To produce a better connection and greater electron transfer efficiency between the TiO2 particles, as well as to eliminate agglomeration and increase the dispersion of TiO2 powders, a silicon dioxide/titanium dioxide (SiO2/TiO2) nanocomposite has been used as a photoanode in this study. An attempt was made to construct dye-sensitized solar cells (DSSCs) at a low cost with reasonable efficiency by replacing the highly costly platinum counter electrode with polypyrrole/sodium dodecyl sulfate (PPy + SDS) as Counter Electrode 1 (C1) and PPy/SDS/multiwalled carbon nanotube (PPy + SDS + MWCNT) as Counter Electrode 2 (C2), using Ru-based dyes Z907, pomegranate (Pom) dye, arugula (Aru) dye, and hibiscus dye as photosensitizers. The working electrode composite was deposited on fluorine-doped tin oxide (FTO) glass using a thermal chemical spraying approach, while the counter electrodes were produced using an electropolymerization method. The structural and optical characteristics are fully examined using several characterization techniques such as X-ray diffraction (XRD), Raman scattering, field-emission scanning electron microscopy (FESEM), and atomic force microscopy (AFM). The photovoltaic properties of the constructed DSSCs were assessed under light irradiation (100 mW/cm2). When compared to the reference cell based on the Pt counter electrode, which has an efficiency of 8.4%, the measured current–voltage (I–V) curve shows that the efficiency of DSSC in the case of Z907 dye with C1 and C2 was 3.037% and 3.743%, respectively. This suggests that the low-cost prepared DSSCs have good efficiency. Natural dyes show an efficiency range of 1.317%–0.66%, which indicates a moderate level of sensitivity.
{"title":"Dye-Sensitized Solar Cell of Silicon Dioxide–Titanium Dioxide Photoanode With Polypyrrole/Sodium Dodecyl Sulfate Low-Cost Counter Electrode","authors":"Oraas Adnan Hatem, Nuhad Saad, Sabrean F. Jawad","doi":"10.1155/2024/9962496","DOIUrl":"https://doi.org/10.1155/2024/9962496","url":null,"abstract":"<p>To produce a better connection and greater electron transfer efficiency between the TiO<sub>2</sub> particles, as well as to eliminate agglomeration and increase the dispersion of TiO<sub>2</sub> powders, a silicon dioxide/titanium dioxide (SiO<sub>2</sub>/TiO<sub>2</sub>) nanocomposite has been used as a photoanode in this study. An attempt was made to construct dye-sensitized solar cells (DSSCs) at a low cost with reasonable efficiency by replacing the highly costly platinum counter electrode with polypyrrole/sodium dodecyl sulfate (PPy + SDS) as Counter Electrode 1 (C1) and PPy/SDS/multiwalled carbon nanotube (PPy + SDS + MWCNT) as Counter Electrode 2 (C2), using Ru-based dyes Z907, pomegranate (Pom) dye, arugula (Aru) dye, and hibiscus dye as photosensitizers. The working electrode composite was deposited on fluorine-doped tin oxide (FTO) glass using a thermal chemical spraying approach, while the counter electrodes were produced using an electropolymerization method. The structural and optical characteristics are fully examined using several characterization techniques such as X-ray diffraction (XRD), Raman scattering, field-emission scanning electron microscopy (FESEM), and atomic force microscopy (AFM). The photovoltaic properties of the constructed DSSCs were assessed under light irradiation (100 mW/cm<sup>2</sup>). When compared to the reference cell based on the Pt counter electrode, which has an efficiency of 8.4%, the measured current–voltage (<i>I</i>–<i>V</i>) curve shows that the efficiency of DSSC in the case of Z907 dye with C1 and C2 was 3.037% and 3.743%, respectively. This suggests that the low-cost prepared DSSCs have good efficiency. Natural dyes show an efficiency range of 1.317%–0.66%, which indicates a moderate level of sensitivity.</p>","PeriodicalId":100886,"journal":{"name":"Material Design & Processing Communications","volume":"2024 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1155/2024/9962496","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142013472","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hiba M. Algailani, Suha I. Al-Nassar, Adel K. Mahmoud, Hanaa A. Al-kaisy, Ahmed A. A. G. Alrubaiy
Metal matrix nanocomposite coatings are promising for tribological applications given their superior hardness and wear resistance compared to metals. The point of this study was to describe the shape and long-term performance of nickel-based coatings that were put on stainless steel using electroless codeposition and made stronger with nanoparticles of zirconia (ZrO2) and alumina (Al2O3). Scanning electron microscopy showed the uniform incorporation of nanoceramics within nickel matrices. Pin-on-disk tribotests evaluated wear performance across loads from 5 to 15 N and sliding speeds up to 480 cm/min. Increasing nanoparticle content from 2 to 4 g/L markedly reduced wear rate due to enhanced hardness and density. At all tested loads, Ni-ZrO2 and Ni-Al2O3 nanocomposites exhibited considerably lower wear than monolithic nickel. The nanometal matrix particles hindered plastic deformation, with weight losses up to 68% lower than base nickel. Initially, wear resistance rose proportionally with sliding speed resulting from protective oxide layers until abrasive wear prevailed. The nanoparticle reinforcement dramatically extended durability, making it ideal for tribological systems involving mixed or abrasive conditions. More research needs to be done to find the best compositions and other matrix materials to use for these nanoscale strengthening effects.
{"title":"Study the Wear Characteristics for Ni-ZrO2 and Ni-Al2O3 Nanocomposite Coatings Produced by Electroless Deposition Technique","authors":"Hiba M. Algailani, Suha I. Al-Nassar, Adel K. Mahmoud, Hanaa A. Al-kaisy, Ahmed A. A. G. Alrubaiy","doi":"10.1155/2024/4907211","DOIUrl":"https://doi.org/10.1155/2024/4907211","url":null,"abstract":"<p>Metal matrix nanocomposite coatings are promising for tribological applications given their superior hardness and wear resistance compared to metals. The point of this study was to describe the shape and long-term performance of nickel-based coatings that were put on stainless steel using electroless codeposition and made stronger with nanoparticles of zirconia (ZrO<sub>2</sub>) and alumina (Al<sub>2</sub>O<sub>3</sub>). Scanning electron microscopy showed the uniform incorporation of nanoceramics within nickel matrices. Pin-on-disk tribotests evaluated wear performance across loads from 5 to 15 N and sliding speeds up to 480 cm/min. Increasing nanoparticle content from 2 to 4 g/L markedly reduced wear rate due to enhanced hardness and density. At all tested loads, Ni-ZrO<sub>2</sub> and Ni-Al<sub>2</sub>O<sub>3</sub> nanocomposites exhibited considerably lower wear than monolithic nickel. The nanometal matrix particles hindered plastic deformation, with weight losses up to 68% lower than base nickel. Initially, wear resistance rose proportionally with sliding speed resulting from protective oxide layers until abrasive wear prevailed. The nanoparticle reinforcement dramatically extended durability, making it ideal for tribological systems involving mixed or abrasive conditions. More research needs to be done to find the best compositions and other matrix materials to use for these nanoscale strengthening effects.</p>","PeriodicalId":100886,"journal":{"name":"Material Design & Processing Communications","volume":"2024 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1155/2024/4907211","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141967127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}