The dissolved chemistry of rivers has been extensively studied to elucidate physical and climatic controls of chemical weathering at local to global spatial scales, as well as the impacts of chemical weathering on climate over short to geologic temporal scales. Within this effort, mixing models with Monte Carlo uncertainty propagation are a common tool for inverting measurements of dissolved river chemistry to distinguish among contributions from end-members with distinct elemental and/or isotopic compositions. However, the methods underlying prior river inversion models have typically been opaque. Here we present Mixing Elements ANd Dissolved Isotopes in Rivers (MEANDIR), a set of MATLAB scripts that enable highly customizable inversion of dissolved river chemistry with Monte Carlo propagation of uncertainty. First, we present an overview of the mathematics underlying MEANDIR. This overview includes, among other topics, derivation of equations for mass balance, implementation of chlorine critical values, construction of cost functions, normalization to the sum of dissolved variables, quantification of river sulfate sourced from pyrite oxidation, resolution of petrogenic organic carbon oxidation, representation of secondary phase formation with isotopic fractionation, and calculation of the impact of weathering on atmospheric carbon dioxide. Second, we apply MEANDIR to five previously published datasets to demonstrate the sensitivity of results to parameter choices. We invert data from two global compilations of river chemistry (Gaillardet and others, 1999; Burke and others, 2018), the major element chemistry and sulfate sulfur isotope ratios of rivers in the Peruvian Amazon (Torres and others, 2016), the major element chemistry of Icelandic rivers (Gíslason and others, 1996), and the major and trace element chemistry of water samples from the Mackenzie River (Horan and others, 2019). MEANDIR and its user guide are freely available online.
{"title":"Presentation and applications of mixing elements and dissolved isotopes in rivers (MEANDIR), a customizable MATLAB model for Monte Carlo inversion of dissolved river chemistry","authors":"P. Kemeny, Mark A. Torres","doi":"10.2475/05.2021.03","DOIUrl":"https://doi.org/10.2475/05.2021.03","url":null,"abstract":"The dissolved chemistry of rivers has been extensively studied to elucidate physical and climatic controls of chemical weathering at local to global spatial scales, as well as the impacts of chemical weathering on climate over short to geologic temporal scales. Within this effort, mixing models with Monte Carlo uncertainty propagation are a common tool for inverting measurements of dissolved river chemistry to distinguish among contributions from end-members with distinct elemental and/or isotopic compositions. However, the methods underlying prior river inversion models have typically been opaque. Here we present Mixing Elements ANd Dissolved Isotopes in Rivers (MEANDIR), a set of MATLAB scripts that enable highly customizable inversion of dissolved river chemistry with Monte Carlo propagation of uncertainty. First, we present an overview of the mathematics underlying MEANDIR. This overview includes, among other topics, derivation of equations for mass balance, implementation of chlorine critical values, construction of cost functions, normalization to the sum of dissolved variables, quantification of river sulfate sourced from pyrite oxidation, resolution of petrogenic organic carbon oxidation, representation of secondary phase formation with isotopic fractionation, and calculation of the impact of weathering on atmospheric carbon dioxide. Second, we apply MEANDIR to five previously published datasets to demonstrate the sensitivity of results to parameter choices. We invert data from two global compilations of river chemistry (Gaillardet and others, 1999; Burke and others, 2018), the major element chemistry and sulfate sulfur isotope ratios of rivers in the Peruvian Amazon (Torres and others, 2016), the major element chemistry of Icelandic rivers (Gíslason and others, 1996), and the major and trace element chemistry of water samples from the Mackenzie River (Horan and others, 2019). MEANDIR and its user guide are freely available online.","PeriodicalId":7660,"journal":{"name":"American Journal of Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2021-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44008045","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In the northernmost segment of the Arabian–Nubian Shield, a post-collisional high-K calc-alkaline volcanic sequence is exposed along Wadi Abu Ma’amel, Eastern Desert of the Nubian Shield. It comprises a series of intermediate to silicic volcanics and associated pyroclastics that include the Imperial Porphyry and calc-alkaline volcanics typical of the Dokhan Volcanics. The Imperial Porphyry occurs as subvolcanic sill-like intrusions forming the young member of the Dokhan Volcanics. The volcanic sequence extruded through synorogenic granite and was intruded by post-collisional granite, which also caused thermal contact metamorphism. The red and purple colors of the Imperial Porphyry reflect hydrothermal alterations, which resulted in the formation of dispersed flakes of hematite, epidote, and piemontite. The entire high-K calc-alkaline volcanic sequence, ranging from andesite through dacite and rhyodacite, exhibits post-collisional geochemical characteristics. Most samples of the Imperial Porphyry and some of the typical Dokhan Volcanics have characteristics of adakitic rocks, including high Sr (694–889 ppm), low Y (10.6–18.8 ppm), high Sr/Y (41.1–83.8), (La/Yb)n (8.6–15.6), and low (Yb)n (5.4–9.0). The mostly calc-alkaline character and other traits of the studied volcanics that were previously interpreted to indicate arc magmatism reflect, instead, remelting of earlier (pre-collisional) arc-related material. The formation of Wadi Abu Ma'amel volcanics resulted from upwelling of hot asthenospheric material during thinning of the previously thickened lithosphere as a consequence of lithospheric delamination. The parental magma was generated by partial melting of mafic lower crust that mixed with upper-crust-derived magma. It evolved mostly through fractionation of clinopyroxene and plagioclase, accompanied by apatite and Fe–Ti oxides in the more-evolved dacitic and rhyodacitic rocks.
在阿拉伯-努比亚地盾的最北端，沿努比亚地盾东部沙漠Wadi Abu Ma 'amel暴露出一个碰撞后的高钾钙碱性火山序列。它由一系列中硅酸火山岩和伴生火山碎屑组成，其中包括帝国斑岩和多汗火山岩的典型钙碱性火山岩。帝国斑岩是次火山岩状侵入体，形成了多汗火山的年轻成员。火山层序在同造花岗岩中挤出，并被后碰撞花岗岩侵入，也引起了热接触变质作用。皇斑岩的红色和紫色反映了热液蚀变，这导致了赤铁矿、绿帘石和片铁矿的分散薄片的形成。整个高钾钙碱性火山序列，从安山岩到英安岩和流纹石，呈现出碰撞后的地球化学特征。大部分御斑岩样品和部分典型多罕火山岩样品具有高Sr (694 ~ 889 ppm)、低Y (10.6 ~ 18.8 ppm)、高Sr/Y(41.1 ~ 83.8)、(La/Yb)n(8.6 ~ 15.6)、低(Yb)n(5.4 ~ 9.0)的埃达质岩石特征。所研究的火山的主要钙碱性特征和其他特征先前被解释为表明弧岩浆作用，相反，反映了早期(碰撞前)与弧相关的物质的重熔。Wadi Abu Ma'amel火山的形成是由于岩石圈剥离导致先前增厚的岩石圈变薄期间，热软流圈物质上涌而成。母岩浆是由基性下地壳部分熔融与上地壳衍生岩浆混合形成的。它主要通过斜辉石和斜长石的分选演化而来，在较演化的英安岩和流纹岩中伴以磷灰石和铁钛氧化物。
{"title":"Origin and magmatic evolution of late Neoproterozoic post-accretion high-K calc-alkaline adakitic volcanics in the northern Arabian–Nubian Shield","authors":"Bassam A. Abuamarah, M. Azer, Heba S. Mubarak","doi":"10.2475/05.2021.02","DOIUrl":"https://doi.org/10.2475/05.2021.02","url":null,"abstract":"In the northernmost segment of the Arabian–Nubian Shield, a post-collisional high-K calc-alkaline volcanic sequence is exposed along Wadi Abu Ma’amel, Eastern Desert of the Nubian Shield. It comprises a series of intermediate to silicic volcanics and associated pyroclastics that include the Imperial Porphyry and calc-alkaline volcanics typical of the Dokhan Volcanics. The Imperial Porphyry occurs as subvolcanic sill-like intrusions forming the young member of the Dokhan Volcanics. The volcanic sequence extruded through synorogenic granite and was intruded by post-collisional granite, which also caused thermal contact metamorphism. The red and purple colors of the Imperial Porphyry reflect hydrothermal alterations, which resulted in the formation of dispersed flakes of hematite, epidote, and piemontite. The entire high-K calc-alkaline volcanic sequence, ranging from andesite through dacite and rhyodacite, exhibits post-collisional geochemical characteristics. Most samples of the Imperial Porphyry and some of the typical Dokhan Volcanics have characteristics of adakitic rocks, including high Sr (694–889 ppm), low Y (10.6–18.8 ppm), high Sr/Y (41.1–83.8), (La/Yb)n (8.6–15.6), and low (Yb)n (5.4–9.0). The mostly calc-alkaline character and other traits of the studied volcanics that were previously interpreted to indicate arc magmatism reflect, instead, remelting of earlier (pre-collisional) arc-related material. The formation of Wadi Abu Ma'amel volcanics resulted from upwelling of hot asthenospheric material during thinning of the previously thickened lithosphere as a consequence of lithospheric delamination. The parental magma was generated by partial melting of mafic lower crust that mixed with upper-crust-derived magma. It evolved mostly through fractionation of clinopyroxene and plagioclase, accompanied by apatite and Fe–Ti oxides in the more-evolved dacitic and rhyodacitic rocks.","PeriodicalId":7660,"journal":{"name":"American Journal of Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2021-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44121077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A thermodynamic model is formulated for (Ca,Na)2(Mg,Fe2+,Al,Fe3+)T1 (Al,Fe3+,Si)2T2O7 melilites. It employs the compositional vertices: åkermanite (Ca2MgSi2O7, 1), gehlenite (Ca2Al2SiO7, 2), iron åkermanite (Ca2Fe2+Si2O7, 3), ferrigehlenite (Ca2Fe23 + SiO7, 4), sodium melilite (NaCaAlSi2O7, 5), and the convergent ordering variables: s = XAl3 + T2a – XAl3+T2b and t = XFe3 + T2a – XFe3 + T2b to describe the distribution of Al3+, Fe3+ and Si4+ between T2 subsites T2a and T2b. It is calibrated for åkermanite–gehlenite melilites based on the calorimetric data of Charlu and others (1981), the assumption that the synthetic samples of Charlu and others approached “equilibrium” states of Al-Si tetrahedral ordering at 970 K, and analogy with the Al2(MgSi) − 1 substitution in CaMgSi2O6 – CaMg1/2Ti1/2AlSiO6 – CaAl2SiO6 fassaites (for example, Sack and Ghiorso, 2017). In this model gehlenite has a disordered Al-Si distribution on T2 sites above 1443 K (1170 °C), consistent with the crystallographic data on c/a ratios of lattice parameters as a function of annealing temperature (Woodhead and Waldbaum, 1974) and the high-temperature heat capacities inferred from drop calorimetric data (Pankratz and Kelley,1964). However, above this critical temperature a partially ordered Al-Si distribution persists between T2a and T2b sites in åkermanite – gehlenite solid solutions with intermediate X2 (for example, 0.19 < X2 < 0.89 at 1573 K). To a first approximation activity-composition relations of the gehlenite component approximate those of ideal mixing (that is, ai = Xi), particularly in gehlenite-rich compositions, but those of åkermanite component display pronounced temperature dependence in intermediate compositions. Enthalpies of formation of åkermanite and gehlenite from the elements at 298.15 K, ΔH¯f 298.15o AK and ΔH¯f 298.15o GEHL, consistent with the experimental brackets on decarbonation equilibria of Walter (1963), Hoschek (1974), and Shmulovich (1974), the thermodynamic model for åkermanite-gehlenite melilites developed here, the thermodynamic properties of the other phases in these reactions tabulated by Berman (1988), and the revised estimates for C¯p and S¯298.15o of diopside of Sack and Ghiorso (2017), are roughly 1 and 3 (kJ/gfw) more positive than those estimated by Berman (1988). More positive standard enthalpies of formation of both endmembers, together with a decrease in the vibrational heat capacity of gehlenite and less negative deviations from ideal mixing compared with previous calibrations, all contribute to reducing the stability of melilites in this model. Together these effects will decrease the predicted temperature of condensation of melilite from nebular vapors, bringing calculated temperatures of melilite condensation into closer alignment with those of MgAl2O4 spinel than the 80 to 100 K separating their appearances in previous calculations (for example, Yoneda and Grossman, 1995; Petaev and Wood,1998; Ebel and Grossman,2000). These eff
{"title":"Thermochemistry of melilites I. Towards resolving an inconsistency in nebular condensation calculations","authors":"R. Sack","doi":"10.2475/04.2021.02","DOIUrl":"https://doi.org/10.2475/04.2021.02","url":null,"abstract":"A thermodynamic model is formulated for (Ca,Na)2(Mg,Fe2+,Al,Fe3+)T1 (Al,Fe3+,Si)2T2O7 melilites. It employs the compositional vertices: åkermanite (Ca2MgSi2O7, 1), gehlenite (Ca2Al2SiO7, 2), iron åkermanite (Ca2Fe2+Si2O7, 3), ferrigehlenite (Ca2Fe23 + SiO7, 4), sodium melilite (NaCaAlSi2O7, 5), and the convergent ordering variables: s = XAl3 + T2a – XAl3+T2b and t = XFe3 + T2a – XFe3 + T2b to describe the distribution of Al3+, Fe3+ and Si4+ between T2 subsites T2a and T2b. It is calibrated for åkermanite–gehlenite melilites based on the calorimetric data of Charlu and others (1981), the assumption that the synthetic samples of Charlu and others approached “equilibrium” states of Al-Si tetrahedral ordering at 970 K, and analogy with the Al2(MgSi) − 1 substitution in CaMgSi2O6 – CaMg1/2Ti1/2AlSiO6 – CaAl2SiO6 fassaites (for example, Sack and Ghiorso, 2017). In this model gehlenite has a disordered Al-Si distribution on T2 sites above 1443 K (1170 °C), consistent with the crystallographic data on c/a ratios of lattice parameters as a function of annealing temperature (Woodhead and Waldbaum, 1974) and the high-temperature heat capacities inferred from drop calorimetric data (Pankratz and Kelley,1964). However, above this critical temperature a partially ordered Al-Si distribution persists between T2a and T2b sites in åkermanite – gehlenite solid solutions with intermediate X2 (for example, 0.19 < X2 < 0.89 at 1573 K). To a first approximation activity-composition relations of the gehlenite component approximate those of ideal mixing (that is, ai = Xi), particularly in gehlenite-rich compositions, but those of åkermanite component display pronounced temperature dependence in intermediate compositions. Enthalpies of formation of åkermanite and gehlenite from the elements at 298.15 K, ΔH¯f 298.15o AK and ΔH¯f 298.15o GEHL, consistent with the experimental brackets on decarbonation equilibria of Walter (1963), Hoschek (1974), and Shmulovich (1974), the thermodynamic model for åkermanite-gehlenite melilites developed here, the thermodynamic properties of the other phases in these reactions tabulated by Berman (1988), and the revised estimates for C¯p and S¯298.15o of diopside of Sack and Ghiorso (2017), are roughly 1 and 3 (kJ/gfw) more positive than those estimated by Berman (1988). More positive standard enthalpies of formation of both endmembers, together with a decrease in the vibrational heat capacity of gehlenite and less negative deviations from ideal mixing compared with previous calibrations, all contribute to reducing the stability of melilites in this model. Together these effects will decrease the predicted temperature of condensation of melilite from nebular vapors, bringing calculated temperatures of melilite condensation into closer alignment with those of MgAl2O4 spinel than the 80 to 100 K separating their appearances in previous calculations (for example, Yoneda and Grossman, 1995; Petaev and Wood,1998; Ebel and Grossman,2000). These eff","PeriodicalId":7660,"journal":{"name":"American Journal of Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2021-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43854564","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Detailed bedrock mapping, structural geology, meta-igneous whole rock geochemistry, and U-Pb geochronology from rocks sampled along a portion of a complexly deformed tectonic boundary between the Ordovician peri-Gondwanan Liberty-Orrington belt and Silurian syn-orogenic strata of the Fredericton trough (a.k.a. the Dog Bay Line) in mid-coastal Maine aid in deciphering the Silurian-Devonian tectonic evolution of the region. The new results provide constraints on several key events. First, initial terrane juxtapositioning occurred along the east-verging Boothbay thrust fault (D1). This tectonism occurred prior to 423 Ma and is associated with the accretion of the Ganderian microcontinent to the Laurentian margin (that is, the Salinic orogeny). Subsequently, intrusion of an ultra-potassic magma, the protolith of the Edgecomb Gneiss, occurred at ca. 413 Ma. Its distinctive whole rock geochemical signature allows for correlation with rocks of similar composition and age along a relatively narrow 140 kilometer long distance on the northwestern margin of the Fredericton trough. This restricted area of ultra-potassic magma generation is attributed to the breakoff of the descending Salinic oceanic slab that triggered decompression melting of a previously metasomatized mantle wedge region beneath the accreted Ganderian microcontinent. Early thrust faults (D1) and the ca. 413 Edgecomb Gneiss igneous protolith were overprinted by an episode of upright folding (D2) and low-pressure amphibolite facies metamorphism associated with the Early to Middle Devonian Acadian orogeny. Zircon overgrowths in the Edgecomb Gneiss dated at ca. 399 Ma grew during this tectonic episode. Comparisons with previous geochronological studies across the region suggest this dominant phase of Acadian deformation and metamorphism was long-lived (ca. 40 m.y.) and associated with the outboard accretion of the Avalonian microcontinent. Dextral shear structures represent the final phase of deformation (D3) superimposed on this terrane boundary and are associated with the Norumbega fault and shear zone system that was active in Middle Devonian-Carboniferous time.
{"title":"Silurian-Devonian tectonic evolution of mid-coastal Maine, U.S.A.: Details of polyphase orogenic processes","authors":"D. P. West, E. Peterman, Jessica Chen","doi":"10.2475/04.2021.03","DOIUrl":"https://doi.org/10.2475/04.2021.03","url":null,"abstract":"Detailed bedrock mapping, structural geology, meta-igneous whole rock geochemistry, and U-Pb geochronology from rocks sampled along a portion of a complexly deformed tectonic boundary between the Ordovician peri-Gondwanan Liberty-Orrington belt and Silurian syn-orogenic strata of the Fredericton trough (a.k.a. the Dog Bay Line) in mid-coastal Maine aid in deciphering the Silurian-Devonian tectonic evolution of the region. The new results provide constraints on several key events. First, initial terrane juxtapositioning occurred along the east-verging Boothbay thrust fault (D1). This tectonism occurred prior to 423 Ma and is associated with the accretion of the Ganderian microcontinent to the Laurentian margin (that is, the Salinic orogeny). Subsequently, intrusion of an ultra-potassic magma, the protolith of the Edgecomb Gneiss, occurred at ca. 413 Ma. Its distinctive whole rock geochemical signature allows for correlation with rocks of similar composition and age along a relatively narrow 140 kilometer long distance on the northwestern margin of the Fredericton trough. This restricted area of ultra-potassic magma generation is attributed to the breakoff of the descending Salinic oceanic slab that triggered decompression melting of a previously metasomatized mantle wedge region beneath the accreted Ganderian microcontinent. Early thrust faults (D1) and the ca. 413 Edgecomb Gneiss igneous protolith were overprinted by an episode of upright folding (D2) and low-pressure amphibolite facies metamorphism associated with the Early to Middle Devonian Acadian orogeny. Zircon overgrowths in the Edgecomb Gneiss dated at ca. 399 Ma grew during this tectonic episode. Comparisons with previous geochronological studies across the region suggest this dominant phase of Acadian deformation and metamorphism was long-lived (ca. 40 m.y.) and associated with the outboard accretion of the Avalonian microcontinent. Dextral shear structures represent the final phase of deformation (D3) superimposed on this terrane boundary and are associated with the Norumbega fault and shear zone system that was active in Middle Devonian-Carboniferous time.","PeriodicalId":7660,"journal":{"name":"American Journal of Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2021-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43300847","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Q. Chang, M. Hren, A. Lin, C. Tabor, Shun Yu, Y. Eley, G. Harris
Fluvial sediments are important archives of paleoenvironments. However, variations in sediment production and transport processes greatly influence sediment geochemistry and resultant interpretations of ancient conditions. Tectonically-active tropical regions are particularly sensitive to climate feedbacks because these areas are often characterized by high precipitation rates, rapid erosion and short sediment residence times. We analyzed the hydrogen and carbon isotope composition of plant-derived n-alkanes (δ2Hn-alkane and δ13Cn-alkane) in sediment cores along the Gaoping River-submarine canyon system in southwestern Taiwan to examine climatic and geomorphic controls on isotope geochemical signatures of fluvial sedimentary archives. These records span the last ∼26 kyr and provide critical insight into the temporal and spatial variations in sedimentary biomarker isotopes within a source-to-sink system. Isotope data are coupled with new results from an iCESM 1.2 Earth System Model of precipitation isotopes during the last glacial-interglacial cycle. Biomarker isotope and modeling results support two important conclusions. First, biomarker isotope values change by ∼10 to 15‰ in δ2Hn-alkane and ∼1 to 2‰ δ13Cn-alkane in offshore SW Taiwan through the late Quaternary deglaciation. These shifts are consistent with iCESM predictions and other records from the South China Sea and are best explained by a shift in isotope hydrology due to regional warming and biologic responses to increased atmospheric pCO2. Second, the δ2Hn-alkane of biomarkers preserved in onshore sediments proximal to the mountain range is ∼15 to 20‰ more negative than biomarkers deposited in offshore sites, and the temporal change in carbon isotopes exceeds that observed in the offshore deposits. The onshore core locality is proximal to the orogen and characterized by a mean elevation > 1 km compared to the offshore site, which has a mean catchment elevation of ∼500 m. These data show that depositional setting and catchment hypsometry strongly bias the geochemical signature of sediments transported through the river system. The magnitude of isotopic variability generated by catchment geometry and sediment integration greatly exceeds the change associated with warming during deglaciation. This result suggests that catchment integration processes may play a similar or larger role in shaping fluvial geochemical records in tropical mountain systems than climatic factors.
{"title":"Terrestrial biomarker isotope records of late Quaternary climate and source-to-sink sediment transport processes in southwestern Taiwan","authors":"Q. Chang, M. Hren, A. Lin, C. Tabor, Shun Yu, Y. Eley, G. Harris","doi":"10.2475/04.2021.01","DOIUrl":"https://doi.org/10.2475/04.2021.01","url":null,"abstract":"Fluvial sediments are important archives of paleoenvironments. However, variations in sediment production and transport processes greatly influence sediment geochemistry and resultant interpretations of ancient conditions. Tectonically-active tropical regions are particularly sensitive to climate feedbacks because these areas are often characterized by high precipitation rates, rapid erosion and short sediment residence times. We analyzed the hydrogen and carbon isotope composition of plant-derived n-alkanes (δ2Hn-alkane and δ13Cn-alkane) in sediment cores along the Gaoping River-submarine canyon system in southwestern Taiwan to examine climatic and geomorphic controls on isotope geochemical signatures of fluvial sedimentary archives. These records span the last ∼26 kyr and provide critical insight into the temporal and spatial variations in sedimentary biomarker isotopes within a source-to-sink system. Isotope data are coupled with new results from an iCESM 1.2 Earth System Model of precipitation isotopes during the last glacial-interglacial cycle. Biomarker isotope and modeling results support two important conclusions. First, biomarker isotope values change by ∼10 to 15‰ in δ2Hn-alkane and ∼1 to 2‰ δ13Cn-alkane in offshore SW Taiwan through the late Quaternary deglaciation. These shifts are consistent with iCESM predictions and other records from the South China Sea and are best explained by a shift in isotope hydrology due to regional warming and biologic responses to increased atmospheric pCO2. Second, the δ2Hn-alkane of biomarkers preserved in onshore sediments proximal to the mountain range is ∼15 to 20‰ more negative than biomarkers deposited in offshore sites, and the temporal change in carbon isotopes exceeds that observed in the offshore deposits. The onshore core locality is proximal to the orogen and characterized by a mean elevation > 1 km compared to the offshore site, which has a mean catchment elevation of ∼500 m. These data show that depositional setting and catchment hypsometry strongly bias the geochemical signature of sediments transported through the river system. The magnitude of isotopic variability generated by catchment geometry and sediment integration greatly exceeds the change associated with warming during deglaciation. This result suggests that catchment integration processes may play a similar or larger role in shaping fluvial geochemical records in tropical mountain systems than climatic factors.","PeriodicalId":7660,"journal":{"name":"American Journal of Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2021-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47592052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
R. McAleer, D. Bish, M. Kunk, P. Valley, G. Walsh, R. Wintsch
A combination of modal estimates from powder X-ray diffraction (XRD) experiments and argon isotopic data shows that muscovite 40Ar/39Ar total gas age correlates with muscovite composition near the retrograde Bald Mountain shear zone (BMSZ) in Claremont, New Hampshire, and that the shear zone was active at ∼245 Ma. Petrologic study demonstrates that chemical disequilibrium is preserved in muscovite grains in these samples. The recognition of this preservation is critical to the interpretation of the 40Ar/39Ar step-heating experiments, which never produce age plateaus and yield spectra with steps that range in age by ∼20 Ma. Petrographic, compositional, and crystallographic data all indicate that the age spectra reflect dissolution of metastable Na-rich muscovite and precipitation of stable Na-poor muscovite associated with deformation in the BMSZ.Comparison of whole rock and muscovite concentrate XRD patterns from individual samples demonstrates that the mineral separation process can fractionate these muscovite populations. Therefore, four muscovite concentrates of varying magnetic susceptibility were prepared from a single hand sample, analyzed by XRD, and dated. These four splits define a mixing line that resolves end-member ages of 244.5 ± 4.2 Ma and 302.5 ± 12.5 Ma (1σ). Although the ages are imprecise, the petrologically supported conclusion that these schists preserve two discrete ages is distinct from an interpretation that the spectra reflect cooling through closure at ∼270 Ma, as might be concluded in the absence of petrologic characterization. The XRD results also demonstrate that, even well above anchizone conditions, petrologic information relevant to 40Ar/39Ar dating is observable in subtle variations in the crystallography of muscovite grains.
{"title":"Unmixing multiple metamorphic muscovite age populations with powder X-ray diffraction and 40Ar/39Ar analysis","authors":"R. McAleer, D. Bish, M. Kunk, P. Valley, G. Walsh, R. Wintsch","doi":"10.2475/03.2021.02","DOIUrl":"https://doi.org/10.2475/03.2021.02","url":null,"abstract":"A combination of modal estimates from powder X-ray diffraction (XRD) experiments and argon isotopic data shows that muscovite 40Ar/39Ar total gas age correlates with muscovite composition near the retrograde Bald Mountain shear zone (BMSZ) in Claremont, New Hampshire, and that the shear zone was active at ∼245 Ma. Petrologic study demonstrates that chemical disequilibrium is preserved in muscovite grains in these samples. The recognition of this preservation is critical to the interpretation of the 40Ar/39Ar step-heating experiments, which never produce age plateaus and yield spectra with steps that range in age by ∼20 Ma. Petrographic, compositional, and crystallographic data all indicate that the age spectra reflect dissolution of metastable Na-rich muscovite and precipitation of stable Na-poor muscovite associated with deformation in the BMSZ.Comparison of whole rock and muscovite concentrate XRD patterns from individual samples demonstrates that the mineral separation process can fractionate these muscovite populations. Therefore, four muscovite concentrates of varying magnetic susceptibility were prepared from a single hand sample, analyzed by XRD, and dated. These four splits define a mixing line that resolves end-member ages of 244.5 ± 4.2 Ma and 302.5 ± 12.5 Ma (1σ). Although the ages are imprecise, the petrologically supported conclusion that these schists preserve two discrete ages is distinct from an interpretation that the spectra reflect cooling through closure at ∼270 Ma, as might be concluded in the absence of petrologic characterization. The XRD results also demonstrate that, even well above anchizone conditions, petrologic information relevant to 40Ar/39Ar dating is observable in subtle variations in the crystallography of muscovite grains.","PeriodicalId":7660,"journal":{"name":"American Journal of Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2021-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46304722","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The Early Cretaceous New England-Quebec igneous province is a classic example of postrift magmatism along the eastern North American passive margin. Although a suite of 40Ar/39Ar ages has been available for the Monteregian Hills lobe in the Quebec portion of the New England-Quebec igneous province for many years, only a single high accuracy radiometric age has been published for the Burlington lobe and none for the Taconic lobe in the New England portion of the province. As a result, the timing of and driving mechanisms behind the magmatism have remained unresolved, and a hotspot origin for the entire province persists in the literature. We have dated four dikes and one pluton in the Burlington and Taconic lobes using 40Ar/39Ar and U–Pb geochronology to improve understanding of the age of magmatism in the New England portion of the province. In the Burlington lobe, 40Ar/39Ar plateau ages include a 137.55 ± 1.80 Ma biotite age and a 136.9 ± 4.2 Ma amphibole age for a lamprophyre dike from Charlotte, Vermont, and a 133.6 ± 2.2 Ma biotite age for a lamprophyre dike from Colchester, Vermont. In the Taconic lobe, ages include an 40Ar/39Ar plateau amphibole age of 107.09 ± 1.32 Ma for a lamprophyre dike from Castleton, Vermont, a 122 Ma minimum 40Ar/39Ar biotite age for a lamprophyre dike from Poultney, Vermont, and a 103.13 ± 0.53 Ma LA-ICP-MS U–Pb zircon age from the quartz syenite of the Cuttingsville complex. These results show that magmatism spanned at least 35 Ma, from ∼138 to 103 Ma, which is broadly consistent with the span of magmatism suggested by workers in the 1970s and 1980s based on K–Ar and Rb–Sr ages. This extended span of magmatism for the Burlington and Taconic lobes is in contrast to the brief 1 to 2 Ma episode of magmatism at ∼124 Ma inferred for the Monteregian Hills lobe. The New England-Quebec igneous province has traditionally been attributed to passage of the Great Meteor hotspot. However, given the close proximity of the Burlington and Taconic lobes, the magmatism in these lobes should span only a few Ma if the product of a hotspot. The age data are also difficult to reconcile with a more complex expression of hotspot magmatism in continental lithosphere related to either plume head magmatism or long-distance migration of plume material. Instead, the extended duration of Early Cretaceous New England-Quebec igneous province magmatism in New England may represent an expression of edge-driven convection, a process known to occur along passive margins and inferred to be operating beneath the eastern North American margin today.
{"title":"40Ar/39Ar and LA-ICP-MS U–Pb geochronology for the New England portion of the Early Cretaceous New England-Quebec igneous province: Implications for the postrift evolution of the eastern North American Margin","authors":"J. C. Boemmels, J. Crespi, L. Webb, J. Fosdick","doi":"10.2475/03.2021.03","DOIUrl":"https://doi.org/10.2475/03.2021.03","url":null,"abstract":"The Early Cretaceous New England-Quebec igneous province is a classic example of postrift magmatism along the eastern North American passive margin. Although a suite of 40Ar/39Ar ages has been available for the Monteregian Hills lobe in the Quebec portion of the New England-Quebec igneous province for many years, only a single high accuracy radiometric age has been published for the Burlington lobe and none for the Taconic lobe in the New England portion of the province. As a result, the timing of and driving mechanisms behind the magmatism have remained unresolved, and a hotspot origin for the entire province persists in the literature. We have dated four dikes and one pluton in the Burlington and Taconic lobes using 40Ar/39Ar and U–Pb geochronology to improve understanding of the age of magmatism in the New England portion of the province. In the Burlington lobe, 40Ar/39Ar plateau ages include a 137.55 ± 1.80 Ma biotite age and a 136.9 ± 4.2 Ma amphibole age for a lamprophyre dike from Charlotte, Vermont, and a 133.6 ± 2.2 Ma biotite age for a lamprophyre dike from Colchester, Vermont. In the Taconic lobe, ages include an 40Ar/39Ar plateau amphibole age of 107.09 ± 1.32 Ma for a lamprophyre dike from Castleton, Vermont, a 122 Ma minimum 40Ar/39Ar biotite age for a lamprophyre dike from Poultney, Vermont, and a 103.13 ± 0.53 Ma LA-ICP-MS U–Pb zircon age from the quartz syenite of the Cuttingsville complex. These results show that magmatism spanned at least 35 Ma, from ∼138 to 103 Ma, which is broadly consistent with the span of magmatism suggested by workers in the 1970s and 1980s based on K–Ar and Rb–Sr ages. This extended span of magmatism for the Burlington and Taconic lobes is in contrast to the brief 1 to 2 Ma episode of magmatism at ∼124 Ma inferred for the Monteregian Hills lobe. The New England-Quebec igneous province has traditionally been attributed to passage of the Great Meteor hotspot. However, given the close proximity of the Burlington and Taconic lobes, the magmatism in these lobes should span only a few Ma if the product of a hotspot. The age data are also difficult to reconcile with a more complex expression of hotspot magmatism in continental lithosphere related to either plume head magmatism or long-distance migration of plume material. Instead, the extended duration of Early Cretaceous New England-Quebec igneous province magmatism in New England may represent an expression of edge-driven convection, a process known to occur along passive margins and inferred to be operating beneath the eastern North American margin today.","PeriodicalId":7660,"journal":{"name":"American Journal of Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2021-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48453777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The rock record of organic carbon abundance and its isotopic composition is consistent with the evolution of life more than 3800 million years ago (Ma). Despite this, there are very few insights as to the ecology of this ancient biosphere or to its level of activity. One possible insight, however, comes from the isotopic composition of inorganic and organic carbon in ancient rocks. This isotope record can be used, in principle, to determine the proportion of inorganic carbon entering the oceans that was buried in sediments as organic matter, and thus it helps constrain the activity level of the ancient biosphere. A quantitative analysis of this isotope record, however, requires that we understand how the Earth-surface carbon reservoir has evolved over time, as burial rates of organic matter in marine sediments depend on the input rates of carbon to the oceans. We must also know how organic matter is weathered as a function of atmospheric oxygen concentrations, thus indicating how much of the organic matter in sediments is newly formed or recycled. To explore these issues, a carbon cycle model is developed here that includes an evolving Earth-surface carbon reservoir as well as the oxygen dependency of the organic matter weathering in rocks. The model also allows for the release of CO2 from organic matter during metamorphism and it contains a rock cycle with young and old reservoirs with appropriate transfer fluxes between them. The model shows that before the Great Oxidation Event (GOE) about 2400 Ma, only about 5 percent to 10 percent as much organic matter was buried into marine sediments as compared with today. Such low rates of organic matter burial would be consistent with a subdued marine biosphere. Such a subdued biosphere could possibly be consistent with primary production driven by anoxygenic photosynthesis coupled to an iron cycle. In association with, and in the aftermath of, the GOE, the biosphere likely increased its activity level by an order of magnitude. This large increase would have completely transformed the biology of the Earth and could have resulted from either the evolution and/or expansion of oxygen-producing cyanobacteria or a dramatic increase in the availability of nutrients to fuel oxygenic phototrophs.
{"title":"Carbon cycle evolution before and after the Great Oxidation of the atmosphere","authors":"D. Canfield","doi":"10.2475/03.2021.01","DOIUrl":"https://doi.org/10.2475/03.2021.01","url":null,"abstract":"The rock record of organic carbon abundance and its isotopic composition is consistent with the evolution of life more than 3800 million years ago (Ma). Despite this, there are very few insights as to the ecology of this ancient biosphere or to its level of activity. One possible insight, however, comes from the isotopic composition of inorganic and organic carbon in ancient rocks. This isotope record can be used, in principle, to determine the proportion of inorganic carbon entering the oceans that was buried in sediments as organic matter, and thus it helps constrain the activity level of the ancient biosphere. A quantitative analysis of this isotope record, however, requires that we understand how the Earth-surface carbon reservoir has evolved over time, as burial rates of organic matter in marine sediments depend on the input rates of carbon to the oceans. We must also know how organic matter is weathered as a function of atmospheric oxygen concentrations, thus indicating how much of the organic matter in sediments is newly formed or recycled. To explore these issues, a carbon cycle model is developed here that includes an evolving Earth-surface carbon reservoir as well as the oxygen dependency of the organic matter weathering in rocks. The model also allows for the release of CO2 from organic matter during metamorphism and it contains a rock cycle with young and old reservoirs with appropriate transfer fluxes between them. The model shows that before the Great Oxidation Event (GOE) about 2400 Ma, only about 5 percent to 10 percent as much organic matter was buried into marine sediments as compared with today. Such low rates of organic matter burial would be consistent with a subdued marine biosphere. Such a subdued biosphere could possibly be consistent with primary production driven by anoxygenic photosynthesis coupled to an iron cycle. In association with, and in the aftermath of, the GOE, the biosphere likely increased its activity level by an order of magnitude. This large increase would have completely transformed the biology of the Earth and could have resulted from either the evolution and/or expansion of oxygen-producing cyanobacteria or a dramatic increase in the availability of nutrients to fuel oxygenic phototrophs.","PeriodicalId":7660,"journal":{"name":"American Journal of Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2021-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46622541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Orogens that form at convergent plate boundaries typically consist of accreted rock units that form an incomplete archive of subducted oceanic and continental lithosphere, as well as of deformed lithosphere of the former upper plate. Reading the construction of orogenic architecture forms the key to decipher the pre-orogenic paleogeographic distribution of oceans and continents, as well as bathymetric and topographic features that existed thereon such as igneous plateaus, seamounts, microcontinents, or magmatic arcs. Current classification schemes of orogens divide between settings associated with termination of subduction [continent-continent collision, continent-ocean collision (obduction)] and with ongoing subduction (accretionary orogenesis), alongside intraplate orogens. Perceived diagnostic features for such classifications, particularly of collisional orogenesis, hinge on dynamic interpretations linking downgoing plate paleogeography to upper plate deformation, plate motion changes, or magmatism. Here, we show, however, that Mesozoic-Cenozoic orogens that undergo collision almost all defy these proposed diagnostic features and behave as accretionary orogens instead. To reconstruct paleogeography of subducted and upper plates, we therefore propose an alternative approach to navigating through orogenic architecture: subducted plate units comprise nappes (or mélanges) with Ocean Plate Stratigraphy (OPS) and Continental Plate Stratigraphy (CPS) stripped from their now-subducted or otherwise underthrust lower crustal and mantle lithospheric underpinnings. Upper plate deformation and paleogeography respond to the competition between absolute motions of the upper plate and the subducting slab. Our navigation approach through orogenic architecture aims to avoid a priori dynamic interpretations that link downgoing plate paleogeography to deformation or magmatic responses in the upper plate, to provide an independent basis for geodynamic analysis. From our analysis we identify ‘rules of orogenesis' that link the rules of rigid plate tectonics with the reality of plate deformation. We use these rules for a thought experiment, in which we predict orogenic architecture that will result from subducting the present-day Indian Ocean and colliding the Somali, Madagascar, and Indian margins using a published continental drift scenario for a future supercontinent as basis. We illustrate that our inferred rules (of thumb) generate orogenic architecture that is analogous to elements of modern orogens, unlocking the well-known modern geography as inspiration for developing testable hypotheses that aid interpreting paleogeography from orogens that formed since the birth of plate tectonics.
{"title":"Deciphering paleogeography from orogenic architecture: Constructing orogens in a future supercontinent as thought experiment","authors":"D. V. Hinsbergen, Thomas L. A. Schouten","doi":"10.31223/x5m895","DOIUrl":"https://doi.org/10.31223/x5m895","url":null,"abstract":"Orogens that form at convergent plate boundaries typically consist of accreted rock units that form an incomplete archive of subducted oceanic and continental lithosphere, as well as of deformed lithosphere of the former upper plate. Reading the construction of orogenic architecture forms the key to decipher the pre-orogenic paleogeographic distribution of oceans and continents, as well as bathymetric and topographic features that existed thereon such as igneous plateaus, seamounts, microcontinents, or magmatic arcs. Current classification schemes of orogens divide between settings associated with termination of subduction [continent-continent collision, continent-ocean collision (obduction)] and with ongoing subduction (accretionary orogenesis), alongside intraplate orogens. Perceived diagnostic features for such classifications, particularly of collisional orogenesis, hinge on dynamic interpretations linking downgoing plate paleogeography to upper plate deformation, plate motion changes, or magmatism. Here, we show, however, that Mesozoic-Cenozoic orogens that undergo collision almost all defy these proposed diagnostic features and behave as accretionary orogens instead. To reconstruct paleogeography of subducted and upper plates, we therefore propose an alternative approach to navigating through orogenic architecture: subducted plate units comprise nappes (or mélanges) with Ocean Plate Stratigraphy (OPS) and Continental Plate Stratigraphy (CPS) stripped from their now-subducted or otherwise underthrust lower crustal and mantle lithospheric underpinnings. Upper plate deformation and paleogeography respond to the competition between absolute motions of the upper plate and the subducting slab. Our navigation approach through orogenic architecture aims to avoid a priori dynamic interpretations that link downgoing plate paleogeography to deformation or magmatic responses in the upper plate, to provide an independent basis for geodynamic analysis. From our analysis we identify ‘rules of orogenesis' that link the rules of rigid plate tectonics with the reality of plate deformation. We use these rules for a thought experiment, in which we predict orogenic architecture that will result from subducting the present-day Indian Ocean and colliding the Somali, Madagascar, and Indian margins using a published continental drift scenario for a future supercontinent as basis. We illustrate that our inferred rules (of thumb) generate orogenic architecture that is analogous to elements of modern orogens, unlocking the well-known modern geography as inspiration for developing testable hypotheses that aid interpreting paleogeography from orogens that formed since the birth of plate tectonics.","PeriodicalId":7660,"journal":{"name":"American Journal of Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2021-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46749578","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Y. Wan, Shoujie Liu, Zhiyong Song, S. Wilde, Laiming Wang, C. Dong, H. Xie, S. Xie, Jianhua Hou, Wenqian Bai, Dunyi Liu
Qixia is a typical area of early Precambrian basement in eastern Shandong Province, eastern North China Craton. Many TTG (tonalite-trondhjemite-granodiorite) assemblages were once considered to be supracrustal rocks (the Jiaodong Group), and the formation ages of the rocks have only been determined in a few outcrops as shown on the early geological map of the area. We carried out geological mapping, geochemical study and SHRIMP U-Pb zircon dating in order to determine the temporal and spatial distribution and origins of the TTG rocks. In the newly compiled geological map (1:50,000), the main rock types of the Archean basement are ∼2.9 Ga, ∼2.7 Ga and ∼2.5 Ga tonalitic gneisses with local occurrences of trondhjemitic gneisses, granodioritic gneisses, (quartz) dioritic gneisses and meta-gabbro showing the same age range. Supracrustal rocks with ages of ∼2.9 Ga and ∼2.5 Ga are locally identified. All rocks broadly extend in a NW-SE direction as a result of strong tectonothermal events of the late Neoarchean and late Paleoproterozoic. Although the late Paleoproterozoic tectonothermal event strongly influenced all 2.7 to 2.9 Ga rocks in the area, metamorphic zircon ages are not widely recorded in these rocks because the high-grade metamorphism at ca. 2.5 Ga caused the older 2.7 to 2.9 Ga rocks to become relatively dry systems. The three generations of TTG rocks are similar in major element composition, characterized by high Na2O and low K2O, except for the late Neoarchean granodioritic gneisses, which locally occur and are relatively high in K2O. All the TTG rocks of different ages commonly have zircon O isotopic compositions within the range determined by Valley and others (2005) for Archean magmatic zircon. The ∼2.9 Ga TTG rocks show large Sr/Y and La/Yb variations and depletion in whole-rock Nd and zircon Hf isotopic compositions. The ∼2.7 Ga TTG rocks are similar in Nd-Hf isotopic compositions to the ∼2.9 Ga TTG rocks but have low Sr/Y and La/Yb ratios. The ∼2.5 Ga TTG rocks are similar in trace element composition to the ∼2.9 Ga TTG rocks, showing large variations in Sr/Y and La/Yb ratios. They can be further subdivided into two types in terms of Nd-Hf isotopic compositions with the depleted type mainly including tonalitic gneisses [εNd(t) = +1.86 to +4.59, εHf(t) = +1.0 to +8.7] and the enriched type including trondhjemitic and granodioritic gneisses [εNd(t) = −2.38 to −0.06, εHf(t) = −1.6 to −2.9]. It is concluded that the ∼2.9 Ga TTG rocks were formed in an oceanic environment (oceanic plateau or intra-ocean subduction), and the 2.7 Ga TTG rocks were formed by mantle underplating that resulted in partial melting of lower crustal mafic rocks under relatively low pressure conditions. More ancient continental materials played a role in the ∼2.5 Ga magmatic process, but more work is required to determine the tectonic environment (underplating or arc magmatism).
栖霞是华北克拉通东部鲁东早前寒武纪基底的典型地区。许多TTG(闪长岩-闪长岩-花岗闪长岩)组合曾被认为是表壳岩(胶东群)，其形成时代仅在该地区早期地质图的少数露头中确定。通过地质填图、地球化学研究和SHRIMP U-Pb锆石定年，确定了TTG岩石的时空分布和成因。在新编制的1:5万地质图中，太古宙基底的主要岩石类型为~ 2.9 Ga、~ 2.7 Ga和~ 2.5 Ga的调性片麻岩，局部有长闪长片麻岩、花岗闪长片麻岩、(石英)闪长片麻岩和变质辉长岩，具有相同的年龄范围。局部鉴定出年龄为~ 2.9 Ga和~ 2.5 Ga的上地壳岩石。由于新太古代晚期和古元古代晚期强烈的构造热事件，所有岩石均向北西-东南方向广泛伸展。虽然晚古元古代构造热事件强烈影响了该区所有2.7 ~ 2.9 Ga的岩石，但由于2.5 Ga左右的高变质作用使较老的2.7 ~ 2.9 Ga岩石成为相对干燥的体系，变质锆石在这些岩石中没有广泛记录。三代TTG岩石除新太古代晚期花岗闪长片麻岩局部发育且K2O含量相对较高外，主要元素组成相似，均表现为高Na2O、低K2O。所有不同年龄的TTG岩石的锆石O同位素组成都在Valley等(2005)对太古宙岩浆锆石确定的范围内。~ 2.9 Ga TTG岩石表现出较大的Sr/Y和La/Yb变化和全岩Nd和锆石Hf同位素组成的耗损。~ 2.7 Ga TTG岩石的Nd-Hf同位素组成与~ 2.9 Ga TTG岩石相似，但Sr/Y和La/Yb比值较低。~ 2.5 Ga TTG岩石的微量元素组成与~ 2.9 Ga TTG岩石相似，Sr/Y和La/Yb比值变化较大。根据Nd-Hf同位素组成可进一步分为两类，贫型主要为调性片麻岩[εNd(t) = +1.86 ~ +4.59， εHf(t) = +1.0 ~ +8.7]，富型主要为长闪质和花岗闪长片麻岩[εNd(t) = - 2.38 ~ - 0.06， εHf(t) = - 1.6 ~ - 2.9]。结果表明，~ 2.9 Ga TTG岩形成于海洋环境(海洋高原或洋内俯冲)，2.7 Ga TTG岩形成于相对低压条件下地幔底沉降导致下地壳基性岩部分熔融作用。更古老的大陆物质在~ 2.5 Ga岩浆过程中发挥了作用，但需要更多的工作来确定构造环境(底板或弧岩浆作用)。
{"title":"The complexities of Mesoarchean to late Paleoproterozoic magmatism and metamorphism in the Qixia area, eastern North China Craton: Geology, geochemistry and SHRIMP U-Pb zircon dating","authors":"Y. Wan, Shoujie Liu, Zhiyong Song, S. Wilde, Laiming Wang, C. Dong, H. Xie, S. Xie, Jianhua Hou, Wenqian Bai, Dunyi Liu","doi":"10.2475/01.2021.01","DOIUrl":"https://doi.org/10.2475/01.2021.01","url":null,"abstract":"Qixia is a typical area of early Precambrian basement in eastern Shandong Province, eastern North China Craton. Many TTG (tonalite-trondhjemite-granodiorite) assemblages were once considered to be supracrustal rocks (the Jiaodong Group), and the formation ages of the rocks have only been determined in a few outcrops as shown on the early geological map of the area. We carried out geological mapping, geochemical study and SHRIMP U-Pb zircon dating in order to determine the temporal and spatial distribution and origins of the TTG rocks. In the newly compiled geological map (1:50,000), the main rock types of the Archean basement are ∼2.9 Ga, ∼2.7 Ga and ∼2.5 Ga tonalitic gneisses with local occurrences of trondhjemitic gneisses, granodioritic gneisses, (quartz) dioritic gneisses and meta-gabbro showing the same age range. Supracrustal rocks with ages of ∼2.9 Ga and ∼2.5 Ga are locally identified. All rocks broadly extend in a NW-SE direction as a result of strong tectonothermal events of the late Neoarchean and late Paleoproterozoic. Although the late Paleoproterozoic tectonothermal event strongly influenced all 2.7 to 2.9 Ga rocks in the area, metamorphic zircon ages are not widely recorded in these rocks because the high-grade metamorphism at ca. 2.5 Ga caused the older 2.7 to 2.9 Ga rocks to become relatively dry systems. The three generations of TTG rocks are similar in major element composition, characterized by high Na2O and low K2O, except for the late Neoarchean granodioritic gneisses, which locally occur and are relatively high in K2O. All the TTG rocks of different ages commonly have zircon O isotopic compositions within the range determined by Valley and others (2005) for Archean magmatic zircon. The ∼2.9 Ga TTG rocks show large Sr/Y and La/Yb variations and depletion in whole-rock Nd and zircon Hf isotopic compositions. The ∼2.7 Ga TTG rocks are similar in Nd-Hf isotopic compositions to the ∼2.9 Ga TTG rocks but have low Sr/Y and La/Yb ratios. The ∼2.5 Ga TTG rocks are similar in trace element composition to the ∼2.9 Ga TTG rocks, showing large variations in Sr/Y and La/Yb ratios. They can be further subdivided into two types in terms of Nd-Hf isotopic compositions with the depleted type mainly including tonalitic gneisses [εNd(t) = +1.86 to +4.59, εHf(t) = +1.0 to +8.7] and the enriched type including trondhjemitic and granodioritic gneisses [εNd(t) = −2.38 to −0.06, εHf(t) = −1.6 to −2.9]. It is concluded that the ∼2.9 Ga TTG rocks were formed in an oceanic environment (oceanic plateau or intra-ocean subduction), and the 2.7 Ga TTG rocks were formed by mantle underplating that resulted in partial melting of lower crustal mafic rocks under relatively low pressure conditions. More ancient continental materials played a role in the ∼2.5 Ga magmatic process, but more work is required to determine the tectonic environment (underplating or arc magmatism).","PeriodicalId":7660,"journal":{"name":"American Journal of Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"69322075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
京公网安备 11010802042870号
京ICP备2023020795号-1
扫码关注我们
求助内容：
应助结果提醒方式：