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Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry最新文献

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Reversible chair ↔ skew conformational interconversion of 1,3,2-dioxaphosphorinane ring in the solid state. 固态中1,3,2-二磷烷环的倾斜构象相互作用。
Pub Date : 2016-02-01 DOI: 10.1107/S2052520615020259
K. Ślepokura
β-NH4[(MeO)2cDHAP] (where cDHAP is cyclic dihydroxyacetone phosphate) has been investigated by X-ray crystallography in the temperature range 350–100 K. Three reversible single-crystal-to-single-crystal phase transitions have been examined and four phases (high-, room-, medium- and low-temperature phase, HTP, RTP, MTP and LTP, respectively) have been structurally determined: HTP (at 350 K, P21/a, Z = 24), RTP (290 K, P overline{1}, Z = 12), MTP (205 K, P21/a, Z = 4) and LTP (100 K, P overline{1}, Z = 24). Various puckering modes of the 1,3,2-dioxaphosphorinane ring of the organic cyclic phosphate anion have been revealed in the crystal: chair and skew. The chair ↔ skew ring flipping, which has been shown to take place during the phase transitions, results in various populations of skew and chair conformers in different phases. The flexibility in the coordination geometry of ammonium cations is considered to assist in the conformational flexibility of the dioxaphosphorinane ring.
用x射线晶体学在350 ~ 100 K的温度范围内研究了β-NH4[(MeO)2cDHAP](其中cDHAP为环磷酸二羟丙酮)。研究了三种可逆的单晶到单晶相变,并确定了四种相(高温,室温,中低温,HTP, RTP, MTP和LTP)的结构:HTP (350 K, P21/a, Z = 24), RTP (290 K, P overline{1}, Z = 12), MTP (205 K, P21/a, Z = 4)和LTP (100 K, P overline{1}, Z = 24)。有机环磷酸阴离子的1,3,2-二磷烷环在晶体中显示出不同的折叠模式:椅状和斜状。在相变期间发生的chair↔skew环翻转导致不同相位的skew和chair构象的不同种群。铵离子配位几何的灵活性被认为有助于二磷烷环的构象灵活性。
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引用次数: 2
Introduction to Nanofiber Materials. By Frank K. Ko and Yuqin Wan. Cambridge University Press, 2014. Pp. 282. Price GBP 65.00, US$ 99.00. ISBN 978-0-521-87983-5. 纳米纤维材料导论。作者:柯震东、温玉琴。剑桥大学出版社,2014。282页。价格65.00英镑,99.00美元。ISBN 978-0-521-87983-5。
Pub Date : 2015-04-01 DOI: 10.1107/S2052520615000165
Seeram Ramakrishnaa
‘Introduction to Nanofiber Materials’ is interesting as it is written for undergraduate and graduate students, as well as research scientists in material engineering, bioengineering and especially nanotechnology. The book is very well planned and well written, with a comprehensive introduction to nanosize scale materials and the chemistry of polymeric materials. An in-depth explanation of the basic properties of polymers helps the reader to refresh knowledge acquired during university courses, and is a very good introduction to further content, especially various methods of fiber formation, with understandable and clear schematics which are essential to fully understand nanofiber formation and their advantages and limits. The chapter on nanofiber technology describes briefly methods of nanofiber production, with special focus on the electrospinning method, and emphasis placed on the influence of process parameters on fiber formation and diameter. Comprehensive knowledge about process parameters is essential when using the electrospinning method. Fiber formation by electrospinning depends on many various parameters, interacting together in many combinations. The work presented updates progress on understanding these dependencies and gives an explanation of the methodology of modelling and electrospinning simulation which still have not been fully understood. The authors of this work focus on the methods of characterization and test nanofibrous materials which have been divided very intuitively. The reader will learn about ways of characterizing polymeric materials with a number of useful examples of satisfying or unsatisfying results like spectra, visualizations and graphs. The principles of every method described in the book are also explained in a very approachable way. Characterization methods are presented in accordance with recent research, which shows the reader how to apply those methods in the laboratory and how to interpret the results. Electrospun polymeric fibers have been investigated extensively for the last decade. A large number of various polymeric materials were used to create nanofibrous sheets in various forms. In this work, the authors summarized the most recent research in bioactive nanofibers, electroactive fibers and nanocomposite fibrous materials. Fiber research has been extensively studied in recent years, and has a high potential for commercialization in the near future. In particular, the presented bioactive properties of nanofibers showed the methodology and possible future areas of development that researchers may be interested in. Nevertheless, the drug delivery section could be extended by including the electrospraying technique, which becomes a complementary method of creating polymeric drug delivery systems. The electroactive properties of nanofibers result from their chemical composition and dimensions. The discovery of carbon nanotubes in 1991 revealed a huge potential for the production of electroconductive and
《纳米纤维材料导论》很有趣,因为它是为本科生和研究生,以及材料工程、生物工程,尤其是纳米技术的研究科学家写的。这本书是非常好的计划和写得很好,与纳米尺度的材料和聚合物材料的化学全面介绍。对聚合物基本性质的深入解释有助于读者更新在大学课程中所学到的知识,并且是对进一步内容的很好的介绍,特别是各种纤维形成方法,具有可理解和清晰的原理图,这对于充分理解纳米纤维的形成及其优点和局限性至关重要。纳米纤维技术一章简要介绍了纳米纤维的生产方法,重点介绍了静电纺丝法,并重点介绍了工艺参数对纤维形成和直径的影响。在使用静电纺丝法时,对工艺参数的全面了解是必不可少的。静电纺丝纤维的形成取决于许多不同的参数,它们以多种组合方式相互作用。提出的工作更新了理解这些依赖关系的进展,并解释了建模和静电纺丝模拟的方法,这些方法仍未完全理解。本文主要研究了纳米纤维材料的表征和测试方法,并对纳米纤维材料进行了较为直观的划分。读者将学习表征聚合物材料的方法与一些有用的例子满意或不满意的结果,如光谱,可视化和图形。书中描述的每种方法的原理也以一种非常平易近人的方式进行了解释。根据最近的研究提出了表征方法,向读者展示了如何在实验室中应用这些方法以及如何解释结果。近十年来,电纺丝聚合物纤维得到了广泛的研究。大量不同的高分子材料被用于制造各种形式的纳米纤维片。本文综述了生物活性纳米纤维、电活性纳米纤维和纳米复合纤维材料的最新研究进展。近年来,纤维研究得到了广泛的研究,在不久的将来具有很高的商业化潜力。特别是,纳米纤维的生物活性特性显示了研究人员可能感兴趣的方法和可能的未来发展领域。然而,可以通过包括电喷涂技术来扩展药物传递部分,该技术成为创建聚合物药物传递系统的补充方法。纳米纤维的电活性是由其化学成分和尺寸决定的。1991年碳纳米管的发现揭示了生产导电和超磁性材料的巨大潜力。静电纺丝技术和纳米材料表征技术的同步发展为这些材料带来了广泛的应用前景,作者对此进行了深入的描述。各种材料的结合形成了一种全新的、有前途的纳米复合纤维纺织品。与前面提到的组件类似,作者强调了纳米复合材料的生产及其优点和局限性,这可能是有经验的读者的有价值的指导。ISSN 2052 - 5206
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引用次数: 1
The continuing development and expansion of Acta Crystallographica Section B 《晶体学报B辑》的持续发展和扩充
Pub Date : 2015-02-01 DOI: 10.1107/S2052520615001663
A. Blake, M. Boissieu
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引用次数: 0
Acronyms and Abbreviations in Natural Sciences and Technology. By Joachim Bohm, 4th expanded and revised edition. Schweizerbart Science Publishers, 2014. Pp. 283. Price Euros 29.80. ISBN 978‐3‐510‐65293‐8. 自然科学与技术中的缩略语。作者:Joachim Bohm,第四次扩充修订版。Schweizerbart Science出版社,2014。283页。价格29.8欧元。ISBN 978量3量510还是65293 8。
Pub Date : 2015-02-01 DOI: 10.1107/S2052520615001286
D. Schaniel
This book compiles 30 300 acronyms and abbreviations from the three fields of: (1) physical analytical methods, and equipment; (2) preparation techniques, building units, and structures; (3) crystals and materials. The acronyms are listed in alphabetical order in tabular form within the three columns ‘acronym’, ‘code’ and ‘english translation; german translation’. The code (greek letters , , , d, ", , , ) allows for the assignment to the categories ‘analytical methods and phenomena’, ‘equipment’, ‘terms’ for the field (1), ‘preparation techniques and phenomena’, ‘functional and structural units’, ‘electronic signal processing and techniques’ for field (2), and ‘crystals’, ‘materials’ for field (3). Some acronyms have more than one distinct meaning which are all listed in alphabetic order, e.g. for the acronym AP one finds 42 translations, ranging from ‘absorbable organic halogen; absorbierbares organisches Halogen’ to ‘all points; alle Punkte’ and ‘azimuthal projection; azimutale Projektion’ all in the category ‘terms’. As can be inferred from this example, the author does not want to prioritize or critically evaluate the acronyms, but has the intention to simply list them and provide a database for the helpless reader in front of (sometimes certainly useless) abbreviations. Completeness is not claimed by the author acknowledging the ever increasing number of such acronyms. However, the listing is quite extensive and there is a good chance of finding the acronym one is puzzled by. I agree with the author that compared to searching online for the meaning of an acronym, which often returns a flood of results, the book has the advantage of limiting explanations to those relevant to the three fields listed above. Furthermore, due to the alphabetical organization access within the book is fast. Overall this book is certainly useful to those who repeatedly encounter unexplained acronyms. It might be especially helpful for researchers needing to access literature outside their own discipline and thus often confronted with unfamiliar ‘language’.
这本书从三个领域汇编了30 300个缩略语和缩写词:(1)物理分析方法和设备;(二)编制技术、建筑单元和结构;(3)晶体和材料。缩略语按字母顺序以表格形式列在“缩略语”、“代码”和“英文翻译”三栏中;德国翻译”。代码(希腊字母,,,d,“,,,”)允许对“分析方法和现象”、“设备”、“术语”(1)、“制备技术和现象”、“功能和结构单元”、“电子信号处理和技术”(2)以及“晶体”、“材料”(3)等类别进行分配。一些首字母缩略词有不止一个不同的含义,它们都按字母顺序列出,例如,对于首字母缩略词AP,人们可以找到42个翻译。从“可吸收有机卤素”;吸收剂将卤素“吸到”所有点;alle Punkte '和'方位投影;方位投影,都在术语的范畴里。从这个例子中可以推断,作者并不想对缩略词进行优先级排序或批判性地评估,而是想简单地列出它们,并为面对缩写词(有时肯定是无用的)的无助读者提供一个数据库。作者承认这种首字母缩略词的数量在不断增加,但并不声称其完整性。然而,这个列表相当广泛,很有可能找到一个让人困惑的缩略词。我同意作者的观点,与在网上搜索缩略语的含义(通常会返回大量结果)相比,这本书的优点是将解释限制在与上面列出的三个领域相关的内容上。此外,由于按字母顺序组织,在书中访问是快速的。总的来说,这本书对于那些反复遇到无法解释的缩写词的人来说肯定是有用的。对于那些需要获取自己学科以外的文献,因而经常面临不熟悉的“语言”的研究人员来说,这可能特别有帮助。
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引用次数: 0
Phase Transitions in Materials. By Brent Fultz. Cambridge University Press, 2014. Pp. 583. Price GBP 60, US$ 90. ISBN 9781107067240. 材料中的相变。布伦特·富尔茨著。剑桥大学出版社,2014。583页。价格60英镑,90美元。ISBN 9781107067240。
Pub Date : 2015-02-01 DOI: 10.1107/S205252061500075X
A. Glazer
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引用次数: 1
Introduction to Graphene-Based Nanomaterials: From Electronic Structure to Quantum Transport. By Luis E. F. Foa Torres, Stephan Roche and Jean-Christophe Charlier. Cambridge University Press, 2014. Pp. 421. Price GBP 60.00, USD $ 98.00 ISBN 978-11078030831 (hardback). 石墨烯基纳米材料简介:从电子结构到量子输运。作者:Luis E. F. Foa Torres、Stephan Roche和Jean-Christophe Charlier。剑桥大学出版社,2014。421页。价格60.00英镑,98.00美元ISBN 978-11078030831(精装本)。
Pub Date : 2014-08-01 DOI: 10.1107/S2052520614008634
S. Lebègue
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引用次数: 2
High-Resolution Electron Microscopy. By John C. H. Spence. Oxford University Press, 2013. Pp. 406. Price £75. ISBN: 978-0-19-966863-2. 高分辨率电子显微镜。约翰·c·h·斯宾塞著。牛津大学出版社,2013。406页。价格£75。ISBN: 978-0-19-966863-2。
Pub Date : 2014-08-01 DOI: 10.1107/S2052520614004934
J. Hadermann
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引用次数: 1
Symmetry Relationships between Crystal Structures. By Ulrich Müller. IUCr/Oxford Science Publications, 2013. Pp. XVI + 332. Price (hardcover) GBP 49.95. ISBN 978‐0‐19‐966995‐0. 晶体结构之间的对称关系。乌尔里希·迈勒著。IUCr/牛津科学出版社,2013。第XVI + 332页。价格(精装)49.95英镑。ISBN 978量0还是19 966995量0。
Pub Date : 2013-10-01 DOI: 10.1107/S2052519213018708
M. Nespolo
HAL is a multi-disciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L’archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d’enseignement et de recherche français ou étrangers, des laboratoires publics ou privés. Symmetry Relationships between Crystal Structures . By Ulrich Müller. IUCr/Oxford Science Publications, 2013. Pp. XVI + 332. Price (hardcover) GBP 49.95. ISBN 978-0-19-966995-0. Massimo Nespolo
它是一个多学科的开放获取档案,用于科学研究文件的存储和传播,无论它们是否出版。这些文件可能来自法国或国外的教学和研究机构,也可能来自公共或私人研究中心。HAL开放多学科档案旨在存放和传播来自法国或外国教育和研究机构、公共或私人实验室的已发表或未发表的研究级科学文件。对称性between水晶结构活性关系。他的父亲是一名律师,母亲是一名律师。他的父亲是一名律师,母亲是一名律师。第16页+ 332页。价格(精装)49.95英镑。en 978-0-19-966995-0。Massimo Nespolo
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引用次数: 1
Problems in Structural Inorganic Chemistry. By Wai-Kee Li, Yu-San Cheung, Kendrew Kin Wah Mak and Thomas Chung Wai Mak. Pp. 320. Oxford University Press, 2012. Price (Paperback) US$ 59.99. ISBN 978 01996 58503 结构无机化学问题。作者:李伟基、张玉生、麦健华、麦钟伟320页。牛津大学出版社,2012。价格(平装本)59.99美元。Isbn 978 01996 58503
Pub Date : 2013-08-01 DOI: 10.1107/S2052519213012141
M. Ruck
The book is intended as a problem text for students in inorganic chemistry at the senior undergraduate and beginning graduate level. It is a compilation of 300 problems that had been designed by the authors for teaching inorganic chemistry courses, either as take-home assignments or examination questions. Notwithstanding the focus on structural aspects of inorganic chemistry indicated in the title the scope is much broader. The topics covered comprise Atomic and Molecular Electronic States, Atomic Orbitals, Hybrid Orbitals, Molecular Symmetry, Molecular Geometry and Bonding, Crystal Field Theory, Molecular Orbital Theory, Vibrational Spectroscopy, and Crystal Structure. Yet the central theme running through these topics is symmetry, molecular or crystalline. Helpful appendices, a bibliography with 150 citations, and a subject index complete the text. The origins of the book go back to the early 80s when the first version of this compilation, entitled Problems in Inorganic and Structural Chemistry, was published by T. C. W. Mak, K. Y. Hui, O. W. Lan and W.-K. Li. During decades of practical use it has been revised and updated. The renowned senior authors Thomas Chung Wai Mak and Wai-Kee Li are now Emeritus Professors of Chemistry. In this sequel book their great expertise in inorganic and physical chemistry is complemented by Yu-San Cheung and Kendrew Kin Wah Mak who are teaching physical and organic chemistry at the Chinese University of Hong Kong. Indeed, the optimization by generations of students and the extension to further aspects of chemistry resulted in a wide range of clearly formulated, challenging problems along with their solutions and helpful explanations. This mature workbook allows students to profoundly test their knowledge in several essential fields of chemistry. The outstanding quality of the content, the high quality printing and the affordable paperback edition make Problems in Structural Inorganic Chemistry highly attractive for students and instructors especially in inorganic and physical chemistry.
这本书的目的是作为一个问题文本的学生在无机化学在高级本科和研究生水平开始。它是由作者设计的300个问题的汇编,用于教授无机化学课程,或作为家庭作业或考试问题。尽管在标题中指出无机化学的结构方面是重点,但范围要广泛得多。涵盖的主题包括原子和分子的电子态、原子轨道、杂化轨道、分子对称、分子几何和键、晶体场理论、分子轨道理论、振动光谱学和晶体结构。然而贯穿这些主题的中心主题是对称,分子或晶体。有用的附录,有150个引用的参考书目,和一个主题索引完成文本。这本书的起源可以追溯到八十年代初,当时由麦振文、许国英、兰玉文和魏国光出版的第一版《无机和结构化学问题》。李。在几十年的实际使用中,它已被修订和更新。著名资深作者麦钟伟及李伟基现为化学名誉教授。在这本续作中,在香港中文大学教授物理化学和有机化学的张玉生和麦健华教授补充了他们在无机化学和物理化学方面的丰富经验。事实上,经过几代学生的优化和对化学进一步方面的扩展,产生了一系列清晰表述的、具有挑战性的问题,以及它们的解决方案和有益的解释。这本成熟的练习册可以让学生深刻地测试他们在几个基本化学领域的知识。出色的内容质量,高质量的印刷和价格合理的平装版使《结构无机化学问题》对学生和教师,特别是无机化学和物理化学的学生和教师极具吸引力。
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引用次数: 0
Crystallographic input data for (001), (110) and (111)-oriented superlattices. Corrigendum (001)、(110)和(111)取向超晶格的晶体学输入数据。应改正的错误
Pub Date : 2013-06-01 DOI: 10.1107/S2052519213009068
Z. Touaa, N. Sekkal
Equations (13)–(18) in the paper by Touaa & Sekkal [(2012), Acta Cryst. B68, 378–388] are corrected.
Touaa & Sekkal(2012)论文中的方程(13)- (18)[j],晶体学报。[B68, 378-388]进行了修正。
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引用次数: 0
期刊
Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry
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