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Comparative occupational exposures to formaldehyde released from inhaled wood product dusts versus that in vapor form. 从吸入木制品粉尘中释放的甲醛与以蒸汽形式释放的甲醛的比较职业暴露。
Pub Date : 2003-05-01 DOI: 10.1080/10473220301371
Nathalie H Gosselin, Robert C Brunet, Gaétan Carrier

Particle boards and other wood boards are usually made with formaldehyde-based resins. Woodworkers are thus exposed to formaldehyde in vapor form as well as from airborne dust once it enters their respiratory tract. These workers remain exposed to formaldehyde released from the dust still present in their upper respiratory tract, even after their work shift. In assessing the risk associated with formaldehyde exposure, one needs to consider the relative importance of these two sources of exposure. This study proposes two kinetic models to estimate and compare the exposures. For various exposure scenarios, one model predicts the amount of formaldehyde absorbed from the ambient vapor form and the other predicts the amount absorbed by the respiratory tract upon its release from wood product dust. Model parameters are determined using data from published studies. Based on a daily work shift of 8 hr, with a dust concentration in air of 5 mg/m(3) and a formaldehyde concentration bound to dust of 9 microg/mg, model simulations predict that the amount of absorbed formaldehyde released from wood dust is approximately 1/100 of the amount absorbed from the ambient vapor form at a concentration level of 0.38 mg/m(3) (0.3 ppm). Since the formaldehyde concentration in wood dust used above is much higher than usually observed while the dust and vapor form formaldehyde concentrations are of the order of acceptable upper values, these results indicate that the formaldehyde exposure from wood dust is comparatively negligible.

刨花板和其他木板通常是用甲醛树脂制成的。木工因此暴露在甲醛的蒸汽形式,以及空气中的灰尘一旦进入他们的呼吸道。这些工人仍然暴露在灰尘释放的甲醛中,即使在轮班后,他们的上呼吸道仍然存在。在评估与甲醛接触有关的风险时,需要考虑这两种接触源的相对重要性。本研究提出了两种动力学模型来估计和比较暴露。对于各种暴露情景,一个模型预测从环境蒸气形式吸收甲醛的量,另一个模型预测从木制品粉尘中释放甲醛后呼吸道吸收的量。模型参数由已发表研究的数据确定。基于每天工作8小时,空气中的粉尘浓度为5 mg/m(3),与粉尘结合的甲醛浓度为9微克/mg,模型模拟预测,从木屑中吸收的甲醛释放量约为从环境蒸汽形式中吸收量的1/100,浓度水平为0.38 mg/m(3) (0.3 ppm)。由于上述木屑中的甲醛浓度比通常观察到的要高得多,而粉尘和蒸汽形成的甲醛浓度在可接受的上限范围内,这些结果表明木屑中的甲醛暴露相对可以忽略不计。
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引用次数: 7
The application of diffusive sampling combined with thermal desorption in occupational exposure monitoring--field evaluation. 扩散采样结合热解吸法在职业暴露监测中的应用——现场评价。
Pub Date : 2003-05-01 DOI: 10.1080/10473220301361
Yeh-Chung Chien, Li-Jue Wu, Jung-Hen Lwo

Diffusive sampling combined with thermal desorption (DSTD) is considered useful in monitoring workers' exposures to organic vapors, not only due to its simplicity of operation in the field but, also, its simplifying the sample treatment, eliminating the use of extracting solvent, and increasing analytical sensitivity. Herein, the feasibility of applying DSTD in field conditions was assessed through a comparison of the results with those from the well-accepted active/charcoal method. Side-by-side active and diffusive (tube-type, Tenax TA as the adsorbent) samples, both personal and area, were collected and analyzed for xylenes, ethyl acetate, styrene, and n-butyl acetate in four different industrial settings. Statistically significant correlations were found between the two methods in personal samples with the correlation coefficients of 0.92, 0.90, 0.83, 0.88, and 0.97 for m&p-xylenes, o-xylene, n-butyl acetate, styrene, and ethyl acetate, respectively. A paired t-test revealed significant difference between the two methods for n-butyl acetate and styrene. For area sampling, statistical differences (p < 0.05) were found between the two methods, except for xylenes. The DSTD method had, mostly, a lower concentration than the active method, with the bias ranging from 10.2 to -54.4 percent. The possible causes for the discrepancies are discussed. These results suggest that though DSTD protocols can be considered as a simple approach for screening workers' exposures to volatile organics, they should be applied with caution since diffusive sampling is potentially affected by various environmental conditions and adsorptive characteristics.

扩散取样结合热解吸(dsd)被认为对监测工人接触有机蒸汽很有用,不仅因为它在现场操作简单,而且它简化了样品处理,消除了提取溶剂的使用,提高了分析灵敏度。在此,通过将结果与公认的活性/木炭方法的结果进行比较,评估了在现场条件下应用DSTD的可行性。在四种不同的工业环境中,收集了个人和区域的并排活性和扩散(管型,Tenax TA作为吸附剂)样品,并分析了二甲苯、乙酸乙酯、苯乙烯和乙酸正丁酯。在个人样品中,两种方法的相关系数分别为0.92、0.90、0.83、0.88和0.97,分别为m&p-二甲苯、邻二甲苯、乙酸正丁酯、苯乙烯和乙酸乙酯。配对t检验表明,两种方法对乙酸正丁酯和苯乙烯的测定差异显著。在面积抽样中,除二甲苯外,两种方法间差异均有统计学意义(p < 0.05)。DSTD法的浓度大多低于活性法,偏差范围为10.2% ~ - 54.4%。讨论了产生差异的可能原因。这些结果表明,尽管DSTD方案可以被认为是筛选工人接触挥发性有机物的一种简单方法,但由于扩散取样可能受到各种环境条件和吸附特性的影响,因此应谨慎使用。
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引用次数: 4
Determination of known exhalation valve damage using a negative pressure user seal check method on full facepiece respirators. 在全面罩式呼吸器上使用负压用户密封检查法测定已知的呼气阀损坏。
Pub Date : 2003-04-01 DOI: 10.1080/10473220301399
Lisa J Delaney, Roy T McKay, Andrew Freeman

A negative pressure user seal check (NPUSC) method was evaluated for its ability to adequately detect known exhalation valve leakage into a respirator. Three valves with different types of damage were included. Twenty-six test subjects, wearing full facepiece respirators, were asked to perform a NPUSC. Their responses as to whether they passed or failed the user seal check were compared to fit testing results from two quantitative fit test methods: ambient aerosol and controlled negative pressure. In addition, equipment developed at the University of Cincinnati was used to measure in-mask pressures that are generated during the performance of NPUSCs. This technique was employed to assess the ability of respirator wearers to properly conduct user seal checks. The data were analyzed to determine if the user seal check procedure is an effective method for detecting known exhalation valve damage. All test subjects reported passing the user seal check with the undamaged valve. With the warped valve installed, 95 percent of test subjects reported passing the user seal check. With the slit valve installed, 73 percent of test subjects reported passing. With the dirty valve installed, 65 percent reported passing. All fit factors, measured with the damaged valves, were below the Occupational Safety and Health Administration-recognized pass/fail criteria except one fit test with the respirator equipped with the slit valve. Results from the in-mask pressure measurements confirmed whether or not the subject properly conducted a user seal check, but did not detect respirator leakage. In conclusion, the performance of a NPUSC rarely helped to identify damaged exhalation valves. These results support the need for respirator inspection prior to donning with periodic fit testing and the performance of user seal checks as necessary components of an adequate respiratory protection program.

对负压用户密封检查(NPUSC)方法进行评估,以充分检测已知的呼气阀泄漏到呼吸器中的能力。包括三个不同类型损坏的阀门。26名戴着全套面罩的测试对象被要求进行NPUSC。他们对用户密封检查是否通过的回答与两种定量匹配测试方法(环境气溶胶和受控负压)的匹配测试结果进行了比较。此外,辛辛那提大学开发的设备用于测量NPUSCs运行过程中产生的掩膜内压力。该技术用于评估呼吸器佩戴者正确进行用户密封检查的能力。对数据进行分析,以确定用户密封检查程序是否是检测已知呼气阀损坏的有效方法。所有测试对象都报告通过了用户密封检查,阀门没有损坏。安装了弯曲阀后,95%的测试对象报告通过了用户密封检查。安装了狭缝阀后,73%的受试者报告通过了测试。安装脏阀后,65%的人报告通过了测试。所有的配合系数,用损坏的阀门测量,都低于职业安全与健康管理局认可的合格/不合格标准,除了一个配备狭缝阀的呼吸器的配合测试。面罩内压力测量的结果证实了受试者是否正确地进行了用户密封检查,但没有检测到呼吸器泄漏。总之,NPUSC的性能很少有助于识别损坏的呼气阀。这些结果支持在戴上口罩之前进行定期的适合性测试和用户密封检查的必要性,作为适当的呼吸保护程序的必要组成部分。
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引用次数: 7
Measurement of biocides in metalworking fluids and in workplace air using capillary electrophoresis. 用毛细管电泳测定金属加工液和工作场所空气中的杀菌剂。
Pub Date : 2003-04-01 DOI: 10.1080/10473220301403
Petra Fischer, Kai Hansen, Dietmar Breuer
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引用次数: 4
Making sense of highway construction: a taxonomic framework for ergonomic exposure assessment and intervention research. 公路建设的意义:人体工程学暴露评估与干预研究的分类框架。
Pub Date : 2003-04-01 DOI: 10.1080/10473220301402
Susan Moir, Victor Paquet, Laura Punnett, Bryan Buchholz, David Wegman

Construction is one of the most hazardous industries in the United States. Occupational health research to characterize the hazards in construction work has been hampered by the lack of a systematic approach to classification of construction work and its associated hazards. A taxonomy of construction work, a nested system of classification, has been developed to systematize the collection and reporting of exposure assessment data for the characterization and reduction of hazards and the prevention of musculoskeletal injury. This taxonomy subdivides construction work into the categories of stage, operation, task, and activity. It is based on a bidding specification system already in use within the industry and thus provides a terminology common among workers, supervisors, and managers. The identification of tasks and activities that are present in multiple stages and/or trades contributes to the efficiency of exposure data collection and facilitates the generalizability to other settings for both exposure data and intervention evaluations. The taxonomy provides a framework and vocabulary that facilitates field work and participatory research activities. It can also potentially be linked to personnel and economic data for estimation of costs of safety and health problems, as well as benefits of interventions. Although developed for construction ergonomics, the taxonomic approach has application to non-routine work in other industry sectors and possibly in occupational health research other than ergonomics.

建筑业是美国最危险的行业之一。由于缺乏对建筑工作及其相关危害进行分类的系统方法,对建筑工作危害特征的职业健康研究受到了阻碍。建筑工作的分类,一个嵌套的分类系统,已经发展系统化的收集和报告暴露评估数据,以表征和减少危害和预防肌肉骨骼损伤。该分类法将构建工作细分为阶段、操作、任务和活动等类别。它基于行业内已经使用的招标规范系统,因此提供了工人、主管和经理之间通用的术语。识别在多个阶段和/或行业中存在的任务和活动有助于提高暴露数据收集的效率,并有助于将暴露数据和干预评估推广到其他环境。该分类法提供了一个框架和词汇,便于实地工作和参与性研究活动。它还可能与人员和经济数据联系起来,用于估计安全和健康问题的成本以及干预措施的效益。尽管分类学方法是为建筑工效学而开发的,但它也可以应用于除工效学之外的其他工业部门的非常规工作,甚至可能应用于职业健康研究。
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引用次数: 23
Numerical determination of personal aerosol sampler aspiration efficiency. 个人气溶胶取样器吸入效率的数值测定。
Pub Date : 2003-04-01 DOI: 10.1080/10473220301397
Simone Lo Savio, Paolo Paradisi, Francesco Tampieri, Franco Belosi, Maria Pia Morigi, Sergio Agostini

In this work the determination of the aspiration efficiency of personal aerosol samplers, commonly used in occupational exposure assessment, is investigated by means of CFD techniques. Specifically, it will be described a code to calculate the particle trajectories in a given flow field. At the present state the code considers only the effects of the mean flow field on the particle motion, whereas the turbulent diffusion effects are neglected. Comparisons with experimental measurements are also given in the framework of a research contract, supported by the European Community, with several experimental contributions from the participants. The main objective of the European research is to develop a new approach to experimentation with airborne particle flows, working on a reduced scale. This methodology has the advantage of allowing real-time aerosol determination and use of small wind tunnels, with a better experimental control. In this article we describe how the methodology has been verified using computational fluid dynamics. Experimental and numerical aspiration efficiencies have been compared and the influence of gravity and turbulence intensity in full and reduced scale has been investigated. The numerical techniques described here are in agreement with previous similar research and allow at least qualitative predictions of aspiration efficiency for real samplers, taking care of orientation from the incoming air flow. The major discrepancies among predicted and experimental results may be a consequence of bounce effects, which are very difficult to eliminate also by greasing the sampler surface.

本文采用CFD技术对职业暴露评估中常用的个人气溶胶采样器的吸入效率进行了研究。具体来说,将描述一个计算给定流场中粒子轨迹的代码。在目前的状态下,程序只考虑平均流场对粒子运动的影响,而忽略了湍流扩散效应。与实验测量的比较也在研究合同的框架内给出,该合同由欧洲共同体支持,参与者提供了几项实验贡献。欧洲研究的主要目标是开发一种新的方法来实验空气中的颗粒流动,以缩小规模。这种方法的优点是允许实时气溶胶测定和使用小型风洞,具有更好的实验控制。在本文中,我们描述了如何使用计算流体动力学来验证该方法。比较了实验和数值抽吸效率,研究了重力和湍流强度对全尺度和缩尺度抽吸效率的影响。这里描述的数值技术与以前的类似研究一致,并且至少可以对真实采样器的吸入效率进行定性预测,同时考虑到进入气流的方向。预测结果和实验结果之间的主要差异可能是弹跳效应的结果,这种弹跳效应很难通过在采样器表面涂油来消除。
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引用次数: 3
Fatal injuries in the United States involving respirators, 1984-1995. 1984-1995年美国涉及呼吸器的致命伤害。
Pub Date : 2003-04-01 DOI: 10.1080/10473220301405
Anthony Suruda, William Milliken, Dale Stephenson, Richard Sesek

There is little published information concerning the epidemiology of fatal injuries involving respiratory protection. We compiled a case series from U.S. Occupational Safety and Health Administration investigation reports from 1984 through 1995. For the 12-year period there were 41 incidents resulting in 45 deaths due to asphyxiation or chemical poisoning while wearing a respirator. There were 23 deaths related to airline respirators, 17 deaths involving use of negative pressure (air purifying) respirators, and 5 deaths involving self-contained breathing apparatus. Among the 23 deaths involving airline respirators, 15 were associated with compatible connection couplings for breathable air and inert gases. Three workers with beards died who wore tight-fitting respirators in an atmosphere that was immediately dangerous to life and health. Most of the fatalities involved regulatory and procedural violations, and would have been prevented by proper training and compliance with existing regulations. The information concerning the victims was limited but it did not appear that medical screening would have prevented any of the deaths.

关于涉及呼吸保护的致命伤害的流行病学的公开资料很少。我们从1984年至1995年美国职业安全与健康管理局的调查报告中汇编了一个案例系列。在这12年期间,发生了41起事故,其中45人在戴呼吸器时因窒息或化学中毒而死亡。其中23例死亡与航空呼吸器有关,17例死亡与使用负压(空气净化)呼吸器有关,5例死亡与自给式呼吸器有关。在涉及航空公司呼吸器的23起死亡事件中,有15起与可呼吸空气和惰性气体的兼容连接接头有关。三名留胡子的工人在立即危及生命和健康的空气中戴着紧身呼吸器死亡。大多数死亡事件涉及违反规章和程序的行为,如果进行适当的培训和遵守现行规章,这些事故本来是可以避免的。关于受害者的信息有限,但医疗检查似乎无法防止任何死亡。
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引用次数: 15
An ergonomic evaluation of snowmobiles. 雪地车的人体工程学评价。
Pub Date : 2003-04-01 DOI: 10.1080/10473220301396
Daniel J Habes, Robert Dick, Randy Tubbs, Fred Biggs, Susan Burt
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引用次数: 2
24-hour noise dose and risk assessment. 24小时噪音剂量及风险评估。
Pub Date : 2003-04-01 DOI: 10.1080/10473220301400
German Suvorov, Eduard Denisov
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引用次数: 0
Engineering controls for selected silica and dust exposures in the construction industry--a review. 建筑业中二氧化硅和粉尘暴露的工程控制综述。
Pub Date : 2003-04-01 DOI: 10.1080/10473220301406
Michael R Flynn, Pam Susi

This literature review summarizes engineering control technology research for dust and silica exposures associated with selected tasks in the construction industry. Exposure to crystalline silica can cause silicosis and lung fibrosis, and evidence now links it with lung cancer. Of over 30 references identified and reviewed, 16 were particularly significant in providing data and analyses capable of documenting the efficacy of various engineering controls. These reports include information on generation rates and worker exposures to silica and dust during four different tasks: cutting brick and concrete block, grinding mortar from between bricks, drilling, and grinding concrete surfaces. The major controls are wet methods and local exhaust ventilation. The studies suggest that while the methods provide substantial exposure reductions, they may not reduce levels below the current ACGIH threshold limit value (TLV) of 0.05 mg/m(3) for respirable quartz. Although further research on controls for these operations is indicated, it is clear that effective methods exist for significant exposure reduction.

这篇文献综述总结了工程控制技术的研究粉尘和二氧化硅暴露与选定的任务在建筑行业。接触结晶二氧化硅会导致矽肺病和肺纤维化,现在有证据表明它与肺癌有关。在确定和审查的30多份参考资料中,有16份在提供能够记录各种工程控制有效性的数据和分析方面特别重要。这些报告包括在四种不同的任务中产生率和工人接触二氧化硅和粉尘的信息:切割砖和混凝土块,从砖之间研磨砂浆,钻孔和研磨混凝土表面。主要控制方法是湿法和局部排气通风。研究表明,虽然这些方法提供了大量的暴露减少,但它们可能无法将可吸入石英的水平降低到目前ACGIH阈值(TLV) 0.05 mg/m(3)以下。虽然对这些操作的控制进行了进一步的研究,但显然存在显著减少接触的有效方法。
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引用次数: 56
期刊
Applied occupational and environmental hygiene
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