升到77.4,与成冰纪前连坨期的76.9一致。其他化学风化(古气候)指标的演变,如风化的化学指数、蚀变的斜长石指数和Rb/Sr,与CIA的演变是一致的。扬子地块成冰期间冰古气候的升温时间约为660 Ma,与澳大利亚和蒙古的斯图阶结束时间大致一致,表明大塘坡组下部可能仍代表斯图阶冰川沉积,从而进一步表明斯图阶末次的全球一致性。
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引用次数: 3
A Mathematical Model Based on Bayesian Theory and Gaussian Copula for the Discrimination of Gabbroic Rocks from Three Tectonic Settings 基于贝叶斯理论和高斯Copula的三种构造背景下辉长岩判别数学模型
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2019-10-04 DOI: 10.1086/705413
Shuai Han, Mingchao Li, Qi Zhang, Heng Li
Discriminating among tectonic settings by the chemical composition of igneous rocks is a feasible method in geochemistry. In this study, the feasibility of using gabbroic rocks to discriminate among tectonic settings is analyzed, and a mathematical model based on Gaussian copula and Bayesian theory is set up to discriminate among three tectonic settings: island arc, ocean island, and mid-oceanic ridge. The derivation of the model includes three steps: (1) determine the probability density functions (PDFs) of the elements in different tectonic settings, (2) determine the joint PDFs of the geochemical components of the rocks from different tectonic settings using copula functions, and (3) determine the tectonic settings of rocks using Bayesian theory. The optimal parameters of the mathematical model are calculated using a genetic algorithm, and finally the definitive form of the model is determined with nine basic elements: TiO2, Al2O3, FeOT, CaO, MnO, K2O, Na2O, Ni, and Sr. An experiment shows that the success rates of the mathematical model on the three tectonic settings are 84.03%, 95.48%, and 91.84%, respectively. The average percent success rate is 92.13%, which is significantly higher than using discrimination diagrams and the naive Bayes algorithm. Such an ideal result indicates that using gabbroic rocks to determine the types of tectonic settings is feasible. Moreover, this study can provide support for the application of machine learning and mathematical methods in the field of geochemistry.
通过火成岩的化学成分来区分构造环境是一种可行的地球化学方法。分析了辉长岩判别构造环境的可行性,建立了基于高斯copula和贝叶斯理论的数学模型,对岛弧、海岛和洋中脊三种构造环境进行了判别。该模型的推导包括三个步骤:(1)确定不同构造环境中元素的概率密度函数(PDF);(2)使用copula函数确定不同构造背景下岩石地球化学成分的联合PDF;(3)使用贝叶斯理论确定岩石的构造环境。利用遗传算法计算数学模型的最佳参数,最终确定了以TiO2、Al2O3、FeOT、CaO、MnO、K2O、Na2O、Ni和Sr九种基本元素为基本元素的数学模型的最终形式。实验表明,数学模型在三种构造环境下的成功率分别为84.03%、95.48%和91.84%。平均成功率为92.13%,显著高于使用判别图和朴素贝叶斯算法。这样一个理想的结果表明,利用辉长岩来确定构造环境的类型是可行的。此外,该研究可以为机器学习和数学方法在地球化学领域的应用提供支持。
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引用次数: 4
Possibility of Mixed Origin of Rare Earth Elements in Sedimentary Marine Apatites: A Case Study from Phosphorites in the Cretaceous (Campanian-Maastrichtian) Duwi Formation, Abu-Tartur Plateau, Egypt 沉积海相磷灰石中稀土元素混合成因的可能性——以埃及Abu-Tartur高原白垩系(Campanian-Maastrichtian) Duwi组磷灰岩为例
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2019-10-04 DOI: 10.1086/705414
G. El-Habaak, M. Askalany, M. Abdel-Hakeem
It is well known that the rare earth elements (REEs) incorporated in the crystal lattice of sedimentary apatite are commonly derived from ambient seawater. This study documents, for the first time, the possibility of mixed origin of apatite REEs present in the Egyptian Western Desert phosphorites, known as the Abu-Tartur phosphorites, one of the most important accumulations of sedimentary phosphorites in the Middle East and North Africa. Shale-like patterns of REEs, negative Ce anomalies, and a (La/Sm)N−(La/Yb)N binary diagram of the studied phosphorites indicate that the incorporation of REEs into apatite crystal lattices has occurred from the ambient seawater by substitution during late-stage diagenesis. The second origin is attributed to REE-bearing supergene fluids, which resulted in the occurrence of sedimentary britholite as green rims and patches containing about 14.93 wt% total REEs in places where the black phosphorites are gradually oxidized into the brown variety. For instance, the intensive chemical weathering induces the crystal lattice of carbonate fluorapatite to preferentially release Ca2+ and CO32− ion species to solution, resulting in the formation of a carbonate-depleted layer in which REEs, particularly heavy REEs, are incorporated into the preferential Ca2+ sites inside the altered apatite lattice, leading to britholite formation.
众所周知,沉积磷灰石晶格中的稀土元素通常来源于环境海水。这项研究首次记录了埃及西部沙漠磷矿中存在的磷灰石稀土元素混合来源的可能性,称为Abu-Tartur磷矿,这是中东和北非最重要的沉积磷矿堆积之一。REEs的页岩状模式、负Ce异常和所研究的磷矿的(La/Sm)N−(La/Yb)N二元图表明,在晚期成岩过程中,环境海水通过置换作用将REEs结合到磷灰石晶格中。第二个成因归因于含REE的浅生流体,这导致沉积辉长岩以绿色边缘和斑块的形式出现,在黑色磷光体逐渐氧化为棕色的地方,总REE含量约为14.93wt%。例如,强烈的化学风化导致碳酸盐-氟磷灰石的晶格优先向溶液释放Ca2+和CO32-离子物种,从而形成碳酸盐贫化层,其中稀土元素,特别是重稀土元素,被掺入蚀变磷灰石晶格内的优先Ca2+位置,从而形成辉橄榄岩。
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引用次数: 3
Petrology and Geochemistry of Mafic Intrusive Rocks from the Sapi-Shergol Ophiolitic Mélange, Indus Suture Zone, Western Ladakh: Constraints on Petrogenesis and Tectonic Setting 拉达克西部印度河缝合带Sapi-Shergol蛇绿岩混杂岩的岩石学和地球化学:对岩石成因和构造环境的制约
IF 1.8 4区 地球科学 Q2 GEOLOGY Pub Date : 2019-08-05 DOI: 10.1086/704254
I. Bhat, T. Ahmad, D. S. Rao
This article reports the existence of subduction-related tholeiitic, normal mid-ocean ridge basalt (N-MORB)-type mafic intrusives emplaced within the Sapi-Shergol ophiolitic mélange of the Indus Suture Zone, western Ladakh. The Shergol mafic intrusives show Fe enrichment with basalt to basaltic-andesite composition. Based on their mineralogy and textures, these mafic rocks can be identified as fine- to medium-grained gabbros that have undergone greenschist-grade metamorphism. These rocks have N-MORB-type geochemical characteristics, exhibiting nearly flat to depleted light rare earth element patterns ((La/Sm)N=0.66–1.05). Petrogenetic modeling suggests <20% partial melting of a depleted MORB-type mantle source, within the spinel peridotite stability. The presence of slightly negative anomalies of high field strength elements like Nb, Zr, and Ti in multielement patterns reflect the influence of subduction zone magmatism. The presence of low-Ti clinopyroxene (En38–50Fe11–25Wo31–43; enstatite-ferrosilite-wollastonite), Ca-rich plagioclase (An2–36; andesine), and pargasitic amphibole also reflects their subduction-related depleted-mantle origin. The MORB–island arc tholeiite signature displayed by the Shergol gabbros intrusive in Shergol peridotites reflect their generation in a mantle wedge associated with the Early Cretaceous intraoceanic subduction within the Neo-Tethys Ocean. They are similar to Spongtang ophiolite gabbros intrusive in the Spongtang ophiolite mantle peridotites from south Ladakh, ophiolitic mélange gabbros from southern Tibet, and Muslim Bagh ophiolite gabbros from Pakistan. Based on this study, we offer a geodynamic model suggesting that the Sapi-Shergol ophiolitic slice was intruded by mafic intrusive rocks that represent the relict of the intraoceanic substratum of the Cretaceous Dras arc complex.
本文报告了在拉达克西部印度河缝合带的Sapi-Shergol蛇绿混杂岩中侵位的俯冲相关拉斑玄武岩、正常大洋中脊玄武岩(N-MORB)型镁铁质侵入岩的存在。Shergol镁铁质侵入岩显示Fe富集,成分为玄武岩至玄武岩安山岩。根据它们的矿物学和结构,这些镁铁质岩石可以被确定为经过绿片岩级变质作用的细到中粒辉长岩。这些岩石具有N-MORB型地球化学特征,表现出几乎平坦到贫化的轻稀土元素模式((La/Sm)N=0.66–1.05)。岩石成因建模表明,在尖晶石橄榄岩稳定性范围内,贫化MORB型地幔源的部分熔融小于20%。Nb、Zr和Ti等高场强元素在多元素模式中的轻微负异常反映了俯冲带岩浆作用的影响。低钛斜辉石(En38–50Fe11–25Wo31–43;顽火辉石-铁硅岩-硅灰石)、富钙斜长石(An2–36;安山岩)和共气化角闪石的存在也反映了它们与俯冲相关的贫化地幔起源。Shergol橄榄岩中Shergol辉长岩侵入体显示的MORB–岛弧拉斑玄武岩特征反映了它们在与新特提斯洋内早白垩世洋内俯冲有关的地幔楔中的生成。它们类似于来自拉达克南部的Spongtang蛇绿岩-地幔橄榄岩中侵入的Spongtong蛇绿岩辉长岩、来自西藏南部的蛇绿混杂辉长岩和来自巴基斯坦的Muslim Bagh蛇绿辉长岩。基于这项研究,我们提供了一个地球动力学模型,表明Sapi-Shergol蛇绿岩片被镁铁质侵入岩侵入,镁铁质侵入岩石代表了白垩纪Dras弧杂岩的海洋内底层遗迹。
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引用次数: 12
期刊
Journal of Geology
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