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Ceramic Materials - Synthesis, Characterization, Applications and Recycling最新文献

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Plasma Resistance Evaluation and Characteristics of Yttria Ceramics Sintered by Using Calcination Yttria 氧化钇煅烧烧结氧化钇陶瓷的等离子体电阻评价及特性研究
Pub Date : 2019-03-20 DOI: 10.5772/intechopen.81750
Jin Sam Choi
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引用次数: 0
Impedance Spectroscopy: A Powerful Technique for Study of Electronic Ceramics 阻抗谱:研究电子陶瓷的一项有力技术
Pub Date : 2019-03-04 DOI: 10.5772/INTECHOPEN.81398
S. Pandey, D. Kumar, O. Parkash, L. Pandey
Electronic ceramics are technological materials having a vast variety of applications such as actuators and sensors, computer memories, electrically controlled microwave tuning devices for RADAR, etc. and are playing key role in electronics industry today. An electronic ceramic component can be visualised as grain-grain boundary-electrode system. Impedance spectroscopy is being widely used to separate out contributions of these to the overall property of a ceramic. This involves equivalent circuit models. To facilitate development of suitable equivalent circuit models and obtain values of the components, some most useful circuits with their simulated behaviour are presented. Steps highly useful in the modelling process are summarised. The procedure of impedance spectroscopy is illustrated by analysing the impedance data of the ceramic system BaFexTi1-xO3 (x = 0.05) containing two phases.
电子陶瓷是一种具有广泛应用的技术材料,如执行器和传感器、计算机存储器、用于雷达的电控微波调谐装置等,在当今的电子工业中发挥着关键作用。电子陶瓷元件可以可视化为晶粒-晶粒边界-电极系统。阻抗谱被广泛用于分离出这些对陶瓷整体性能的贡献。这涉及等效电路模型。为了方便建立合适的等效电路模型和获得元件的值,给出了一些最有用的电路及其模拟行为。总结了建模过程中非常有用的步骤。通过分析含两相陶瓷体系BaFexTi1-xO3 (x = 0.05)的阻抗数据,说明了阻抗谱的过程。
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引用次数: 9
Introductory Chapter: Ceramic Materials - Synthesis, Characterization, Applications and Recycling 导论章:陶瓷材料-合成、表征、应用和回收
Pub Date : 2019-02-21 DOI: 10.5772/INTECHOPEN.84710
D. Eliche-Quesada, L. Pérez-Villarejo, P. Sánchez-Soto
Ceramic materials can be defined as inorganic materials constituted by the combination of metallic and nonmetallic elements whose properties depend on the way in which these elements are linked [1, 2]. Ceramic materials are the most versatile branch of materials. The origin of this versatility lies in the chemical nature of its bonds, since they are mainly constituted by strong ionic and covalent bonds in different proportions. The bonds determine a series of particular properties of ceramic materials among which are relatively high fusion temperatures, high modulus, high wear strength, poor thermal properties, high hardness and fragilities combined with tenacities, and low ductility. In addition to the lack of conduction electrons since they are combined forming chemical bonds, they are good electrical insulators. Ceramic materials can be divided into two large groups: traditional ceramics and technical or advanced ceramics. Traditional ceramics can be defined as those that are based on silicates, among which are cement, clay products, and refractories. Traditional ceramics are produced in large volumes and constitute an important market. Traditional ceramic materials are made with raw materials from natural deposits such as clay materials. The second group, technical or advanced ceramics, is manufactured with artificial raw materials that have undergone an important chemical processing to achieve a high purity and an improvement of their physical characteristics. Therefore, they are manufactured with more advanced and sophisticated methods. Among them are carbides, nitrides, borides, pure oxides, and a great variety of ceramics with magnetic, ferroelectric, piezoelectric, and superconducting applications, among others. These ceramics possess excellent mechanical properties under extreme conditions of tension, high wear strength or excellent electrical, magnetic, or optical properties, or exceptional strength to high temperatures and corrosive environments, showing high strength to chemical attack [3]. There is a third group that is glasses that, although considered ceramic, are studied separately because they differ from the first group in the order reached by their crystalline structures as glass-ceramics. The versatility mentioned above also allows ceramics to be used for a large number of end user and applications for the construction and building industry such as clay bricks and blocks, sanitary ware, and wall and floor tiles; in household
陶瓷材料可以定义为由金属和非金属元素组合而成的无机材料,其性质取决于这些元素的连接方式[1,2]。陶瓷材料是材料中用途最广的一个分支。这种多功能性的起源在于其化学键的化学性质,因为它们主要由不同比例的强离子键和共价键组成。这些键决定了陶瓷材料的一系列特殊性能,其中包括较高的熔合温度、高模量、高耐磨强度、较差的热性能、高硬度和脆性结合韧性以及低延展性。除了由于它们结合形成化学键而缺乏传导电子之外,它们还是很好的电绝缘体。陶瓷材料可分为两大类:传统陶瓷和技术或高级陶瓷。传统陶瓷可以定义为以硅酸盐为基础的陶瓷,其中包括水泥、粘土制品和耐火材料。传统陶瓷产量大,是一个重要的市场。传统的陶瓷材料是用天然沉积物中的原料制成的,比如粘土材料。第二种是技术陶瓷或高级陶瓷,是用经过重要化学处理的人工原料制造的,以达到高纯度并改善其物理特性。因此,它们是用更先进和复杂的方法制造的。其中包括碳化物、氮化物、硼化物、纯氧化物,以及各种具有磁性、铁电、压电和超导等用途的陶瓷。这些陶瓷在极端拉伸条件下具有优异的机械性能,高耐磨强度或优异的电、磁或光学性能,或在高温和腐蚀环境下具有优异的强度,具有很高的抗化学侵蚀强度[3]。第三类是玻璃,虽然被认为是陶瓷,但要分开研究,因为它们与第一种玻璃陶瓷的晶体结构顺序不同。上述多功能性还允许陶瓷用于建筑和建筑行业的大量最终用户和应用,如粘土砖和砌块,卫生洁具以及墙地砖;在家庭
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引用次数: 1
Synthesis of High-Purity Ceramic Nano-Powders Using Dissolution Method 溶解法制备高纯度纳米陶瓷粉体
Pub Date : 2018-11-27 DOI: 10.5772/INTECHOPEN.81983
S. Pratapa, Ella Agustin Dwi Kiswanti, Dien Rosma Diana, Y. Hariyani, Lisma Dian Kartika Sari, M. Musyarofah, T. Triwikantoro, M. Baqiya
A set of ceramic powders has been synthesized using a “ bottom-up ” approach which is denoted here as the dissolution method. The raw materials were metal powders or minerals. The dissolution media were strong acid or base solutions. In the case of metallic raw materials, magnesium and titanium powders were sepa-rately dissolved in hydrochloric acid to obtain their precursors. They were then dried, washed, and calcined in air at various temperatures to produce pure MgO and TiO 2 nano-powders. Pure MgTiO 3 nano-powders by mixing the precursors at the stoichiometric ratio and calcining the dried mixture at a temperature as low as 700°C have also been successfully synthesized. In the mineral case, local zircon sand was used as the raw material. A standard procedure to extract the “ clean ” and pure zircon powder was applied which included washing, magnetic separation, and reac-tions using hydrochloric acid and sodium hydroxide. A pure zircon nano-powder was obtained by applying mechanical ball-milling to the zircon powder. The zircon powder was also chemically dissociated to give amorphous silica (SiO 2 ), cristobalite, amorphous zirconia (ZrO 2 ), and nanometric tetragonal zirconia powders.
采用“自下而上”的方法合成了一组陶瓷粉末,这里称为溶解法。原料是金属粉末或矿物。溶解介质为强酸或强碱溶液。以金属原料为例,将镁粉和钛粉分别溶解在盐酸中,得到它们的前体。然后将它们干燥,洗涤,并在不同温度下在空气中煅烧,以生产纯MgO和二氧化钛纳米粉末。将前驱体按化学计量比混合,在低至700℃的温度下煅烧,成功地合成了纯净的mgtio3纳米粉体。在矿物案例中,以当地的锆石砂为原料。采用标准程序提取“干净”的纯锆石粉末,包括洗涤、磁选和盐酸和氢氧化钠反应。采用机械球磨法制备了纯锆石纳米粉。锆石粉末也被化学解离得到无定形二氧化硅(sio2)、方石英、无定形氧化锆(ZrO 2)和纳米四边形氧化锆粉末。
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引用次数: 1
The Use of Ceramic Waste Powder (CWP) in Making Eco-Friendly Concretes 陶瓷废粉(CWP)在环保混凝土中的应用
Pub Date : 2018-11-05 DOI: 10.5772/INTECHOPEN.81842
A. El-Dieb, M. Taha, S. I. Abu-eishah
The global production of ceramic waste powder (CWP), which is produced during the final polishing process of ceramic tiles, exceeds 22 billion tons. The disposal of CWP in landfills will cause significant environmental problems (i.e., soil, air, and groundwater pollution). CWP is characterized by its chemical composition that is mainly composed of silica (SiO 2 ) and alumina (Al 2 O 3 ). Both minerals represent more than 80% of the CWP composition. CWP has potentials to be used as an ingredient to partially or entirely replacing Portland cement to make eco-friendly concretes. This chapter summarizes the effect of using CWP in making eco-friendly concretes, with a particular focus on using CWP as a partial cement replacement in conventional-vibrated concrete (CVC) and self-compacting concrete (SCC), and the production of zero-cement alkali-activated concrete (AAC). for RCPT, bulk resistivity and permeable tests and the average used. by at microstructure characteristics are identified using scanning electron microscopy (SEM).
在瓷砖最后抛光过程中产生的陶瓷废粉(CWP)的全球产量超过220亿吨。在堆填区弃置水能会造成严重的环境问题(即土壤、空气和地下水污染)。CWP的特点是其化学成分主要由二氧化硅(sio2)和氧化铝(al2o3)组成。这两种矿物占CWP组成的80%以上。CWP有潜力作为一种成分,部分或完全取代波特兰水泥,以制造环保混凝土。本章总结了使用CWP制造环保混凝土的效果,特别关注使用CWP作为常规振动混凝土(CVC)和自密实混凝土(SCC)中的部分水泥替代品,以及零水泥碱活化混凝土(AAC)的生产。对于RCPT,使用体电阻率和渗透性试验和平均值。利用扫描电子显微镜(SEM)对其微观结构特征进行了表征。
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引用次数: 20
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Ceramic Materials - Synthesis, Characterization, Applications and Recycling
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