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Porphyrin Langmuir-Blodgett Thin Film for Organic Vapor Detection 用于有机蒸气检测的卟啉-Langmuir-Blodgett薄膜
Pub Date : 2019-01-28 DOI: 10.17265/2159-5348/2019.01.002
R. Çapan
The detection of volatile organic compounds (VOC’s) is a very important task due to stringent environmental standards and regulations on VOC’s in many countries. They are highly toxic and may cause metabolic diseases, genetic disorders, acute, chronic or long-term effects and cancer. In order to control the air quality and human health respect to standards and regulations gas sensors are widely used to measure the level of VOCs. The performance of the gas sensing devices mostly depends on the performance of the sensing materials which depends on their chemical structures. Organic materials are widely studied in the field of VOC’s sensor application due to their low cost, physical and chemical properties. Porphyrin molecule was deposited as an Langmuir-Blodgett thin film onto gold substrates for the study of sensor properties using benzene, toluene, ethyl benzene and xylene. Surface plasmon resonance technique was employed for the characterization of these LB films. A high quality and uniform Langmuir monolayer from the water surface can be transferred onto a gold coated substrate with a transfer ratio of over 90%. For the sensing application towards benzene vapor, this LB film yields a fast and almost fully reversible response to benzene in few seconds.
由于各国对挥发性有机化合物的环境标准和法规都比较严格,因此挥发性有机化合物的检测是一项非常重要的工作。它们具有剧毒,可能导致代谢疾病、遗传疾病、急性、慢性或长期影响以及癌症。为了从标准和法规的角度控制空气质量和人类健康,气体传感器被广泛用于测量挥发性有机化合物的水平。气体传感装置的性能主要取决于传感材料的性能,而传感材料的性能又取决于其化学结构。有机材料因其成本低、物理化学性质好,在VOC传感器应用领域得到了广泛的研究。将卟啉分子作为Langmuir-Blodgett薄膜沉积在金衬底上,研究了苯、甲苯、乙苯和二甲苯的传感器性能。采用表面等离子体共振技术对LB薄膜进行表征。高质量和均匀的朗缪尔单层从水面转移到金涂层基材上,转移率超过90%。对于苯蒸汽的传感应用,这种LB膜在几秒钟内对苯产生快速且几乎完全可逆的响应。
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引用次数: 2
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物理科学与应用:英文版
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