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Isotopic study of the Pb-Zn (Cu-Ag) Santa Maria Deposit, Caçapava do Sul Region, Rio Grande do Sul, Brazil 巴西南里奥格兰德州南卡帕拉帕瓦地区圣玛利亚铅锌(铜银)矿床同位素研究
IF 1.4 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2021-01-01 DOI: 10.1590/2317-4889202120200091
David Ramos Pereira, M. Macambira, Karen Pires, Samuel Bouças do Lago
The Camaquã Mines, in the central-southern region of Rio Grande do Sul State, Brazil, contain the largest deposits of base metals (Camaquã, Cu; Santa Maria, Pb-Zn) in the Camaquã Basin. The host rocks are consisted of sandstones and conglomerates of the Santa Bárbara Group and interbedded volcanic rocks of undefined stratigraphic position. Peperitic features were identified in a mineralized trachytic sill. An age of 565 ± 5 Ma (U-Pb LA-MC-ICP-MS) was obtained for another trachytic rock, which allowed for the identification, for the first time, of the Acampamento Velho Formation in the Camaquã Mines region. Stratigraphic relations demonstrate that both rocks represent this magmatism. Data from Pb isotopes and spatial relationship observed in the field indicate a possible genetic link between Acampamento Velho Formation and Camaquã mineralization. Pb isotopic data also suggest a predominantly older crustal source (1.07 Ga model age) for Pb and possibly for the other metals, with intermediate or mixed origin, suggesting that magmatic-hydrothermal fluids leached the metals from the percolated rocks of the basement.
Camaquã矿山位于巴西南里奥格兰德州中南部地区,含有最大的贱金属矿床(Camaquã, Cu;Santa Maria, Pb-Zn)在Camaquã盆地。寄主岩为Santa Bárbara群的砂岩、砾岩和地层位置不明确的互层火山岩。在矿化浅裂岩中发现了浅裂岩特征。另一组粗质岩的年龄为565±5 Ma (U-Pb LA-MC-ICP-MS),首次对Camaquã矿区的Acampamento Velho组进行了鉴定。地层关系表明,这两种岩石都代表了这种岩浆活动。Pb同位素数据和野外观测的空间关系表明,Acampamento Velho组与Camaquã成矿作用可能存在成因联系。铅同位素数据还表明,铅和其他金属的主要来源是较老的地壳(1.07 Ga模式年龄),可能是中间或混合来源,表明岩浆热液流体从基底渗透岩石中浸出金属。
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引用次数: 2
Evidence of Paleoproterozoic phosphogenesis in the Salvador-Curaçá Orogen (Tanque Novo-Ipirá Complex), northeastern São Francisco Craton, Brazil 巴西<s:1>弗朗西斯科克拉通东北部萨尔瓦多-库拉<s:1>造山带(Tanque novo - ipir<e:1>杂岩)古元古代磷化作用的证据
IF 1.4 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2021-01-01 DOI: 10.1590/2317-4889202120190137
Tatiana Silva Ribeiro, A. Misi, Luís Rodrigues Oliveira, J. H. S. Sá, D. Debruyne, Ib Silva Câmara
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引用次数: 1
Origin and metamorphism of graphite from Formiga, Minas Gerais (Brazil) 巴西米纳斯吉拉斯州Formiga地区石墨的成因及变质作用
IF 1.4 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2021-01-01 DOI: 10.1590/2317-4889202120200083
Luiza Carneiro de Rezende, A. O. Chaves, S. L. Ramos
During the Paleoproterozoic Era, the Brazilian cratons experienced orogenic events that modified the archean basement and sedimentary successions. In the southern São Francisco Craton, it can be recognized evidence of an orogenic event that happened between Rhyacian and Orosirian periods. It is related to the closure of an oceanic basin at this time, which led to the collision between the Archean Divinópolis and Campo Belo metamorphic complexes. Graphite schist occurs close to the cities of Formiga and Itapecerica (Minas Gerais), located between these complexes. To contribute to the understanding of the origin and metamorphism of the graphite from Formiga, petrographic studies, X-ray diffraction (XRD) and Raman spectroscopy analyses have been done. XRD and Raman methods revealed that the temperatures record-ed by graphite are around 460°C. However, Raman data showed that the crystallite sizes correspond to higher metamorphic grade conditions (amphibolite to granulite facies). Temperatures of 460°C are probably associated with hydrothermal processes along faults in post-collisional stage. The presence of todorokite, a mineral typical of deep-sea Mn nodules formed by microorganisms, in association with graphite from Formiga, suggests a biogenic origin for the graphite occurrence.
在古元古代,巴西克拉通经历了造山活动,改变了太古宙基底和沉积序列。在圣弗朗西斯科克拉通南部,它可以被认为是发生在利亚纪和奥罗纪之间的造山事件的证据。这与当时一个海洋盆地的关闭有关,这导致了太古代Divinópolis和Campo Belo变质杂岩之间的碰撞。石墨片岩发生在Formiga和Itapecerica (Minas Gerais)城市附近,位于这些复合体之间。为进一步了解Formiga石墨的成因和变质作用,对其进行了岩相学、x射线衍射(XRD)和拉曼光谱分析。XRD和Raman方法表明,石墨记录的温度约为460℃。然而,拉曼数据显示,晶体尺寸对应于较高变质等级的条件(角闪岩相到麻粒岩相)。460°C的温度可能与后碰撞阶段沿断层的热液作用有关。todorokite(一种由微生物形成的深海锰结核的典型矿物)的存在与Formiga的石墨有关,表明石墨的生物成因。
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引用次数: 1
Sequence stratigraphy of clastic and carbonate successions: applications for exploration and production of natural resources 碎屑和碳酸盐岩层序地层学:在自然资源勘探和生产中的应用
IF 1.4 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2021-01-01 DOI: 10.1590/2317-4889202120210014
A. Magalhães, D. G. C. Fragoso, G. Gabaglia, G. J. S. Terra, A. H. Melo, P. R. O. Andrade, F. Guadagnin, F. P. Lima-Filho
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引用次数: 3
Accretionary models for the Neoproterozoic evolution of the Borborema Province: advances and open questions borborrema省新元古代演化的增生模式:进展与悬而未决的问题
IF 1.4 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2021-01-01 DOI: 10.1590/2317-4889202120200104
Lauro Santos, F. Caxito
The current knowledge on the accretionary evolution of the Borborema Province is evaluated considering recently published data and inter-pretations. Early to late Neoproterozoic eclogite, ophiolite, and magmatic arc remnants have been documented and point to oceanic crust consumption. Isotopic contrasts as well as geophysical anomalies across the major domain boundaries are suggestive of collisional sutures and a speculative model of terrane accretion is presented here. On the other hand, the lack of concise evidence for some of the proposed deep-seated structures as well as putative lithospheric continuity in both sides of it suggest reworking of previously continuous lithosphere through intracontinental deformation in localized sectors of the province interior. It is patent that one model does not preclude the other and available evidence so far has triggered the emergence of conciliatory proposals for the Neoporterozoic history the Borborema Province.
考虑到最近公布的数据和解释,目前对Borborema省增生演化的知识进行了评估。新元古代早期至晚期的榴辉岩、蛇绿岩和岩浆弧遗迹已被记录,并指向海洋地壳的消耗。同位素对比以及主要区域边界上的地球物理异常提示了碰撞缝合线的存在,本文提出了一个推测的地表增生模型。另一方面,对于某些提出的深部构造以及假定的两侧岩石圈连续性缺乏简明的证据表明,在该省内部局部地区,通过陆内变形对先前连续的岩石圈进行了改造。很明显,一种模式并不排除另一种模式,到目前为止,现有的证据已经引发了关于borborrema省新古宙历史的和解提议的出现。
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引用次数: 13
Deformation mechanisms, mineral chemistry and zircon U-Pb geochronological constraints in the south Patos shear zone: implications for the crustal evolution of the Borborema Province, NE Brazil 南Patos剪切带的变形机制、矿物化学和锆石U-Pb年代学约束:对巴西东北部borborrema省地壳演化的启示
IF 1.4 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2021-01-01 DOI: 10.1590/2317-4889202120210048
Carolina Peixoto de Souza, Luís Gustavo Ferreira Viegas, Lauro Santos
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引用次数: 4
Mineral chemistry and genetic implications of garnet from the São João del Rei Pegmatitic Province, Minas Gerais, Brazil 巴西米纳斯吉拉斯州<s:1> o jo<e:1> o del Rei伟晶岩省石榴石矿物化学及成因意义
IF 1.4 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2021-01-01 DOI: 10.1590/2317-4889202120190136
Sarah Siqueira da Cruz Guimarães Sousa, C. Ávila, R. Neumann, F. Faulstich, F. Alves, Taís Proença Cidade, V. Silva
The pegmatites of the São João del Rei Pegmatitic Province are related to the Siderian protoliths of the Cassiterita and Resende Costa orthogneisses and to the Ritápolis metagranitoid of Ryacian age. Chemical analysis of garnet from twelve pegmatites reveal two different types of grains, which were found in the same pegmatitic body in six of these samples. One garnet type has almandine-spessartine composition (Sps 11.7-58.8 Alm 36.8-86.5 Prp 0.1-4.1 Grs 0.0-1.4 Adr 0.0-2.6 ), grains with orange and pink tones, and scarce mineral inclusions. These garnet grains may have been formed at the magmatic stage of pegmatite crystallization. The composition of these grains plot exclusively on the Alm-Sps axis at the Prp+Grs+Adr+Uvr × Alm × Sps diagram, as expected from garnet crystallized in pegmatites, and an expansion of the field associated to pegmatites is proposed. The second type has a distinct chemical composition (Sps 26.9-84.8 Alm 3.6-40.0 Prp 0.0-10.4 Grs 9.3-45.6 Adr 0.1-3.4 ), displaying enrichment in Ca. This Ca-enriched garnet has irregular shaped colourless grains and abundant mineral inclusions. These grains may have been formed by Ca-metasomatism during the late-stage crystallization of the pegmatites.
o jo o del Rei伟晶岩省的伟晶岩与Cassiterita和Resende Costa正长岩的Siderian原岩和Ryacian时代的Ritápolis变花岗岩有关。对12个伟晶岩中石榴石的化学分析显示,其中6个样品在同一伟晶岩体中发现了两种不同类型的石榴石颗粒。一种石榴石类型具有铝石榴石组成(Sps 11.7-58.8 Alm 36.8-86.5 Prp 0.1-4.1 Grs 0.0-1.4 Adr 0.0-2.6),颗粒呈橙色和粉红色,矿物包裹体稀少。这些石榴石颗粒可能形成于伟晶岩结晶的岩浆阶段。在Prp+Grs+Adr+Uvr × Alm × Sps图上,这些颗粒的组成完全在Alm-Sps轴上,正如在伟晶岩中结晶的石榴石所期望的那样,并且提出了与伟晶岩相关的场的扩展。第二种类型的石榴石具有独特的化学成分(Sps 26.9-84.8 Alm 3.6-40.0 Prp 0.0-10.4 Grs 9.3-45.6 Adr 0.1-3.4),富含Ca。该富Ca石榴石具有不规则的无色晶粒和丰富的矿物包裹体。这些颗粒可能是伟晶岩结晶后期的钙交代作用形成的。
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引用次数: 2
Field availability and mobility of metals in Ferralsols developed on ultramafic rock of Niquelândia, Brazil 在巴西niquel<s:1>印度超基性岩石上开发的Ferralsols金属的现场可用性和流动性
IF 1.4 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2021-01-01 DOI: 10.1590/2317-4889202120200092
J. Garnier, C. Quantin, S. Raous, E. Guimarães, T. Becquer
Ultramafic (UM) rocks are defined as igneous rocks that contain more than 90% of mafic minerals. Soils derived from ultramafic rock are generally nutrient-deficient and have concomitant high concentrations of potentially phytotoxic trace elements (Ni, Cr, Co, Mn). Consequently, to assess the dynamics of nutrients and metals in the ultramafic complex of Niquelândia (Brazil), soil solutions have been sampled in soils characterized by high Cr(VI) availability. The metal contents in surficial water have also been analyzed to investigate the metals’ leaching and mobility. Soil solutions featured low nutrient contents, a large Ca:Mg imbalance, and high Ni and Cr concentrations. Chromium was present in its toxic dissolved form (Cr(VI)) in the soil and surficial solutions. Metals concentrations were often above the toxic limit for biota and were therefore able to affect soil functioning. Ni behavior in the topsoil appeared to be primarily controlled by organic matter, while Cr was more likely to be released from Fe-oxides by anionic exchange. This result agreed with the Cr(VI) lability assessed using isotopic exchange kinetics in a companion study. In these serpentinic tropical soils, the highly leached Fe-oxide horizons appear to play a large role in the sequestration and diffuse leaching of labile Cr(VI) and Ni, respectively, in the deeper part of soil profiles and the topsoil. At the catchment scale, surficial solutions results suggest that metals may be exported to surrounding ecosystems that are not adapted to these metals.
超镁铁质(UM)岩石被定义为含有90%以上镁铁质矿物的火成岩。来自超镁质岩石的土壤通常缺乏营养,并伴有高浓度的潜在植物毒性微量元素(Ni, Cr, Co, Mn)。因此,为了评估niquel印度(巴西)超镁铁复合体中营养物质和金属的动态,在具有高Cr(VI)有效性的土壤中对土壤溶液进行了采样。分析了地表水中金属的含量,探讨了金属的淋溶和迁移。土壤溶液具有养分含量低、Ca:Mg失衡大、Ni和Cr浓度高的特点。铬以其有毒的溶解形式(Cr(VI))存在于土壤和地表溶液中。金属浓度往往超过生物群的有毒限度,因此能够影响土壤功能。表层土壤中Ni的行为主要受有机质控制,而Cr更可能通过阴离子交换从铁氧化物中释放出来。这一结果与一项伴随研究中使用同位素交换动力学评估的Cr(VI)不稳定性一致。在这些蛇形热带土壤中,高浸出的氧化铁层分别在土壤剖面的深层和表层土壤中对活性Cr(VI)和Ni的固存和扩散浸出发挥了重要作用。在流域尺度上,表面解决方案的结果表明,金属可能会出口到周围不适应这些金属的生态系统。
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引用次数: 2
Climatically induced changes in late Quaternary bathyal ostracod assemblages of the Camamu Basin, Brazil 巴西Camamu盆地晚第四纪深海介形类组合的气候变化
IF 1.4 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2021-01-01 DOI: 10.1590/2317-4889202120210039
C. T. Bergue, M. Ritter, J. Coimbra, K. B. Costa
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引用次数: 3
Marine or freshwater? Accessing the paleoenvironmental parameters of the Caldas Bed, a key marker bed in the Crato Formation (Araripe Basin, NE Brazil) 海洋的还是淡水的?巴西东北部Araripe盆地克拉托组关键标志层Caldas层古环境参数获取
IF 1.4 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2021-01-01 DOI: 10.1590/2317-4889202120200009
F. G. Varejão, V. D. Silva, M. L. Assine, L. Warren, S. Matos, M. G. Rodrigues, F. Fürsich, M. Simões
The Aptian Crato Formation is world renowned for its well-preserved fossils in microbially-induced laminated limestones, which are regarded as one of the main Cretaceous Konservat-Lagerstätte of the geological record. Detailed stratigraphic investigation and mapping of the up to 90-m-thick Crato Formation at the eastern border of the Araripe Plateau allowed recognition of a regionally persistent fossil-bearing muddy interval, herein defined as the Caldas Bed. At its type locality, it is defined as an up to 2-m-thick coarsening-upward succession of grey/green mudstone and interbedded sandy siltstone and claystone. The 0.85- to 2-m-thick interval was recognized in several localities along the outcrop belt, and it is bounded by sharp, lower ( Konservat-Lagerstätte limestone) and upper (sandstone and heterolithic facies) contacts. Despite previous literature data suggesting the presence of marine mollusks, the bed contains freshwater bivalves, small gastropods, spinicaudatans, plant remains, trace fossils, and rare ostracods. The Caldas Bed records benthic paleocommunities representing a short-term isochronous regional freshening event, marked by abrupt changes in sedimentation pattern, bathymetry, salinity, oxygenation and water
阿普提亚克拉托地层以其保存完好的微生物层状石灰岩化石而闻名于世,被认为是白垩纪地质记录的主要化石之一Konservat-Lagerstätte。对Araripe高原东部边界厚达90米的克拉托组进行了详细的地层学调查和测绘,发现了一个区域性持久的含化石的泥质层,这里定义为Caldas层。在其类型位置,定义为厚达2 m的灰绿色泥岩和砂质粉砂岩、粘土岩互层的粗化向上演替。在露头带的几个地方发现了0.85 ~ 2 m厚的层段,并被尖锐的、下部(Konservat-Lagerstätte灰岩)和上部(砂岩和异质石器相)接触层所包围。尽管以前的文献数据表明存在海洋软体动物,但该床含有淡水双壳类,小型腹足类,棘足类,植物遗骸,痕迹化石和罕见的介形类。卡尔达斯床记录的底栖生物群落代表了一个短期等时区域性更新事件,其特征是沉积模式、水深、盐度、氧合和水的突变
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引用次数: 17
期刊
Brazilian Journal of Geology
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