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Geochemical and mineralogical characterization of mine tailings at the Rautuvaara mine site and aspects to environmental conditions and resource potential Rautuvara矿场尾矿的地球化学和矿物学特征以及环境条件和资源潜力方面
IF 0.7 4区 地球科学 Q2 GEOLOGY Pub Date : 2023-06-22 DOI: 10.17741/bgsf/95.1.005
Mitro Juutinen, Markku Seitsaari, P. Sarala
Mining industry generates a significant amount of waste including waste rock and tailings. The disposal of mine tailings has environmental impacts, such as the releasing of heavy metals to surface and underground waters. Therefore, adequate rehabilitation of mining waste storage facilities is essential. Abandoned tailings ponds may contain significant amounts of valuable minerals, including critical raw materials, and offer opportunities as secondary mineral resources. In this study geochemical and mineralogical characterization were made for the diverse mine tailings of the Rautuvaara tailings pond which was the final disposal site for different ore deposits. The samples were collected from two different locations in the tailings pond, preconcentrated and analysed with several methods including PSA, XRD, FE-SEM, EPMA, pXRF, WD-XRF and AAS. The geochemical results indicate substantially elevated Cu, As, Ni and Zn concentrations in the tailings. Mineralogical investigations revealed that the tailings contain valuable minerals such as gold, cobaltite, and W-bearing rutile. The last could be used as an indicator mineral in tailings classification and possibly also in future ore exploration. The study of secondary mineralogy revealed that the most weathered top layers of the tailings show secondary alteration rims on the surfaces of mineral particles, and the enrichment of As and Ni in the Fe- and Mn-oxide minerals.
采矿业产生大量废物,包括废石和尾矿。尾矿的处理会对环境产生影响,例如重金属会释放到地表水和地下水中。因此,充分修复采矿废物储存设施至关重要。废弃的尾矿库可能含有大量有价值的矿物,包括关键的原材料,并提供了作为次要矿产资源的机会。在本研究中,对Rautuvara尾矿库的不同尾矿进行了地球化学和矿物学表征,该尾矿库是不同矿床的最终处置场。从尾矿库的两个不同位置采集样品,进行预浓缩,并采用多种方法进行分析,包括PSA、XRD、FE-SEM、EPMA、pXRF、WD-XRF和AAS。地球化学结果表明尾矿中Cu、As、Ni和Zn的浓度显著升高。矿物学调查表明,尾矿中含有有价值的矿物,如金、钴矿和含钨金红石。最后一种可作为尾矿分类的指示矿物,也可能用于未来的矿石勘探。次生矿物学研究表明,尾矿风化程度最高的顶层在矿物颗粒表面表现出次生蚀变边缘,Fe和Mn氧化物矿物中As和Ni富集。
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引用次数: 0
Multiscale mapping and scaling analysis of the censored brittle structural framework within the crystalline bedrock of southern Finland 芬兰南部结晶基岩中截尾脆性结构框架的多尺度制图和尺度分析
IF 0.7 4区 地球科学 Q2 GEOLOGY Pub Date : 2023-06-22 DOI: 10.17741/bgsf/95.1.001
N. Nordbäck, Nikolas Ovaskainen, M. Markovaara‐Koivisto, P. Skyttä, A. Ojala, Jon Engström, C. Nixon
Fracture studies commonly lack data for the length range between 10 m to 1 km. For this reason, scaling laws are required to extrapolate fracture properties, for example in discrete fracture network models. This study focused on analysis and correlation of topology, orientation and length distribution of multiscale fracture datasets to assess their scalability. The used datasets comprise UAV-derived photogrammetric models from natural outcrops and lineaments mapped using airborne LiDAR, bathymetry and aerogeophysical data, in several contrasting scales and resolutions. This study highlights challenges in acquiring uncensored and coherent brittle structural datasets from source data characterized by a large span of resolutions between the remote sensing datasets and models of the fractured outcrop. In specific, collected data was found to be potentially biased and affected by uncertainties related to both the censoring by sedimentary cover and the scale of observation. Our results revealed differences between lineament and outcrop fracture orientations, as well as difficulties in assessing topological parameters from lineament datasets. The 1:200000 resolution was found best suited to the mapping of lineament length and resulted in a length distribution power law exponent of -1.92. For outcrop fractures that are less than 2 m long, the lognormal length distribution provided the only good fit to our data, while the longer outcrop fractures fitted relatively well with a power law exponent of -2.26.
裂缝研究通常缺乏10米至1公里长度范围内的数据。因此,需要使用尺度定律来推断裂缝性质,例如在离散裂缝网络模型中。本研究主要对多尺度裂缝数据集的拓扑、方位和长度分布进行分析和关联,以评估其可扩展性。使用的数据集包括利用机载激光雷达、测深和航空地球物理数据绘制的自然露头和轮廓的无人机衍生摄影测量模型,具有不同的比例尺和分辨率。本研究强调了从源数据中获取未删节的、连贯的脆性结构数据集的挑战,这些数据集的特征是遥感数据集和裂缝露头模型之间的分辨率跨度很大。具体而言,发现所收集的数据可能存在偏差,并受到与沉积覆盖和观测规模有关的不确定性的影响。我们的研究结果揭示了线状和露头裂缝方向之间的差异,以及从线状数据集中评估拓扑参数的困难。发现1:20万分辨率最适合于绘制线条长度,并导致长度分布幂律指数为-1.92。对于长度小于2 m的露头裂缝,对数正态长度分布与我们的数据只有很好的拟合,而较长的露头裂缝的幂律指数为-2.26。
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引用次数: 2
Clay mineral and Nd, Pb, and Sr isotope provenance of a MIS 4-3 sediment record from the Lomonosov Ridge, central Arctic Ocean 北冰洋中部罗蒙诺索夫海岭MIS 4-3沉积记录的黏土矿物及Nd、Pb、Sr同位素物源
IF 0.7 4区 地球科学 Q2 GEOLOGY Pub Date : 2023-06-22 DOI: 10.17741/bgsf/95.1.003
Raisa Alatarvas, Ninna Immonen, K. Strand
Modern techniques for detrital mineral provenance were applied to sediment core 96/12-1pc from the Lomonosov Ridge in the central Arctic Ocean. The techniques include quantitative clay mineralogy analysis combined with determination of Nd, Pb, and Sr isotopes from clay fraction. The clay mineral assemblage and the isotope signatures depict distinct changes during the Marine Isotope Stage (MIS) 4-3 transition corresponding to the Middle Weichselian deglaciation. This transition is characterised by a homogenous, 48 cm thick, dark grey, silty clay layer with a distinctive IRD concentration, forming a prominent marker bed for the central Arctic Ocean sediments. The elevated smectite and kaolinite contents in the transitional interval are possible weathering products of the Siberian basaltic rocks, such as the Putorana Plateau, feeding the shelves of the Kara Sea and the western Laptev Sea. The Nd and Sr isotope values are compatible with input from the basaltic rocks and fall within the isotopic range of sediments from these shelves. The abrupt changes in the Nd, Pb and Sr isotopic data from the distinct grey layer attributed to the MIS 4-3 transition likely mark a pronounced deglaciation event. An increase in coarse debris in the grey layer indicates a change in the sedimentation regime with a strong iceberg rafting component. This change may also be related to a sudden release of meltwater from a large ice-dammed lake in the northern Siberia.
将现代碎屑矿物来源技术应用于北冰洋中部罗蒙诺索夫山脊96/12-12pc沉积物岩心。这些技术包括定量粘土矿物学分析,以及从粘土组分中测定Nd、Pb和Sr同位素。粘土矿物组合和同位素特征描述了海洋同位素阶段(MIS)4-3转换期间的明显变化,对应于中魏克塞利期的消冰作用。这种过渡的特征是一层厚度为48厘米的均质深灰色粉质粘土层,具有独特的IRD浓度,形成了北冰洋中部沉积物的显著标志层。过渡层段中蒙脱石和高岭石含量的升高可能是西伯利亚玄武岩的风化产物,如Putorana高原,为卡拉海和拉普捷夫海西部的陆架提供食物。Nd和Sr同位素值与玄武岩的输入值一致,属于这些大陆架沉积物的同位素范围。MIS 4-3转换引起的不同灰色层Nd、Pb和Sr同位素数据的突然变化可能标志着明显的冰川消退事件。灰色层中粗碎屑的增加表明沉积机制发生了变化,具有强烈的冰山漂流成分。这种变化也可能与西伯利亚北部一个大型冰堰塞湖的融水突然释放有关。
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引用次数: 0
The morphostratigraphic imprint of the Baltic Ice Lake drainage event in southern Finland 芬兰南部波罗的海冰湖排水事件的形态地层印记
IF 0.7 4区 地球科学 Q2 GEOLOGY Pub Date : 2023-06-22 DOI: 10.17741/bgsf/95.1.004
J. Lunkka
Digital elevation models, based on laser scanning imageries (LiDAR-DEM) and aided by ground penetrating radar (GPR) data, were used to study glaciofluvial Gilbert-type ice-contact deltas in the Younger Dryas Salpausselkä end-moraine zone in southern Finland. The geomorphological data analysed were used to reconstruct the water-level drop of the late glacial Baltic Ice Lake to the early Holocene Yoldia Sea and tie these changes to a wider stratigraphic context. The results indicate that the sudden drainage event at around 11 650 cal. yrs BP left its imprint not only on the varved sediments but also on ice-contact glaciofluvial deltas in the Second Salpausselkä zone throughout southern Finland. This morphostratigraphic boundary can be placed at locations where the ice-contact deltas occur at two different levels; the higher-level deltas formed during the Baltic Ice Lake B III water-level stage and the lower-level deltas during the Yoldia Sea Y I water-level stage. This morphostratigraphically defined boundary in southern Finland marks the Pleistocene/Holocene chronostratigraphic boundary in southern Finland and shows the corresponding positions of the Scandinavian Ice Sheet’s Finnish Lake District Ice Lobe and the Baltic Sea Ice Lobe.
基于激光扫描图像(LiDAR-DEM)和探地雷达(GPR)数据的数字高程模型,研究了芬兰南部新仙女木Salpausselkä终碛带的冰川-河流吉尔伯特型冰接触三角洲。分析的地貌数据用于重建冰川晚期波罗的海冰湖到全新世早期约尔迪亚海的水位下降,并将这些变化与更广泛的地层背景联系起来。结果表明,11 650 calyrs BP左右的突发性降水事件不仅在芬兰南部第二Salpausselkä带的破碎沉积物上留下了印记,而且在冰接触冰川河流三角洲上也留下了印记。这种形态-地层界线可以放置在两个不同层次的冰接触三角洲发生的位置;高水位三角洲形成于波罗的海冰湖B III水位阶段,低水位三角洲形成于约迪亚海Y I水位阶段。芬兰南部的这个形态地层边界标志着芬兰南部更新世/全新世的年代地层边界,并显示了斯堪的纳维亚冰盖的芬兰湖区冰瓣和波罗的海冰瓣的相应位置。
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引用次数: 0
Editorial: The 3rd PalaeoArc 2022 Conference in Finland 编辑:第三届2022年芬兰古弧会议
IF 0.7 4区 地球科学 Q2 GEOLOGY Pub Date : 2023-06-22 DOI: 10.17741/bgsf/95.1.002
P. Sarala
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引用次数: 0
Implications on crustal structure from the South Finland Coastal (SOFIC) deep seismic sounding profile 南芬兰海岸(SOFIC)深层地震测深剖面对地壳结构的影响
IF 0.7 4区 地球科学 Q2 GEOLOGY Pub Date : 2022-12-27 DOI: 10.17741/bgsf/94.2.004
T. Tiira, T. Janik, T. Veikkolainen, K. Komminaho, T. Skrzynik, Sakari Väkevä, A. Heinonen
We present results from a deep seismic sounding (DSS) experiment carried out along the southern coast of Finland in summer 2015. Data used in the survey derived from industrial blasts recorded by temporary project stations and permanent network stations. The western 220 km part of the 450 km long Southern Finland Coastal (SOFIC) profile runs along the Uusimaa belt (UB) in the 1.7–1.9 Ga Southern Finland subprovince (SFS) of the Svecofennian domain, while the 170 km part in the east crosses the 1.62–1.65 Ga Wiborg rapakivi batholith (WRB). The farthest 60 km cross a geologically diverse area consisting of supracrustal rocks and granitoids of the Saimaa area (SA), an eastern extension of the SFS. Our results show that the Moho boundary depth varies significantly, from ca. 52–54 km below UB to 40–45 km below WRB. All three crustal layers (upper, middle, and lower) have their maximum depth in the contact zone between UB and the WRB. Below WRB, a lower crust with Vp ~6.7–6.9 km/s is observed. High velocity lower crust was observed below UB (Vp ~7.2 km/s) and possibly below SA (Vp ~7.35 km/s). The modelling was based on ray tracing, using the extrapolation of seismic wave arrival times with the help of travel times predicted from a one-dimensional velocity model. The resulting two-dimensional velocity model partly relies on data from the intersecting DSS profiles and supports previous observations of the lithospheric structure of southeastern Fennoscandia.
我们介绍了2015年夏天在芬兰南部海岸进行的深地震测深(DSS)实验的结果。调查中使用的数据来源于临时项目站和永久网络站记录的工业爆炸。450公里长的芬兰南部海岸(SOFIC)剖面的西部220公里部分沿Svecofennian域1.7–1.9 Ga芬兰南部子省(SFS)的Uusimaa带(UB)延伸,而东部170公里部分穿过1.62–1.65 Ga Wiborg rapakivi岩基(WRB)。最远的60 km穿过由Saimaa地区(SA)的表壳岩石和花岗岩组成的地质多样性区域,该地区是SFS的东部延伸。我们的结果表明,莫霍边界深度变化很大,从UB下方52–54公里到WRB下方40–45公里不等。所有三个地壳层(上部、中部和下部)在UB和WRB之间的接触带中具有最大深度。在WRB下方,观测到Vp~6.7–6.9 km/s的下地壳。在UB以下(Vp~7.2km/s)和SA以下(Vp ~7.35km/s)观测到高速下地壳。建模基于射线追踪,利用一维速度模型预测的传播时间对地震波到达时间进行外推。由此产生的二维速度模型部分依赖于相交DSS剖面的数据,并支持先前对芬诺斯坎迪亚东南部岩石圈结构的观测。
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引用次数: 1
Zircon dating of the basalt and felsic dyke in Haveri, SW Finland 芬兰西南部Haveri地区玄武岩和长英质岩脉的锆石定年
IF 0.7 4区 地球科学 Q2 GEOLOGY Pub Date : 2022-12-27 DOI: 10.17741/bgsf/94.2.001
Jaakko Kara, M. Väisänen, H. O'Brien
The E-MORB type Haveri basalt differs from the volcanic arc type rocks in the Tampere belt showing no subduction signature. It is considered to have formed in a marginal basin prior to the volcanic arc. We present here zircon U-Pb dating on two samples. The basalt and the felsic dyke yielded 207Pb/206Pb ages of 1902 ± 5 Ma and 1891 ± 2 Ma, respectively, interpreted as crystallisation ages. The basalt also contains older 1.98 Ga grains while the felsic dyke contains older 1.92 Ga, 1.94 Ga, 1.98 Ga and 2.0 Ga grains, which are inferred as inherited. The age dating of E-MORB type basalts can be used to identify the extensional episodes of the accretionary Svecofennian orogeny.
E-MORB型哈维里玄武岩与坦佩雷带的火山弧型岩石不同,没有显示俯冲特征。它被认为是在火山弧之前的边缘盆地中形成的。我们在这里给出了两个样品的锆石U-Pb测年。玄武岩和长英质岩脉的207Pb/206Bb年龄分别为1902±5Ma和1891±2Ma,被解释为结晶年龄。玄武岩还含有较老的1.98 Ga颗粒,而长英质岩脉含有较老1.92 Ga、1.94 Ga、1.9 8 Ga和2.0 Ga颗粒。E-MORB型玄武岩的年龄测定可用于识别增生Svecofennian造山运动的伸展事件。
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引用次数: 2
Hiekkapohja hydrothermal system – ore mineral, lithogeochemical and paleomagnetic evidence from the Paleoproterozoic Central Finland Granitoid Complex Hiekkapohja热液系统——古元古代芬兰中部花岗岩杂岩的矿石、岩石地球化学和古地磁证据
IF 0.7 4区 地球科学 Q2 GEOLOGY Pub Date : 2022-12-27 DOI: 10.17741/bgsf/94.2.003
E. Heilimo, Sini Halonen, S. Mertanen, Sami Niemi, Perttu Mikkola
The Paleoproterozoic Svecofennian Central Finland Granitoid Complex (CFGC) has been regarded as an area of low mineralisation potential. The Hiekkapohja area, 20km north-east of the town of Jyväskylä, host a concentration of variable metalliferous showings. Samples from mineralised boulders and outcrops display variable combinations of anomalously high concentrations of Cu, Mo, Zn, Pb, W, Pb, Ag, As, and Au. The area is composed mainly of peraluminous and ferroan granitoids. The dominant porphyritic Hiekkapohja granodiorite (~1.88 Ga) is cross-cut by the equigranular Soimavuori granite of similar age. The porphyritic Lehesvuori granite on the western side of the study area represents marginally older (~1.89 Ga) magmatism. The paragenetic sequence of the ore minerals shows that the Hiekkapohja area has been affected by at least two separate stages of hydrothermal activity. The first mineralisation stage was widespread, crystallising typically chalcopyrite, pyrrhotite, sphalerite, galena, arsenopyrite, magnetite and Ag-bearing minerals. After the first stage, a low temperature oxidising phase formed hematite and marcasite. The second mineralisation stage enclosed low temperature minerals, such as marcasite and native Ag and Ag-minerals, as inclusions inside chalcopyrite, pyrite, pyrrhotite, sphalerite, and arsenopyrite. The mineralised samples typically display signs of K-metasomatism and less commonly signs of propylitic alteration. During the second mineralisation stage the fluid flow was controlled by the dominant 120°–135° trending shear zones. Both the hydrothermal activity and the regional geology indicate that porphyry type ore forming processes have occurred in the Hiekkapohja area. Paleoproterozoic resetting of the remanent magnetisation is further evidence for the role of the hydrothermal system.
古元古代芬兰中部Svecofennian花岗质杂岩(CFGC)被认为是一个矿化潜力较低的区域。Hiekkapohja地区位于Jyväskylä镇东北20公里处,是各种金属展示的集中地。矿化巨砾和露头的样品显示出异常高浓度的Cu、Mo、Zn、Pb、W、Pb、Ag、As和Au的可变组合。该区域主要由过铝质和铁质花岗岩组成。主要的斑状Hiekkapohja花岗闪长岩(~1.88 Ga)被类似年龄的等粒Soimavuori花岗岩横切。研究区西侧的斑状Lehesvuori花岗岩代表稍老(~1.89 Ga)的岩浆作用。矿石的共生序列表明,Hiekkapohja地区至少受到两个独立的热液活动阶段的影响。第一个矿化阶段分布广泛,通常结晶黄铜矿、磁黄铁矿、闪锌矿、方铅矿、毒砂、磁铁矿和含银矿物。在第一阶段之后,低温氧化相形成赤铁矿和marcasite。第二个矿化阶段包含低温矿物,如marcasite和天然Ag和Ag矿物,作为黄铜矿、黄铁矿、磁黄铁矿、闪锌矿和毒砂内部的包裹体。矿化样品通常表现出钾交代作用的迹象,而不太常见的丙基蚀变迹象。在第二个矿化阶段,流体流动受到主导的120°-135°走向剪切带的控制。热液活动和区域地质都表明,Hiekkapohja地区发生了斑岩型成矿过程。古元古代残余磁化的重置是热液系统作用的进一步证据。
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引用次数: 1
Palaeoproterozoic structural evolution of polyphase migmatites in Olkiluoto, SW Finland 芬兰西南部Olkiluoto地区古元古代多相杂岩的构造演化
IF 0.7 4区 地球科学 Q2 GEOLOGY Pub Date : 2022-12-27 DOI: 10.17741/bgsf/94.2.002
Jon Engström, A. Kärki, S. Paulamäki, I. Mänttäri
In migmatitic environments the behaviour of the system is controlled by the generation and amount of the anatectic melt. Accordingly, migmatites typically show a genetic linkage between the tectonic deformation and melt migration. We investigated this relationship in Olkiluoto (SW Finland) and identified four phases of ductile deformation, which are distinguished by the multiple folding phases, ductile shear events and cross-cutting features associated with pegmatitic leucosomes and/or a specific type of diatexitic migmatite with feldspar megacrysts. U–Pb LA-MC-ICPMS data on zircon cores and rims from migmatites and cross-cutting pegmatites indicate two distinct metamorphic events associated with melt generation and migration at 1.87–1.84 Ga and 1.82–1.78 Ga. These two migmatitic events suggest that the orogenic evolution of the area was long-lasting and characterized by slow cooling. The structural data and the age constraints presented in this paper support the idea of similar tectonic evolution and metamorphic environment in SW Finland and central E Sweden.
在混染岩环境中,系统的行为受消熔熔体的产生和数量的控制。因此,混合岩在构造变形和熔体迁移之间具有典型的成因联系。我们研究了Olkiluoto(芬兰西南部)的这种关系,并确定了四个韧性变形阶段,这些阶段以多个褶皱阶段、韧性剪切事件和与伟晶质白色小体和/或具有长石巨晶的特定类型的闪长质混辉岩相关的交叉切割特征为特征。混合岩和横切辉晶岩的锆石芯和边缘的U-Pb LA-MC-ICPMS数据表明,在1.87 ~ 1.84 Ga和1.82 ~ 1.78 Ga,两个不同的变质事件与熔体的产生和迁移有关。这两次混染事件表明该地区的造山演化是长期的,具有缓慢降温的特征。本文的构造资料和年龄约束支持芬兰西南部和瑞典中部具有相似的构造演化和变质环境的观点。
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引用次数: 1
Leveraging active-source seismic data in mining tailings: Refraction and MASW analysis, elastic parameters, and hydrogeological conditions 利用尾矿中的有源地震数据:折射和MASW分析、弹性参数和水文地质条件
IF 0.7 4区 地球科学 Q2 GEOLOGY Pub Date : 2021-12-16 DOI: 10.17741/bgsf/93.2.002
R. Mollehuara-Canales, N. Afonin, E. Kozlovskaya, J. Lunkka, D. Pedretti
We applied active-source seismic method for the interpretation of elastic parameters in tailings facilities which is essential for evaluating stability and seismic response. The methodology uses different analysis methods on the same dataset, i.e., conventional seismic refraction (SR) to determine compressional-wave velocity (Vp) and multichannel analysis of surface wave (MASW) to estimate shear-wave velocity (Vs). Seismic velocities in conjunction with tailings physics approach revealed interpretable data in terms of elastic parameters and hydrogeological conditions. The results determined the empirical linear relationships between Vp and Vs that are particular to an unconsolidated media such as tailings and showed that variability of hydrogeological conditions influences the elastic seismic response (Vp and Vs) and the elastic parameters. The analysis of the elastic parameters identified the state condition of the tailings at the time of the survey. The Bulk modulus K that relates the change in hydrostatic stress to the volumetric strain was predominant between 1.0−2.0 GPa. The Young’s modulus E in the tailings media was in the low range of 0.15−0.23 GPa. Poisson’s ratio values in all sections were in the upper limit in the range of 0.37−0.49, meaning that the tailings media is highly susceptible to transverse deformation under axial compression.
我们将有源地震方法应用于尾矿设施弹性参数的解释,这对评估稳定性和地震反应至关重要。该方法在同一数据集上使用不同的分析方法,即传统的地震折射(SR)来确定纵波速度(Vp),多通道表面波分析(MASW)来估计剪切波速(Vs)。地震速度与尾矿物理方法相结合,揭示了弹性参数和水文地质条件方面的可解释数据。结果确定了Vp和Vs之间的经验线性关系,这是尾矿等松散介质特有的,并表明水文地质条件的可变性影响弹性地震响应(Vp和Vs)和弹性参数。对弹性参数的分析确定了调查时尾矿的状态。体积模量K(将静水应力的变化与体积应变联系起来)在1.0−2.0 GPa之间占主导地位。尾矿介质中的杨氏模量E在0.15−0.23 GPa的低范围内。所有截面的泊松比值都在0.37−0.49的上限范围内,这意味着尾矿介质在轴向压缩下极易发生横向变形。
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引用次数: 2
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Bulletin of the Geological Society of Finland
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