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DETERGENTS and detergency. 洗涤剂和去污剂。
Pub Date : 2020-02-13 DOI: 10.1002/047167849X.BIO033
J. Lynn
The cleaning of a solid object, i.e., the removal of unwanted foreign matter from its surface, is done by methods ranging from simple mechanical separation such as blotting or abrasion to removal by solution or selective chemical action. The term detergency is limited to systems in which a liquid bath is present and is the main cleaning component of the system. The action of the bath involves more than simple solution or simple hydraulic dislodging of soil, although both will occur and contribute to the cleaning. The cleaning is enhanced primarily by the presence in the bath of a special solute, the surfactant, that alters interfacial effects at the various phase boundaries within the system. Thus, a typical detersive system consists of a solid object to be cleaned, called the substrate, soil or dirt attached to it that is to be removed in the washing process, and a liquid bath that is applied to the soiled substrate. In turn, each of these elements can vary widely in properties and composition. The final cleaning benefit results from interaction of these elements and the conditions used, i.e., temperature, time, mechanical energy input (agitation), and, in the case of aqueous baths, the presence of hardness ions in the water. In the cleaning or washing process in a typical detersive system, the soiled substrate is immersed in or brought into contact with a large excess of the bath liquor. Enough bath is used to provide a thick layer over the whole surface of the substrate. During this stage, air is displaced from soil and substrate surfaces; i.e., they are wetted by the bath. The system is subjected to mechanical agitation, either rubbing or shaking, which provides the necessary shearing action to separate the soil from substrate and disperse it in the bath. Agitation also promotes mass transfer in the system, just as in a heterogeneous chemical reaction. The bath carrying the removed soil is drained, wiped, squeezed, or otherwise removed from the substrate. The substrate is rinsed free of the remaining soiled bath. This rinsing step determines the final cleanliness of the substrate. The cleaned substrate is dried or otherwise finished. A meaningful discussion of detergency requires a definition of clean. In the physiochemical sense, a surface is clean if it contains no molecular species other than those in the interior of the two adjoining phases. It is difficult to achieve such a state even under the most exacting laboratory conditions. Practically, a surface is clean if it has been brought to a desired state with regard to foreign matter present upon it, as judged by agreed-upon criteria. Household linen, for example, is considered clean when it is free of visible soil even though it may carry a starch and a softening finish. In the dyehouse of a textile mill, a piece of goods such as this would be rejected as dirty and returned for scouring because these finishes interfere with dyeing. Most standards for cleanness involve a vis
固体物体的清洗,即从其表面去除不需要的异物,可通过各种方法完成,从简单的机械分离(如印迹或磨损)到通过溶液或选择性化学作用去除。去污剂一词仅限于存在液体浴的系统,并且是系统的主要清洁成分。浴槽的作用不仅仅是简单的溶液或简单的土壤水力位移,尽管两者都会发生并有助于清洁。清洗效果的增强主要是由于镀液中存在一种特殊的溶质,即表面活性剂,它改变了系统内不同相界的界面效应。因此,典型的去污剂系统由待清洗的固体物体(称为基材)、附着在基材上的要在洗涤过程中除去的土壤或污垢以及涂在被污染的基材上的液体浴液组成。反过来,这些元素中的每一个在性质和组成上都有很大的不同。最终的清洁效果来自于这些元素和所用条件的相互作用,即温度、时间、机械能输入(搅拌),以及在水浴的情况下,水中硬度离子的存在。在典型的洗涤剂系统的清洗或洗涤过程中,被污染的基材浸入或与大量过量的浴液接触。使用足够的镀液在基材的整个表面上提供一层厚厚的镀液。在这一阶段,空气从土壤和基质表面排出;也就是说,他们被浴盆弄湿了。该系统受到机械搅拌,摩擦或震动,这提供了必要的剪切作用,将土壤从基质中分离出来,并将其分散在槽中。搅拌也促进了系统中的传质,就像在非均相化学反应中一样。将携带被移走的土壤的槽排干、擦拭、挤压或以其他方式从基材上移走。将基材冲洗干净,使其不含残留的污物。这个冲洗步骤决定了基材的最终清洁度。清洗后的基材干燥或以其他方式完成。关于去污力的有意义的讨论需要一个清洁的定义。从物理化学的意义上说,如果一个表面除了两个相邻相内部的分子外,不含其他分子,那么它就是干净的。即使在最严格的实验室条件下,也很难达到这样的状态。实际上,如果按照商定的标准来判断,表面上的异物已经达到了理想的状态,那么表面就是干净的。例如,家用亚麻布被认为是干净的,当它没有可见的土壤,即使它可能含有淀粉和软化整理。在纺织厂的染坊里,像这样的一件商品会被认为是脏的而被拒绝,因为这些整理物会干扰染色。大多数洁净度标准涉及对异物存在的视觉或光学判断。在某些系统中,例如,棉花的退浆,清洁程度可以用基质上土壤的重量百分比来规定。在其他系统中,如金属的脱脂,它是每单位面积的基材表面土壤的重量来指定清洁度。在洗盘子或玻璃器皿时,清洁通常是通过完全的水润湿性或不破裂以及外观来确定的。虽然不可能列出所有可能遇到的实用防腐系统,但很大一部分属于少数类别。这种分类不考虑表面活性剂的结构和底物的类型(纤维或硬表面),仅限于考虑底物上存在的土壤、采用的机械作用、浴液比和使用的洗涤剂。在此基础上对一些更常见的防腐系统进行了分类。关键词:洗净;使清洁的系统;表面活性剂;水的硬度;antiredeposition代理商;泡沫;油性污渍;固体土壤;测量;洗钱;洗碗;金属;液体产品;固体产品;富营养化
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引用次数: 6
Garlic.
Pub Date : 2020-02-07 DOI: 10.32388/vzuyfv
J. Rae
Garlic has a long tradition as a food and as a medicinal plant. Therapeutic effects, routes of application and modes of preparation of garlic are very varied. In order to be able to assess which mode of preparation is suitable for which application, it is necessary to explain certain substance characteristics of garlic. The garlic bulb contains cysteine sulphoxides belonging to the secondary plant components. During the processing these compounds undergo a rapid enzymatic respectively non-enzymatic conversion. Depending on the mode of preparation, different substances with different effects can be found in the resulting products. Most of the data available on the chemopreventive and curative effects of garlic is based on the use of the freshly prepared garlic. Epidemiological studies prove that the risk for different malignant diseases, especially of the gastro-intestinal tract is significantly reduced by regular consumption of large amount of garlic. In numerous investigations it was possible to demonstrate different pharmacological properties, for some cysteine sulphoxides, like antimicrobial, anticancer, and antioxidant activity. The antioxidant potential of garlic is of great interest in connection with the antiatherosclerotic and cardioprotective effects observed epidemiologically and clinically.
大蒜作为一种食物和药用植物有着悠久的传统。大蒜的治疗效果、应用途径和制备方式各不相同。为了能够评估哪种制备方式适合于哪种应用,有必要解释大蒜的某些物质特性。大蒜球茎含有半胱氨酸亚砜,属于次生植物成分。在加工过程中,这些化合物分别经历快速的酶转化和非酶转化。根据制备方式的不同,在最终产物中可以发现具有不同效果的不同物质。大多数关于大蒜的化学预防和治疗作用的现有数据都是基于使用新鲜制备的大蒜。流行病学研究证明,经常大量食用大蒜可显著降低患各种恶性疾病,尤其是胃肠道疾病的风险。在大量的研究中,有可能证明某些半胱氨酸硫化物的不同药理特性,如抗菌、抗癌和抗氧化活性。大蒜的抗氧化潜力与流行病学和临床观察到的抗动脉粥样硬化和心脏保护作用有关。
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引用次数: 0
Antiseptics and Disinfectants 杀菌剂和消毒剂
Pub Date : 2019-11-06 DOI: 10.1007/978-3-319-40221-5_36-2
J. Lachapelle
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引用次数: 1
PLANT and equipment. 厂房和设备。
Pub Date : 2012-01-02 DOI: 10.1002/9781119204008.ch30
James P. Catty, Dita Vadron, Andrea R. Isom
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引用次数: 0
PLANT and equipment. 厂房和设备。
Pub Date : 2011-11-23 DOI: 10.1108/eb034907
Kevin M Gowdie
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引用次数: 2
一時的放出(fugitive emissions)を防止する 防止临时释放(fugitive emissions)
Pub Date : 2010-01-01 DOI: 10.1093/annhyg/25.4.454
A. Michael, Ehlers Pete
Fugitive emissions in the United States have been estimated to account for upwards of 300,000 metric tonnes of industrial waste per year, making them responsible for one-third of the total organic compounds released by chemical and petrochemical plants.What's more, valves alone account for 50% of the loss in pipes and fittings. This situation is mirrored in Europe, and is likely much worse in other parts of the world where environmental standards and levels of policing are less stringent. Environmental devastation aside, petrochemical resources are becoming ever more valuable, and plants can no longer afford to operate wastefully. In addition to the visible cost of emissions, invisible costs include labor and material needed to repair leaks, wasted energy, low plant efficiency, environmental clean up and potential fines, loss of market share due to poor public perception, and, increasingly, claims due to personal injury. Industries worldwide are facing enormous pressure to establish programs that will help minimize potential harm to the environment. On the vanguard of industry regulations are two major standards, ISO15848-1 and API622, which were released in 2005 and 2006 respectively.The ISO15848-1 standard classifies valves into three tightness classes (A, B, C), with class A valves having the lowest leak rate.The API622 standard, on the other hand, classifies the packing arrangements used in the valve.
据估计,美国每年排放的工业废物超过30万吨,占化学和石化工厂释放的有机化合物总量的三分之一。更重要的是,仅阀门就占管道和配件损失的50%。这种情况在欧洲也有反映,而在世界上其他环境标准和治安水平不那么严格的地区,情况可能更糟。抛开对环境的破坏不谈,石油化工资源正变得越来越有价值,工厂再也负担不起浪费经营了。除了可见的排放成本外,无形的成本还包括修复泄漏所需的劳动力和材料、浪费的能源、工厂效率低下、环境清理和潜在的罚款、由于公众认知不佳而导致的市场份额损失,以及越来越多的由于人身伤害而导致的索赔。世界各地的工业都面临着巨大的压力,需要建立有助于将对环境的潜在危害降到最低的项目。行业法规的先锋是两个主要标准,ISO15848-1和API622,分别于2005年和2006年发布。ISO15848-1标准将阀门分为A、B、C三个密封性等级,其中A级阀门泄漏率最低。另一方面,API622标准对阀门中使用的填料安排进行了分类。
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引用次数: 7
PLANT and equipment. 厂房和设备。
Pub Date : 2003-04-30 DOI: 10.1039/9781847551047-00086
R. Day, E. Rowland
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引用次数: 7
Chips with everything 薯条配各种食物
Pub Date : 2003-01-01 DOI: 10.1108/eb058972
T. Owen, M. Kuschel
Lab-on-a-chip technology is rapidly being adopted for QC of bioproducts because of its ease of use and reproducibility, say Tony Owen and Meike Kuschel, of Agilent Technologies.
安捷伦科技公司的Tony Owen和Meike Kuschel说,芯片实验室技术由于易于使用和可重复性,正迅速被用于生物产品的质量控制。
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引用次数: 0
VITAMIN B12; the anti-pernicious anaemia factor. 维生素B12;抗恶性贫血因子。
Pub Date : 1977-02-01 DOI: 10.1108/EB058668
I. Sharman
Anaemia is a disease characterised by a reduction in the number of red cells in the blood, or in the amount of the iron‐containing red pigment, haemoglobin. Various types of anaemia are known, thus macrocytic anaemia is the name given to the condition when there is an increase in the average size of the red cells in the blood. It is now known that two vitamins, viz. folic acid and vitamin B12, are involved in the prevention of some anaemias.
贫血是一种以血液中红细胞数量减少或含铁红色色素血红蛋白数量减少为特征的疾病。各种类型的贫血是已知的,因此巨细胞性贫血是指血液中红细胞平均大小增加的情况。现在已知有两种维生素,即叶酸和维生素B12,与预防某些贫血有关。
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引用次数: 0
CHEMOTHERAPY of cancer. 癌症的化疗。
Pub Date : 1970-11-01 DOI: 10.1001/ARCHINTE.1970.00310110186038
R. Moser
Malignancy remains the bleakest area of therapy in medicine. Except for methotrexate in choriocarcinoma and surgical removal and local irradiation for unilateral Wilms' tumor, we hesitate to speak of cure . But shafts of light are penetrating the darkness; we have seen dramatic improvement in survival in patients with Hodgkin's disease and acute lymphoblastic leukemia. Other tumors are beginning to budge from dead center where they have been entrenched since anyone can remember. The current state of chemotherapy is summarized in this excellent book edited by surgeon Warren H. Cole. With his 30 carefully selected experts, he explores the depths of cancer chemotherapy in a series of nine separate essays. Early chapters are concerned with mechanisms of action, drug treatment of leukemia, and the role of chemotherapy in lymphoma. Three chapters tackle the details of systemic chemotherapy and two discuss regional perfusion. There is a separate section on Wilms' tumor by
恶性肿瘤仍然是医学治疗中最黯淡的领域。除了绒毛膜癌的甲氨蝶呤治疗和单侧Wilms肿瘤的手术切除和局部放疗外,我们不愿谈论治愈。但一缕缕光明正穿透黑暗;我们已经看到霍奇金氏病和急性淋巴细胞白血病患者的生存率显著提高。其他肿瘤开始从死角向外移动,从任何人都能记得起,它们就在死角根深蒂固。在外科医生Warren H. Cole编辑的这本优秀的书中总结了化疗的现状。他和他精心挑选的30位专家一起,在9篇独立的文章中深入探讨了癌症化疗的深度。早期章节涉及作用机制,白血病的药物治疗,以及化疗在淋巴瘤中的作用。三章讨论全身化疗的细节,两章讨论局部灌注。关于威尔姆斯的肿瘤有一个单独的章节
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引用次数: 0
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Manufacturing chemist and aerosol news
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