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2018 IEEE International Magnetic Conference (INTERMAG)最新文献

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The effect of surface spin disorder on magnetic properties of Fe/FexOy core-shell nanoparticles 表面自旋无序对Fe/ feexoy核壳纳米粒子磁性能的影响
Pub Date : 2018-04-23 DOI: 10.1109/INTMAG.2018.8508833
M. Lostun, D. Herea, M. Grigoraș, G. Ababei, I. Ghemes, N. Lupu
Fe-oxide nanoparticles are of considerable interest nowadays because of their unique characteristics, such as superparamagnetism, high saturation fields, and extra anisotropy contributions, which arise from the effects of finite size and large surface area. Usually they are obtained by chemical methods, but more recently some groups reported on their successful preparation by wet high-energy ball-milling. It is also well known that as the size of the nanoparticles decreases, surface effects would become more significant due to the increasing surface relative to their volume. We report here our recent results on the effect of ligands on the induced surface anisotropies and magnetic properties of Fe/Fe2O3 and Fe/Fe3O4 core-shell nanoparticles functionalized with 3-aminopropyltriethoxysilane (APTS) for biomedical applications (image contrast agents in magnetic resonance imaging (MRI) and magnetic carriers for drug delivery). Core-shell nanoparticles have been prepared by high-energy ball milling. In the presence of air or Ar, the Fe core was progressively covered with a Fe2O3 shell, and the obtained Fe/ Fe2O3 nanoparticles have diameters of 200–300 nm after 68 h of milling. Fe/ Fe3O4 nanoparticles of 20–60 nm were obtained by wet milling of Fe microparticles for 42 h. For milling times larger than 42 h the whole amount of Fe is transformed into Fe3O4, and the resulting magnetite nanoparticles have diameters ranging from 15 to 50 nm (Fig. 1). The magnetic properties of Fe/ FexOy core-shell nanoparticles can be tailored from ferromagnetic Fe/Fe2O3 to weak ferromagnetic Fe/Fe3O4 and superparamagnetic Fe3O4 (Fig. 2). By choosing the appropriate milling conditions and starting materials is possible to tune the magnetic properties and make the Fe/FeOx core-shell NPs suitable for different biomedical applications. The main advantage of such coreshell nanoparticles in biomedical applications, compared with simple Fe-oxides nanoparticles, resides in their easier use and manipulation for specific applications. To understand the surface spin disorder and its influence on the magnetic properties of Fe/Fe-oxide core-shell nanoparticles, their surface was systematically modified with APTS, by increasing progressively the concentration of the ligand. APTS was chosen as ligand because the bonding with the magnetic NPs is made through Si-O, NH2 remaining free for bonding with different types of biomolecules. Low temperature magnetization measurements and ZFC/FC curves indicate a strong influence of the ligand on the magnetic properties. The change of the magnetic properties of nanoparticles also correlates with the specific coordinating functional group bound on the nanoparticles surface. The correlation suggests the decrease in spin-orbital coupling and surface anisotropy of magnetic nanoparticles due to the surface coordination. Because of the high saturation magnetization, these Fe/FeOx core-shell NPs have a higher Specific Absorption Rate (SAR), making them suit
氧化铁纳米颗粒由于其独特的特性,如超顺磁性、高饱和场和额外的各向异性贡献,而这些特性是由有限尺寸和大表面积的影响引起的。通常它们是通过化学方法获得的,但最近一些小组报道了用湿高能球磨法成功制备它们。众所周知,随着纳米颗粒尺寸的减小,表面效应将变得更加显著,因为相对于它们的体积,表面增加了。本文报道了配体对生物医学应用(磁共振成像(MRI)中的图像造影剂和药物递送的磁性载体)中3-氨基丙基三乙基氧基硅烷(APTS)功能化的Fe/Fe2O3和Fe/Fe3O4核壳纳米颗粒诱导表面各向异性和磁性能的影响。采用高能球磨法制备了核壳纳米粒子。在空气或氩气存在的情况下,铁芯逐渐被Fe2O3外壳覆盖,经过68 h的铣削,得到的Fe/ Fe2O3纳米颗粒直径在200 ~ 300 nm之间。湿磨42 h得到了20 ~ 60 nm的Fe/ Fe3O4纳米颗粒,当磨矿次数大于42 h时,Fe全部转化为Fe3O4;得到的磁铁矿纳米颗粒直径在15 ~ 50 nm之间(图1)。Fe/ feexoy核壳纳米颗粒的磁性可以从铁磁性的Fe/Fe2O3定制为弱铁磁性的Fe/Fe3O4和超顺磁性的Fe3O4(图2)。通过选择合适的研磨条件和起始材料,可以调整磁性,使Fe/FeOx核壳纳米颗粒适合不同的生物医学应用。与简单的氧化铁纳米颗粒相比,这种核壳纳米颗粒在生物医学应用中的主要优势在于它们更容易使用和操作特定应用。为了了解Fe/Fe-氧化物核壳纳米粒子的表面自旋无序性及其对磁性能的影响,利用APTS系统地对其表面进行了修饰,并逐渐增加配体的浓度。之所以选择APTS作为配体,是因为与磁性NPs的结合是通过Si-O、NH2自由地与不同类型的生物分子结合而实现的。低温磁化测量和ZFC/FC曲线表明配体对磁性能有很强的影响。纳米粒子磁性能的变化还与纳米粒子表面结合的特定配位官能团有关。这种相关性表明,由于表面配位,磁性纳米粒子的自旋轨道耦合和表面各向异性降低。由于高饱和磁化强度,这些铁/FeOx核壳NPs具有更高的比吸收率(SAR),使其适合热疗应用。由于铁氧化物的外壳,它们也可以通过磁共振成像可视化。这项工作得到了3MAP NUCLEU计划(2018)的财政支持。
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引用次数: 0
Improvement of efficiency and vibration noise characteristics depending on excitation waveform of a brushless DC motor 基于励磁波形的无刷直流电动机效率和振动噪声特性的改进
Pub Date : 2018-04-23 DOI: 10.1109/INTMAG.2018.8508570
Shunsuke Noguchi, H. Dohmeki
The 10poles-l2slots brushless DC motor is superior as AC servo motor by sine-wave excitation, but its characteristics like efficiency get worse by using as BLDC motor by square-wave excitation. However, 150degree excitation which adjusted excitation angle and excitation phase can increase 3% of efficiency from general120degree excitation, and it can make phase current similar to sine wave. And then, square wave excitation which used hall sensors and counters is simple way of BLDC drives, and it needs less supply voltage than that to drive BLDC by sine-wave excitation. Therefore, we shows that 150degree square-wave excitation is suitable in high efficiency and simple BLDC drive.
采用正弦波励磁的10极- 12槽无刷直流电动机优于交流伺服电机,而采用方波励磁的无刷直流电动机效率较差。而150度励磁可以调节励磁角度和励磁相位,比一般的120度励磁效率提高3%,并且可以使相电流接近正弦波。其次,采用霍尔传感器和计数器的方波激励是一种简单的无刷直流驱动方式,与正弦波激励相比,它所需的供电电压更小。因此,我们证明了150度方波激励适用于高效、简单的无刷直流驱动。
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引用次数: 2
Analytical and FEM Calculation of Electrical Parameters of Carbon Steel Pipe in DEH Systems DEH系统中碳钢管电气参数的分析与有限元计算
Pub Date : 2018-04-23 DOI: 10.1109/INTMAG.2018.8508568
Anyuan Chen, A. Nysveen, M. Høyer-Hansen, J. Lervik
In Direct Electrical Heating (DEH) systems, the pipeline of subsea oil productions conducts a large AC current to generate heat. To further improve the effectiveness of the DEH, higher operating frequency is preferable. The electrical parameters of the carbon steel pipe are critical for a DEH system design. At higher frequency, the hysteresis power loss in the solid pipe becomes considerable and has to be taken into account. This paper presents analytical calculations of electrical parameters of the pipe based on the measured properties of carbon steel in laboratory. The hysteresis power loss has been considered as from an equivalent resistance. The total resistance and inductance of the pipe are analytically calculated and verified by FEM simulations.
在直接电加热(DEH)系统中,海底采油管道通过大的交流电流来产生热量。为了进一步提高DEH的效率,更高的工作频率是可取的。碳钢管的电气参数对DEH系统的设计至关重要。在较高的频率下,固体管道中的迟滞功率损耗变得相当大,必须加以考虑。本文根据实验室测量的碳钢性能,对钢管的电气参数进行了解析计算。迟滞功率损耗从等效电阻考虑。对管道的总电阻和总电感进行了解析计算,并通过有限元仿真进行了验证。
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引用次数: 3
The effect of easy axis deviations on the magnetic property of Co nanowire. 易轴向偏差对钴纳米线磁性能的影响。
Pub Date : 2018-04-01 DOI: 10.1109/INTMAG.2018.8508621
Y. Peng, M. Yue, H. Li, Y. Li, C. Li, H. Xu, Q. Wu
The 3d transition metals such as iron, cobalt, and their alloys bear high saturation magnetization $(M_{s})$ and high Curie temperatures $(T_{C})$, which are necessary for the giant energy product and good thermal stability, respectively. For the nanowire of 3d transition metals, such as Co nanowires, the effective anisotropy field can be as much as 16.5 kOe by combining the shape anisotropy and magnetocrystalline anisotropy. However, such high coercivity has never been achieved, because there are much defects and the easy axis deviation from the length direction for the nanowires. Therefore, in this study, we investigate the influence of the defects and deviation of easy axis on the coercivity and magnetization reversal process via 3D micromagnetic simulations.
三维过渡金属如铁、钴及其合金具有高饱和磁化强度$(M_{s})$和高居里温度$(T_{C})$,这是获得巨大能量积和良好热稳定性所必需的。对于三维过渡金属纳米线,如钴纳米线,结合形状各向异性和磁晶各向异性,有效各向异性场可达16.5 kOe。然而,由于纳米线存在许多缺陷,并且容易偏离长度方向,因此从未实现过如此高的矫顽力。因此,在本研究中,我们通过三维微磁模拟研究了易轴缺陷和偏差对矫顽力和磁化反转过程的影响。
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引用次数: 0
A Magneto-elastic Correlator Using Acoustic Wave Pumping of Spin Waves 利用声波泵送自旋波的磁弹性相关器
Pub Date : 2018-04-01 DOI: 10.1109/INTMAG.2018.8508380
I. Lisenkov, M. Hansen, J. Davies, P. Dhagat, A. Jander
The group velocity of both acoustic waves and spin waves in crystals are orders of magnitude less than those of electromagnetic waves. As a result, complex analog signal processing tasks that span multiple periods of a signal can be implemented more compactly with acoustic or spin waves than with electromagnetic waves. Acoustic wave devices have thus become common in RF communications circuits, realizing complex linear filter functions in a compact and efficient manner. Although spin-wave-based devices could, in principle, perform many of the same functions as acoustic wave devices, the much higher losses and non-linear effects have limited the practical application of spin wave signal processors. However, we propose that for nonlinear signal processing functions, such as signal correlation, the combination of acoustic and spin wave signals in a single device may prove advantageous. We have developed a magneto-elastic device that exploits the nonlinear interactions between acoustic waves and spin waves to implement a microwave signal correlator. The device, illustrated schematically in Fig. 1a, uses an acoustic wave signal generated by a piezoelectric transducer to parametrically pump [1–3] a signal spin wave launched into a thin-film yttrium-iron-garnet (YIG) waveguide by an antenna. The resulting idler spin wave is picked up by an output antenna. The frequencies of the three waves are related ${{text{f}}_{p}}={{text{f}}_{s}}+{{text{f}}_{i}}$. In our experiments, the acoustic pump signal is at a frequency of $mathrm {f}_{p}=2.4$ GHz while the signal and idler spin wave frequencies, fs and fi, are a few MHz above and below 1.2 GHz. It can be shown that if the microwave input signal and pump signal are modulated with signals S(t) and P(t) respectively, the generated idler signal is modulated by the combination of the two signals as $mathrm {I}( mathrm {t}) = int _{0 {o}}^{t}mathrm {S} ( 2 tau - mathrm {t}) mathrm {P}( tau ) mathrm {d}tau $, thus implementing a signal correlator. The correlation time window, to, depends on the length of time that the spin wave transits the pumping region. The correlation signal processing is used to increase the signal-to-noise ratio of weak signals in a presence of an interference. In our proposed scheme the weak signal is used to generate spin-waves via the input spin-wave transducer, while the “reference” code is applied to the pumping acoustic transducer. We created a theoretical formalism, which allows us to predict the characteristics of the output idler signal taking into account the features of the magneto-elastic parametric interactions, magnetic damping and the non-linearities in spinwaves associated with the pumping process. As an example we calculate the distribution of the spin-wave amplitude under the transducer for two orthogonal Walsh codes, while the pumping signal is modulated with one these codes. Fig. 2a demonstrate the distribution of two “signal” spin-waves, while Fig.2b shows the correspondin
晶体中声波和自旋波的群速度都比电磁波的群速度小几个数量级。因此,跨越多个信号周期的复杂模拟信号处理任务可以用声波或自旋波比电磁波更紧凑地实现。声波器件因此在射频通信电路中变得普遍,以紧凑和高效的方式实现复杂的线性滤波功能。虽然基于自旋波的器件原则上可以执行许多与声波器件相同的功能,但更高的损耗和非线性效应限制了自旋波信号处理器的实际应用。然而,我们提出,对于非线性信号处理功能,如信号相关,声学和自旋波信号在单个设备中的组合可能是有利的。我们开发了一种磁弹性装置,利用声波和自旋波之间的非线性相互作用来实现微波信号相关器。如图1a所示,该装置使用压电换能器产生的声波信号,通过天线将信号自旋波参数化泵送[1-3],并发射到薄膜钇铁石榴石(YIG)波导中。产生的闲散自旋波由输出天线接收。三个波的频率是相关的${{text{f}}_{p}}={{text{f}}_{s}}+{{text{f}}_{i}}$。在我们的实验中,声泵信号的频率为$mathrm {f}_{p}=2.4$ GHz,而信号和空闲自旋波频率fs和fi分别在1.2 GHz上下几个MHz。可以看出,如果分别用S(t)和P(t)信号调制微波输入信号和泵浦信号,则产生的空闲信号由这两个信号组合调制为$mathrm {I}( mathrm {t}) = int _{0 {o}}^{t}mathrm {S} ( 2 tau - mathrm {t}) mathrm {P}( tau ) mathrm {d}tau $,从而实现了信号相关器。相关时间窗为,取决于自旋波通过抽运区域的时间长度。相关信号处理用于在存在干扰的情况下提高弱信号的信噪比。在我们提出的方案中,弱信号通过输入自旋波换能器产生自旋波,而“参考”代码应用于抽运声换能器。我们创建了一个理论形式,它允许我们考虑到磁弹性参数相互作用、磁阻尼和与抽运过程相关的自旋波的非线性特征来预测输出空闲信号的特性。作为一个例子,我们计算了两个正交的沃尔什码在换能器下的自旋波幅值的分布,同时用其中一个沃尔什码调制抽运信号。图2a显示了两个“信号”自旋波的分布,图2b显示了在泵浦信号影响下对应的两个“闲散”自旋波。仿真结果表明:1)当信号自旋波码与参考信号匹配时,输出空闲功率增强,反之则被抑制;2)相对高的抽运幅值所引入的非线性不会破坏相关过程;3)自旋波阻尼不会破坏相关处理。我们已经制作了这样一个装置,其在连续泵下运行的示例结果如图1b所示。在信号通道上持续时间为$mathrm {t}_{s} quad =30$ ns的输入微波脉冲产生一个空闲脉冲,该脉冲在输出端出现一些延迟后出现。由于泵是连续的,输出跨越时间$mathrm {t}_{s} + mathrm {t}_{o}$,其中约为200ns,脉冲穿越2毫米长的设备所需的时间。我们目前正在实现调制泵信号的能力,这样就可以演示如图2所示的两个信号的卷积。这样的信号相关器可以在码分多址(CDMA)通信接收器(如蜂窝电话)的输入处具有很大的优势,以便在模拟域中解除输入代码序列的相关性。将此功能转移到模拟域可以显著节省功率,并可以提高接收器对干扰信号的恢复能力。
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引用次数: 1
Comparative Studies of Modular PMSMs with Symmetrical or Asymmetrical Six-Phase Windings. 对称与非对称六相绕组模块化永磁同步电机的比较研究。
Pub Date : 2018-04-01 DOI: 10.1109/INTMAG.2018.8508819
L. Cheng, Y. Sui, P. Zheng, Z. Yin, R. Ma
Nowadays, multiphase permanent-magnet synchronous machines (PMSMs) equipped with fractional-slot concentrated windings (FSCWs) are increasingly attractive for the industrial applications due to their high torque density, high efficiency and high fault-tolerant capacity [1], [2]. Meanwhile, owing to their characteristics of easy manufacturing, convenient transportation and high fault-tolerant capacity, the modular permanent magnet synchronous machines (PMSMs) are also favored by various industrial applications, such as electric vehicle and wind turbine applications [3]. Fortunately, the FSCWs, especially the single-layer FSCWs, are inherently easy to modular manufacture. However, due to the manufacturing tolerance, the additional mechanical gaps between the modules are inevitable which will affect the magnetic field distribution and hence the electromagnetic performances. The influences of the additional mechanical gaps on electromagnetic performances of three-phase modular PMSM have been investigated [4]. Nevertheless, the influences of the additional gaps between the modules in a six-phase modular machine have not been covered. Moreover, the influences of the mechanical gaps on the performances under post-fault operating conditions in a six-phase PMSM have not been investigated in current literature. Therefore, in this paper, the influences of the additional mechanical gaps on the performance under healthy, faulty and post-fault operating conditions of modular PMSM with symmetrical or asymmetrical six-phase windings are investigated. In this paper, firstly, by analyzing the slot star diagram of a conventional 12-slot/14(10) -pole three-phase PMSM with double-layer FSCW, three different six-phase winding layouts can be obtained by dividing the conventional 12-slot/14(10) -pole three-phase winding into two sets of independent three-phase windings as shown in Fig. 1. It can be found that the winding of scheme I is asymmetrical six-phase winding with an electrical angle of 30° between the two sets of three-phase windings and the other two schemes are symmetrical six-phase winding with an electrical angle of 60° between the two sets of three-phase windings. Scheme III will be abandoned because the electromagnetic performances of scheme III are all the same with II while its magnetic isolation capacity is much lower than scheme II. To enhance their magnetic isolation capacity further, the 12 double-layer slots are divided into 24 single-layer slots so that three 24-slot/14(10)-pole six-phase PMSM with unequal teeth can be obtained. And, the modular stators are used to enhance their practicability and fault-tolerant capacity, as shown in Fig. 2. It can be seen that for scheme I, there is only one modular method—one module with one coil. On the other hand, there can be two different modular methods—one modular with one coil and one modular with one-phase (one phase possesses two adjacent coils). The different modular methods will introduce different add
目前,采用分数槽集中绕组的多相永磁同步电机(pmms)因其高转矩密度、高效率和高容错能力而越来越受到工业应用的青睐[1],[2]。同时,模块化永磁同步电机因其制造简单、运输方便、容错能力强等特点,也受到了各种工业应用的青睐,如电动汽车、风力发电等应用[3]。幸运的是,fscw,特别是单层fscw,本质上很容易模块化制造。然而,由于制造公差,模块之间的额外机械间隙是不可避免的,这将影响磁场分布,从而影响电磁性能。研究了附加机械间隙对三相模块化永磁同步电机电磁性能的影响[4]。然而,六相组合式机器中各模块之间额外间隙的影响尚未包括在内。此外,目前文献尚未研究六相永磁同步电机故障后运行状态下机械间隙对其性能的影响。因此,本文研究了对称或不对称六相绕组的模块化PMSM在正常、故障和故障后运行状态下附加机械间隙对其性能的影响。本文首先对传统12槽/14(10)极带双层FSCW三相永磁同步电机的槽星图进行分析,将传统12槽/14(10)极三相绕组划分为两组独立的三相绕组,得到三种不同的六相绕组布局,如图1所示。可以发现,方案1的绕组为不对称的六相绕组,两组三相绕组之间的电角为30°,另外两种方案为对称的六相绕组,两组三相绕组之间的电角为60°。方案III将被放弃,因为方案III的电磁性能与方案II相同,但其隔磁能力远低于方案II。为了进一步提高其磁隔离能力,将12个双层槽划分为24个单层槽,得到3个24槽/14(10)极不等齿的六相永磁同步电机。采用模块化定子,增强了定子的实用性和容错能力,如图2所示。可以看出,对于方案1,只有一种模块化方法,即一个模块带一个线圈。另一方面,可以有两种不同的模块化方法,一种是单线圈模块化,一种是单相模块化(一相有两个相邻的线圈)。不同的模块化方法将引入不同的额外机械间隙,这是由于制造限制和公差而无法避免的,如图2所示。研究了这些机械间隙对绕组系数、平均转矩、转矩脉动和定子磁动势分布等电磁性能的影响。此外,还研究了这些间隙在单相开路、两相开路和单相短路故障等故障工况下以及故障后运行工况下的影响。
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引用次数: 2
Gel-casting Hexagonal Ferrites for High Density and Low Loss Microwave Devices. 高密度低损耗微波器件用凝胶铸造六方铁氧体。
Pub Date : 2018-04-01 DOI: 10.1109/INTMAG.2018.8508400
J. Adams, A. Sokolov, V. Harris
Abstract
摘要
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引用次数: 0
Finding the Separation Between First-and Second-Order Phase transitions in La(Fe,Ni,Si)13 magnetocaloric materials. La(Fe,Ni,Si)13磁热材料中一、二级相变的分离。
Pub Date : 2018-04-01 DOI: 10.1109/INTMAG.2018.8508032
L. M. Moreno-Ramírez, J. Law, C. Romero-Muñiz, V. Franco, A. Conde, F. Maccari, I. Radulov, K. Skokov, O. Gutfleisch
Magnetocaloric (MC) materials have the potential to renew the basis of refrigeration technologies for the next years. To date (and since first commercial devices in 1927), refrigerators operate by expansion/compression of gases in a closed circuit where the condensation/evaporation produces wasted heating/the cooling of a load. The main disadvantages of such devices are their usage of non-environmental-friendly gases (e.g. ozone depletion) and low energy efficiency. Conversely, magnetic refrigerator using magnetocaloric materials addresses these issues by utilizing solids of non-contaminating refrigerants and their prototypes show a larger energetic efficiency. In this case, the MC material replaces those gases and the expansion/compression is replaced by the application/removal of a magnetic field. The largest reversible temperature variation of a material submitted to a variable magnetic field in adiabatic conditions (ΔTS) occurs near the temperature of a magnetic or magnetostructural phase transition. These phase transitions can be classified as first order (FOPT) or second order ones (SOPT) according to the Ehrenfest classification. Therefore, the MC characterization is not only useful from a technological point of view but can also be used to extract information about the phase transition. It has been demonstrated that assuming a power law expression for the field dependence of the magnetic entropy change (ΔST), taking the form $Delta S_{T}(T,H)=a(T)Delta H^{{{n {(}} {T {,}}} {H {)}}}$. The values of the exponent n at the transition temperature (Ttrans) are related with the critical exponents of a SOPT as $n= 1 +(1 -1/ beta )/ delta $, where the exponents β and δ give the temperature dependence of M at zero field and the field dependence of M at Ttrans, respectively. For materials with long range interactions the values of $n(T_{trans})$ in SOPT are typically close to those using the critical exponents for mean field model (0.67). On the other hand, for short range interactions, the typical values are close to Heisenberg or 3D-Ising models (0.63 and 0.57, respectively). For the $n(T_{trans})$ of SOPT there exists a lower limit that corresponds to the case where the material transits from a SOPT to a FOPT character, this point is called the critical point of the second order phase transition. The value at that point is 0.4 according to the critical exponents obtained from theoretical considerations. For FOPT, even if there is no critical region, the field dependence of ΔST in the high field range leads to n values lower than 0.4. Therefore, a clear criterion exits to identify the change from SOPT to FOPT according to the values of n(Ttrans). One of the most promising families of magnetocaloric materials are LaFeSi alloys. These alloys show a magnetic FOPT that implies a large magnetocaloric response. Hydrogenation of the samples shifts the transition temperature from ≈ 200 K to temperatures close to room temperature, to facilitate their appli
磁热材料有潜力在未来几年更新制冷技术的基础。迄今为止(自1927年第一台商用设备以来),冰箱通过在封闭回路中膨胀/压缩气体来运行,其中冷凝/蒸发产生浪费的加热/冷却负载。这种装置的主要缺点是使用非环境友好型气体(例如臭氧耗损)和能源效率低。相反,使用磁热材料的磁制冷机通过使用无污染制冷剂的固体来解决这些问题,其原型机显示出更大的能量效率。在这种情况下,MC材料取代了这些气体,膨胀/压缩被磁场的施加/去除所取代。在绝热条件下,材料在变磁场作用下的最大可逆温度变化(ΔTS)发生在磁性或磁结构相变温度附近。根据Ehrenfest分类,这些相变可分为一阶相变(FOPT)和二阶相变(SOPT)。因此,MC表征不仅从技术的角度来看是有用的,而且可以用来提取有关相变的信息。假设磁熵变化的场依赖性为幂律表达式(ΔST),其形式为$Delta S_{T}(T,H)=a(T)Delta H^{{{n {(}} {T {,}}} {H {)}}}$。在转变温度(Ttrans)处的指数n值与SOPT的临界指数$n= 1 +(1 -1/ beta )/ delta $有关,其中指数β和δ分别表示M在零场和M在Ttrans处的场依赖关系。对于具有长距离相互作用的材料,在SOPT中的$n(T_{trans})$值通常接近使用平均场模型的临界指数(0.67)。另一方面,对于短程相互作用,典型值接近Heisenberg或3D-Ising模型(分别为0.63和0.57)。对于SOPT的$n(T_{trans})$存在一个下限,该下限对应于材料从SOPT特征过渡到FOPT特征的情况,这个点称为二级相变的临界点。根据从理论考虑得到的临界指数,该点的值为0.4。对于FOPT,即使不存在临界区域,ΔST在高场范围内的场依赖性也会导致n值低于0.4。因此,根据n(Ttrans)的值,存在一个明确的标准来识别从SOPT到FOPT的变化。其中最有前途的磁热材料家族是LaFeSi合金。这些合金显示出磁性FOPT,这意味着大的磁热响应。样品的氢化将转变温度从≈200 K转移到接近室温的温度,以促进其在器件中的应用。然而,在商业化之前还需要解决一些问题:需要提高其循环稳定性和最小化热滞后。不同的掺杂剂可用于调整Ttrans、MC响应和滞后等特性。本文研究了掺杂Ni (LaFe11.6-x Nix Si1, x = 0、0.1、0.2、0.3和0.4)的LaFeSi合金的磁热性能。显微组织表征(BSE和XRD)表明,合金中LaFe13相的含量较高。EDX分析证实了所需的标称成分。通过间接测量ΔST(磁化测量)和直接测量ΔTS(达姆施塔特工业大学内置的专用设备)来进行磁热表征。图1显示了加入Ni后ΔTS的温度依赖性是如何改变的。从ΔST的场依赖指数值中区分相变顺序的准则已经被应用(图2)。这个过程使我们能够估计过渡处于二阶相变临界点的成分(x = 0.21的样本),也如图2所示。为了解释Ni原子在LaFe13相中的作用,进行了DFT计算,结果与实验数据吻合良好。这项工作得到了MINECO和EU FEDER(项目MAT2013-45165-P), AEI/ federal - ue(项目MAT-2016-77265-R), Andalucía地区政府PAI, Deutscher akademitcher ausstauschdienst DAAD (Award A/13/09434)的支持。l.m. Moreno-Ramírez承认来自西班牙MECD的FPU奖学金。o.g., i.r.和K.S.想要感谢DFG在优先项目“铁质冷却”(SPP1599)框架下的资助。
{"title":"Finding the Separation Between First-and Second-Order Phase transitions in La(Fe,Ni,Si)13 magnetocaloric materials.","authors":"L. M. Moreno-Ramírez, J. Law, C. Romero-Muñiz, V. Franco, A. Conde, F. Maccari, I. Radulov, K. Skokov, O. Gutfleisch","doi":"10.1109/INTMAG.2018.8508032","DOIUrl":"https://doi.org/10.1109/INTMAG.2018.8508032","url":null,"abstract":"Magnetocaloric (MC) materials have the potential to renew the basis of refrigeration technologies for the next years. To date (and since first commercial devices in 1927), refrigerators operate by expansion/compression of gases in a closed circuit where the condensation/evaporation produces wasted heating/the cooling of a load. The main disadvantages of such devices are their usage of non-environmental-friendly gases (e.g. ozone depletion) and low energy efficiency. Conversely, magnetic refrigerator using magnetocaloric materials addresses these issues by utilizing solids of non-contaminating refrigerants and their prototypes show a larger energetic efficiency. In this case, the MC material replaces those gases and the expansion/compression is replaced by the application/removal of a magnetic field. The largest reversible temperature variation of a material submitted to a variable magnetic field in adiabatic conditions (ΔTS) occurs near the temperature of a magnetic or magnetostructural phase transition. These phase transitions can be classified as first order (FOPT) or second order ones (SOPT) according to the Ehrenfest classification. Therefore, the MC characterization is not only useful from a technological point of view but can also be used to extract information about the phase transition. It has been demonstrated that assuming a power law expression for the field dependence of the magnetic entropy change (ΔST), taking the form $Delta S_{T}(T,H)=a(T)Delta H^{{{n {(}} {T {,}}} {H {)}}}$. The values of the exponent n at the transition temperature (Ttrans) are related with the critical exponents of a SOPT as $n= 1 +(1 -1/ beta )/ delta $, where the exponents β and δ give the temperature dependence of M at zero field and the field dependence of M at Ttrans, respectively. For materials with long range interactions the values of $n(T_{trans})$ in SOPT are typically close to those using the critical exponents for mean field model (0.67). On the other hand, for short range interactions, the typical values are close to Heisenberg or 3D-Ising models (0.63 and 0.57, respectively). For the $n(T_{trans})$ of SOPT there exists a lower limit that corresponds to the case where the material transits from a SOPT to a FOPT character, this point is called the critical point of the second order phase transition. The value at that point is 0.4 according to the critical exponents obtained from theoretical considerations. For FOPT, even if there is no critical region, the field dependence of ΔST in the high field range leads to n values lower than 0.4. Therefore, a clear criterion exits to identify the change from SOPT to FOPT according to the values of n(Ttrans). One of the most promising families of magnetocaloric materials are LaFeSi alloys. These alloys show a magnetic FOPT that implies a large magnetocaloric response. Hydrogenation of the samples shifts the transition temperature from ≈ 200 K to temperatures close to room temperature, to facilitate their appli","PeriodicalId":6571,"journal":{"name":"2018 IEEE International Magnetic Conference (INTERMAG)","volume":"130 1","pages":"1-1"},"PeriodicalIF":0.0,"publicationDate":"2018-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74845427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Anomalous Nernst effect related to magnetic domains in a microfabricated thermoelectric element made of noncollinear antiferromagnet Mn3Sn. 非共线反铁磁体Mn3Sn微晶热电元件中与磁畴相关的反常能子效应。
Pub Date : 2018-04-01 DOI: 10.1109/INTMAG.2018.8508841
H. Narita, M. Ikhlas, M. Kimata, A. Nugroho, S. Nakatsuji, Y. Otani
Recently, antiferromagnetic materials have attracted increasing attention because of their large magnetotransport and thermomagnetic effects, in which the electronic band structure associated with the noncollinear spin configuration is responsible for generating Berry curvature through spin-orbit coupling 1–3. The anomalous Nernst effect (ANE) is a thermoelectric phenomenon typically observed in ferromagnets under the application of a temperature gradient, in which a transverse voltage is induced perpendicular to both the temperature gradients and the magnetization. Recent experimental studies have shown large ANE in a noncollinear antiferromagnetic metal Mn3Sn with a vanishingly small magnetization of 0.002 μB per Mn atom 4, 5, whose band structure has the Weyl points near 6, 7. In previous studies, the fabrication of thermoelectric devices with the enhanced Seebeck effect has proven to be complicated, owing to the requirement for alternately aligned p- and n-type semiconductor pillars 8. On the other hand, the ANE allows the design of much simpler thermopiles composed of laterally series-connected wires. Toward realizing a thermopile made of the chiral anti-ferromagnet Mn3Sn, focused ion beam (FIB) lithography was employed to microfabricate a thermoelectric element consisting of a Ta/Al2O3/Mn3Sn layered structure 9. Figures 1(a) and (b) show a schematic illustration of the microfabricated Mn3Sn device structure for measuring ANE and the magnetic structure of the Mn3Sn when the magnetic field is applied along the [01–10] axis, where the thermal gradient is applied along the [0001] axis. In this device, the Ta layer acts as a heater producing Joule heat diffusing across the Al2O3 insulating layer into the thin Mn3Sn layer. All measurements were performed at room temperature in vacuum. Figure 2 shows the ANE results for the configuration shown in Fig. 1(a) obtained for a dc current of ±1.5 mA applied to the Ta heater. The measured AN signal exhibits a clear hysteresis in an applied temperature gradient and magnetic field. The $V_{ANE}$ is indeed independent of the direction of the applied electrical current in the Ta heater. This indicates that the hysteresis loop in Fig. 2(a) is arising from the ANE in Mn3Sn. The observation of the spontaneous, zero field value is essential for construction of the thermopile element. Figure 2(b) shows the electrical current dependence of $V_{ANE}$. The voltage increases with the electrical current in the Ta heater. The sign and magnitude do not depend on the direction of the electrical current. The magnitude is also proportional to the square of the electrical current applied to the Ta heater. In addition, the angular dependence of ANE in the configuration shown in Figure 1(a) shows a small anomaly around 60° when the magnetic field is rotated from the [2-1-10] axis (0°) to the [01–10] axis (90°). On the other hand, in another ANE-measurement device of Mn3Sn, the shape of the hysteresis of ANE has a step structur
近年来,反铁磁材料由于具有较大的磁输运和热磁效应而受到越来越多的关注,其中与非共线自旋构型相关的电子能带结构通过自旋-轨道耦合产生Berry曲率1-3。反常能效应(ANE)是在温度梯度作用下铁磁体中观察到的一种典型的热电现象,在这种现象中,一个垂直于温度梯度和磁化强度的横向电压被诱导出来。最近的实验研究表明,在非共线反铁磁金属Mn3Sn中存在较大的ANE,其磁化强度为0.002 μB / Mn原子4,5,其能带结构在6,7附近有Weyl点。在先前的研究中,由于需要交替排列的p型和n型半导体柱8,具有增强塞贝克效应的热电器件的制造已被证明是复杂的。另一方面,ANE允许设计由横向串联电线组成的简单得多的热电堆。为了实现手性反铁磁Mn3Sn热电堆,采用聚焦离子束(FIB)光刻技术对Ta/Al2O3/Mn3Sn层状结构的热电元件进行了微加工。图1(a)和(b)显示了用于测量ANE的微加工Mn3Sn器件结构的示意图,以及当磁场沿[01-10]轴施加时Mn3Sn的磁性结构,其中热梯度沿[0001]轴施加。在该装置中,Ta层充当加热器,产生焦耳热,穿过Al2O3绝缘层扩散到薄的Mn3Sn层。所有的测量都是在室温真空中进行的。图2显示了在Ta加热器上施加±1.5 mA直流电流时,图1(a)所示配置的ANE结果。测量到的AN信号在外加温度梯度和磁场中表现出明显的滞后。$V_{ANE}$确实与Ta加热器中施加电流的方向无关。这表明图2(a)中的磁滞回线是由Mn3Sn中的ANE引起的。自发零场值的观测对于热电堆元件的构造是必不可少的。图2(b)显示了$V_{ANE}$的电流依赖性。电压随着Ta加热器内电流的增大而增大。符号和大小不取决于电流的方向。大小也与施加在Ta加热器上的电流的平方成正比。此外,图1(a)所示构型中ANE的角依赖性显示,当磁场从[2-1-10]轴(0°)旋转到[01-10]轴(90°)时,在60°附近有一个小的异常。另一方面,在另一种Mn3Sn的ANE测量装置中,ANE的磁滞形状具有阶阶结构,取决于微加工Mn3Sn旁边的Ta加热器中的电流。根据理论研究,在mn3sn10中提出了6个各60°方向不同的磁畴。然而,需要进一步的研究来澄清这种结构的起源。总之,我们在手性反铁磁体Mn3Sn组成的微制造器件中评估了ANE,作为实现热电堆器件的第一步。器件中自发的零场电压信号为几μV量级,与在温度梯度下的Mn3Sn块体单晶中观察到的零场电压信号几乎相同。利用有限元模拟的温度梯度确定了微加工元件的反常能系数${{S}_{text{ANE}}}$。实验和仿真结果表明,ANE系数为0.27 μV/K,与本体值吻合较好。这一结果表明,FIB微加工并没有显著改变本体Mn3Sn的热电性能。由于手性反铁磁体几乎不产生杂散场,本研究为通过密装微制反铁磁元件来制造高效热电堆开辟了道路。在这项工作中,Mn3Sn微器件是由块状晶体制成的,而不是通过薄膜沉积。这种方法使我们能够在更广泛的材料范围内研究纳米尺度上的热电现象,而不是在薄膜基器件中使用的传统材料。
{"title":"Anomalous Nernst effect related to magnetic domains in a microfabricated thermoelectric element made of noncollinear antiferromagnet Mn3Sn.","authors":"H. Narita, M. Ikhlas, M. Kimata, A. Nugroho, S. Nakatsuji, Y. Otani","doi":"10.1109/INTMAG.2018.8508841","DOIUrl":"https://doi.org/10.1109/INTMAG.2018.8508841","url":null,"abstract":"Recently, antiferromagnetic materials have attracted increasing attention because of their large magnetotransport and thermomagnetic effects, in which the electronic band structure associated with the noncollinear spin configuration is responsible for generating Berry curvature through spin-orbit coupling 1–3. The anomalous Nernst effect (ANE) is a thermoelectric phenomenon typically observed in ferromagnets under the application of a temperature gradient, in which a transverse voltage is induced perpendicular to both the temperature gradients and the magnetization. Recent experimental studies have shown large ANE in a noncollinear antiferromagnetic metal Mn3Sn with a vanishingly small magnetization of 0.002 μB per Mn atom 4, 5, whose band structure has the Weyl points near 6, 7. In previous studies, the fabrication of thermoelectric devices with the enhanced Seebeck effect has proven to be complicated, owing to the requirement for alternately aligned p- and n-type semiconductor pillars 8. On the other hand, the ANE allows the design of much simpler thermopiles composed of laterally series-connected wires. Toward realizing a thermopile made of the chiral anti-ferromagnet Mn3Sn, focused ion beam (FIB) lithography was employed to microfabricate a thermoelectric element consisting of a Ta/Al2O3/Mn3Sn layered structure 9. Figures 1(a) and (b) show a schematic illustration of the microfabricated Mn3Sn device structure for measuring ANE and the magnetic structure of the Mn3Sn when the magnetic field is applied along the [01–10] axis, where the thermal gradient is applied along the [0001] axis. In this device, the Ta layer acts as a heater producing Joule heat diffusing across the Al2O3 insulating layer into the thin Mn3Sn layer. All measurements were performed at room temperature in vacuum. Figure 2 shows the ANE results for the configuration shown in Fig. 1(a) obtained for a dc current of ±1.5 mA applied to the Ta heater. The measured AN signal exhibits a clear hysteresis in an applied temperature gradient and magnetic field. The $V_{ANE}$ is indeed independent of the direction of the applied electrical current in the Ta heater. This indicates that the hysteresis loop in Fig. 2(a) is arising from the ANE in Mn3Sn. The observation of the spontaneous, zero field value is essential for construction of the thermopile element. Figure 2(b) shows the electrical current dependence of $V_{ANE}$. The voltage increases with the electrical current in the Ta heater. The sign and magnitude do not depend on the direction of the electrical current. The magnitude is also proportional to the square of the electrical current applied to the Ta heater. In addition, the angular dependence of ANE in the configuration shown in Figure 1(a) shows a small anomaly around 60° when the magnetic field is rotated from the [2-1-10] axis (0°) to the [01–10] axis (90°). On the other hand, in another ANE-measurement device of Mn3Sn, the shape of the hysteresis of ANE has a step structur","PeriodicalId":6571,"journal":{"name":"2018 IEEE International Magnetic Conference (INTERMAG)","volume":"16 1","pages":"1-1"},"PeriodicalIF":0.0,"publicationDate":"2018-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78748921","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magnetic Force Equations Based on Computer Simulation and the Effect of Load Line 基于计算机仿真的磁力方程及载重线的影响
Pub Date : 2018-04-01 DOI: 10.1109/INTMAG.2018.8508636
C. Chen, H. Meng, M. Fan
The Maxwell magnetic force equation $mathrm {F}= mathrm {B}^{2}mathrm {A}/ ( 2 mu _{0})$[1–6] can be used for determining the magnetic force of magnetic components, where F is the force in newton (N), B is the flux density in tesla (T), A is the area of cross-section in square meter (m2), and $mu _{0}$ is the permeability of the vacuum $( 4 pi times 10 ^{-7}mathrm {H} /mathrm {m})$. The formula can be converted to an easy to remember expression of F = 40B2A, in which the unit of A is cm2. This equation says that if the field is 1T, and the area is 1cm2, then the magnetic force is 40N or 4kgf. However, it is somehow difficult to determine the B value in many practical cases, and the accuracy is usually not satisfactory. Computer simulation using finite element method can determine the magnetic forces with various boundary conditions, but usually it is not convenient for industrial users. In this paper, we report several simple equations, which are established based on the large database generated by using 3D computer simulation. The users can use the equations to obtain the force by simply inputting the magnet’s$mathrm{B}_{mathrm{r}}$, area and thickness. The effect of load line is also analyzed in this paper. Infolytica’s MagNet software was chosen for the simulation. Parameterization function with newton tolerance 0.1% was used to systematically solve the problems for NdFeB cylinders, rings, and rectangular blocks interacting with CR1010 steel. The steel plates are both thicker and larger than the magnets. The maximum sizes for the magnets are shown in Table 1. The result database for each gap in a single boundary condition includes 62500 data points for rectangular blocks, 30625 data points for rings, and 1250 data points for cylinders. The gaps between the magnets and steel plates are in the range of 0.01 – 15mm with 23 unequal intervals. The itemized data were then plotted and analyzed to establish the force equations for the magnets with relative high load lines. Figure 1 shows the magnetic force vs the area of N52 magnet rings with gap = 0.01 mm to steel plates. Fig. 1a and 1b have different boundary conditions: 1a has CR1010 steel on both ends of the magnets, and 1b has the steel only on one end. The load line of a standalone magnet can be estimated by using the equations described in Parker’s book[7], but the magnets in this project have much higher load lines compared to the standalone magnets since steel plates are associated with these magnets. Boundary condition 1a obviously gives much higher load line compared to boundary condition 1b. For these ring magnets with higher load line in condition 1a, the force value vs area for each thickness can generate 2nd degree polynomial formulas, which has R-squared R2>0.9997 as shown in Figure 1. (R2 of 1.0000 was obtained for all the thicknesses of rectangular blocks). These formulas were then analyzed to establish a general equation $F = B_{r}^{2} {(aA}^{2}+ {bA)}$. Using the equation, the magn
麦克斯韦磁力方程$mathrm {F}= mathrm {B}^{2}mathrm {A}/ ( 2 mu _{0})$[1-6]可用于确定磁性元件的磁力,其中F为力,单位为牛顿(N), B为磁通密度,单位为特斯拉(T), A为横截面面积,单位为平方米(m2), $mu _{0}$为真空的磁导率$( 4 pi times 10 ^{-7}mathrm {H} /mathrm {m})$。这个公式可以转换成一个容易记住的表达式F = 40B2A,其中A的单位是cm2。这个方程说,如果磁场是1T,面积是1m2,那么磁力是40N或4kgf。然而,在许多实际情况下,确定B值有些困难,而且精度通常不令人满意。利用有限元方法进行计算机模拟可以确定各种边界条件下的磁力,但通常不方便工业用户使用。在本文中,我们报告了几个简单的方程,这些方程是基于三维计算机模拟生成的大型数据库建立的。用户可以通过简单地输入磁铁的$mathrm{B}_{mathrm{r}}$、面积和厚度来使用公式来获得力。本文还分析了载重线的作用。我们选择Infolytica的MagNet软件进行模拟。参数化功能,牛顿公差0.1% was used to systematically solve the problems for NdFeB cylinders, rings, and rectangular blocks interacting with CR1010 steel. The steel plates are both thicker and larger than the magnets. The maximum sizes for the magnets are shown in Table 1. The result database for each gap in a single boundary condition includes 62500 data points for rectangular blocks, 30625 data points for rings, and 1250 data points for cylinders. The gaps between the magnets and steel plates are in the range of 0.01 – 15mm with 23 unequal intervals. The itemized data were then plotted and analyzed to establish the force equations for the magnets with relative high load lines. Figure 1 shows the magnetic force vs the area of N52 magnet rings with gap = 0.01 mm to steel plates. Fig. 1a and 1b have different boundary conditions: 1a has CR1010 steel on both ends of the magnets, and 1b has the steel only on one end. The load line of a standalone magnet can be estimated by using the equations described in Parker’s book[7], but the magnets in this project have much higher load lines compared to the standalone magnets since steel plates are associated with these magnets. Boundary condition 1a obviously gives much higher load line compared to boundary condition 1b. For these ring magnets with higher load line in condition 1a, the force value vs area for each thickness can generate 2nd degree polynomial formulas, which has R-squared R2>0.9997 as shown in Figure 1. (R2 of 1.0000 was obtained for all the thicknesses of rectangular blocks). These formulas were then analyzed to establish a general equation $F = B_{r}^{2} {(aA}^{2}+ {bA)}$. Using the equation, the magnetic force for any $B_{r}$ value can be determined by inputting magnet’s $B_{r}$, area, and thickness. As shown in Table 1, the factor a is a function of thickness in 2nd degree polynomial, and the factor b is also a function of thickness but in power form. The effect of boundary condition is tremendous. Condition1b has much lower load line compared to condition 1a, hence the magnetic force values vs the area cannot generate satisfactory equations. As shown in the Fig. 1b, for the same magnet area, the magnetic force values are in a range with various values due to different load lines. For example, the ring magnets with exact the same thickness 0.1cm and area 2.8cm2, the force values range from 18.4N to 74N for ID/OD values from 0.1/1.9cm to 4.3/4.7cm. Details for all the magnet shapes with two boundary conditions will be reported
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2018 IEEE International Magnetic Conference (INTERMAG)
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