首页 > 最新文献

African Journal of Science and Technology最新文献

英文 中文
Statistical mechanics model for orientational motion of two-dimensional rigid rotator 二维刚性旋转器定向运动的统计力学模型
Pub Date : 2010-06-04 DOI: 10.4314/AJST.V6I2.55177
J. Malo
A comparison of thermodynamics properties of two-dimensional linear rigid rotator is presented in the absence, and presence of an impressed weak electric field at low and high temperatures. It is shown that specific heat and entropy fall off rapidly at low temperatures. At ultra low temperatures, the entire normal entropy is lost and we have complete ordering by the impressed field. In the classical limit it is shown that there is a temperature dependent polarizability
比较了二维线性刚性旋转体在低温和高温条件下外加弱电场和无外加弱电场条件下的热力学性质。结果表明,在低温下,比热和熵迅速下降。在超低温下,整个正常熵丢失,外加场完全有序。在经典极限下,证明了存在与温度相关的极化率
{"title":"Statistical mechanics model for orientational motion of two-dimensional rigid rotator","authors":"J. Malo","doi":"10.4314/AJST.V6I2.55177","DOIUrl":"https://doi.org/10.4314/AJST.V6I2.55177","url":null,"abstract":"A comparison of thermodynamics properties of two-dimensional linear rigid rotator is presented in the absence, and presence of an impressed weak electric field at low and high temperatures. It is shown that specific heat and entropy fall off rapidly at low temperatures. At ultra low temperatures, the entire normal entropy is lost and we have complete ordering by the impressed field. In the classical limit it is shown that there is a temperature dependent polarizability","PeriodicalId":7641,"journal":{"name":"African Journal of Science and Technology","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2010-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89478043","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of ground insulation and greenhouse microenvironment on the rate and quality of biogas production 地面保温和温室微环境对沼气产量和质量的影响
Pub Date : 2010-03-04 DOI: 10.4314/BJT.V18I2.52254
P. Cheruiyot, C. Ndiema, M. C. Chemelil, R. Wambua
A study was conducted at Egerton University, Njoro, Kenya to establish the potential of plastic digester to produce biogas under natural and greenhouse microenvironment. The specific objectives were to evaluate the effects of greenhouse and ground insulation on the rate and quality of biogas generation. A greenhouse measuring 6m long, 4m wide and 2m high was constructed. Inside the greenhouse and the outside environment, three replications of thirty (30)-litre plastic biogas digester filled to two third capacity with slurry were used. The digesters were partially exposed to the environment and when fully buried in the ground. Biogas yields averaged 90.3 and 63.0 litres per kilogramme (l/kg) of volatile solids added for partially buried digesters under greenhouse and natural conditions, respectively. The corresponding digester temperatures averaged 27.5 and 22.2 o C. The respective biogas yields averaged 312.8 and 226 litres per kilogramme volatile solid added, while the temperatures averaged 27.9 and 24.1 o C for fully buried digesters. The average methane content in the biogas was 61.5% and 56.4% under greenhouse and natural conditions, respectively. At the 0.05 significance level, greenhouse effect was found to enhance both the quantity and quality of biogas generation from dairy cattle dung. The effects of ground insulation had a far much effect on the quantity of biogas generation as compared to the effects of greenhouse conditions. Therefore ground insulation of plastic biogas digester under greenhouse conditions significantly enhances biogas generation. Keywords: Anaerobic conditions, greenhouse, natural conditions, ground insulation, greenhouse effect
在肯尼亚Njoro的Egerton大学进行了一项研究,以确定塑料沼气池在自然和温室微环境下产生沼气的潜力。具体目标是评估温室和地面隔热对沼气生成速率和质量的影响。建造了长6米、宽4米、高2米的温室。在温室内部和外部环境中,使用了三个三十(30)升的塑料沼气池,填充了泥浆的三分之二容量。消化器部分暴露在环境中,完全埋在地下。在温室和自然条件下,每公斤挥发性固体添加部分埋置沼气池的沼气产量平均分别为90.3升和63.0升。相应的沼气池温度平均为27.5℃和22.2℃。每添加一公斤挥发性固体,沼气产量平均为312.8升和226升,而全埋式沼气池的平均温度为27.9℃和24.1℃。温室和自然条件下沼气平均甲烷含量分别为61.5%和56.4%。在0.05显著水平下,温室效应显著提高了牛粪产气的数量和质量。与温室条件的影响相比,地面保温对沼气产生量的影响要大得多。因此,在温室条件下对塑料沼气池进行地面保温,可以显著提高沼气产量。关键词:厌氧条件,温室,自然条件,地面保温,温室效应
{"title":"Effects of ground insulation and greenhouse microenvironment on the rate and quality of biogas production","authors":"P. Cheruiyot, C. Ndiema, M. C. Chemelil, R. Wambua","doi":"10.4314/BJT.V18I2.52254","DOIUrl":"https://doi.org/10.4314/BJT.V18I2.52254","url":null,"abstract":"A study was conducted at Egerton University, Njoro, Kenya to establish the potential of plastic digester to produce biogas under natural and greenhouse microenvironment. The specific objectives were to evaluate the effects of greenhouse and ground insulation on the rate and quality of biogas generation. A greenhouse measuring 6m long, 4m wide and 2m high was constructed. Inside the greenhouse and the outside environment, three replications of thirty (30)-litre plastic biogas digester filled to two third capacity with slurry were used. The digesters were partially exposed to the environment and when fully buried in the ground. Biogas yields averaged 90.3 and 63.0 litres per kilogramme (l/kg) of volatile solids added for partially buried digesters under greenhouse and natural conditions, respectively. The corresponding digester temperatures averaged 27.5 and 22.2 o C. The respective biogas yields averaged 312.8 and 226 litres per kilogramme volatile solid added, while the temperatures averaged 27.9 and 24.1 o C for fully buried digesters. The average methane content in the biogas was 61.5% and 56.4% under greenhouse and natural conditions, respectively. At the 0.05 significance level, greenhouse effect was found to enhance both the quantity and quality of biogas generation from dairy cattle dung. The effects of ground insulation had a far much effect on the quantity of biogas generation as compared to the effects of greenhouse conditions. Therefore ground insulation of plastic biogas digester under greenhouse conditions significantly enhances biogas generation. Keywords: Anaerobic conditions, greenhouse, natural conditions, ground insulation, greenhouse effect","PeriodicalId":7641,"journal":{"name":"African Journal of Science and Technology","volume":"36 1","pages":"23-33"},"PeriodicalIF":0.0,"publicationDate":"2010-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81695057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
L'OR, LE ZIRCON ET LA TOURMALINE : TRACEURS DE L'ORIGINE DES MATERIAUX DES PROFILS LATERITIQUES D'AFRIQUE 金、锆石和电气石:非洲红土剖面材料起源的示踪剂
Pub Date : 2009-07-28 DOI: 10.4314/AJST.V2I2.44667
M. Ouangrawa, Fr Yongue
The thick lateritic cover of tropical zones are often considered as old soils which have undergone several evolutionary cycles throughout time. Nevertheless, they contain some resistant minerals like gold, zircon and tourmaline which remain after surficial processes.These residual minerals, used as tracers of the genesis and evolution of laterites, have enabled us to identify the differents layers of the profile. They are also useful in demonstrating the presence or absence of filiation with the substratum. In an auriferous region of the soudano-sahelian zone of Burkina Faso, gold and zircon have been accumulated on non-mineralized granites, by physical transport. The chemical transfer of iron has cimented and protect this allochtonous material, forming an iron crust. In the ultrabasic region of the humid tropical zone of Cameroon, chemical transfers made up mainly of aluminium from acid country rocks, have favoured the individualization of manganesiferous phases bearing cobalt and nickel. Physical transport also occur and is revealed by the presence of residual tourmaline grains, mainly in the upper part of the profiles, thus reworked and semiautochtonous.
热带地区的厚红土覆盖层通常被认为是古老的土壤,在整个时间里经历了几个进化循环。然而,它们含有一些抗性矿物,如金、锆石和电气石,这些矿物经过表面处理后仍会残留下来。这些残余矿物作为红土成因和演化的示踪剂,使我们能够识别剖面的不同层。它们在证明与基质是否有亲缘关系方面也很有用。在布基纳法索的索达诺-萨赫勒地区的一个含金地区,金和锆石通过物理运输积聚在未矿化的花岗岩上。铁的化学转移强化并保护了这种异质物质,形成了铁外壳。在喀麦隆潮湿热带地区的超基性地区,主要由酸性乡村岩石中的铝组成的化学转移有利于含钴和镍的含锰相的个别化。物理输运也会发生,主要表现在剖面上部残留的电气石颗粒,因此是重新加工和半自生的。
{"title":"L'OR, LE ZIRCON ET LA TOURMALINE : TRACEURS DE L'ORIGINE DES MATERIAUX DES PROFILS LATERITIQUES D'AFRIQUE","authors":"M. Ouangrawa, Fr Yongue","doi":"10.4314/AJST.V2I2.44667","DOIUrl":"https://doi.org/10.4314/AJST.V2I2.44667","url":null,"abstract":"The thick lateritic cover of tropical zones are often considered as old soils which have undergone several evolutionary cycles throughout time. Nevertheless, they contain some resistant minerals like gold, zircon and tourmaline which remain after surficial processes.These residual minerals, used as tracers of the genesis and evolution of laterites, have enabled us to identify the differents layers of the profile. They are also useful in demonstrating the presence or absence of filiation with the substratum. In an auriferous region of the soudano-sahelian zone of Burkina Faso, gold and zircon have been accumulated on non-mineralized granites, by physical transport. The chemical transfer of iron has cimented and protect this allochtonous material, forming an iron crust. In the ultrabasic region of the humid tropical zone of Cameroon, chemical transfers made up mainly of aluminium from acid country rocks, have favoured the individualization of manganesiferous phases bearing cobalt and nickel. Physical transport also occur and is revealed by the presence of residual tourmaline grains, mainly in the upper part of the profiles, thus reworked and semiautochtonous.","PeriodicalId":7641,"journal":{"name":"African Journal of Science and Technology","volume":"45 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2009-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81553311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
INFLUENCE OF FERMENTATION AND COWPEA STEAMING ON SOME QUALITY CHARACTERISTICS OF MAIZE-COWPEA BLENDS 发酵和豇豆蒸熟对玉米-豇豆混酿品质特性的影响
Pub Date : 2009-07-28 DOI: 10.4314/AJST.V2I2.44674
S. Sefa-Dedeh, Y. Kluvitse, E. Afoakwa
Fermentation and cowpea steaming can be used to improve the protein quality and quantity of fermented maize dough. In the production of maize-cowpea blends, it is important that the quality characteristics are evaluated to determine their functionality in the products. A 5x4x2x2 factorial experiment with cowpea level, fermentation time, cowpea steaming time and fermentation method as the variable was performed. The cowpeas were dehulled, steamed, dried at 65EC for 24 hours and milled into flours. Maize was soaked in water (18 hours), drained and milled into flour. The maize-cowpea blends were made into a 50% moisture dough, fermented for the specified periods, dried at 65EC and milled into flour. Samples were evaluated for pH, titratable acidity, water absorption and sugars. The pH and titratable acidity of the samples were affected by fermentation time, steaming time, and the levels of cowpeas in the blend. Cowpeas was the main source of glucose/galactose. Fermentation caused a reduction in stacchyose and glucose/galactose. The mixing of cowpea flour with fermented maize dough prior to drying (single component fermentation) gave similar effects on sugar concentrations as detected in the co-fermented samples (multi-component fermentation). Fermentation and steamed cowpea fortification can be used to produce high protein fermented cereal foods with reduced anti-nutritional factors.
采用发酵和豇豆蒸法可以提高玉米发酵面团的蛋白质质量和数量。在玉米-豇豆混合物的生产中,评估其质量特性以确定其在产品中的功能是很重要的。以豇豆水平、发酵时间、豇豆蒸煮时间和发酵方式为变量,进行5x4x2x2的析因试验。豇豆去皮,蒸熟,在65摄氏度下干燥24小时,磨成面粉。将玉米浸泡在水中(18小时),沥干水分,磨成面粉。将玉米和豇豆混合制成含水量为50%的面团,在规定的时间内发酵,在65摄氏度下干燥,然后磨成面粉。评估样品的pH值,可滴定酸度,吸水率和糖。样品的pH值和可滴定酸度受发酵时间、蒸煮时间和混和物中豇豆含量的影响。豇豆是葡萄糖/半乳糖的主要来源。发酵导致了断糖和葡萄糖/半乳糖的减少。在干燥前将豇豆粉与发酵的玉米面团混合(单组分发酵)对糖浓度的影响与在共发酵样品(多组分发酵)中检测到的相似。发酵和蒸豇豆强化可用于生产高蛋白发酵谷物食品,降低抗营养因子。
{"title":"INFLUENCE OF FERMENTATION AND COWPEA STEAMING ON SOME QUALITY CHARACTERISTICS OF MAIZE-COWPEA BLENDS","authors":"S. Sefa-Dedeh, Y. Kluvitse, E. Afoakwa","doi":"10.4314/AJST.V2I2.44674","DOIUrl":"https://doi.org/10.4314/AJST.V2I2.44674","url":null,"abstract":"Fermentation and cowpea steaming can be used to improve the protein quality and quantity of fermented maize dough. In the production of maize-cowpea blends, it is important that the quality characteristics are evaluated to determine their functionality in the products. A 5x4x2x2 factorial experiment with cowpea level, fermentation time, cowpea steaming time and fermentation method as the variable was performed. The cowpeas were dehulled, steamed, dried at 65EC for 24 hours and milled into flours. Maize was soaked in water (18 hours), drained and milled into flour. The maize-cowpea blends were made into a 50% moisture dough, fermented for the specified periods, dried at 65EC and milled into flour. Samples were evaluated for pH, titratable acidity, water absorption and sugars. The pH and titratable acidity of the samples were affected by fermentation time, steaming time, and the levels of cowpeas in the blend. Cowpeas was the main source of glucose/galactose. Fermentation caused a reduction in stacchyose and glucose/galactose. The mixing of cowpea flour with fermented maize dough prior to drying (single component fermentation) gave similar effects on sugar concentrations as detected in the co-fermented samples (multi-component fermentation). Fermentation and steamed cowpea fortification can be used to produce high protein fermented cereal foods with reduced anti-nutritional factors.","PeriodicalId":7641,"journal":{"name":"African Journal of Science and Technology","volume":"39 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2009-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83173790","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 35
Hydrobiological studies on Ibiekuma river at Ekpoma, Southern Nigeria, after impoundment: The faunal characteristics 尼日利亚南部埃克波马Ibiekuma河蓄水后的水生生物学研究:区系特征
Pub Date : 2009-07-28 DOI: 10.4314/AJST.V2I1.44647
C. A. Edokpayi, E. C. Osimen
A study of a 3 Km stretch of a perennial rainforest stream in southern Nigeria describes the macrobenthic faunal characteristics of pools (dam site stations) and runs. A total of 84 invertebrate taxa made up of 2,535 individuals were recorded. The overall faunal abundance was not significantly different at the study stretch. The abundance of the major taxonomic groups was however significantly different (P < 0.05) at the study stations. Hemiptera and Diptera were the most abundant invertebrate groups recorded. The high number of benthic invertebrates observed is a reflection of the physical and chemical stability of the study stream.
一项对尼日利亚南部一段长3公里的多年生雨林溪流的研究描述了水库(水坝站点)和河流的大型底栖动物的动物特征。共记录无脊椎动物类群84个,个体2535个。在研究区间内,总区系丰度无显著差异。各试验站主要类群的丰度差异有统计学意义(P < 0.05)。半翅目和双翅目是记录最多的无脊椎动物类群。观察到的大量底栖无脊椎动物反映了研究流的物理和化学稳定性。
{"title":"Hydrobiological studies on Ibiekuma river at Ekpoma, Southern Nigeria, after impoundment: The faunal characteristics","authors":"C. A. Edokpayi, E. C. Osimen","doi":"10.4314/AJST.V2I1.44647","DOIUrl":"https://doi.org/10.4314/AJST.V2I1.44647","url":null,"abstract":"A study of a 3 Km stretch of a perennial rainforest stream in southern Nigeria describes the macrobenthic faunal characteristics of pools (dam site stations) and runs. A total of 84 invertebrate taxa made up of 2,535 individuals were recorded. The overall faunal abundance was not significantly different at the study stretch. The abundance of the major taxonomic groups was however significantly different (P < 0.05) at the study stations. Hemiptera and Diptera were the most abundant invertebrate groups recorded. The high number of benthic invertebrates observed is a reflection of the physical and chemical stability of the study stream.","PeriodicalId":7641,"journal":{"name":"African Journal of Science and Technology","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2009-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81025162","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 24
ACTIVATION OF CYCLOPENTANE IN AQUEOUS MEDIUM AND AT ROOM TEMPERATURE USING TRIS-BIPYRIDINE RUTHENIUM COMPLEX AS A PHOTOSENSITIZER. 用三联吡啶钌络合物作为光敏剂在水介质和室温下活化环戊烷。
Pub Date : 2009-07-28 DOI: 10.4314/AJST.V2I2.44665
Nj Njapba, W. Waltz
In this study, the use of a transition metal complex, tris (2,2-bipyridine) ruthenium (II) as a photosensitizer to convert cyclopentane into other compounds in an aqueous medium and at room temperature and pressure has been investigated. Peroxydisulphate ion has been used as a radical source. The irradiation of the solutions have been carried out at 436- nm wavelength using a high pressure mercury lamp for the light source. Cyclopentanol and cyclopentanone have been obtained as organic products. The products were detected and characterized using gas chromatography and mass spectrometry methods. They were formed at concentration levels of 10- 4M. The quantum yields of total product formation were about 0.2 at a light intensity of 5 x 1016 quanta/s. Dans cette etude, l’utilisation d’un complexe du metal de transition, le tris (bipyridine-2,2) ruthenium (II), comme photosensibilisateur pour transformer le cyclopentane en d’autres composes dans un milieu aqueux et a temperature et pression ambiantes a ete examine. Nous avons utilise l’ion peroxydisulfate comme souce radicale. L’irradiation des solutions s’est effectuee a 436 nm de longueur d’onde avec utilisation d’une lampe de mercure a forte pression pour la source lumineuse. Nous avons obtenu du cyclopentanol et de la cyclopentanone comme produits organiques. Pour la detection et la caracterisation des produits, nous avons eu recours aux methodes de chromatographie de gaz et de spectrometrie de masse. Les produits etaient formes a des niveaux de concentration de 10-4 M. Les rapports quantiques de la formation totale des produits etaient d’environ 0,2 pour une intensite lumineuse de 5 x 1016 quanta/s. Dans cette etude, l’utilisation d’un complexe du metal de transition, le tris (bipyridine-2,2) ruthenium (II), comme  photosensibilisateur pour transformer le cyclopentane en d’autres composes dans un milieu aqueux et a temperature et pression ambiantes a ete examine. Nous avons utilise l’ion peroxydisulfate comme souce radicale. L’irradiation des solutions s’est effectuee a 436 nm de longueur d’onde avec utilisation d’une lampe de mercure a forte pression pour la source lumineuse. Nous avons obtenu du cyclopentanol et de la cyclopentanone comme produits organiques. Pour la detection et la caracterisation des produits, nous avons eu recours aux methodes de chromatographie de gaz et de spectrometrie de masse. Les produits etaient formes a des niveaux de concentration de 10-4 M. Les rapports quantiques de la formation totale des produits etaient d’environ 0,2 pour une intensite lumineuse de 5 x 1016 quanta/s.
在本研究中,研究了利用过渡金属配合物三(2,2-联吡啶)钌(II)作为光敏剂,在水介质和室温常压下将环戊烷转化为其他化合物。过氧化二硫酸盐离子已被用作自由基源。用高压汞灯作为光源,对溶液进行了436nm波长的辐照。环戊醇和环戊酮是有机产物。采用气相色谱法和质谱法对产物进行了检测和表征。它们在浓度水平为10- 4M时形成。在5 × 1016量子/秒的光强下,总产物形成的量子产率约为0.2。在这个练习曲,l 'utilisation d一个complexe du金属过渡,勒三羟甲基氨基甲烷(bipyridine-2, 2)钌(II)液,像photosensibilisateur倒变压器le环戊烷在联合国环境中其他组成aqueux等温度等压力ambiantes疾病检查。现在雅芳使用过硫酸氢离子作为自由基源。L '辐照解决方案的最佳效果是436 nm的长时间的d 'onde平均利用d 'une灯的汞灯,一个强大的压力倾泻光源发光。环戊醇和环戊酮的合成产物。对产品进行检测和表征,采用色谱法、气相法、质谱法等多种方法进行检测和表征。Les产品质量形成了一个浓度为10-4 m的产品质量形成了一个浓度为10-4 m的产品质量形成了一个浓度为5 × 1016量子/s的产品质量形成总量。在这个练习曲,l 'utilisation d一个complexe du金属过渡,勒三羟甲基氨基甲烷(bipyridine-2, 2)钌(II)液,像photosensibilisateur倒变压器le环戊烷在联合国环境中其他组成aqueux等温度等压力ambiantes疾病检查。现在雅芳使用过硫酸氢离子作为自由基源。L '辐照解决方案的最佳效果是436 nm的长时间的d 'onde平均利用d 'une灯的汞灯,一个强大的压力倾泻光源发光。环戊醇和环戊酮的合成产物。对产品进行检测和表征,采用色谱法、气相法、质谱法等多种方法进行检测和表征。Les产品质量形成了一个浓度为10-4 m的产品质量形成了一个浓度为10-4 m的产品质量形成了一个浓度为5 × 1016量子/s的产品质量形成总量。
{"title":"ACTIVATION OF CYCLOPENTANE IN AQUEOUS MEDIUM AND AT ROOM TEMPERATURE USING TRIS-BIPYRIDINE RUTHENIUM COMPLEX AS A PHOTOSENSITIZER.","authors":"Nj Njapba, W. Waltz","doi":"10.4314/AJST.V2I2.44665","DOIUrl":"https://doi.org/10.4314/AJST.V2I2.44665","url":null,"abstract":"In this study, the use of a transition metal complex, tris (2,2-bipyridine) ruthenium (II) as a photosensitizer to convert cyclopentane into other compounds in an aqueous medium and at room temperature and pressure has been investigated. Peroxydisulphate ion has been used as a radical source. The irradiation of the solutions have been carried out at 436- nm wavelength using a high pressure mercury lamp for the light source. Cyclopentanol and cyclopentanone have been obtained as organic products. The products were detected and characterized using gas chromatography and mass spectrometry methods. They were formed at concentration levels of 10- 4M. The quantum yields of total product formation were about 0.2 at a light intensity of 5 x 1016 quanta/s. Dans cette etude, l’utilisation d’un complexe du metal de transition, le tris (bipyridine-2,2) ruthenium (II), comme photosensibilisateur pour transformer le cyclopentane en d’autres composes dans un milieu aqueux et a temperature et pression ambiantes a ete examine. Nous avons utilise l’ion peroxydisulfate comme souce radicale. L’irradiation des solutions s’est effectuee a 436 nm de longueur d’onde avec utilisation d’une lampe de mercure a forte pression pour la source lumineuse. Nous avons obtenu du cyclopentanol et de la cyclopentanone comme produits organiques. Pour la detection et la caracterisation des produits, nous avons eu recours aux methodes de chromatographie de gaz et de spectrometrie de masse. Les produits etaient formes a des niveaux de concentration de 10-4 M. Les rapports quantiques de la formation totale des produits etaient d’environ 0,2 pour une intensite lumineuse de 5 x 1016 quanta/s. Dans cette etude, l’utilisation d’un complexe du metal de transition, le tris (bipyridine-2,2) ruthenium (II), comme  photosensibilisateur pour transformer le cyclopentane en d’autres composes dans un milieu aqueux et a temperature et pression ambiantes a ete examine. Nous avons utilise l’ion peroxydisulfate comme souce radicale. L’irradiation des solutions s’est effectuee a 436 nm de longueur d’onde avec utilisation d’une lampe de mercure a forte pression pour la source lumineuse. Nous avons obtenu du cyclopentanol et de la cyclopentanone comme produits organiques. Pour la detection et la caracterisation des produits, nous avons eu recours aux methodes de chromatographie de gaz et de spectrometrie de masse. Les produits etaient formes a des niveaux de concentration de 10-4 M. Les rapports quantiques de la formation totale des produits etaient d’environ 0,2 pour une intensite lumineuse de 5 x 1016 quanta/s.","PeriodicalId":7641,"journal":{"name":"African Journal of Science and Technology","volume":"62 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2009-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88285801","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption isotherme de l’acide acétique par des charbons d’origine végétale 植物源煤对醋酸的等温吸附
Pub Date : 2009-07-28 DOI: 10.4314/AJST.V2I2.44663
Jérôme Avom, Jk Mbadcam, Mrl Matip, P. Germain
The adsorption properties of six samples of carbons of which two are obtained from AYOUS (Triplochiton Scleroxylon), two from AKOM (Terminalia Superba) and two obtained commercially were studied from their adsorption isotherms of acetic acid at 30° and 45°C. This study has resulted in the determination of the two types of adsorption isotherms : the Freundlich and Langmuir type I adsorption isotherms. The maximum capacities of adsorption vary between 0,98 x 10-4mol/g and 18,3 x 10-4 mol/g. The heat adsorption obtained have values < 40 kJ/mol indicating a physical and exothermic type adsorption.
研究了6个碳样品的吸附性能,其中2个来自AYOUS (Triplochiton Scleroxylon), 2个来自AKOM (Terminalia Superba)和2个来自工业生产的碳样品在30°和45°C下对乙酸的吸附等温线。本研究确定了两种类型的吸附等温线:Freundlich和Langmuir I型吸附等温线。最大吸附量在0,98 × 10-4mol/g和18.3 × 10-4mol/g之间变化。所得热吸附值< 40 kJ/mol,为物理和放热型吸附。
{"title":"Adsorption isotherme de l’acide acétique par des charbons d’origine végétale","authors":"Jérôme Avom, Jk Mbadcam, Mrl Matip, P. Germain","doi":"10.4314/AJST.V2I2.44663","DOIUrl":"https://doi.org/10.4314/AJST.V2I2.44663","url":null,"abstract":"The adsorption properties of six samples of carbons of which two are obtained from AYOUS (Triplochiton Scleroxylon), two from AKOM (Terminalia Superba) and two obtained commercially were studied from their adsorption isotherms of acetic acid at 30° and 45°C. This study has resulted in the determination of the two types of adsorption isotherms : the Freundlich and Langmuir type I adsorption isotherms. The maximum capacities of adsorption vary between 0,98 x 10-4mol/g and 18,3 x 10-4 mol/g. The heat adsorption obtained have values < 40 kJ/mol indicating a physical and exothermic type adsorption.","PeriodicalId":7641,"journal":{"name":"African Journal of Science and Technology","volume":"43 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2009-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88531287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 26
Évolution géochimique des formations latéritiques dans l’écosystème périforestier du sud-est cameroun : le site de kandara. 喀麦隆东南部森林周边生态系统中红土地层的地球化学演化:坎达拉遗址。
Pub Date : 2009-07-28 DOI: 10.4314/AJST.V2I1.44631
G. Ekodeck, V. Beyala, Ni Konfor
Kandara is representative of the ecosystem of the forest borderline of South-East Cameroon. It is characterized by a mosaic of small forest units mingled in the savanna. A thick and complex lateritic cover made of indurated and clayey lithic groups which serve as the substratum for the vegetation. The analysis of the laterites in Kandara reveal their petrologic characteristics, their interrelations and geochemical changes. The genesis and evolution of these superficial formations could thus be defined, as well as the forest dynamics and the phytogeography. Kandara est representatif de l’ecosysteme periforestier du Sud-Est du Cameroun, caracterise par une mosaique d’unites forestieres qui s’imbriquent avec des ilots de savane. Une epaisse couverture pedologique lateritique, entite complexe ou s’harmonisent des ensembles lithiques indures et meubles, sert de support a cette vegetation. Le decryptage des formations lateritiques de Kandara revele les caracteristiques petrologiques des ensembles, leurs relations mutuelles et leurs evolutions geochimiques. Il pourrait permettre de definir les etapes de la genese et de l’evolution de ces formations superficielles, de meme que leur influence sur la dynamique forestiere et la distribution phytogeographique.
坎达拉是喀麦隆东南部森林边界生态系统的代表。它的特点是混合在稀树草原上的小森林单元的马赛克。一种厚而复杂的红土覆盖物,由硬化和粘土岩屑群构成,作为植被的基质。通过对坎大拉红土的分析,揭示了其岩石学特征、相互关系和地球化学变化。因此,可以确定这些表层地层的成因和演化,以及森林动态和植物地理学。坎达拉是喀麦隆南部-东部森林生态系统的代表,其特点是森林的多样性和森林的多样性。单一的土壤结构,完整的复杂结构,和谐的整体结构,岩石结构和岩石结构,支撑着一个小的植被。坎大拉的地层特征揭示了岩石学的特征、相互关系的特征和演化的特征。它定义了物种的演化特征、地层的演化特征、表层结构特征、对动态森林的影响特征和分布地理特征。
{"title":"Évolution géochimique des formations latéritiques dans l’écosystème périforestier du sud-est cameroun : le site de kandara.","authors":"G. Ekodeck, V. Beyala, Ni Konfor","doi":"10.4314/AJST.V2I1.44631","DOIUrl":"https://doi.org/10.4314/AJST.V2I1.44631","url":null,"abstract":"Kandara is representative of the ecosystem of the forest borderline of South-East Cameroon. It is characterized by a mosaic of small forest units mingled in the savanna. A thick and complex lateritic cover made of indurated and clayey lithic groups which serve as the substratum for the vegetation. The analysis of the laterites in Kandara reveal their petrologic characteristics, their interrelations and geochemical changes. The genesis and evolution of these superficial formations could thus be defined, as well as the forest dynamics and the phytogeography. Kandara est representatif de l’ecosysteme periforestier du Sud-Est du Cameroun, caracterise par une mosaique d’unites forestieres qui s’imbriquent avec des ilots de savane. Une epaisse couverture pedologique lateritique, entite complexe ou s’harmonisent des ensembles lithiques indures et meubles, sert de support a cette vegetation. Le decryptage des formations lateritiques de Kandara revele les caracteristiques petrologiques des ensembles, leurs relations mutuelles et leurs evolutions geochimiques. Il pourrait permettre de definir les etapes de la genese et de l’evolution de ces formations superficielles, de meme que leur influence sur la dynamique forestiere et la distribution phytogeographique.","PeriodicalId":7641,"journal":{"name":"African Journal of Science and Technology","volume":"30 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2009-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81873869","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
STRUCTURAL EVOLUTION OF BODE SAADU AREA, SOUTHWESTERN NIGERIA 尼日利亚西南部bode saadu地区构造演化
Pub Date : 2009-07-28 DOI: 10.4314/AJST.V2I2.44666
C. Okonkwo
The Bode Saadu area comprises metasedimentary and metaigneous rocks which have been subjected to polyphase deformation and have subsequently been intruded by post-tectonic granitic rocks of probably Pan-African (600 ± 150Ma)age. Five phases of post-sedimentary tectonic deformation have been recognized in the rocks of this area. The first phase was associated with the development of the regional foliation, S1, and tight to isoclinal minor folds. The second phase involved heterogeneous deformation which gave rise to ductile shear zones, extensional and contractional faults. Second phase structures also include minor asymmetrical folds which deform S1 and S0. The third phase produced the dominant major folding on approximately N-S axis including the major Bode Saadu antiform. The fourth phase gave rise to open folds and crenulation of the earlier structures. Late brittle structures include transcurrent faults, both dextral and sinistral, which occasionally occurred in conjugate sets under generally N-S trending, maximum conpressive stress.
Bode Saadu地区由变质沉积岩和变质岩组成,它们经历了多期变形,随后被可能是泛非(600±150Ma)时代的后构造花岗质岩石侵入。该区岩石发育5期沉积后构造变形。第一阶段与区域片理S1和紧致至等斜小褶皱发育有关。第二阶段为非均质变形,形成韧性剪切带、伸展和收缩断裂。第二相结构还包括较小的不对称褶皱,使S1和S0变形。第三阶段产生了约N-S轴上的主要折叠,包括主要的Bode Saadu反形。第四阶段形成了早期构造的张开褶皱和砾岩作用。晚期脆性构造包括右向和左向的跨断层,它们偶尔出现在一般为N-S向、最大压应力下的共轭集合中。
{"title":"STRUCTURAL EVOLUTION OF BODE SAADU AREA, SOUTHWESTERN NIGERIA","authors":"C. Okonkwo","doi":"10.4314/AJST.V2I2.44666","DOIUrl":"https://doi.org/10.4314/AJST.V2I2.44666","url":null,"abstract":"The Bode Saadu area comprises metasedimentary and metaigneous rocks which have been subjected to polyphase deformation and have subsequently been intruded by post-tectonic granitic rocks of probably Pan-African (600 ± 150Ma)age. Five phases of post-sedimentary tectonic deformation have been recognized in the rocks of this area. The first phase was associated with the development of the regional foliation, S1, and tight to isoclinal minor folds. The second phase involved heterogeneous deformation which gave rise to ductile shear zones, extensional and contractional faults. Second phase structures also include minor asymmetrical folds which deform S1 and S0. The third phase produced the dominant major folding on approximately N-S axis including the major Bode Saadu antiform. The fourth phase gave rise to open folds and crenulation of the earlier structures. Late brittle structures include transcurrent faults, both dextral and sinistral, which occasionally occurred in conjugate sets under generally N-S trending, maximum conpressive stress.","PeriodicalId":7641,"journal":{"name":"African Journal of Science and Technology","volume":"5 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2009-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75453604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Response of meloidogyne hapla to mycorrhiza fungi inoculation on pyrethrum 除虫菊上接种菌根真菌对褐蝽的影响
Pub Date : 2009-07-28 DOI: 10.4314/AJST.V2I2.44673
J. Waceke, S. Waudo, R. Sikora
Five arbuscular mycorrhiza fungi (AMF) isolated from pyrethrum were screened in the greenhouse for efficacy in improving pyrethrum growth and in suppressing a root-knot nematode, Meloidogyne hapla. The fungi screened were Glomus spp. (isolates LM61, ML34 and ML35), Scutellospora sp. (isolate KS74) and Gigaspora sp. (isolate LM83). A 20g mixed fungal inoculum was incorporated into sterilized sand-soil mixture before transplanting 6-week-old pyrethrum seedlings. The inoculum consisted of the growth medium, spores, external mycelia and infected root segments. The plants were inoculated with 6000 M. hapla second stage juvenile (J-2) 3 months after fungal inoculation. Dry shoot weights, fresh root weights, percent root colonization by the fungi, nematode gall indices, number of eggs and females in the root system and number of J-2 in the soil were determined at the end of the experiment, two months after nematode inoculation. Glomus LM61 and Scutellospora KS74 significantly improved top biomasses of fungus-treated and fungus-nematodetreated plants. Glomus LM61was more effective (33% top biomass increase). Glomus ML34 and ML35 and Gigaspora LM83 improved top biomasses of fungus-nematode-treated plants. Scutellospora KS74 and Glomus ML34 significantly increased fresh root weights of pyrethrum by 45% and 50%, respectively. Glomus LM61, Scutellospora KS74 and Gigaspora LM83 caused 86%, 32% and 37% nematode suppression, respectively. All the fungal isolates significantly reduced the number of females and J-2. The presence of nematodes in fungus-treated plants did not affect root colonization by the fungi except in plants treated with Glomus ML34 and ML35.
从除虫菊中分离的5株丛枝菌根真菌(AMF)在温室中进行了促进除虫菊生长和抑制根结线虫(Meloidogyne hapla)的筛选。筛选到的真菌有Glomus spp.(分离株LM61、ML34和ML35)、Scutellospora sp.(分离株KS74)和Gigaspora sp.(分离株LM83)。在6周龄除虫菊幼苗移栽前,将20g混合真菌接种物加入无菌的沙土混合物中。接种物由培养基、孢子、外菌丝和侵染根段组成。接种真菌3个月后,用6000株M. hapla二期幼虫(J-2)接种植株。试验结束,即接种线虫2个月后,测定干梢重、鲜根重、真菌在根系上的定殖率、线虫瘿指数、根系中卵和雌虫的数量以及土壤中J-2的数量。Glomus LM61和Scutellospora KS74显著提高了真菌处理和真菌线虫处理植株的顶生物量。Glomus lm61更有效(最高生物量增加33%)。Glomus ML34、ML35和Gigaspora LM83提高了真菌线虫处理植株的顶生物量。Scutellospora KS74和Glomus ML34分别能显著提高除虫菊鲜根重45%和50%。Glomus LM61、Scutellospora KS74和Gigaspora LM83对线虫的抑制作用分别为86%、32%和37%。所有真菌分离株均显著降低了雌性和J-2的数量。除Glomus ML34和ML35处理植株外,真菌处理植株中线虫的存在不影响真菌的根定植。
{"title":"Response of meloidogyne hapla to mycorrhiza fungi inoculation on pyrethrum","authors":"J. Waceke, S. Waudo, R. Sikora","doi":"10.4314/AJST.V2I2.44673","DOIUrl":"https://doi.org/10.4314/AJST.V2I2.44673","url":null,"abstract":"Five arbuscular mycorrhiza fungi (AMF) isolated from pyrethrum were screened in the greenhouse for efficacy in improving pyrethrum growth and in suppressing a root-knot nematode, Meloidogyne hapla. The fungi screened were Glomus spp. (isolates LM61, ML34 and ML35), Scutellospora sp. (isolate KS74) and Gigaspora sp. (isolate LM83). A 20g mixed fungal inoculum was incorporated into sterilized sand-soil mixture before transplanting 6-week-old pyrethrum seedlings. The inoculum consisted of the growth medium, spores, external mycelia and infected root segments. The plants were inoculated with 6000 M. hapla second stage juvenile (J-2) 3 months after fungal inoculation. Dry shoot weights, fresh root weights, percent root colonization by the fungi, nematode gall indices, number of eggs and females in the root system and number of J-2 in the soil were determined at the end of the experiment, two months after nematode inoculation. Glomus LM61 and Scutellospora KS74 significantly improved top biomasses of fungus-treated and fungus-nematodetreated plants. Glomus LM61was more effective (33% top biomass increase). Glomus ML34 and ML35 and Gigaspora LM83 improved top biomasses of fungus-nematode-treated plants. Scutellospora KS74 and Glomus ML34 significantly increased fresh root weights of pyrethrum by 45% and 50%, respectively. Glomus LM61, Scutellospora KS74 and Gigaspora LM83 caused 86%, 32% and 37% nematode suppression, respectively. All the fungal isolates significantly reduced the number of females and J-2. The presence of nematodes in fungus-treated plants did not affect root colonization by the fungi except in plants treated with Glomus ML34 and ML35.","PeriodicalId":7641,"journal":{"name":"African Journal of Science and Technology","volume":"16 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2009-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88193980","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
期刊
African Journal of Science and Technology
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1