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Performance of concrete grout under aggressive chloride environment in Sabah 沙巴侵蚀性氯化物环境下混凝土灌浆性能研究
Pub Date : 2013-01-24 DOI: 10.5281/ZENODO.1083519
S. Imbin, S. Dullah, H. Asrah, Paramasivam Suresh Kumar, M. E. Rahman, M. Mannan
Service life of existing reinforced concrete (RC) structures in coastal towns of Sabah has been affected very much. Concrete crack, spalling of concrete cover and reinforcement rusting of RC buildings are seen even within 5 years of construction in Sabah. Hence, in this study a new mix design of concrete grout was developed using locally available materials and investigated under two curing conditions and workability, compressive strength, Accelerated Mortar Bar Test (AMBT), water absorption, volume of permeable voids (VPV), Sorptivity and 90-days salt ponding test were conducted. The compressive strength of concrete grout at the age 90 days was found to be 44.49 N/mm 2 under water curing. It was observed that the percentage of mortar bar length change was below 1% for developed concrete grout. The water absorption of the concrete grout was in between the range of 0.88 % to 3.60 % under two different curing up to the age 90 days. It was also observed that the VPV of concrete was in the range of 0 % to 9.75 and 2.44% to 13.05% under water curing and site curing respectively. It was found that the Sorptivity of the concrete grout under water curing at the age of 28 days is 0.211mm/√min and at the age 90 day are 0.067 mm/√min. The chloride content decreased greatly, 90% after a depth of 15 mm. It was noticed that the site cured samples showed higher chloride contents near surface compared to water cured samples. This investigation suggested that the developed mix design of concrete grout using locally available construction materials can be used for crack repairing of existing RC structures in Sabah. Keywords—Concrete grout, Salt ponding, Sorptivity, Water absorption.
沙巴州沿海城镇既有钢筋混凝土结构的使用寿命受到很大影响。在沙巴,混凝土裂缝、混凝土覆盖层剥落和钢筋锈蚀甚至在5年内就可以看到钢筋混凝土建筑。因此,在本研究中,使用当地可用的材料开发了一种新的混凝土灌浆配合比设计,并在两种养护条件下进行了和易性、抗压强度、加速砂浆棒试验(AMBT)、吸水率、渗透空隙体积(VPV)、吸附性和90天盐池试验。水养护条件下,90 d龄期混凝土浆液抗压强度为44.49 N/mm 2。研究发现,发达的混凝土灌浆砂浆杆长变化百分比小于1%。龄期90 d前,两种养护方式下的混凝土浆液吸水率均在0.88% ~ 3.60%之间。在水养护和现场养护条件下,混凝土的VPV分别为0% ~ 9.75和2.44% ~ 13.05%。结果表明,水养护龄期28 d时混凝土浆液的吸水率为0.211mm/√min,龄期90 d时的吸水率为0.067 mm/√min。深度为15mm后,氯含量下降幅度较大,达90%。现场固化样品的近表面氯化物含量高于水固化样品。该调查表明,利用当地可用的建筑材料开发的混凝土灌浆配合比设计可用于沙巴现有RC结构的裂缝修复。关键词:混凝土灌浆;盐池;吸附性;
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引用次数: 3
SWNT sensors for monitoring the oxidation of edible oils 用于监测食用油氧化的SWNT传感器
Pub Date : 2011-02-01 DOI: 10.5369/jsst.2013.22.4.239
Keun-soo Lee, Kyongsoo Lee, V. W. Lau, K. Shin, B. Ju
Abstract Several methods are available to measure the oxidation of edible oils, such as their acid, peroxide, and anisidine values. However, thesemethods require large quantities of reagents and are time-consuming tasks. Therefore, a more convenient and time-saving way to measurethe oxidation of edible oils is required. In this study, an edible oil-condition sensor was fabricated using single-walled nanotubes(SWNTs) made using the spray deposition method. SWNTs were dispersed in a dimethylformamide solution. The suspension was thensprayed using a spray gun onto a prefabricated Au/Ti electrode. To test the sensor, oxidized edible oils, each with a different acid value,were prepared. The SWNT sensors were immersed into these oxidized oils, and the resistance changes in the sensors were measured. Wefound that the conductivity of the sensors decreased as the oxidation level of the oil increased. In the case of the virgin oil, the resistancechange ratio in the SWNT sensor S(%) = {[(Rf _ Ri)]/Ri}(%) was more than 40% after immersion for 1 min. However, in the case of theoxidized oil, the resistance change ratio decreased to less than that of the response of the virgin oil. This result suggests that the change inthe oil components induced by the oxidation process in edible oils is related to the conductivity change in the SWNT sensor.
几种方法可用于测量食用油的氧化,如它们的酸,过氧化物和茴香胺值。然而,这些方法需要大量的试剂,是耗时的任务。因此,需要一种更方便省时的方法来测量食用油的氧化程度。本研究采用喷雾沉积法制备了单壁纳米管(SWNTs),制备了食用油状态传感器。单壁碳纳米管分散在二甲基甲酰胺溶液中。然后用喷枪将悬浮液喷到预制的Au/Ti电极上。为了测试传感器,制备了具有不同酸值的氧化食用油。将SWNT传感器浸入氧化油中,测量传感器的电阻变化。我们发现,传感器的电导率随着油的氧化水平的增加而下降。对于原油,浸泡1 min后,SWNT传感器的电阻变化率S(%) = {[(Rf _ Ri)]/Ri}(%)大于40%,而对于氧化油,电阻变化率下降到小于原油的响应。这一结果表明,食用油中氧化过程引起的油组分变化与SWNT传感器的电导率变化有关。
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引用次数: 7
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World academy of science, engineering and technology
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