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Human–Robot Co-Facilitation in Collaborative Learning: A Comparative Study of the Effects of Human and Robot Facilitation on Learning Experience and Learning Outcomes 协作学习中的人机协同辅导:人类和机器人辅助对学习体验和学习成果影响的比较研究
J
Pub Date : 2024-07-14 DOI: 10.3390/j7030014
Ilona Buchem, Stefano Sostak, Lewe Christiansen
Collaborative learning has been widely studied in higher education and beyond, suggesting that collaboration in small groups can be effective for promoting deeper learning, enhancing engagement and motivation, and improving a range of cognitive and social outcomes. The study presented in this paper compared different forms of human and robot facilitation in the game of planning poker, designed as a collaborative activity in the undergraduate course on agile project management. Planning poker is a consensus-based game for relative estimation in teams. Team members collaboratively estimate effort for a set of project tasks. In our study, student teams played the game of planning poker to estimate the effort required for project tasks by comparing task effort relative to one another. In this within- and between-subjects study, forty-nine students in eight teams participated in two out of four conditions. The four conditions differed in respect to the form of human and/or robot facilitation. Teams 1–4 participated in conditions C1 human online and C3 unsupervised robot, while teams 5–8 participated in conditions C2 human face to face and C4 supervised robot co-facilitation. While planning poker was facilitated by a human teacher in conditions C1 and C2, the NAO robot facilitated the game-play in conditions C3 and C4. In C4, the robot facilitation was supervised by a human teacher. The study compared these four forms of facilitation and explored the effects of the type of facilitation on the facilitator’s competence (FC), learning experience (LX), and learning outcomes (LO). The results based on the data from an online survey indicated a number of significant differences across conditions. While the facilitator’s competence and learning outcomes were rated higher in human (C1, C2) compared to robot (C3, C4) conditions, participants in the supervised robot condition (C4) experienced higher levels of focus, motivation, and relevance and a greater sense of control and sense of success, and rated their cognitive learning outcomes and the willingness to apply what was learned higher than in other conditions. These results indicate that human supervision during robot-led facilitation in collaborative learning (e.g., providing hints and situational information on demand) can be beneficial for learning experience and outcomes as it allows synergies to be created between human expertise and flexibility and the consistency of the robotic assistance.
协作学习已在高等教育及其他领域得到广泛研究,表明小组协作可以有效促进深入学习、提高参与度和积极性,并改善一系列认知和社会成果。本文介绍的研究比较了人类和机器人在规划扑克游戏中的不同协助形式,该游戏被设计为敏捷项目管理本科课程中的一项协作活动。规划扑克是一种基于共识的团队相对估算游戏。团队成员共同估算一组项目任务的工作量。在我们的研究中,学生团队玩规划扑克游戏,通过比较任务的相对努力程度来估算项目任务所需的努力程度。在这项被试内和被试间研究中,8 个团队的 49 名学生参加了四个条件中的两个条件。这四个条件在人类和/或机器人协助形式上有所不同。1-4小组参与了C1人类在线和C3无监督机器人的条件,而5-8小组则参与了C2人类面对面和C4有监督机器人共同协助的条件。在 C1 和 C2 条件下,规划扑克牌的工作由人类教师协助进行,而在 C3 和 C4 条件下,NAO 机器人则协助进行游戏。在C4中,机器人在人类教师的监督下进行协助。研究比较了这四种协助形式,并探讨了协助类型对协助者能力(FC)、学习经验(LX)和学习成果(LO)的影响。根据在线调查的数据得出的结果显示,不同条件下存在一些显著差异。与机器人(C3、C4)条件相比,人类(C1、C2)条件下主持人的能力和学习成果评分更高,而在机器人监督条件下(C4),参与者体验到了更高的专注度、积极性和相关性,以及更强的控制感和成功感,他们对认知学习成果和学以致用意愿的评分也高于其他条件。这些结果表明,在以机器人为主导的协作学习过程中,人类的监督(例如,根据需要提供提示和情景信息)对学习体验和结果是有益的,因为它可以在人类的专业知识和灵活性与机器人协助的一致性之间产生协同效应。
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引用次数: 0
Synergisms between Surfactants, Polymers, and Alcohols to Improve the Foamability of Mixed Systems 表面活性剂、聚合物和醇类之间的协同作用可改善混合体系的发泡性
J
Pub Date : 2024-05-10 DOI: 10.3390/j7020010
L. Alves, Solange Magalhães, Cátia Esteves, Marco Sebastião, Filipe Antunes
In order to produce detergents with improved performance and good market acceptability, it is crucial to develop formulations with improved foamability and cleaning performance. The use of a delicate balance of surfactants and additives is an appealing strategy to obtain good results and enables a reduction in the amount of chemicals used in formulations. Mixtures of hydrophobically modified linear polymers and surfactants, as well as balanced mixtures with co-surfactants and/or hydrotropes, are the most effective parameters to control foamability and foam stability. In the present study, the effect of the addition of hydrophobically modified linear polymers, nonionic co-surfactants and hydrotropes, and their mixtures to anionic and zwitterionic surfactant aqueous solutions was evaluated. It was found that the presence of the hydrophobically modified polymer (HM-P) prevented the bubbles from bursting, resulting in better stability of the foam formed using zwitterionic surfactant solutions. Also, the surfactant packing was inferred to be relevant to obtaining foamability. Mixtures of surfactants, in the presence of a co-surfactant or hydrotrope led, tendentially, to an increase in the critical packing parameter (CPP), resulting in higher foam volumes and lower surface tension for most of the studied systems. Additionally, it was observed that the good cleaning efficiency of the developed surfactant formulations obtained a higher level of fat solubilization compared to a widely used brand of commercial dishwashing detergent.
为了生产出性能更好、市场接受度更高的洗涤剂,关键是要开发出泡沫性和清洁性能更好的配方。使用表面活性剂和添加剂的微妙平衡是获得良好效果的一种有吸引力的策略,并能减少配方中的化学品用量。疏水性改性线性聚合物和表面活性剂的混合物,以及含有助表面活性剂和/或水促剂的平衡混合物,是控制起泡性和泡沫稳定性的最有效参数。本研究评估了在阴离子和齐聚物表面活性剂水溶液中添加疏水性改性线性聚合物、非离子助表面活性剂和水合作用剂及其混合物的效果。结果发现,疏水改性聚合物(HM-P)的存在可防止气泡破裂,从而使使用齐聚物表面活性剂溶液形成的泡沫具有更好的稳定性。此外,还推断出表面活性剂的填料与获得发泡性有关。表面活性剂的混合物在共表面活性剂或水传质的存在下,往往会导致临界堆积参数(CPP)的增加,从而使大多数研究体系的泡沫体积增大,表面张力降低。此外,据观察,与一种广泛使用的商用洗洁精品牌相比,所开发的表面活性剂配方具有良好的清洁效率,可获得更高的脂肪溶解度。
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引用次数: 0
Aerodynamic Modification of High-Rise Buildings by the Adjoint Method 用积分法对高层建筑进行空气动力改造
J
Pub Date : 2024-02-05 DOI: 10.3390/j7010004
Amirfarhang Nikkhoo, A. Esmaeili, Shayan Rabizade, Majid Zamiri
This study presents a novel numerical methodology that is designed for the dynamic adjustment of three-dimensional high-rise building configurations in response to aerodynamic forces. The approach combines two core components: a numerical simulation of fluid flow and the adjoint method. Through a comprehensive sensitivity analysis, the influence of individual variables on aerodynamic loads, including lift and drag coefficients, is assessed. The findings underscore that the architectural design, specifically the building’s construction pattern, exerts the most substantial impact on these forces, accounting for a substantial proportion (76%). Consequently, the study extends its evaluation to the sensitivity of fluid flow across various sections of the tower by solving the adjoint equation throughout the entire fluid domain. As a result, the derived sensitivity vector indicates a remarkable reduction of approximately 31% in the applied loads on the tower. This notable improvement has significant implications for the construction of tall buildings, as it effectively mitigates aerodynamic forces, ultimately enhancing the overall comfort and structural stability of these architectural marvels.
本研究提出了一种新颖的数值方法,旨在针对空气动力对三维高层建筑结构进行动态调整。该方法结合了两个核心部分:流体流动数值模拟和邻接法。通过全面的敏感性分析,评估了各个变量对空气动力负荷(包括升力和阻力系数)的影响。研究结果表明,建筑设计,特别是建筑结构模式,对这些力的影响最大,占很大比例(76%)。因此,研究通过求解整个流体域的邻接方程,将评估范围扩大到塔楼各部分流体流动的敏感性。结果,得出的灵敏度矢量显示,塔上的外加载荷显著减少了约 31%。这一显著改进对高层建筑的建造具有重要意义,因为它能有效减轻空气动力,最终提高这些建筑奇迹的整体舒适度和结构稳定性。
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引用次数: 0
Aerodynamic Modification of High-Rise Buildings by the Adjoint Method 用积分法对高层建筑进行空气动力改造
J
Pub Date : 2024-02-05 DOI: 10.3390/j7010004
Amirfarhang Nikkhoo, A. Esmaeili, Shayan Rabizade, Majid Zamiri
This study presents a novel numerical methodology that is designed for the dynamic adjustment of three-dimensional high-rise building configurations in response to aerodynamic forces. The approach combines two core components: a numerical simulation of fluid flow and the adjoint method. Through a comprehensive sensitivity analysis, the influence of individual variables on aerodynamic loads, including lift and drag coefficients, is assessed. The findings underscore that the architectural design, specifically the building’s construction pattern, exerts the most substantial impact on these forces, accounting for a substantial proportion (76%). Consequently, the study extends its evaluation to the sensitivity of fluid flow across various sections of the tower by solving the adjoint equation throughout the entire fluid domain. As a result, the derived sensitivity vector indicates a remarkable reduction of approximately 31% in the applied loads on the tower. This notable improvement has significant implications for the construction of tall buildings, as it effectively mitigates aerodynamic forces, ultimately enhancing the overall comfort and structural stability of these architectural marvels.
本研究提出了一种新颖的数值方法,旨在针对空气动力对三维高层建筑结构进行动态调整。该方法结合了两个核心部分:流体流动数值模拟和邻接法。通过全面的敏感性分析,评估了各个变量对空气动力负荷(包括升力和阻力系数)的影响。研究结果表明,建筑设计,特别是建筑结构模式,对这些力的影响最大,占很大比例(76%)。因此,研究通过求解整个流体域的邻接方程,将评估范围扩大到塔楼各部分流体流动的敏感性。结果,得出的灵敏度矢量显示,塔上的外加载荷显著减少了约 31%。这一显著改进对高层建筑的建造具有重要意义,因为它能有效减轻空气动力,最终提高这些建筑奇迹的整体舒适度和结构稳定性。
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引用次数: 0
Blockchain in Smart Grids: A Bibliometric Analysis and Scientific Mapping Study 智能电网中的区块链:文献计量分析与科学绘图研究
J
Pub Date : 2024-01-06 DOI: 10.3390/j7010002
Georgios Lampropoulos
To achieve sustainability and fulfill sustainable development goals, the digitalization of the power sector is vital. This study aims to examine how blockchain can be integrated into and enrich smart grids. In total, 10 research questions are explored. Scopus and Web of Science (WoS) were used to identify documents related to the topic. The study involves the analysis of 1041 scientific documents over the period 2015–2022. The related studies are analyzed from different dimensions including descriptive statistics, identification of the most common keywords and most widely used outlets, examination of the annual scientific production, the analysis of the most impactful and productive authors, countries, and affiliations. The advancement of the research focus and the most popular topics are also examined. Additionally, the results are analyzed, the main findings are discussed, open issues and challenges are presented, and suggestions for new research directions are provided. Based on the results, it was evident that blockchain plays a vital role in securing smart grids and realizing power sector digitalization, as well as in achieving sustainability and successfully meeting sustainable development goals.
为实现可持续性和可持续发展目标,电力部门的数字化至关重要。本研究旨在探讨如何将区块链集成到智能电网中,并丰富智能电网。共探讨了 10 个研究问题。研究使用 Scopus 和 Web of Science (WoS) 来识别与该主题相关的文档。研究分析了 2015-2022 年间的 1041 篇科学文献。从不同维度对相关研究进行了分析,包括描述性统计、确定最常见的关键词和最广泛使用的网点、检查年度科研成果、分析最有影响和最有成果的作者、国家和所属单位。此外,还研究了研究重点的进展情况和最受欢迎的主题。此外,还对结果进行了分析,讨论了主要发现,提出了有待解决的问题和挑战,并对新的研究方向提出了建议。研究结果表明,区块链在确保智能电网安全、实现电力行业数字化以及实现可持续性和成功实现可持续发展目标方面发挥着至关重要的作用。
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引用次数: 0
An Overview of Mathematical Methods Applied in the Biomechanics of Foot and Ankle–Foot Orthosis Models 足踝生物力学中应用的数学方法概述--足部矫形器模型
J
Pub Date : 2023-12-22 DOI: 10.3390/j7010001
H. Nazha, S. Szávai, D. Juhre
Ankle–foot orthoses (AFOs) constitute medical instruments designed for patients exhibiting pathological gait patterns, notably stemming from conditions such as stroke, with the primary objective of providing support and facilitating rehabilitation. The present research endeavors to conduct a comprehensive review of extant scholarly literature focusing on mathematical techniques employed for the examination of AFO models. The overarching aim is to gain deeper insights into the biomechanical intricacies underlying these ankle–foot orthosis models from a mathematical perspective, while concurrently aiming to advance novel models within the domain. Utilizing a specified set of keywords and their configurations, a systematic search was conducted across notable academic databases, including ISI Web of Knowledge, Google Scholar, Scopus, and PubMed. Subsequently, a total of 23 articles were meticulously selected for in-depth review. These scholarly contributions collectively shed light on the utilization of nonlinear optimization techniques within the context of ankle–foot orthoses (AFOs), specifically within the framework of fully Cartesian coordinates, encompassing both kinematic and dynamic dimensions. Furthermore, an exploration of a two-degree-of-freedom AFO design tailored for robotic rehabilitation, which takes into account the interplay between foot and orthosis models, is delineated. Notably, the review article underscores the incorporation of shape memory alloy (SMA) elements in AFOs and overviews the constitutive elastic, viscoelastic, and hyperelastic models. This comprehensive synthesis of research findings stands to provide valuable insights for orthotists and engineers, enabling them to gain a mathematical understanding of the biomechanical principles underpinning AFO models and fostering the development of innovative AFO designs.
踝足矫形器(AFO)是专为表现出病态步态的患者设计的医疗器械,主要用于为中风等疾病患者提供支撑和促进康复。本研究致力于对现存的学术文献进行全面回顾,重点关注用于研究 AFO 模型的数学技术。总体目标是从数学角度深入了解这些踝足矫形器模型所蕴含的生物力学的复杂性,同时旨在推进该领域的新型模型。利用一组特定的关键词及其配置,在著名的学术数据库(包括 ISI 知识网、谷歌学术、Scopus 和 PubMed)中进行了系统搜索。随后,共精心挑选了 23 篇文章进行深入审查。这些学术论文共同揭示了在踝足矫形器(AFOs)中非线性优化技术的应用,特别是在完全笛卡尔坐标的框架内,包括运动学和动力学两个维度。此外,文章还探讨了为机器人康复量身定制的两自由度踝足矫形器设计,其中考虑到了足部和矫形器模型之间的相互作用。值得注意的是,这篇综述文章强调了形状记忆合金(SMA)元素在 AFO 中的应用,并概述了构成弹性、粘弹性和超弹性模型。这篇研究成果的综合综述为矫形师和工程师提供了宝贵的见解,使他们能够从数学角度理解支撑 AFO 模型的生物力学原理,并促进创新 AFO 设计的发展。
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引用次数: 0
A Comparative Study of Finite Element Method and Hybrid Finite Element Method–Spectral Element Method Approaches Applied to Medium-Frequency Transformers with Foil Windings 应用于带箔绕组中频变压器的有限元法和有限元法-谱元法混合方法比较研究
J
Pub Date : 2023-12-13 DOI: 10.3390/j6040041
S. Pourkeivannour, Joost S. B. van Zwieten, L. Friedrich, M. Curti, E. Lomonova
This study aims to improve the computational efficiency of the frequency domain analysis of medium-frequency transformers (MFTs) with the presence of large clearance distances and fine foil windings. The winding loss and magnetic energy in MFTs in the medium-frequency range are calculated utilizing a finite element method (FEM) using common triangular and alternative rectilinear mesh elements. Additionally, in order to improve the computational efficiency of the calculations, a spectral element method (SEM) is coupled with a FEM, thus creating a hybrid FEM–SEM formulation. In such a hybrid approach, the FEM is used to calculate the current density distribution in the two-dimensional (2D) cross-section of the foil conductors to achieve reliable accuracy, and the SEM is adopted in the nonconducting clearance distances of the winding window to reduce the system of equations. The comparative analysis of the calculated resistance and reactance of the under-study models showed that the FEM with rectilinear mesh elements and the FEM–SEM model outperformed the FEM with triangular mesh elements in terms of accuracy and computational cost. The hybrid FEM–SEM model enables a reduced system of equations for modeling the electromagnetic behavior of MFTs. This research provides valuable insights into both the computational approaches and meshing challenges in the analysis of MFTs and offers a foundation for future research on the design and optimization of MFTs.
本研究旨在提高存在大间隙距离和细箔绕组的中频变压器(MFT)频域分析的计算效率。研究采用有限元法(FEM),使用常见的三角形网格元素和替代的直线网格元素,计算了中频范围内中频变压器的绕组损耗和磁能。此外,为了提高计算效率,还将谱元法 (SEM) 与有限元法结合起来,从而创建了 FEM-SEM 混合公式。在这种混合方法中,有限元用于计算箔导体二维(2D)横截面上的电流密度分布,以达到可靠的精度,而 SEM 则用于计算绕组窗口的非导电间隙距离,以减少方程系统。对所研究模型的电阻和电抗计算结果进行的对比分析表明,采用直线网格元素的有限元模型和 FEM-SEM 模型在精度和计算成本方面均优于采用三角形网格元素的有限元模型。FEM-SEM 混合模型可减少用于 MFT 电磁行为建模的方程系统。这项研究为 MFT 分析中的计算方法和网格划分挑战提供了宝贵的见解,并为未来 MFT 的设计和优化研究奠定了基础。
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引用次数: 0
Relationship between Plasma Lipopolysaccharide Concentration and Health Status in Healthy Subjects and Patients with Abnormal Glucose Metabolism in Japan: A Preliminary Cross-Sectional Study 日本健康受试者和葡萄糖代谢异常患者血浆脂多糖浓度与健康状况之间的关系:初步横断面研究
J
Pub Date : 2023-11-30 DOI: 10.3390/j6040040
Nobuo Fuke, Shojiro Sawada, T. Ito-Sasaki, Kumi Y. Inoue, Yusuke Ushida, Ikuo Sato, T. Matsue, Hideki Katagiri, Hiroyuki Ueda, Hiroyuki Suganuma
Lipopolysaccharides are components of Gram-negative bacteria. The relationship between blood lipopolysaccharide levels and health status has mainly been investigated in Europe, and there is a lack of information about Asia, particularly Japan. This study aimed to investigate the relationship between blood lipopolysaccharide levels and health status in the Japanese. We conducted two cross-sectional studies in 36 healthy subjects (Study 1) and 36 patients with abnormal glucose metabolism (AGM; Study 2). The plasma lipopolysaccharide concentration in healthy subjects was positively correlated with body mass index. The plasma lipopolysaccharide concentration in AGM patients was obviously higher than that in healthy subjects. Furthermore, in AGM patients, the plasma lipopolysaccharide concentration was positively correlated with C-peptide, fasting plasma glucose levels, triglycerides, and stage of diabetic nephropathy. The plasma lipopolysaccharide concentration was also negatively correlated with 20/(C-peptide × fasting plasma glucose), an indicator of insulin resistance, and high-density lipoprotein cholesterol. In particular, the correlation between plasma lipopolysaccharide concentration and triglycerides in AGM patients was maintained in multiple regression analyses adjusted for age, sex, or body mass index. These results suggest a possible role of lipopolysaccharides in obesity in healthy subjects and in the deterioration of triglyceride metabolism in AGM patients in the Japanese population.
脂多糖是革兰氏阴性细菌的成分。有关血液中脂多糖水平与健康状况之间关系的研究主要集中在欧洲,而有关亚洲,尤其是日本的研究还很缺乏。本研究旨在调查日本人血液中脂多糖水平与健康状况之间的关系。我们对 36 名健康受试者(研究 1)和 36 名糖代谢异常患者(研究 2)进行了两项横断面研究。健康受试者的血浆脂多糖浓度与体重指数呈正相关。AGM 患者的血浆脂多糖浓度明显高于健康人。此外,AGM 患者的血浆脂多糖浓度与 C 肽、空腹血浆葡萄糖水平、甘油三酯和糖尿病肾病分期呈正相关。血浆脂多糖浓度还与胰岛素抵抗指标 20/(C 肽×空腹血浆葡萄糖)和高密度脂蛋白胆固醇呈负相关。特别是,AGM 患者血浆脂多糖浓度与甘油三酯之间的相关性在调整了年龄、性别或体重指数后的多元回归分析中保持不变。这些结果表明,在日本人群中,脂多糖可能在健康人的肥胖和AGM患者的甘油三酯代谢恶化中发挥作用。
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引用次数: 0
Antioxidant Activity of Selected Medicinal Plants Used by Traditional Herbal Practitioners to Treat Cancer in Malawi 马拉维传统草药医师用于治疗癌症的部分药用植物的抗氧化活性
J
Pub Date : 2023-11-20 DOI: 10.3390/j6040039
F. F. Masumbu, J. Kamanula, A. Mwakikunga, Bonface Mwamatope, D. Tembo
This study evaluated the phytochemical composition and antioxidant activity of Piliostigma thonningii (Schumach.) Milne-Redh, Psorospermum febrifugum Spach, Inula glomerata Oliv. and Hiern, Zanthoxylum chalybeum Engl. and Monotes africanus A.DC., claimed to treat cancer by Malawian traditional herbal practitioners. Ground and dried plant extracts were analyzed for total phenolic content (TPC), total flavonoid content (TFC), total alkaloid content (TAC), ferric reducing antioxidant power (FRAP) and 2,2-Diphenyl-1-Picrylhydrazyl (DPPH) using standard assays. The TPC, TFC, and TAC ranged from 539 ± 2.70 to 4602 ± 32 mg GAE/g DW, 6.18 ± 0.03 to 64.04 ± 0.16 mg QE/g DW and 19.25 ± 0.07 to 76.05 ± 0.36 mg CE/g DW, respectively, and the variations were significant, p < 0.05. FRAP values ranged from 82.15 ± 0.7 to 687.28 ± 0.71 mg TEAC/g DW and decreased in the following order: P. thoningii (Schumach.) Milne-Redh > P. febrifugum Spach > M. africanus A.DC > Z. chalybeum Engl > I. glomerata Oliv. and Hiern. The scavenging activity (SA50) of the extracts ranged from 0.09 ± 0.01 to 1.57 ± 0.01 μg/mL of extract with P. thonningii (Schumach.) Milne-Redh showing the lowest value. Based on the levels of phenolic compounds and their antioxidant activity, the plants in this study could be considered for use as medicinal agents and sources of natural bioactive compounds and antioxidants.
本研究评估了马拉维传统草药从业者声称可治疗癌症的 Piliostigma thonningii (Schumach.) Milne-Redh、Psorospermum febrifugum Spach、Inula glomerata Oliv. and Hiern、Zanthoxylum chalybeum Engl. 和 Monotes africanus A.DC. 的植物化学成分和抗氧化活性。采用标准方法对研磨和干燥的植物提取物进行了总酚含量(TPC)、总黄酮含量(TFC)、总生物碱含量(TAC)、铁还原抗氧化力(FRAP)和 2,2-二苯基-1-苦基肼(DPPH)分析。TPC、TFC 和 TAC 分别为 539 ± 2.70 至 4602 ± 32 mg GAE/g DW、6.18 ± 0.03 至 64.04 ± 0.16 mg QE/g DW 和 19.25 ± 0.07 至 76.05 ± 0.36 mg CE/g DW,差异显著,P < 0.05。FRAP 值从 82.15 ± 0.7 到 687.28 ± 0.71 mg TEAC/g DW 不等,依次降低:P. thoningii (Schumach.) Milne-Redh > P. febrifugum Spach > M. africanus A.DC > Z. chalybeum Engl > I. glomerata Oliv.提取物的清除活性(SA50)介于 0.09 ± 0.01 至 1.57 ± 0.01 μg/mL 之间,其中 P. thonningii (Schumach.) Milne-Redh 的清除活性最低。根据酚类化合物的含量及其抗氧化活性,本研究中的植物可考虑用作药剂以及天然生物活性化合物和抗氧化剂的来源。
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引用次数: 0
Photocatalytic Reduction of Cr(VI) and Pb(II) with Biogenically Synthesized Copper Oxide Nanoparticles Using an Extract of the Myriophyllum spicatum Plant 生物合成氧化铜纳米粒子光催化还原Cr(VI)和Pb(II)的研究
J
Pub Date : 2023-10-31 DOI: 10.3390/j6040037
Opeyemi A. Oyewo, Seshibe S. Makgato
The biogenic synthesis of copper oxide nanoparticles was explored using the Myriophyllum spicatum plant through a process involving co-precipitation and was utilized as an effective photocatalyst for the reduction of Cr(VI) and Pb(II) ions in an aqueous solution. The plant-mediated CuO nanoparticles were characterized using microscopic techniques (TEM and SEM), FT-IR, and XRD analyses. The amount of the reduced metal ions was determined by UV–visible and Atomic Absorption (AA) spectrophotometers. The analyses of the functional group present in the leaf extract revealed the type of bioactive molecules that were involved in the formation of copper oxide nanoparticles. The nanoparticles were used in the photo-enhanced reduction of hexavalent Cr and divalent Pb ions, and the impact of solution pH, initial metal concentrations, and photocatalyst dosage was investigated to establish the optimal performance of the CuO nanoparticles. Results revealed a direct association between the reduction of metal ions and catalyst dosage in both cases. A maximum percentage reduction of 89.2% and 79.1% was achieved for Cr(VI) and Pb(II), respectively, using 3 g of the CuO nanoparticles. This confirms that the CuO nanoparticles exhibited higher efficiency for Cr(VI) reduction as compared to Pb(II) reduction and indicates that CuO nanoparticles are a promising photocatalyst that is capable of reducing these metal ions into less toxic products.
利用狐尾豆科植物共沉淀法研究了氧化铜纳米粒子的生物合成,并将其作为一种有效的光催化剂用于还原水溶液中的Cr(VI)和Pb(II)离子。采用TEM、SEM、FT-IR和XRD等显微技术对植物介导的CuO纳米颗粒进行了表征。用紫外可见分光光度计和原子吸收分光光度计测定金属离子的还原量。对叶提取物中存在的官能团的分析揭示了参与氧化铜纳米颗粒形成的生物活性分子的类型。将纳米CuO用于光增强还原六价Cr和二价Pb离子,并考察了溶液pH、初始金属浓度和光催化剂用量对CuO纳米粒子性能的影响。结果表明,在这两种情况下,金属离子的还原与催化剂用量之间存在直接关联。3 g CuO纳米颗粒对Cr(VI)和Pb(II)的最大还原率分别为89.2%和79.1%。这证实了CuO纳米颗粒对Cr(VI)的还原比Pb(II)的还原效率更高,表明CuO纳米颗粒是一种很有前途的光催化剂,能够将这些金属离子还原成毒性较小的产物。
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引用次数: 0
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J
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