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Design of Multi-Cell FDM Build Bed Systems for Optimal Material Usage in Additive Manufacturing Process 增材制造过程中优化材料使用的多单元FDM构建床系统设计
Pub Date : 2026-02-09 DOI: 10.1155/mdp2/7334170
Addisu Workiye, Yonas Tsega

Support structures are essential in additive manufacturing (AM) processes such as material extrusion, particularly for fabricating parts with overhanging features. However, conventional supports are typically removed after printing and cannot be reused, resulting in significant material waste and increased printing time. To address these limitations, this research introduces a novel multi-cell FDM build bed support system designed to minimize support-related challenges in fused deposition modeling (FDM). The proposed system employs an array of movable pins that function as a dynamically adjustable build platform controlled by an Arduino-based program. During the printing process, the pins elevate layer by layer, corresponding to the layer thickness. Each pin automatically stops at a predetermined height through an electromechanical control system. The lifting mechanism operates via a programmable stepper motor, whereas magnetic coupling between permanent magnets and metallic washers ensures stable support and protects the printed component from damage during detachment. Additionally, a hybrid support approach has been developed for printing curved geometries. This method combines traditional printed supports with the multi-cell FDM bed system, allowing the adjustable platform to provide sufficient support and significantly reduce the need for printed material. For highly complex overhangs beyond the bed′s adjustable range, conventional supports are selectively employed. Experimental results demonstrate that the proposed multi-cell FDM build bed system achieves up to 16.22% reduction in material consumption and 22.19% reduction in printing time compared with tree support and conventional FDM printing methods.

支撑结构在增材制造(AM)工艺中是必不可少的,例如材料挤压,特别是用于制造具有悬垂特征的部件。然而,传统的支撑通常在打印后被移除,不能重复使用,导致大量的材料浪费和增加打印时间。为了解决这些限制,本研究引入了一种新型的多单元FDM构建床支撑系统,旨在最大限度地减少熔融沉积建模(FDM)中与支撑相关的挑战。该系统采用一系列可移动的引脚,作为一个动态可调的构建平台,由基于arduino的程序控制。在印刷过程中,别针逐层升高,对应于层厚。每个引脚通过机电控制系统自动停止在预定的高度。提升机构通过可编程步进电机运行,而永久磁铁和金属垫圈之间的磁耦合确保稳定的支撑,并保护打印部件在分离过程中免受损坏。此外,还开发了一种用于打印弯曲几何形状的混合支撑方法。该方法将传统的打印支架与多单元FDM床系统相结合,允许可调节平台提供足够的支撑,并显着减少对打印材料的需求。对于超出床的可调节范围的高度复杂的悬垂,可以选择性地使用传统的支撑。实验结果表明,与树形支撑和传统的FDM打印方法相比,所提出的多单元FDM构建床系统的材料消耗减少了16.22%,打印时间减少了22.19%。
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引用次数: 0
Joining Optimization, Temperature, and IMC Evaluation for AL to Steel Friction Stir Spot Welding 铝与钢搅拌摩擦点焊的连接优化、温度及IMC评价
Pub Date : 2025-12-29 DOI: 10.1155/mdp2/5713884
Mohanad Kadhim Mejbel, Isam Tareq Abdullah, Bassim Mohammed Abd

Friction stir spot welding (FSSW) effectively solves many problematic welding metals, such as dissimilar metals and thin alloy sheets. Carbon steel-AISI 1006 top sheet and an aluminum alloy AA2024-T3 bottom sheet were joined by FSSW with a cylindrical pinless tool. Joints are evaluated in terms of temperature, mechanical characteristics, microstructure, and macrostructure. With the other variables of the welding operation being constant, the influence of spindle speed, dwell duration, and penetration depth on the force of tensile shear failure has been studied throughout the welding process. The welding parameters were 10 and 15-s preheating time, 0.2, 0.4, and 0.6 mm plunging depth. Rotational speed was 710, 900, 1400, and 1800 rpm. A shear tensile test was utilized to examine the bonded specimens. At the optimal conditions, a microstructural analysis was conducted. Both interfacial and pullout fractures were found in the AA2024-T3 and carbon steel sheets. Intermetallic compounds (IMCs) located at the weld interface were evaluated.

搅拌摩擦点焊(FSSW)有效地解决了异种金属和薄板合金等金属的焊接难题。碳钢- aisi 1006顶板和铝合金AA2024-T3底板采用FSSW与圆柱无销刀具连接。从温度、力学特性、微观结构和宏观结构等方面对接头进行评估。在其他焊接操作变量不变的情况下,研究了焊接过程中主轴转速、停留时间、焊深对拉伸剪切破坏力的影响。焊接参数分别为预热时间10和15s,熔深0.2、0.4和0.6 mm。转速分别为710、900、1400和1800 rpm。采用剪切拉伸试验对粘结试件进行了检验。在最佳条件下,进行了显微组织分析。AA2024-T3和碳钢板均存在界面断裂和拉出断裂。对焊缝界面的金属间化合物(IMCs)进行了评价。
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引用次数: 0
Morphological and Mechanical Analysis of Epoxy–Chicken Feather Fiber Composites With COMSOL-Assisted Simulation comsol辅助模拟环氧-鸡毛纤维复合材料的形态和力学分析
Pub Date : 2025-12-18 DOI: 10.1155/mdp2/5587820
Zeina Talib Kareem, Zainab Waheed Abdullah, Heyam Razaq Atwan

This study utilized epoxy as a matrix for biocomposites reinforced with chicken feather fibers, which were produced by a manual mixing technique. Various loadings of feather fibers of 0.5, 1, 1.5, and 2 wt% were utilized following chemical treatment. Optical and scanning electron microscopies were employed to examine the morphological structure of biocomposites. Additionally, tensile, bending, impact, and hardness tests were conducted to assess the mechanical properties of biocomposites. Low fiber loadings of 0.5 and 1 wt% yielded enhanced mechanical properties relative to 1.5 and 2 wt% feather fiber loadings, attributable to better dispersion and integration within the epoxy matrix, as corroborated by morphological images. The manual mixing technique was more appropriate for feather loading below 2 wt%. Furthermore, the simulated results aligned well with the experimental tensile outcomes. The eco-friendly materials developed in this study could serve alternative applications, significantly reducing chicken feather waste in the environment and mitigating pollution issues.

本研究以环氧树脂为基质,通过人工混合技术制备鸡毛纤维增强生物复合材料。化学处理后,不同重量的羽毛纤维分别为0.5、1、1.5和2 wt%。利用光学显微镜和扫描电镜对生物复合材料的形态结构进行了研究。此外,还进行了拉伸、弯曲、冲击和硬度测试,以评估生物复合材料的机械性能。形态学图像证实,相对于1.5 wt%和2 wt%的羽毛纤维负荷,0.5 wt%和1 wt%的低纤维负荷产生了更好的机械性能,这是由于在环氧基体中更好的分散和整合。人工混合技术更适合于2 wt%以下的羽毛负荷。此外,模拟结果与实验拉伸结果吻合良好。本研究开发的环保材料可用于替代应用,显著减少鸡毛在环境中的浪费,缓解污染问题。
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引用次数: 0
Correlation Between Electrochemical Impedance Spectroscopy and LCR Parameter Meter in the Corrosion Processes of Steel-Reinforced Mortars 电化学阻抗谱与LCR参数计在钢增强砂浆腐蚀过程中的相关性研究
Pub Date : 2025-12-15 DOI: 10.1155/mdp2/9210864
Juan Diego Bolaños Ortiz, Abilo Andres Velasquez Salazar, Yhan Paul Arias Jaramillo

Measuring corrosion in reinforcing steel embedded in mortar or concrete is a challenge that must always be considered. Electrochemical impedance spectroscopy (EIS) provides a useful estimation of corrosion rates, but its complexity and sensitivity mainly confine it to laboratory testing. On the other hand, the LCR meter, a small and portable device commonly used for testing circuits, measures impedance, capacitance, and inductance. Applying the EIS approach, which views elements as arrays of resistances and capacitances, allows inferring that it is possible to measure corrosion with the LCR meter by comparing it with EIS. To explore this, tests were conducted on cylindrical mortar samples with reinforcing steel, following a 2 × 3 factorial design with three replicates. After accelerated corrosion, a linear relationship was observed between the Rct parameter from EIS and the 100 Hz impedance from the LCR meter in samples subjected to impressed current. However, in samples subjected to carbonation, the techniques could not be correlated, possibly because the carbonation front had not yet depassivated the steel. The combination of chlorides and carbonation showed opposite effects: chlorides reduce the impedance of the mortar cover, while carbonation increases its resistivity. These results are a first step towards developing a new corrosion detection method based on the LCR meter, offering advantages in handling, time, cost, and portability.

测量嵌入砂浆或混凝土中的钢筋的腐蚀是一个必须始终考虑的挑战。电化学阻抗谱(EIS)提供了有用的腐蚀速率估计,但其复杂性和灵敏度主要局限于实验室测试。另一方面,LCR计是一种小型便携式设备,通常用于测试电路,测量阻抗、电容和电感。采用EIS方法,将元件视为电阻和电容阵列,可以通过与EIS进行比较,推断LCR仪表可以测量腐蚀。为了探讨这一点,在带有钢筋的圆柱形砂浆样品上进行了试验,遵循3个重复的2 × 3析因设计。加速腐蚀后,EIS的Rct参数与外加电流下LCR计的100hz阻抗之间存在线性关系。然而,在经过碳化的样品中,这两种技术不能相互关联,可能是因为碳化锋尚未使钢脱钝化。氯化物与碳化的组合表现出相反的效果:氯化物降低了砂浆覆盖层的阻抗,而碳化增加了砂浆覆盖层的电阻率。这些结果是开发基于LCR仪表的新型腐蚀检测方法的第一步,在操作、时间、成本和便携性方面具有优势。
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引用次数: 0
Improved Lap Shear Strength of Ti6Al4V/CF-PPS Joints Through Electrical Discharge Machining Surface Texturing 电火花加工表面织构提高Ti6Al4V/CF-PPS接头搭接剪切强度
Pub Date : 2025-12-11 DOI: 10.1155/mdp2/8956926
Victor Caso Moreira, Artur Fernando de Vito Jr., Adalto Farias, Fabrizio Leonardi, Sergio Delijaicov, Rodrigo Magnabosco

This study investigates friction-assisted spot joining (FASJ) of Ti6Al4V alloy and carbon fiber–reinforced polyphenylene sulfide (CF-PPS) composites using electrical discharge machining (EDM) surface pretreatment combined with process parameter optimization. EDM texturing generated superficial roughness that promoted mechanical interlocking between the molten polymer and the titanium surface. A central composite design was applied to evaluate the effects of rotational speed (RS) and plunge depth (PD), identifying optimal conditions that maximized lap shear strength while minimizing polymer degradation. Results showed that intermediate RSs favored bond formation by maintaining temperatures within the PPS melting range and preventing excessive thermal damage. Posttest characterization confirmed the formation of a bonded annular region that governed joint performance. The optimized process achieved lap shear strength values comparable to and, in some cases, exceeding those reported for other metal–composite joining techniques. Specifically, the EDM texturing process reached 33.1 MPa, outperforming most laser-welded Ti/CF-PEEK joints (2–37.3 MPa) and approaching the strength levels typically observed in aluminum–polymer benchmarks (≈55 MPa). These results demonstrate the effectiveness of the EDM-induced surface features in enhancing mechanical interlocking and interfacial adhesion. These findings demonstrate that combining EDM pretreatment with controlled thermal input enhances the reliability of FASJ for lightweight structural applications.

采用电火花加工(EDM)表面预处理与工艺参数优化相结合的方法,研究了Ti6Al4V合金与碳纤维增强聚苯硫醚(CF-PPS)复合材料的摩擦辅助点连接(FASJ)。电火花加工产生的表面粗糙度促进了熔融聚合物和钛表面之间的机械联锁。采用中心复合设计来评估转速(RS)和倾入深度(PD)的影响,确定最大限度地提高堆接剪切强度,同时最大限度地减少聚合物降解的最佳条件。结果表明,中间RSs通过将温度保持在PPS熔化范围内并防止过度热损伤而有利于键的形成。后测表征证实形成了一个粘合的环形区域,控制了接头的性能。优化后的工艺达到了与其他金属复合材料连接技术相当的搭接剪切强度值,在某些情况下,甚至超过了其他金属复合材料连接技术。具体来说,EDM织构过程达到33.1 MPa,优于大多数激光焊接Ti/CF-PEEK接头(2-37.3 MPa),接近铝聚合物基准中典型的强度水平(≈55 MPa)。这些结果证明了电火花诱导的表面特征在增强机械联锁和界面粘附方面的有效性。这些研究结果表明,将电火花加工预处理与可控热输入相结合,可以提高FASJ在轻量化结构应用中的可靠性。
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引用次数: 0
Preparation and Characterization of Multiphase WxTixMoNbTaV Refractory High-Entropy Alloys 多相WxTixMoNbTaV难熔高熵合金的制备与表征
Pub Date : 2025-11-14 DOI: 10.1155/mdp2/8780187
Mohammed Khazal Hussain, Moneer H. Tolephih, Nasri S. M. Namer, Masoud Atapour

Refractory high-entropy alloys (RHEAs) have emerged as promising materials. They offer a viable alternative to nickel-based superalloys due to their excellent mechanical property stability at high temperatures, superior oxidation and corrosion resistance, and phase stability under extreme conditions. In this study, three different RHEA compositions of WxTixMoNbTaV RHEAs (x1 = (1, 0), x2 = (0, 1), and x3 = (0.5, 0.5)) were synthesized by partially or fully substituting titanium for tungsten under identical conditions to investigate the effect of this modification on the microstructure. Mechanical alloying was performed for 60 h to obtain powders with a single-phase BCC structure, followed by spark plasma sintering (SPS) at temperatures varying from 1200°C to 1400°C. XRD results indicated a relative stability of the BCC phase structure, with some phase segregations leading to the formation of some secondary phases in low percent. These secondary phases′ proportion and chemical composition varied depending on the alloy composition and sintering temperature. On the other hand, elevating the sintering temperature clearly enhances densification, although the extent of enhancement differs according to various alloy designs. Finally, the presence of the ductile-element–enriched phases is expected to significantly influence the microstructure and contribute to the enhancement of mechanical properties, which will be explored in a subsequent study.

难熔高熵合金(RHEAs)是一种很有前途的材料。它们提供了镍基高温合金的可行替代品,因为它们在高温下具有优异的机械性能稳定性,卓越的抗氧化和耐腐蚀性,以及极端条件下的相稳定性。本研究在相同的条件下,通过部分或完全取代钨,合成了三种不同的WxTixMoNbTaV RHEAs (x1 = (1,0), x2 = (0,1), x3 =(0.5, 0.5))的RHEA组成,研究了这种改性对微观结构的影响。机械合金化60 h得到单相BCC结构的粉末,然后在1200 ~ 1400℃的温度下进行放电等离子烧结(SPS)。XRD结果表明,BCC的相结构相对稳定,存在一定程度的相偏析,形成了一定比例的次级相。这些次级相的比例和化学成分随合金成分和烧结温度的变化而变化。另一方面,提高烧结温度明显增强致密化,尽管增强程度因合金设计不同而不同。最后,富含韧性元素的相的存在预计会显著影响微观组织,并有助于提高力学性能,这将在后续的研究中进行探讨。
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引用次数: 0
Advancements and Future Perspectives in Oil–Water Membrane Technology 油水膜技术的研究进展与展望
Pub Date : 2025-10-10 DOI: 10.1155/mdp2/1885168
Nthabiseng Jane Ramanamane, Mothibeli Pita

This review paper provides a comprehensive analysis of the advancements and future directions in oil–water membrane technology, a critical solution for addressing environmental challenges associated with wastewater treatment and oil pollution. The review focuses on various membrane technologies employed in oil–water separation, including microfiltration, ultrafiltration, and nanofiltration, highlighting their effectiveness and operational mechanisms. It discusses key challenges encountered by these technologies, such as membrane fouling, high operational costs, and limitations in large-scale applications, which hinder their broader adoption. The paper further examines the characteristics of oil–water membranes, including hydrophilicity, oleophobicity, pore size, and surface roughness, which are crucial in determining separation efficiency. Commonly used materials for developing oil–water filtration membranes are also explored, encompassing polymeric, ceramic, and hybrid materials, with a focus on innovations that enhance performance and sustainability. Additionally, the evaluation of membrane performance is addressed through metrics such as flux, rejection rate, and fouling resistance, offering insights into their suitability for various applications. The review also investigates the parameters varied during oil–water filtration, such as pressure and temperature, and their impact on membrane efficiency and durability. This paper is aimed at providing a roadmap for future research and development in oil–water membrane technology, emphasizing the need for durable, fouling-resistant membrane designs and the exploration of cost-effective materials (such as quartz-based media) to meet global water treatment demands.

油水膜技术是解决污水处理和石油污染相关环境挑战的关键解决方案,本文综述了油水膜技术的研究进展和未来发展方向。综述了目前应用于油水分离的各种膜技术,包括微滤、超滤和纳滤,重点介绍了它们的效果和作用机理。讨论了这些技术面临的主要挑战,如膜污染、高运行成本和大规模应用的局限性,这些都阻碍了它们的广泛应用。本文进一步研究了油水膜的特性,包括亲水性、疏油性、孔径和表面粗糙度,这些都是决定分离效率的关键因素。还探讨了用于开发油水过滤膜的常用材料,包括聚合物,陶瓷和混合材料,重点是提高性能和可持续性的创新。此外,通过通量、截留率和抗污性等指标来评估膜的性能,从而深入了解膜在各种应用中的适用性。研究了油水过滤过程中压力、温度等参数变化对膜效率和耐久性的影响。本文旨在为油水膜技术的未来研究和发展提供路线图,强调需要耐用,耐污染的膜设计和探索具有成本效益的材料(如石英基介质),以满足全球水处理需求。
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引用次数: 0
Ultrasonic Vibration-Assisted Milling of AISI H19 Hardened Hot Working Tool Steel AISI H19淬火热加工工具钢的超声振动辅助铣削
Pub Date : 2025-09-30 DOI: 10.1155/mdp2/6800758
Mohanad Kadhim Mejbel, Isam Tareq Abdullah

Manufacturers, particularly those working in the mould and die industry, encounter several challenges in achieving the optimal surface finish. Approximately 40–60 HRC hardened hot working tool steel is used for the majority of the mould and die materials. Because of the tremendous strength of these materials, the conventional machining processes were limited in their capacity to machine them. When using conventional machining, it will encounter issues such as high tool wear rates and a poor machined surface finish. To address these issues, this research presented a hybrid machining method that incorporates ultrasonic vibration in an axial orientation into the conventional system tooling, referred to as ultrasonic vibration-assisted milling (UVAM), to solve the issues mentioned above. This research was undertaken to understand the effect of axial UVAM parameters on AISI H19 hardened hot working tool steel surface finish. To verify the efficiency of the suggested approach in improving the level of hardened AISI H19 tool steel machined surface roughness, we compared conventional milling (CM) to UVAM for various parameters, including milling spindle revolving speed, rate of feed and cutting depth. Axial UVAM dramatically reduced the machined surface roughness, with up to a 36.7% decrease in the value of Ra compared to the CM approach under the same cutting circumstances, according to the results of the milling tests. The surface prepared by UVAM was homogeneous and had proportionate peak-to-peak magnitude, which enhanced the surface quality, according to the macroscopic examination of the machined surface. Ra values have been strongly affected by the interlinkage between the cutting variables investigated. Continual hammering between the workpiece and cutter teeth greatly influences surface roughness, which is greatly influenced by frequency vibration. When ultrasonic vibration is applied, the level of surface roughness drops dramatically.

制造商,特别是那些在模具行业工作的制造商,在实现最佳表面光洁度方面遇到了一些挑战。大约40-60 HRC淬火热加工工具钢用于大多数模具和模具材料。由于这些材料的巨大强度,传统的加工工艺在加工它们的能力上是有限的。当使用常规加工时,会遇到刀具磨损率高、加工表面光洁度差等问题。为了解决这些问题,本研究提出了一种混合加工方法,将超声振动轴向结合到传统系统刀具中,称为超声振动辅助铣削(UVAM),以解决上述问题。本研究旨在了解轴向UVAM参数对AISI H19淬火热加工工具钢表面光洁度的影响。为了验证该方法在提高淬硬AISI H19工具钢加工表面粗糙度水平方面的有效性,我们将常规铣削(CM)与UVAM在铣削主轴转速、进给速率和切削深度等参数上进行了比较。根据铣削测试的结果,轴向UVAM显著降低了加工表面的粗糙度,在相同的切削情况下,与CM方法相比,Ra值降低了36.7%。通过对加工表面的宏观检测,UVAM制备的表面均匀且峰峰大小成比例,提高了表面质量。Ra值受到所研究的切削变量之间的相互联系的强烈影响。工件与刀齿之间的连续锤击对表面粗糙度影响很大,而表面粗糙度受频率振动的影响较大。当施加超声振动时,表面粗糙度水平急剧下降。
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引用次数: 0
Synergistic Effects of W and Ti on the Mechanical Performance of WxTixMoNbTaV Refractory High-Entropy Alloys W和Ti对WxTixMoNbTaV难熔高熵合金力学性能的协同效应
Pub Date : 2025-09-16 DOI: 10.1155/mdp2/2598334
Mohammed Khazal Hussain, Moneer H. Tolephih, Nasri S. M. Namer, Masoud Atapour

Recent research has shown a growing interest in refractory high-entropy alloys (RHEAs) due to the increasing demand for materials that exhibit exceptional mechanical strength, high ductility, excellent thermal stability and superior resistance to oxidation and corrosion. This study focuses on designing and fabricating three WxTixMoNbTaV RHEAs to achieve an optimal balance between strength and ductility at room temperature. The selection strategy was based on leveraging the high strength of tungsten (W) and the excellent ductility of titanium (Ti) to develop an alloy with superior mechanical performance. Three distinct compositions (x1 = [1, 0], x2 = [0, 1] and x3 = [0.5, 0.5]) were synthesised under identical conditions using mechanical alloying (MA), followed by spark plasma sintering (SPS). In our previous study, we conducted an in-depth characterisation of phase transformations during MA and the microstructural evolution after SPS. As a continuation of that research, this study explores the mechanical behaviour of these alloys, revealing exceptional properties. The results demonstrated that the combination of Ti and W is the most effective approach for developing RHEAs with an optimal strength–ductility balance, along with significantly high hardness values, achieving an impressive strength of 1300 MPa and ductility exceeding 20% at room temperature, underscoring their potential for advanced structural applications. These results locate WxTixMoNbTaV alloys as strong candidates for applications in extreme refractory environments and present a promising alternative to conventional nickel-based superalloys for applications in turbines and nuclear reactor walls.

最近的研究表明,由于对具有特殊机械强度、高延展性、优异的热稳定性和优异的抗氧化和抗腐蚀性能的材料的需求不断增加,对耐火高熵合金(RHEAs)的兴趣日益浓厚。本研究的重点是设计和制造三种WxTixMoNbTaV RHEAs,以实现室温下强度和延展性的最佳平衡。选择策略是基于利用钨(W)的高强度和钛(Ti)的优异延展性来开发具有优异机械性能的合金。采用机械合金化(MA)和火花等离子烧结(SPS)在相同条件下合成了三种不同的成分(x1 = [1,0], x2 =[0,1]和x3 =[0.5, 0.5])。在我们之前的研究中,我们对MA过程中的相变和SPS后的显微组织演变进行了深入的表征。作为该研究的延续,本研究探索了这些合金的机械行为,揭示了特殊的性能。结果表明,Ti和W的组合是开发具有最佳强度-塑性平衡的RHEAs的最有效方法,并且具有显着的高硬度值,在室温下实现了令人惊叹的1300 MPa强度和超过20%的塑性,强调了它们在先进结构应用的潜力。这些结果将WxTixMoNbTaV合金定位为极端难熔环境应用的强有力候选者,并为涡轮机和核反应堆壁应用提供了传统镍基高温合金的有希望的替代品。
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引用次数: 0
Development of Thermally Enhanced Ultrafine Nanofiber From Polyacrylonitrile/Ethylene-co-vinyl Alcohol Blend Using Solution Electrospinning 用溶液静电纺丝法制备聚丙烯腈/乙烯-共乙烯醇共混物热增强超细纳米纤维
Pub Date : 2025-08-30 DOI: 10.1155/mdp2/4376656
Md. Razaul Karim, Saeed Hasan, Koji Nakane, Mohammad Zakaria

The reduction of fiber diameter from micro to nanolevel greatly enhances the surface area, thermal properties, filtration efficiency, reactivity, and overall functionality. Using a blend of polyacrylonitrile (PAN) and ethylene-co-vinyl alcohol (EVOH), solution electrospinning was employed to develop ultrafine nanofibers with a diameter of a few hundred nanometers. The impact of different weight percentages of EVOH blended with PAN on fiber diameters was studied. Fiber diameters drastically decreased with higher EVOH content in the blend, and a slight reduction was observed following isopropyl alcohol (IPA) treatment. The initial diameters of PAN-incorporated EVOH (POH) nanofibers were between 880 and 47 nm, which were reduced to 719 and 41 nm after IPA treatment. The smallest diameter of 102 nm was achieved by POH nanofibers with 75% EVOH after IPA treatment. Furthermore, the thermal properties demonstrate a synergistic effect with the melting temperature increasing from 290°C for pure PAN to 301°C for POH nanofiber with 75% EVOH. The fabricated ultrafine nanofibers with enhanced thermal properties can be applied in advanced air and water filtration systems.

纤维直径从微米级减小到纳米级,大大提高了表面积、热性能、过滤效率、反应性和整体功能。以聚丙烯腈(PAN)和乙烯醇(EVOH)为原料,采用溶液静电纺丝法制备了直径为几百纳米的超细纳米纤维。研究了不同质量百分比的聚丙烯腈共混物对纤维直径的影响。随着EVOH含量的增加,纤维直径急剧下降,异丙醇(IPA)处理后纤维直径略有下降。pan - EVOH (POH)纳米纤维的初始直径为880 ~ 47 nm,经IPA处理后,POH纳米纤维的初始直径降至719 ~ 41 nm。经IPA处理后,75% EVOH的POH纳米纤维的直径最小为102 nm。此外,热性能表现出协同效应,熔融温度从纯PAN的290°C增加到含75% EVOH的POH纳米纤维的301°C。所制备的超细纳米纤维具有增强的热性能,可用于先进的空气和水过滤系统。
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引用次数: 0
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Material Design & Processing Communications
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