Pub Date : 2024-08-09DOI: 10.1134/S0036023624600631
P. G. Gagarin, A. V. Guskov, V. Guskov, G. Nikiforova, K. S. Gavrcihev
{"title":"Heat Capacity and Thermal Expansion of LaMgAl_11O_19","authors":"P. G. Gagarin, A. V. Guskov, V. Guskov, G. Nikiforova, K. S. Gavrcihev","doi":"10.1134/S0036023624600631","DOIUrl":"https://doi.org/10.1134/S0036023624600631","url":null,"abstract":"","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141921448","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-09DOI: 10.1134/S003602362460062X
T. G. Cherkasova, N. Pervukhina, N. V. Kuratieva, T. V. Panasina, Yu. R. Giniyatullina, E. S. Tatarinova, E. V. Cherkasova
{"title":"Crystal Structures of Solids Produced by Reacting ε-Caprolactam with Hydrofluorosilicic Acid and Copper(II) Hexafluorosilicate","authors":"T. G. Cherkasova, N. Pervukhina, N. V. Kuratieva, T. V. Panasina, Yu. R. Giniyatullina, E. S. Tatarinova, E. V. Cherkasova","doi":"10.1134/S003602362460062X","DOIUrl":"https://doi.org/10.1134/S003602362460062X","url":null,"abstract":"","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141922221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-09DOI: 10.1134/s003602362460103x
N. M. Murashova, M. Y. Kuptsova, P. O. Tokarev
{"title":"Synthesis of Zinc Oxide Nanoparticles during the Processing of Galvanic Sludges","authors":"N. M. Murashova, M. Y. Kuptsova, P. O. Tokarev","doi":"10.1134/s003602362460103x","DOIUrl":"https://doi.org/10.1134/s003602362460103x","url":null,"abstract":"","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141922861","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-09DOI: 10.1134/S0036023624600643
S. E. Maksimov, K. O. Yanushkevich, D. Tishkevich, V. E. Borisenko
{"title":"Structure and Photocatalytic Activity of Composites of Semiconducting Nanoparticles in Polymethyl Мethacrylate","authors":"S. E. Maksimov, K. O. Yanushkevich, D. Tishkevich, V. E. Borisenko","doi":"10.1134/S0036023624600643","DOIUrl":"https://doi.org/10.1134/S0036023624600643","url":null,"abstract":"","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141923929","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-09DOI: 10.1134/s0036023624600059
A. V. Golubev, D. V. Baltovskaya, A. S. Kubasov, A. Bykov, K. Zhizhin, N. Kuznetsov
{"title":"Synthesis of 1,10-Disulfanyl-closo-Decaborate Anion and Its Disulfonium Tetraacetylamide Derivative","authors":"A. V. Golubev, D. V. Baltovskaya, A. S. Kubasov, A. Bykov, K. Zhizhin, N. Kuznetsov","doi":"10.1134/s0036023624600059","DOIUrl":"https://doi.org/10.1134/s0036023624600059","url":null,"abstract":"","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141924954","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-09DOI: 10.1134/s0036023624601065
Yu. S. Haiduk, E. V. Korobko, L. V. Radkevich, R. P. Golodok, A. E. Usenka, V. V. Pankov
Abstract
Iron(II) manganese(II) ferrite Mn0.3Fe2.7O4 was synthesized by co-precipitation (with various options for the subsequent heat and mechanical treatment of the precipitate). The material was studied by powder X-ray diffraction, infrared spectroscopy, scanning electron microscopy, and magnetometry. The powder that was annealed under argon at 740°С (8.0 h) and subjected to high-energy milling (1.0 h) at the final stage of the synthesis is a promising functional filler for magnetorheological materials, owing to high shear stress (3500 Pa at 625 mT) of an oil suspension based on this powder and high oil absorption capacity, which ensures sedimentation stability of the suspension.
{"title":"Synthesis, Structure, and Magnetic Properties of Mn-Substituted Magnetite for Magnetorheological Materials","authors":"Yu. S. Haiduk, E. V. Korobko, L. V. Radkevich, R. P. Golodok, A. E. Usenka, V. V. Pankov","doi":"10.1134/s0036023624601065","DOIUrl":"https://doi.org/10.1134/s0036023624601065","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Iron(II) manganese(II) ferrite Mn<sub>0.3</sub>Fe<sub>2.7</sub>O<sub>4</sub> was synthesized by co-precipitation (with various options for the subsequent heat and mechanical treatment of the precipitate). The material was studied by powder X-ray diffraction, infrared spectroscopy, scanning electron microscopy, and magnetometry. The powder that was annealed under argon at 740°С (8.0 h) and subjected to high-energy milling (1.0 h) at the final stage of the synthesis is a promising functional filler for magnetorheological materials, owing to high shear stress (3500 Pa at 625 mT) of an oil suspension based on this powder and high oil absorption capacity, which ensures sedimentation stability of the suspension.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141931535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-09DOI: 10.1134/s0036023624600874
A. S. Zyubin, T. Zyubina, O. V. Kravchenko, M. V. Solov’ev, V. P. Vasiliev, A. A. Zaitsev, A. V. Shikhovtsev, Yu. A. Dobrovol’sky
{"title":"Quantum–Chemical Simulation of Molecular Hydrogen Abstraction from Magnesium Borohydride Diammoniate","authors":"A. S. Zyubin, T. Zyubina, O. V. Kravchenko, M. V. Solov’ev, V. P. Vasiliev, A. A. Zaitsev, A. V. Shikhovtsev, Yu. A. Dobrovol’sky","doi":"10.1134/s0036023624600874","DOIUrl":"https://doi.org/10.1134/s0036023624600874","url":null,"abstract":"","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141922581","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-09DOI: 10.1134/S0036023624600102
A. V. Burchakov, I. Garkushin, E. M. Egorova, U. A. Emel’yanova, A. Finogenov
{"title":"Interactions in the Li^+,Na^+,K^+||F^–,Cl^– System and a 3D Model of the LiF–NaCl–KCl Stable Triangle","authors":"A. V. Burchakov, I. Garkushin, E. M. Egorova, U. A. Emel’yanova, A. Finogenov","doi":"10.1134/S0036023624600102","DOIUrl":"https://doi.org/10.1134/S0036023624600102","url":null,"abstract":"","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141923778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-09DOI: 10.1134/s0036023624601168
N. N. Bushuev, G. K. Tatosyan
Abstract
Co-crystallization of neodymium and strontium sulfates was studied using powder X-ray diffraction, energy dispersive X-ray spectroscopy, and microscopy. High absorption activity of crystalline matrices, trigonal SrSO4∙0.5H2O and dehydrated monoclinic SrSO4, towards the isomorphic heterovalent inclusion of Nd3+ ions to give solid solutions stable in the absence of water was established for the first time. The unit cell parameters and the structural similarity of the solid solutions were determined. In a moist environment, solid solutions degrade within 6–10 h to give stable poorly soluble single compounds Nd2(SO4)3∙8H2O and orthorhombic SrSO4.
摘要 利用粉末 X 射线衍射、能量色散 X 射线光谱和显微镜研究了钕和锶硫酸盐的共晶。首次确定了晶体基质(三棱 SrSO4∙0.5H2O 和脱水单斜 SrSO4)对 Nd3+ 离子的同构异价包合的高吸收活性,从而得到在无水条件下稳定的固溶体。确定了固溶体的单胞参数和结构相似性。在潮湿环境中,固溶体会在 6-10 小时内降解,生成稳定的难溶单一化合物 Nd2(SO4)3∙8H2O 和正方体 SrSO4。
{"title":"Study of Co-crystallization of Neodymium and Strontium Sulfates in the Absence of Potassium Ions","authors":"N. N. Bushuev, G. K. Tatosyan","doi":"10.1134/s0036023624601168","DOIUrl":"https://doi.org/10.1134/s0036023624601168","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Co-crystallization of neodymium and strontium sulfates was studied using powder X-ray diffraction, energy dispersive X-ray spectroscopy, and microscopy. High absorption activity of crystalline matrices, trigonal SrSO<sub>4</sub>∙0.5H<sub>2</sub>O and dehydrated monoclinic SrSO<sub>4</sub>, towards the isomorphic heterovalent inclusion of Nd<sup>3+</sup> ions to give solid solutions stable in the absence of water was established for the first time. The unit cell parameters and the structural similarity of the solid solutions were determined. In a moist environment, solid solutions degrade within 6–10 h to give stable poorly soluble single compounds Nd<sub>2</sub>(SO<sub>4</sub>)<sub>3</sub>∙8H<sub>2</sub>O and orthorhombic SrSO<sub>4</sub>.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141931496","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-09DOI: 10.1134/s0036023624600801
S. Zaitseva, S. Zdanovich, V. S. Sukharev, O. Koifman
{"title":"Chemical Generation and Reactivity of Highly Oxidized Oxo-Species of Water-Soluble μ-Carbido Ruthenium(IV) Sulfophthalocyaninate Dimer","authors":"S. Zaitseva, S. Zdanovich, V. S. Sukharev, O. Koifman","doi":"10.1134/s0036023624600801","DOIUrl":"https://doi.org/10.1134/s0036023624600801","url":null,"abstract":"","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141921209","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}