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2019 IEEE 20th International Conference on Dielectric Liquids (ICDL)最新文献

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The History and Significance of the Carbon Oxide Ratio 碳氧比的历史和意义
Pub Date : 2019-06-01 DOI: 10.1109/ICDL.2019.8796815
Randy Cox
This paper describes the traditional interpretation of the CO CO2/CO ratio as it relates to dissolved gas analysis and what new research has revealed about the ratio in recent years. The industry at large has considered this ratio as a single number, for diagnostic purposes, at a given point in time. New information suggests that this is likely not the most beneficial position to take. Traditionally the ratio has been used as an indicator of the thermal decomposition of cellulose. More recent research of this topic has revealed that this ratio may even predict the deterioration of cellulose prior to any thermal acceleration.
本文介绍了与溶解气体分析有关的CO2/CO比值的传统解释以及近年来有关该比值的新研究成果。整个行业都认为这个比率是一个单一的数字,用于诊断目的,在一个给定的时间点。新的信息表明,这可能不是最有利的立场。传统上,该比率被用作纤维素热分解的指标。最近对这一主题的研究表明,这个比例甚至可以预测纤维素在任何热加速之前的变质。
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引用次数: 1
A SERS Substrate For Detecting Methanol In Transformer Oil 一种检测变压器油中甲醇的SERS底物
Pub Date : 2019-06-01 DOI: 10.1109/ICDL.2019.8796557
Shuhua Zhang, Weigen Chen, Fu Wan, Haiyang Shi, Weiran Zhou, Jiayi Zhang, Chengzhi Zhu
In the development of on-line monitoring technique for transformer aging status, detecting concentration of methanol dissolved in transformer oil by the method of surface enhanced Raman spectroscopy (SERS) is a novel and promising technique. By use of Raman spectroscopy technique, we can improve various shortcomings of traditional detection technology. In this paper, the concentration of methanol dissolved in 2 mL/L methanol-oil solution was effectively detected by surface enhanced Raman spectroscopy. In the first, Raman spectra of single methanol molecule and its SERS were simulated to analyze the Raman peaks of methanol. A SERS substrate was prepared with selective enhancement. Based on prepared SERS substrate, concentration of methanol dissolved in transformer oil with content of 2 mL/L have been effectively detected. This helped us to further study the lower concentration of methanol in oil and make quantitative analysis.
在变压器老化状态在线监测技术的发展中,利用表面增强拉曼光谱(SERS)方法检测变压器油中溶解甲醇的浓度是一种新颖而有前途的技术。利用拉曼光谱技术可以改善传统检测技术的种种不足。本文采用表面增强拉曼光谱法对2 mL/L甲醇油溶液中甲醇的浓度进行了有效检测。首先,模拟单个甲醇分子的拉曼光谱及其SERS,分析甲醇的拉曼峰。制备了选择性增强的SERS底物。利用所制备的SERS底物,对2 mL/L变压器油中溶解甲醇的浓度进行了有效检测。这有助于我们进一步研究油中较低浓度甲醇并进行定量分析。
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引用次数: 0
Investigation of the factors affecting the dielectric dissipation factor of synthetic and natural esters 影响合成酯和天然酯介电耗散系数的因素研究
Pub Date : 2019-06-01 DOI: 10.1109/ICDL.2019.8796834
P. Livesey, M. Lashbrook, Russell Martin
Traditionally, mineral oil has been used as the insulating liquid in transformers due to its high electrical breakdown strength and cooling ability. More recently, natural and synthetic ester based dielectric liquids are increasingly adopted as alternatives, offering much improved fire safety and environmental protection. The dielectric dissipation factor (DDF), via tan delta measurement, has traditionally been used as one of the key metrics for quality evaluation of unused transformer mineral oils. Understanding the chemical differences between esters and mineral oil and which factors affect material properties such as ester DDF is rapidly becoming of greater importance. By monitoring the individual effects of increased ambient temperature and UV exposure on the DDF of synthetic and natural esters, this investigation aims to provide data which can be used to refine interpretation of dielectric dissipation factor for esters. The overall condition of high DDF esters, and the implications this could have for a transformer, are also evaluated to allow conclusions to be drawn on the relevance of a DDF limit in ester standards.
传统上,矿物油由于具有较高的击穿强度和冷却能力而被用作变压器的绝缘液。近年来,越来越多地采用天然和合成酯基介电液体作为替代品,大大提高了消防安全和环境保护。传统上,介质耗散系数(DDF)是评价未使用变压器矿物油质量的关键指标之一。了解酯类和矿物油之间的化学差异以及影响酯类DDF等材料性能的因素正迅速变得越来越重要。通过监测环境温度升高和紫外线照射对合成酯和天然酯的DDF的个别影响,本研究旨在提供可用于改进酯的介电耗散因子解释的数据。还评估了高DDF酯的总体状况,以及这可能对变压器产生的影响,以便得出DDF限制在酯标准中的相关性的结论。
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引用次数: 2
Study on temperature distribution in oil-immersed inverted current transformer 油浸式逆变电流互感器温度分布研究
Pub Date : 2019-06-01 DOI: 10.1109/ICDL.2019.8796597
Xiaoping Yang, Yiming Wu, Jiansheng Li, Chao Wei, Shengquan Wang, Leifeng Huang, Bonan Li, Youyuan Wang
Oil-immersed inverted current transformer, as an important electrical equipment in power grid, is mainly used in power plants and substations. Accidents caused by oil-immersed inverted current transformers are generally accompanied by explosions, which not only reduce the amount of electricity delivered, but also damage other nearby equipment in the substation and even cause casualties. Therefore, it is very necessary to detect and evaluate the operation status of oil-immersed inverted current transformer and study the fault prevention technology to reduce the probability of accidents. According to the common faults of oil-immersed inverted current transformer, this paper firstly analyzed the parts and components with high fault rate of current transformer. Combined with the operating condition of current transformer and its internal insulation structure, the internal temperature field simulation model of current transformer and the temperature calculation model of key parts were established. It was found that the temperature near the winding of the oil-immersed inverted current transformer was the highest, while the temperature rise at the lower part far from the heat source was very small. The simulation results were basically consistent with the experimental results, and it was found that the temperature distribution on both sides of the primary conductor in the head region of the current transformer was symmetrical.
油浸式逆变电流互感器是电网中重要的电气设备,主要用于发电厂和变电站。油浸式逆变电流互感器引起的事故一般都伴有爆炸,不仅使送电量减少,还会损坏变电站附近的其他设备,甚至造成人员伤亡。因此,对油浸式逆变电流互感器的运行状态进行检测和评估,研究故障预防技术,降低事故发生的概率是十分必要的。针对油浸式逆变电流互感器的常见故障,首先对电流互感器的高故障率零部件进行了分析。结合电流互感器运行工况及其内部绝缘结构,建立了电流互感器内部温度场仿真模型和关键部件温度计算模型。研究发现,油浸式逆变电流互感器绕组附近的温度最高,而远离热源的下部温升很小。仿真结果与实验结果基本一致,发现电流互感器头区一次导体两侧的温度分布是对称的。
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引用次数: 0
The theoretical study of dielectric properties of water using the modified Onsager-Kirkwood-Fröhlich theory 修正Onsager-Kirkwood-Fröhlich理论对水介电特性的理论研究
Pub Date : 2019-06-01 DOI: 10.1109/ICDL.2019.8796591
D. Putintsev, N. M. Putintsev
In the work, we present the new method for calculation dielectric properties for Water in the wide temperature range. We use the modified Onsager-Kirkwood-Fröhlich theory, which makes it possible to calculate the polarization characteristics without using the static permittivity. We assumed that the dielectric is an isotropic medium consisting of molecules that do not interact with each other and are located in molecular electric fields. It allows us to use the average cosine of the angle between local electric field vectors and the dipole moment vectors of molecules in a medium as the average measure of the local orientation of the dipoles. This approach also makes it possible to equate the value of the energy of the interaction of dipoles with molecular fields to the value of the internal interaction energy if the energy of the interaction of the dipoles with external fields used for the experimental determination of the value of static permittivity is much less than the energy of the interaction. The calculated values of the dipole moment agree with the modern quantum mechanical calculations, and the results of calculating the values of permittivity are in practical agreement with experiment in the wide range of123.15K-573.15K. The method allows to calculate the static permittivity of water in various aggregate states: ice Ih in the range from 123K to melting point, supercooled water in the range from 238K to melting point, water at the saturation line from the melting point to the precritical region.
在工作中,我们提出了计算水在宽温度范围内介电特性的新方法。我们使用了修正的Onsager-Kirkwood-Fröhlich理论,使得在不使用静态介电常数的情况下计算极化特性成为可能。我们假设电介质是一种各向同性介质,由互不相互作用的分子组成,并且位于分子电场中。它允许我们使用局部电场矢量和介质中分子偶极矩矢量之间夹角的平均余弦值作为偶极子局部取向的平均度量。如果用于测定静态介电常数值的实验用的偶极子与外场的相互作用的能量远小于相互作用的能量,那么这种方法也使偶极子与分子场相互作用的能量等于内部相互作用能的值成为可能。偶极矩的计算值与现代量子力学计算结果一致,介电常数的计算结果在123.15 k -573.15 k范围内与实验结果基本一致。该方法可以计算水在各种聚集状态下的静态介电常数:冰Ih在123K到熔点范围内,过冷水在238K到熔点范围内,水在熔点到临界区域的饱和线上。
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引用次数: 0
Transport of Heat and Mass with Electrical Field - from Earth to Space 带电场的热量和质量输运——从地球到太空
Pub Date : 2019-06-01 DOI: 10.1109/ICDL.2019.8796729
J. Yagoobi
Pumping of single-phase liquid or two-phase liquid/vapor is encountered in a wide range of technological applications. Utilization of electro-hydro-dynamics (EHD) to induce fluid motion is known as an effective approach for situations where special requirements and restrictions are imposed, while enhanced heat and mass transfer are required. The implementation of the EHD phenomena to heat and mass transport introduces complex interactions among inter-dependent variables. The EHD pumping phenomena involve interaction of electric fields and flow fields in a dielectric fluid medium. This interaction induces the fluid motion through the presence of electric body force.In this paper, the fundamentals of EHD driven fluid flow are described. The evolution of EHD driven heat and mass transport technologies for space applications are presented. Specifically, the results of single-phase liquid and two-phase heat transport experiments that were conducted on board variable-gravity parabolic flights are provided. The EHD conduction pumping technology is expected to provide technological advances that will support various space missions.
单相液体或两相液体/蒸汽的泵送在广泛的技术应用中遇到。利用电流体动力学(EHD)来诱导流体运动被认为是施加特殊要求和限制的情况下的有效方法,同时需要加强传热和传质。将EHD现象应用于热和质量输运,引入了相互依赖变量之间复杂的相互作用。EHD抽运现象涉及到介电流体介质中电场和流场的相互作用。这种相互作用通过电体力的存在诱导流体运动。本文介绍了EHD驱动流体流动的基本原理。介绍了空间应用中EHD驱动的热量和质量输运技术的发展。给出了在变重力抛物线飞行器上进行的单相液体和两相传热实验结果。EHD传导泵送技术有望提供支持各种太空任务的技术进步。
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引用次数: 0
Comparison of X-Wax Formation in Different Insulation Liquids 不同绝缘液体中x -蜡形成的比较
Pub Date : 2019-06-01 DOI: 10.1109/ICDL.2019.8796699
M. Kuhnke, K. Homeier, P. Werle
The formation of solid wax-like ageing products in mineral oil under high voltage stress is known for almost a century. It was observed in oil-impregnated cables, bushings and capacitors. Its formation was generally attributed to high field strength and partial discharges. Since these types of equipment do not rely on oil flow for cooling the wax formation was seen as a sign of wear and not by itself as threat to the equipment.With the improvement of materials and design tools, the field strength in transformers increased. In recent years there was a significant number of outages in distribution transformers, which were related to partial discharges and wax formation. The purpose of this research is to understand how this wax is formed and how different insulation liquids behave in regard to the wax formation. Observations from the investigation of faulty transformers are compared to a lab experiment. A scaled model of the high voltage insulation of a distribution transformer was designed and build to investigate the influence of temperature and partial discharges on the generation of waxlike substances in the laboratory. Different insulation fluids, such as synthetic and natural esters and silicone fluids are investigated as well as a mineral oil for comparison. They are stressed with partial discharges for a duration of 200h. The partial discharges are monitored to allow a comparison between the PD energy and the amount of wax formed during the experiment. The tests are performed at different temperatures, as previous investigations have shown a significant influence of the temperature.
矿物油在高压应力下形成固体蜡状老化产物,这一现象在近一个世纪前就已为人所知。在油浸电缆、套管和电容器中观察到这种现象。它的形成一般归因于高场强和局部放电。由于这些类型的设备不依赖油流来冷却,因此蜡形成被视为磨损的迹象,而不是对设备的威胁。随着材料和设计工具的改进,变压器的场强不断提高。近年来,配电变压器发生了大量因局部放电和成蜡引起的故障。本研究的目的是了解这种蜡是如何形成的,以及不同的绝缘液体在蜡形成方面的表现。对故障变压器的调查结果与实验室实验结果进行了比较。设计并建立了配电变压器高压绝缘的比例模型,在实验室中研究了温度和局部放电对蜡样物质产生的影响。不同的绝缘流体,如合成和天然酯和硅流体进行了研究,以及矿物油进行比较。局部放电持续200小时。监测局部放电,以便在PD能量和实验期间形成的蜡量之间进行比较。这些试验是在不同的温度下进行的,因为以前的调查已经表明温度的影响很大。
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引用次数: 1
New equation for calculating electronic polarizability using refractometry 用折射法计算电子极化率的新方程
Pub Date : 2019-06-01 DOI: 10.1109/ICDL.2019.8796562
D. Putintsev, N. M. Putintsev
The determination of the electronic polarizability of molecules is carried out by quantum-mechanical, refractometric and spectrometric methods. Refractometry is the simplest and most reliable method, since to determine the values of the electronic polarizability, it is required to have data on the absolute refractive index, substance density (molar volume) and the theoretical relation relating these parameters to electron polarizability. The Lorentz-Lorenz equation is currently used as such a relation. In this paper the justification of the new equation for determining the electronic component of the isotropic polarizability of molecules is given. From the experimental data on the density and absolute refractive index of a substance, the values of the average electronic polarizability of 62 different molecules were determined. The calculation was performed for the condensed state of a substance at 293.15K.
分子的电子极化率的测定是通过量子力学、折射法和光谱法进行的。折射法是最简单和最可靠的方法,因为要确定电子极化率的值,需要有绝对折射率、物质密度(摩尔体积)以及这些参数与电子极化率的理论关系的数据。洛伦兹-洛伦兹方程目前被用作这样一种关系。本文给出了确定分子各向同性极化率电子分量的新方程的证明。根据物质的密度和绝对折射率的实验数据,测定了62种不同分子的平均电子极化率。计算了293.15K时物质的凝聚态。
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引用次数: 0
Reliability Study of Furan Level Analysis for Transformer Health Prediction 变压器健康预测中呋喃水平分析的可靠性研究
Pub Date : 2019-06-01 DOI: 10.1109/ICDL.2019.8796785
M. Meissner, Martin Darmann, S. Schober, M. Mittelbach, C. Sumereder
To determine the reliability of furan compound analysis for insulation-system health prediction, the furan level found in oil, paper and pressboard was monitored throughout a large-scale ageing study. Therefore, thermally upgraded and normal Kraft paper as well as transformer pressboard were immersed in 4 different types of insulation liquid (mineral oil, G-t-L oil, synthetic and natural ester) at 3 different ageing temperatures (110, 130 and $150^{circ}mathrm{C})$ and studied throughout a 56 day ageing setup, resulting in 100 mixed samples and 300 furan analyses. While the evolution of furan compounds in each system was somehow steady, comparisons between different material mixes and temperatures show significant aberrations. For similar stages of wear, standard deviations of 100% and more are detectable for the total furan compound concentration in oil, while deviations in solid insulation materials can be even higher. Due to the complexity and high number of variables, irregular analysis intervals without supporting information seem to be highly arguable for transformer health prediction.
为了确定呋喃化合物分析用于绝缘系统健康预测的可靠性,在一项大规模老化研究中监测了油、纸和纸板中的呋喃水平。因此,在3种不同的老化温度(110、130和150^{circ} mathm {C})下,将热升级和普通牛皮纸以及变压器压板浸泡在4种不同类型的绝缘液体(矿物油、G-t-L油、合成和天然酯)中,并在56天的老化设置中进行研究,产生100个混合样品和300个呋喃分析。虽然呋喃化合物在每个体系中的演变在某种程度上是稳定的,但不同材料混合物和温度之间的比较显示出明显的偏差。对于类似的磨损阶段,油中总呋喃化合物浓度的标准偏差可以检测到100%以上,而固体绝缘材料的偏差可能更高。由于变量的复杂性和数量多,在没有支持信息的情况下,不规则的分析间隔似乎对变压器健康预测有很大的争议。
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引用次数: 5
Investigation of Temperature Effect on Conductance Characteristics of Transformer Oil-based Nanofluids 温度对变压器油基纳米流体电导特性影响的研究
Pub Date : 2019-06-01 DOI: 10.1109/ICDL.2019.8796575
Ming Dong Xinyi, Xinyi Ma, Yang Li, Jiacheng Xie, M. Ren
Adding some nanoparticles to the transformer oil can improve its heat exchange properties as well as its dielectric withstanding characteristics, which has attract more and more attentions in the world. The conductance characteristics of transformer oil-based nanofluids (TNFs), especially at different temperatures, will help to understand the modification theory. The charge carrier transport processes at different electric fields can be divided into three stages: Ohmic, tunneling and space charge limited current (SCLC), respectively. In Ohmic stage at a very low field, the addition of nanoparticles increases the carrier number density, thus the conduction current is increased. In tunneling stage at medium to high electric field strengths, the main charge carriers in the transformer oil change from ions and colloidal particles to electrons emitted from the electrodes. The addition of nanoparticles increases the barrier thickness at the metal-liquid interface, which reduces the amount of electrons passing through the interface region. Therefore, the field strength required for electron transport is enhanced, and the dielectric strength is improved. In the space charge limited current stage at a very high electric field, the large trap density of TNFs lowers the carrier mobility, suppressing the discharge. In addition, as the temperature increases, the accelerated movement of the carriers increases the conduction current in the transformer oil. However, the electron tunneling process in the tunneling stage is little affected by the change in temperature.
在变压器油中加入纳米颗粒可以改善变压器油的换热性能和耐介电性能,这一研究越来越受到世界各国的关注。变压器油基纳米流体(TNFs)的电导特性,特别是在不同温度下的电导特性,将有助于理解改性理论。不同电场下的载流子输运过程可分为欧姆输运、隧穿输运和空间电荷限流输运三个阶段。在极低电场的欧姆阶段,纳米粒子的加入增加了载流子数密度,从而增加了导电电流。在中、强电场作用下的隧穿阶段,变压器油中的主要载流子由离子和胶体粒子转变为电极发射的电子。纳米粒子的加入增加了金属-液体界面的势垒厚度,从而减少了通过界面区域的电子数量。因此,提高了电子输运所需的场强,提高了介电强度。在空间电荷限流阶段,在非常高的电场下,tnf的大陷阱密度降低了载流子迁移率,抑制了放电。此外,随着温度的升高,载流子的加速运动增加了变压器油中的传导电流。而在隧穿阶段,电子隧穿过程受温度变化的影响较小。
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引用次数: 0
期刊
2019 IEEE 20th International Conference on Dielectric Liquids (ICDL)
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