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Processes in the vapour phase oxidation of ether. II 乙醚气相氧化过程。2
Pub Date : 1948-01-01 DOI: 10.1016/S1062-2896(49)80045-6
G.H.N. Chamberlain, A.D. Walsh

Extensive experimental work is described and interpreted on the oxidation of diethyl and diisopropyl ethers under the headings “Ignition in the “high” temperature region,” “Ignition to hot flames in the “low” temperature region” and “Slow oxidation in the “low” temperature region.”

在“在“高”温区点火”、“在“低”温区向热火焰点火”和“在“低”温区缓慢氧化”的标题下,对二乙基醚和二异丙基醚氧化的大量实验工作进行了描述和解释。
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引用次数: 0
Diffusion in laminar flame jets 层流火焰射流中的扩散
Pub Date : 1948-01-01 DOI: 10.1016/S1062-2896(49)80034-1
H.C. Hottel , W.R. Hawthorne

The lengths and concentration patterns offlames from circular nozzles burning in free air have been determined over a wide range of velocities with several nozzle diameters and for various gases and primary air-gas ratios. As the nozzle velocity is increased from zero the flame, burning under conditions of diffusional mixing with air, increases in length until a transition occurs to turbulent combustion with a consequent change in flame length to a value which is substantially independent of further increase in velocity.

the present paper covers that portion of the data related to laminar jets and to transition phenomena. The progress of combustion is treated analytically, assuming that molecular diffusion is controlling and that the concentration of oxygen and fuel are zero at the flame interface. A relation is obtained between the time of flow of fuel gas to the flame tip and the proportion of nozzle fluid and air required for complete combustion as follows:

1/θf=4loge(1+atata0)

where θf=4Dvtf/D2 Dv=molecular diffusivity tf=time of flow from nozzle to flame tip D=nozzle diameter at=mols air/mol fuel gas for complete combustion a0=mols air/mol fuel gas in nozzle fluid When the flame is short the time of flow is proportional to flame length, L; for longer flames, the generalized flow-time for a given nozzle fluid, θf, should be a function of L/D, volumetric flow rate, Q, diffusivity, Dv, and the Grashof group which enters wherever the major force overcoming viscous drag is one of buoyancy. The actual relationship is established empirically from data on flames of carbon monoxide and of city gas. For flames longer than 6 inches, issuing from nozzles of diameters 0.125 to 0.82 inches, the following relation is suggested: L=A log f+B, where A and B are constants depending only on the fuel gas and the primary air-fuel ratio.

Data on phenomena of transition from laminar to turbulent flow in the flame jet are also presented.

在自由空气中燃烧的圆形喷嘴燃烧火焰的长度和浓度模式已经在不同喷嘴直径和不同气体和一次空气-气体比的宽速度范围内确定。随着喷嘴速度从零开始增加,在与空气扩散混合的条件下燃烧的火焰长度增加,直到发生湍流燃烧的过渡,火焰长度随之变化到一个基本上与速度进一步增加无关的值。本文涵盖了与层流射流和跃迁现象有关的那部分数据。假设控制分子扩散,火焰界面处氧和燃料的浓度为零,对燃烧过程进行了分析处理。得到燃料气体流向火焰尖端的时间与完全燃烧所需喷嘴流体和空气的比例的关系式如下:1/θf=4log (e) (1+atat - a0)其中,θf=4Dvtf/D2 Dv=分子扩散系数tf=从喷嘴到火焰尖端的流动时间D=喷嘴直径at=完全燃烧所需空气/燃料气体的摩尔数a0=喷嘴流体中空气/燃料气体的摩尔数当火焰较短时,流动时间与火焰长度L成正比;对于较长的火焰,给定喷嘴流体的广义流动时间θf应是L/D、体积流量、Q、扩散率、Dv和进入克服粘性阻力的主要力为浮力的格拉什夫群的函数。根据一氧化碳火焰和城市煤气火焰的实测数据,建立了两者之间的实际关系。对于直径为0.125 ~ 0.82英寸的喷嘴发出的长度大于6英寸的火焰,建议采用以下关系式:L=A log Qθf+B,其中A和B是常数,仅取决于燃气和一次空气-燃料比。文中还介绍了火焰射流中由层流向湍流过渡的现象。
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引用次数: 103
The stability of open flames 明火的稳定性
Pub Date : 1948-01-01 DOI: 10.1016/S1062-2896(49)80005-5
Kurt Wohl, Numer M. Kapp, Carl Gazley
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引用次数: 56
A study of recombination reactions of active particles produced by an electric discharge in water vapor 水蒸气中放电产生的活性粒子的复合反应的研究
Pub Date : 1948-01-01 DOI: 10.1016/S1062-2896(49)80063-8
John F. Byrne
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引用次数: 0
Oxidation of metal alkyls and related compounds the ignition of hydrocarbons 金属烷基和相关化合物的氧化,碳氢化合物的点火
Pub Date : 1948-01-01 DOI: 10.1016/S1062-2896(49)80048-1
Elmer J. Badin
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引用次数: 1
The thermal initiation of explosion in liquid explosives 液体炸药的热起爆
Pub Date : 1948-01-01 DOI: 10.1016/S1062-2896(49)80073-0
A.J.B. Robertson
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引用次数: 2
The hydrogen content of carbon monoxide flames 一氧化碳燃烧时所含的氢
Pub Date : 1948-01-01 DOI: 10.1016/S1062-2896(49)80062-6
E. Sterling, J.R. Arthur
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引用次数: 0
Kinetic aspects of the combustion of solid fuels 固体燃料燃烧的动力学方面
Pub Date : 1948-01-01 DOI: 10.1016/S1062-2896(49)80060-2
J.R. Arthur, D.H. Bangham, J.R. Bowring
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引用次数: 5
Development of a combustion wave in a flowing gas 流动气体中燃烧波的发展
Pub Date : 1948-01-01 DOI: 10.1016/S1062-2896(49)80032-8
Robert J. Dery
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引用次数: 7
Application of dimensionless numbers to flash-back and other combustion phenomena 无量纲数在闪回及其他燃烧现象中的应用
Pub Date : 1948-01-01 DOI: 10.1016/S1062-2896(49)80011-0
Abbott A. Putnam, Randolph A. Jensen
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引用次数: 70
期刊
Symposium on Combustion and Flame, and Explosion Phenomena
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