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Dye-Sensitized Solar Cell of Silicon Dioxide–Titanium Dioxide Photoanode With Polypyrrole/Sodium Dodecyl Sulfate Low-Cost Counter Electrode 具有聚吡咯/十二烷基硫酸钠低成本反电极的二氧化硅-二氧化钛光阳极染料敏化太阳能电池
Pub Date : 2024-08-20 DOI: 10.1155/2024/9962496
Oraas Adnan Hatem, Nuhad Saad, Sabrean F. Jawad

To produce a better connection and greater electron transfer efficiency between the TiO2 particles, as well as to eliminate agglomeration and increase the dispersion of TiO2 powders, a silicon dioxide/titanium dioxide (SiO2/TiO2) nanocomposite has been used as a photoanode in this study. An attempt was made to construct dye-sensitized solar cells (DSSCs) at a low cost with reasonable efficiency by replacing the highly costly platinum counter electrode with polypyrrole/sodium dodecyl sulfate (PPy + SDS) as Counter Electrode 1 (C1) and PPy/SDS/multiwalled carbon nanotube (PPy + SDS + MWCNT) as Counter Electrode 2 (C2), using Ru-based dyes Z907, pomegranate (Pom) dye, arugula (Aru) dye, and hibiscus dye as photosensitizers. The working electrode composite was deposited on fluorine-doped tin oxide (FTO) glass using a thermal chemical spraying approach, while the counter electrodes were produced using an electropolymerization method. The structural and optical characteristics are fully examined using several characterization techniques such as X-ray diffraction (XRD), Raman scattering, field-emission scanning electron microscopy (FESEM), and atomic force microscopy (AFM). The photovoltaic properties of the constructed DSSCs were assessed under light irradiation (100 mW/cm2). When compared to the reference cell based on the Pt counter electrode, which has an efficiency of 8.4%, the measured current–voltage (IV) curve shows that the efficiency of DSSC in the case of Z907 dye with C1 and C2 was 3.037% and 3.743%, respectively. This suggests that the low-cost prepared DSSCs have good efficiency. Natural dyes show an efficiency range of 1.317%–0.66%, which indicates a moderate level of sensitivity.

为了使二氧化钛颗粒之间产生更好的连接和更高的电子传递效率,以及消除团聚和提高二氧化钛粉末的分散性,本研究采用了二氧化硅/二氧化钛(SiO2/TiO2)纳米复合材料作为光阳极。研究人员尝试用聚吡咯/十二烷基硫酸钠(PPy + SDS)作为对电极 1(C1),用聚吡咯/十二烷基硫酸钠/多壁碳纳米管(PPy + SDS + MWCNT)作为对电极 2(C2),以取代成本高昂的铂对电极,从而以低成本构建具有合理效率的染料敏化太阳能电池(DSSC)、使用 Ru 基染料 Z907、石榴(Pom)染料、芝麻菜(Aru)染料和芙蓉染料作为光敏剂。工作电极复合材料采用热化学喷涂法沉积在掺氟氧化锡(FTO)玻璃上,而对电极则采用电聚合法生产。利用多种表征技术,如 X 射线衍射 (XRD)、拉曼散射、场发射扫描电子显微镜 (FESEM) 和原子力显微镜 (AFM),对其结构和光学特性进行了全面研究。在光照射(100 mW/cm2)条件下,对所构建的 DSSC 的光伏特性进行了评估。与效率为 8.4% 的基于铂对电极的参考电池相比,测得的电流-电压(I-V)曲线显示,含有 C1 和 C2 的 Z907 染料 DSSC 的效率分别为 3.037% 和 3.743%。这表明低成本制备的 DSSC 具有良好的效率。天然染料的效率范围为 1.317%-0.66%,这表明其灵敏度处于中等水平。
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引用次数: 0
Study the Wear Characteristics for Ni-ZrO2 and Ni-Al2O3 Nanocomposite Coatings Produced by Electroless Deposition Technique 研究无电解沉积技术制备的 Ni-ZrO2 和 Ni-Al2O3 纳米复合涂层的磨损特性
Pub Date : 2024-07-30 DOI: 10.1155/2024/4907211
Hiba M. Algailani, Suha I. Al-Nassar, Adel K. Mahmoud, Hanaa A. Al-kaisy, Ahmed A. A. G. Alrubaiy

Metal matrix nanocomposite coatings are promising for tribological applications given their superior hardness and wear resistance compared to metals. The point of this study was to describe the shape and long-term performance of nickel-based coatings that were put on stainless steel using electroless codeposition and made stronger with nanoparticles of zirconia (ZrO2) and alumina (Al2O3). Scanning electron microscopy showed the uniform incorporation of nanoceramics within nickel matrices. Pin-on-disk tribotests evaluated wear performance across loads from 5 to 15 N and sliding speeds up to 480 cm/min. Increasing nanoparticle content from 2 to 4 g/L markedly reduced wear rate due to enhanced hardness and density. At all tested loads, Ni-ZrO2 and Ni-Al2O3 nanocomposites exhibited considerably lower wear than monolithic nickel. The nanometal matrix particles hindered plastic deformation, with weight losses up to 68% lower than base nickel. Initially, wear resistance rose proportionally with sliding speed resulting from protective oxide layers until abrasive wear prevailed. The nanoparticle reinforcement dramatically extended durability, making it ideal for tribological systems involving mixed or abrasive conditions. More research needs to be done to find the best compositions and other matrix materials to use for these nanoscale strengthening effects.

与金属相比,金属基纳米复合涂层具有更高的硬度和耐磨性,因此在摩擦学应用中大有可为。本研究的目的是描述镍基涂层的形状和长期性能,这些涂层是用无电解共沉积法镀在不锈钢上,并用氧化锆(ZrO2)和氧化铝(Al2O3)纳米颗粒使其更坚固。扫描电子显微镜显示,纳米陶瓷均匀地融入了镍基质中。针盘摩擦试验评估了磨损性能,载荷范围从 5 到 15 N,滑动速度最高达 480 cm/min。由于硬度和密度的提高,纳米粒子含量从 2 g/L 增加到 4 g/L 明显降低了磨损率。在所有测试载荷下,Ni-ZrO2 和 Ni-Al2O3 纳米复合材料的磨损都大大低于整体镍。纳米基质颗粒阻碍了塑性变形,重量损失比基镍低 68%。起初,耐磨性随着滑动速度的增加而成正比,这是因为保护性氧化物层的存在,直到磨料磨损占了上风。纳米颗粒的增强大大延长了耐久性,使其成为涉及混合或磨损条件的摩擦学系统的理想选择。还需要进行更多的研究,以找到实现这些纳米级强化效果的最佳成分和其他基体材料。
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引用次数: 0
Measurement of the Dielectric Properties of Tropical Wood Species for Application to Millimetre-Band Antennas 应用于毫米波段天线的热带木材介电性能测量结果
Pub Date : 2024-06-13 DOI: 10.1155/2024/7777701
Ndanga Adamou Eric, Eke Samuel, Matanga Jacques, Doka Yamigno Serge, Tan Phu Vuong

The purpose of this article is to determine the dielectric characteristics of wood species from Central African forests at microwave frequency for use as patch antenna substrate. The measurements were carried out on dried wood at frequencies of 930 MHz and 2.48 GHz. The suitability of the wood as a printed microwave antenna substrate will be determined by the values taken by the complex parameters “permittivity” ε, loss tangent “tanδ,” and “permeability” μ = 1. The measurement method chosen in this work is the method of small disturbances in a cylindrical cavity operating in the TM010 mode. The values obtained for each species confirm the anisotropic nature of the wood. These measurements will also confirm that losses, which are the main criterion for selecting wood as substrate, increase with the wood species category and its density. The design and simulation results at 28 GHz of a travelling wave antenna on a wood substrate show that antennas can radiate with these materials in the millimetre band.

本文旨在确定中非森林中用作贴片天线基板的木材在微波频率下的介电特性。测量在 930 MHz 和 2.48 GHz 频率下对干燥木材进行。木材是否适合用作印刷微波天线基板将由复数参数 "介电常数 "ε′、损耗正切 "tanδ "和 "磁导率 "μ = 1 的值决定。本研究选择的测量方法是在以 TM010 模式运行的圆柱形空腔中进行小扰动测量的方法。每个树种的测量值都证实了木材的各向异性。这些测量结果还证实,作为选择木材作为基材的主要标准,损耗会随着木材种类和密度的增加而增加。木质基底上的行波天线在 28 千兆赫的设计和模拟结果表明,使用这些材料的天线可以在毫米波段进行辐射。
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引用次数: 0
The Influence of Processing Parameters on the Process and Product Properties of Polylactic Acid/Natural Rubber Blown Films 加工参数对聚乳酸/天然橡胶吹塑薄膜的加工和产品特性的影响
Pub Date : 2024-05-31 DOI: 10.1155/2024/5568117
Chananchida Pongpakdee, Kornchanok Akaradechakul, Cattaleeya Pattamaprom

This research investigates key parameters in the pilot-scale production of polylactic acid (PLA)/natural rubber (NR) blends for film-blowing applications. The study is aimed at analyzing the influence of process parameters including screw speed, output rate, compounding steps, and screw configuration on die stock pressure, temperature, %Torque, and retention time. The compounds were characterized for morphology, melt flow index, and film processability, whereby the resulting films were evaluated for surface appearance, transparency, and mechanical properties. It was found that the MFI value could be a good indicator of effective natural rubber dispersion, where higher screw speed and output rate contributed to slightly improved rubber dispersion due to higher shearing effects. Furthermore, an increase in the number of compounding steps and screw configurations with moderate mixing intensity led to further improved rubber dispersion. This was reflected by the reduced average rubber size from 4.1 to 1.0 μm, lower viscosity (higher MFI), smoother films, and improved mechanical properties.

本研究调查了用于吹膜应用的聚乳酸(PLA)/天然橡胶(NR)混合物中试生产的关键参数。研究旨在分析螺杆速度、产出率、混料步骤和螺杆配置等工艺参数对模头压力、温度、扭矩百分比和停留时间的影响。研究人员对化合物的形态、熔体流动指数和薄膜加工性能进行了表征,并对所得薄膜的表面外观、透明度和机械性能进行了评估。研究发现,MFI 值可以很好地反映天然橡胶的有效分散性,螺杆转速和输出率越高,橡胶的分散性越好,因为剪切效应越强。此外,增加混炼步骤和螺杆配置的数量以及适度的混炼强度可进一步改善橡胶分散性。这体现在橡胶平均粒径从 4.1 μm 减小到 1.0 μm、粘度降低(MFI 提高)、薄膜更光滑以及机械性能提高。
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引用次数: 0
Simulation of the Compression Testing of Additively Manufactured Lattice Structures Using Inputs from Microcomputed Tomography 利用微计算机断层扫描输入模拟快速成型晶格结构的压缩测试
Pub Date : 2023-11-28 DOI: 10.1155/2023/8000727
Minsol Park, Martin Philip Venter, Anton Du Plessis

Finite element (FE) modeling is a powerful tool for the virtual testing of components, especially for high-value manufacturing like additive manufacturing (AM). AM often involves lattice structures in parts, imparting unique mechanical properties. Numerical models allow for cost-effective virtual testing, but computational limitations hinder comprehensive investigations on lattice structures, and idealized models may not fully represent actual manufactured behavior. This study proposes a simplified numerical model for analyzing lattice structure compression behavior before failure, incorporating X-ray microcomputed tomography (CT) scan data. The model includes real manufacturing defects, such as geometrical inaccuracies, internal porosity, and surface roughness. It closely fits compression test results from samples with varied defects, with a maximum error of 17% for stiffness, 13% for yield stress, and 7% for peak stress. The model offers promise for developing manufacturing defect-incorporated lattice representative volume elements (RVEs) to design AM parts with lattice regions. Replacing complex lattice structures with solid-infilled RVEs in simulations reduces computational costs significantly. This approach allows efficient exploration of lattice AM components’ mechanical behavior, accounting for manufacturing defects and offering insights for design optimization and material selection.

有限元(FE)建模是对部件进行虚拟测试的强大工具,尤其适用于增材制造(AM)等高价值制造。增材制造通常涉及零件的晶格结构,从而赋予其独特的机械性能。数值模型可实现经济高效的虚拟测试,但计算能力的限制阻碍了对晶格结构的全面研究,而且理想化的模型可能无法完全代表实际制造行为。本研究结合 X 射线微计算机断层扫描(CT)数据,提出了一种简化的数值模型,用于分析晶格结构失效前的压缩行为。该模型包含真实的制造缺陷,如几何误差、内部孔隙率和表面粗糙度。该模型与存在各种缺陷的样品的压缩测试结果非常吻合,刚度的最大误差为 17%,屈服应力的最大误差为 13%,峰值应力的最大误差为 7%。该模型有望用于开发制造缺陷融入晶格代表体积元素(RVE),以设计具有晶格区域的 AM 零件。在模拟中用固体填充的 RVE 取代复杂的晶格结构,可大大降低计算成本。这种方法可以有效探索晶格 AM 部件的机械行为,考虑制造缺陷,并为设计优化和材料选择提供见解。
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引用次数: 0
Experimental Investigations of Damage Identification for Aluminum Foam Sandwich Beams Using Two-Step Method 使用两步法识别铝泡沫夹层梁损伤的实验研究
Pub Date : 2023-11-22 DOI: 10.1155/2023/6551830
Xinyu He, Dongsheng Ge, Yi An

In the experiment, strain gauges and dynamic signal acquisition instruments are used to collect and record data, and the stochastic subspace algorithm is used to extract the first three strain modal parameters of each case. The damage amount identified by the second natural frequency based on the modified Timoshenko beam theory is more in line with the actual situation. The damage depth of case 2 and case 4 is 2 mm, and the identified damage amount is 10% and 9%, respectively. The damage depth of case 3 and case 5 is 4 mm, and the identified damage amount is 16% and 23%, respectively. The damage location information of case 6 is well identified by using the normalized strain modal shape difference index and the enhanced strain modal shape difference index. Taking the strain response signal of case 6 as an example, it is proved that the stochastic subspace strain modal parameter identification algorithm has strong anti-interference ability under the action of 1.5 times, 4 times, and 9 times noise. In addition, the method is verified by theoretical calculation and numerical simulation, and the damage law has a high degree of coincidence with the test. The experimental results show that this method expands the theoretical basis of foam metal damage degree information identification and improves the accuracy of damage location information identification and the anti-interference of parameter identification.

实验中使用应变仪和动态信号采集仪采集和记录数据,并采用随机子空间算法提取每种情况的前三个应变模态参数。基于修正的季莫申科梁理论的第二固有频率确定的破坏量更符合实际情况。案例 2 和案例 4 的破坏深度均为 2 mm,确定的破坏量分别为 10%和 9%。案例 3 和案例 5 的破坏深度为 4 毫米,确定的破坏量分别为 16% 和 23%。利用归一化应变模态形差指数和增强应变模态形差指数可以很好地识别出案例 6 的损坏位置信息。以案例 6 的应变响应信号为例,证明了随机子空间应变模态参数识别算法在 1.5 倍、4 倍和 9 倍噪声作用下具有很强的抗干扰能力。此外,该方法还通过理论计算和数值模拟进行了验证,其损伤规律与试验具有较高的吻合度。实验结果表明,该方法拓展了泡沫金属损伤程度信息识别的理论基础,提高了损伤位置信息识别的准确性和参数识别的抗干扰性。
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引用次数: 0
Toughness Enhancement of PLA-Based Filaments for Material Extrusion 3D Printing 用于材料挤压3D打印的pla基长丝的韧性增强
Pub Date : 2023-08-09 DOI: 10.1155/2023/2707510
Siriwan Pongsathit, Jutamas Kamaisoom, Atikarn Rungteerabandit, Pakorn Opaprakasit, Krit Jiamjiroch, Cattaleeya Pattamaprom

Poly(lactic acid) (PLA) is one of the most popular biodegradable thermoplastics in the market of 3D printing filaments used in the material extrusion (ME) technique. This is because it can be printed easily at low temperatures. However, its inherent brittleness limits its use in many applications. In this work, the toughness of PLA filament was improved by blending with various types of rubbers including natural rubber (NR), acrylic core–shell rubber (CSR), and thermoplastic polyurethane (TPU) in the amount of 15% by weight. PLA/TPU filament was found to have the smoothest surface with the best shape and dimension stability, while PLA/NR filament rendered the highest tensile toughness. In term of the effect of printing temperature, the highest printing temperature in this study (210°C) provided the highest smoothness with the best shape stability and dimension accuracy. Interestingly, the tensile toughness and elongation at break of 3D printed specimens were found to be higher than those of compression-molded specimens for all filament types. This could be explained by the ability of the 3D printing technique to produce specimens that aligned in the printing direction in a fiber-like pattern.

聚乳酸(PLA)是目前市场上最流行的生物可降解热塑性塑料之一,用于材料挤压(ME)技术的3D打印长丝。这是因为它可以在低温下轻松打印。然而,其固有的脆性限制了其在许多应用中的使用。本文通过与天然橡胶(NR)、丙烯酸核壳橡胶(CSR)、热塑性聚氨酯(TPU)等不同类型的橡胶共混,以15%的质量比提高PLA长丝的韧性。PLA/TPU长丝表面最光滑,形状和尺寸稳定性最好,而PLA/NR长丝具有最高的拉伸韧性。在打印温度的影响方面,本研究中最高的打印温度(210℃)提供了最高的光滑度,具有最佳的形状稳定性和尺寸精度。有趣的是,在所有长丝类型中,3D打印样品的拉伸韧性和断裂伸长率都高于压缩成型样品。这可以用3D打印技术的能力来解释,3D打印技术可以产生在打印方向上以纤维状图案排列的样品。
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引用次数: 0
Investigation of the Effect of Tool Temperature on Microstructure, Hardness, and Wear Behaviour of Aluminium 6061-T6 Alloy Welded by the Friction Stir Welding Process 刀具温度对6061-T6铝合金搅拌摩擦焊组织、硬度及磨损性能影响的研究
Pub Date : 2023-05-13 DOI: 10.1155/2023/1795150
Mothibeli Pita

The friction stir welding (FSW) tool is a critical component to the success of the welding process. The aim of the paper is to investigate the effect of tool temperature on the microstructure and mechanical properties of the aluminium alloy during the friction stir welding process. The welding experiment was conducted at a tool rotational speed of 550 rpm, and tool temperature was measured with the increment of a 60 mm distance. Three different tool temperatures were obtained, and samples were characterised by scanning electron microscopy (SEM). The ASTM E384 standard was followed when conducting the Vickers hardness test, and material wear behaviour was tested using the ASTM G99 tribology testing standard. The results show that the tool temperature increases with distance during the FSW process (40.5, 46, and 54°C). A high tool temperature produces the weld butt with high mechanical properties (87.5 HV). The wear rate is low at a high tool temperature (1.169E − 006 mm3/N/m).

搅拌摩擦焊(FSW)工具是焊接过程成功与否的关键部件。研究了搅拌摩擦焊接过程中刀具温度对铝合金组织和力学性能的影响。焊接实验在550 rpm的转速下进行,以增加60 mm的距离测量刀具温度。获得了三种不同的刀具温度,并用扫描电镜(SEM)对样品进行了表征。进行维氏硬度测试时遵循ASTM E384标准,使用ASTM G99摩擦学测试标准测试材料磨损行为。结果表明:在FSW过程中,刀具温度随距离的增加而升高(40.5℃、46℃和54℃);较高的刀具温度可产生具有高机械性能(87.5 HV)的焊接对接。在刀具温度较高(1.169E−006 mm3/N/m)时,磨损率较低。
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引用次数: 0
Porous Titanium Scaffold: A New Design for Controlled Drug Delivery 多孔钛支架:一种新的药物控制递送设计
Pub Date : 2023-04-05 DOI: 10.1155/2023/4664178
Sima Sadeghzade, Reza Amini Najafabadi, Mohammad Meysami, Amirhossein Meysami, Mohammad Khodaei, Taghi Isfahani

Gelatin crosslinking using conventional methods is usually associated with some toxic side effects. In this research, therefore, the vacuum heating method at 10 Pascal and 140°C under different times of 8, 16, and 32 h was used to cross-link strontium-loaded gelatin microparticles with varying degrees obtained by the oil/water mixing method on titanium scaffolds by the dip-coating method to avoid toxicity and also to control the strontium release rate to the surrounding tissue. The possible phases formed on the surface of the porous titanium scaffolds, the gelatin microparticle distribution, gelatin strontium loading, and strontium release were characterized using thin film X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy (SEM), and inductively coupled plasma-mass spectrometer (ICP-MS) machines, respectively. The results indicated that at 600°C, the rutile phase was formed on the surface of the heat-treated titanium scaffolds. Furthermore, strontium was successfully loaded in the spherical gelatin microparticles, and the strontium-loaded gelatin microparticles were distributed uniformly on the surface of the titanium scaffolds, while the rate of the in vitro strontium release decreased by increasing the time of the gelatin microparticle vacuum-heat crosslinking, whereas at the burst release step, the in vitro strontium release rates were around 5, 4.4, and 2.5 ppm/h, for the 8, 16, and 32 h vacuum-heat cross-linked gelatin microparticles, respectively.

明胶交联采用常规方法通常伴随着一些毒副作用。因此,本研究采用10帕斯卡、140℃的真空加热方法,在8、16、32 h的不同时间下,将油水混合法获得的不同程度的载锶明胶微粒通过浸渍包膜法交联在钛支架上,以避免毒性,同时控制锶向周围组织的释放速度。利用薄膜x射线衍射、傅里叶变换红外光谱、扫描电子显微镜(SEM)和电感耦合等离子体质谱仪(ICP-MS)分别表征了多孔钛支架表面可能形成的相、明胶微粒的分布、明胶锶的负载和锶的释放。结果表明:在600℃时,热处理后的钛支架表面形成金红石相;此外,锶被成功加载到球形明胶微颗粒中,并且载锶的明胶微颗粒均匀分布在钛支架表面,而体外锶的释放速率随着明胶微颗粒真空-热交联时间的增加而降低,而在爆发释放步骤中,体外锶的释放速率分别为5、4.4和2.5 ppm/h。真空加热32 h交联明胶微粒。
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引用次数: 0
Characterization of Refractory Alloys Produced by Laser Additive Manufacturing 激光增材制造耐火合金的表征
Pub Date : 2022-11-24 DOI: 10.1155/2022/1928643
Andrew B. Kustas, Jonathan Pegues, Michael A. Melia, Shaun R. Whetten, Morgan Jones, Nicolas Argibay

Refractory alloys often possess superior thermomechanical properties compared to conventional materials, such as steels, Ni-based superalloys, and Ti alloys, especially in high-temperature environments. While these materials promise to revolutionize numerous industries, significant hurdles remain for insertion into applications due to an incomplete understanding of structure-property relationships and conventional processing challenges. We explore laser-based additive manufacturing (AM) to construct refractory alloys consisting of combinations of Mo, Nb, Ta, and Ti with systematically increasing compositional complexity. Microstructure, composition, and hardness of the AM-processed alloys were characterized. Results are discussed in the context of pairing additive manufacturing with refractory metals to enable next-generation alloys.

与传统材料(如钢、镍基高温合金和钛合金)相比,耐火合金通常具有优越的热机械性能,特别是在高温环境中。虽然这些材料有望彻底改变许多行业,但由于对结构-性能关系的不完全理解和传统加工挑战,在应用中仍然存在重大障碍。我们探索基于激光的增材制造(AM)来构建由Mo, Nb, Ta和Ti组合组成的耐火合金,并系统地增加成分复杂性。对am合金的组织、成分和硬度进行了表征。在将增材制造与难熔金属配对以实现下一代合金的背景下讨论了结果。
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引用次数: 0
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Material Design & Processing Communications
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