Pub Date : 2021-12-22DOI: 10.5772/intechopen.101296
Gustavo Morari do Nascimento
{"title":"Introductory Chapter: Polymers and Clays - A Fruitful Combination","authors":"Gustavo Morari do Nascimento","doi":"10.5772/intechopen.101296","DOIUrl":"https://doi.org/10.5772/intechopen.101296","url":null,"abstract":"<jats:p />","PeriodicalId":10241,"journal":{"name":"Clay and Clay Minerals [Working Title]","volume":"233 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84950378","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-11-15DOI: 10.5772/intechopen.99009
M. Achik, Boutaina Moumni, H. Benmoussa, A. Oulmekki, A. Touache, Gil Gonzalez Álvaro, Francisco Guitián Rivera, A. Infantes-Molina, D. Eliche-Quesada, O. Kizinievič
This chapter deals with the study of the possibility of using yellow clay - which was only used in pottery so far- in the civil engineering field as building materials, especially in the field of fired bricks. With the aim to improve the technological properties of yellow clay based bricks, two wastes were used as secondary raw materials. The first one is a mineral waste - pyrrhotite ash - this waste was neither characterized nor valued before by any other author. While the second waste is an organic waste - cedar sawdust - which is from the artisanal sector. Clay bricks containing yellow clay and different content of wastes were prepared and tested to evaluate their technological properties: water absorption, bulk density, porosity and mechanical strength… The test results indicate that the addition of wastes to clay bricks improves their technological properties and highlights the possibility of wastes reuse in a safe and sustainable way.
{"title":"Towards the Use of Yellow Clay in Fired Bricks","authors":"M. Achik, Boutaina Moumni, H. Benmoussa, A. Oulmekki, A. Touache, Gil Gonzalez Álvaro, Francisco Guitián Rivera, A. Infantes-Molina, D. Eliche-Quesada, O. Kizinievič","doi":"10.5772/intechopen.99009","DOIUrl":"https://doi.org/10.5772/intechopen.99009","url":null,"abstract":"This chapter deals with the study of the possibility of using yellow clay - which was only used in pottery so far- in the civil engineering field as building materials, especially in the field of fired bricks. With the aim to improve the technological properties of yellow clay based bricks, two wastes were used as secondary raw materials. The first one is a mineral waste - pyrrhotite ash - this waste was neither characterized nor valued before by any other author. While the second waste is an organic waste - cedar sawdust - which is from the artisanal sector. Clay bricks containing yellow clay and different content of wastes were prepared and tested to evaluate their technological properties: water absorption, bulk density, porosity and mechanical strength… The test results indicate that the addition of wastes to clay bricks improves their technological properties and highlights the possibility of wastes reuse in a safe and sustainable way.","PeriodicalId":10241,"journal":{"name":"Clay and Clay Minerals [Working Title]","volume":"18 11 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82914132","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-09-19DOI: 10.5772/intechopen.98368
Murugesan Manikkampatti Palanisamy, Akilamudhan Palaniappan, V. Myneni, K. Kandasamy, Minar Mohamed Lebbai, Padmapriya Veerappan
The recent advancements in technology play a pivotal role in mankind’s life and have a significant stint in the generation of E-waste. The present investigation focuses on the recovery of heavy metals from Printed Circuit boards (PCBs) by applying two efficient techniques viz., leaching and adsorption. A combination of leaching and adsorption is a novel and productive approach to recovering heavy metals from like PCBs. After the phases of chemical leaching, the solution was recovered through adsorption and is eco-friendly. The process is carried out to increase the separation rate, reduce the time spent and reach the limits of incineration and pyrolysis methods. Adsorption provides the recovery of heavy metals with respect to the required adsorbent since it is a surface phenomenon. The optimum condition of process variables was found through response surface methodology (RSM). The maximum recovery of copper ions (97.33%) was obtained at the optimum operating conditions such as adsorbent size of 0.04 mm, adsorbent dosage of 3.5 gm L−1 and the temperature of 80°C with 0.845 desirability. This investigation was found to be an eco-friendly way to recover copper ions and does not cause any environmental issues.
{"title":"Clay Minerals Effects for Metal Reclamation from Leached Solution","authors":"Murugesan Manikkampatti Palanisamy, Akilamudhan Palaniappan, V. Myneni, K. Kandasamy, Minar Mohamed Lebbai, Padmapriya Veerappan","doi":"10.5772/intechopen.98368","DOIUrl":"https://doi.org/10.5772/intechopen.98368","url":null,"abstract":"The recent advancements in technology play a pivotal role in mankind’s life and have a significant stint in the generation of E-waste. The present investigation focuses on the recovery of heavy metals from Printed Circuit boards (PCBs) by applying two efficient techniques viz., leaching and adsorption. A combination of leaching and adsorption is a novel and productive approach to recovering heavy metals from like PCBs. After the phases of chemical leaching, the solution was recovered through adsorption and is eco-friendly. The process is carried out to increase the separation rate, reduce the time spent and reach the limits of incineration and pyrolysis methods. Adsorption provides the recovery of heavy metals with respect to the required adsorbent since it is a surface phenomenon. The optimum condition of process variables was found through response surface methodology (RSM). The maximum recovery of copper ions (97.33%) was obtained at the optimum operating conditions such as adsorbent size of 0.04 mm, adsorbent dosage of 3.5 gm L−1 and the temperature of 80°C with 0.845 desirability. This investigation was found to be an eco-friendly way to recover copper ions and does not cause any environmental issues.","PeriodicalId":10241,"journal":{"name":"Clay and Clay Minerals [Working Title]","volume":"13 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79773641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-08-12DOI: 10.5772/intechopen.98902
U. Ekpunobi, C. Ihueze, P. Igbokwe, A. Ekpunobi, Happiness Obiora-Ilouno, C. Onu, S. Agbo, S. Ezennaya, Uzochukwu Onuigbo, Ifenyinwa Tabugbo, A. Etukudoh, C. Onu, E. Amalu
This paper reviewed the production of electric porcelain insulators utilizing from local raw materials from developing countries. The raw materials used were feldspar, quartz/silica and kaolin. The chemical composition, mineralogy, and thermal properties of the raw materials were characterized using AAS, XRD, and TGA respectively. Different weight percentage combinations of the individual raw materials were investigated by the authors. Most of the results showed relatively acceptable porcelain insulators properties such as low water absorption, porosity, high insulation resistance, dielectric strength and bulk density. The paper showed that electric porcelain insulators with good properties can be produced from available local raw materials in some developing countries using appropriate formulations. However, for production of improved porcelain insulators properties, suggestions were made on the areas for future research.
{"title":"Production of Electrical Porcelain Insulators from Local Raw Materials: A Review","authors":"U. Ekpunobi, C. Ihueze, P. Igbokwe, A. Ekpunobi, Happiness Obiora-Ilouno, C. Onu, S. Agbo, S. Ezennaya, Uzochukwu Onuigbo, Ifenyinwa Tabugbo, A. Etukudoh, C. Onu, E. Amalu","doi":"10.5772/intechopen.98902","DOIUrl":"https://doi.org/10.5772/intechopen.98902","url":null,"abstract":"This paper reviewed the production of electric porcelain insulators utilizing from local raw materials from developing countries. The raw materials used were feldspar, quartz/silica and kaolin. The chemical composition, mineralogy, and thermal properties of the raw materials were characterized using AAS, XRD, and TGA respectively. Different weight percentage combinations of the individual raw materials were investigated by the authors. Most of the results showed relatively acceptable porcelain insulators properties such as low water absorption, porosity, high insulation resistance, dielectric strength and bulk density. The paper showed that electric porcelain insulators with good properties can be produced from available local raw materials in some developing countries using appropriate formulations. However, for production of improved porcelain insulators properties, suggestions were made on the areas for future research.","PeriodicalId":10241,"journal":{"name":"Clay and Clay Minerals [Working Title]","volume":"130 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79592066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-08-12DOI: 10.5772/intechopen.99461
Carlos Hernando Aramburo Varela, Luiz Felipe de Pinho, César Pedrajas Nieto-Márquez, Rafael Morales
The thermal activation of clays to produce highly reactive artificial pozzolans on a large scale is one of the most important technologies developed on an industrial scale to reduce CO2 emissions in cement manufacture. This technical document deals with the scientific basis for the thermal activation of clays to produce an extraordinarily high quality supplementary cementitious material (SCM) based on the contents of its hydraulic factors, reactive silica (SiO2r–) and reactive alumina (Al2O3r–). The production process and the optimization of its use in the new cements offers better performance, features and durability. Furthermore, its mixture with Portland cement is much more appropriate when carried out in a blending station after both components, activated clay and Portland cement, are ground separately and not jointly in a single mill.
{"title":"Activated Clays and Their Potential in the Cement Industry","authors":"Carlos Hernando Aramburo Varela, Luiz Felipe de Pinho, César Pedrajas Nieto-Márquez, Rafael Morales","doi":"10.5772/intechopen.99461","DOIUrl":"https://doi.org/10.5772/intechopen.99461","url":null,"abstract":"The thermal activation of clays to produce highly reactive artificial pozzolans on a large scale is one of the most important technologies developed on an industrial scale to reduce CO2 emissions in cement manufacture. This technical document deals with the scientific basis for the thermal activation of clays to produce an extraordinarily high quality supplementary cementitious material (SCM) based on the contents of its hydraulic factors, reactive silica (SiO2r–) and reactive alumina (Al2O3r–). The production process and the optimization of its use in the new cements offers better performance, features and durability. Furthermore, its mixture with Portland cement is much more appropriate when carried out in a blending station after both components, activated clay and Portland cement, are ground separately and not jointly in a single mill.","PeriodicalId":10241,"journal":{"name":"Clay and Clay Minerals [Working Title]","volume":"15 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75221148","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-07-30DOI: 10.5772/intechopen.99075
T. Choudhury
Most of NF membranes which are developed recently are composite membranes, whose support layer is covered with an active layer. Among different ceramic support materials that are currently used as support layer, α-alumina supports are integral part of the membrane which is made of artificial materials like alumina and thus adds to the high price of the membrane. This draws our attention in making low cost support material of natural clay which aims to be an excellent membrane support as it possesses high mechanical strength, high permeability, narrow pore size distribution and low manufacturing cost. Titania as active layer for ceramic membrane is preferred over Al2O3 membranes. One of the problems encountered when photocatalysts are immobilized on support is the detachment of the micro particles from the support for high flow rates of liquid effluent. This can be overcome by using Montmorillonite clay as support material as it is a great binder.
{"title":"Clay Hybrid Membranes in Wastewater Treatment","authors":"T. Choudhury","doi":"10.5772/intechopen.99075","DOIUrl":"https://doi.org/10.5772/intechopen.99075","url":null,"abstract":"Most of NF membranes which are developed recently are composite membranes, whose support layer is covered with an active layer. Among different ceramic support materials that are currently used as support layer, α-alumina supports are integral part of the membrane which is made of artificial materials like alumina and thus adds to the high price of the membrane. This draws our attention in making low cost support material of natural clay which aims to be an excellent membrane support as it possesses high mechanical strength, high permeability, narrow pore size distribution and low manufacturing cost. Titania as active layer for ceramic membrane is preferred over Al2O3 membranes. One of the problems encountered when photocatalysts are immobilized on support is the detachment of the micro particles from the support for high flow rates of liquid effluent. This can be overcome by using Montmorillonite clay as support material as it is a great binder.","PeriodicalId":10241,"journal":{"name":"Clay and Clay Minerals [Working Title]","volume":"53 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73705030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-07-23DOI: 10.5772/INTECHOPEN.98908
M. Fu, Zepeng Zhang, R. Jiang, Hongbao Liu
Magnetic particles can be oriented along the magnetic field direction to achieve orderly arrangement under the magnetic field. Optical functional materials such as photonic crystal and liquid crystal can be obtained according to magnetic induced ordered nanostructure assembly. One-dimensional natural clay minerals with unique structure, composition and properties can be used as structural base to prepare anisotropic magnetic nanoparticles by decorated with magnetic particles, achieving unique optical functional properties. In this chapter, one-dimensional clay minerals@Fe3O4 nanocomposites were prepared by co-precipitation. The resulting one-dimensional clay minerals@Fe3O4 nanocomposites are superparamagnetic. They can be oriented along the direction of the magnetic field and produce an instantaneously reversible response. These magnetic mineral materials can be dispersed in a dilute acid solution to form stable colloid solutions. These stable colloid solutions produce a similar magnetically controlled liquid crystal with Bragg diffraction under an external magnetic field. Their optical properties are affected by magnetic field intensity, magnetic field direction and solid content. The results show that the functionalization of one-dimensional clay minerals has potential applications in display devices, photonic switches and other fields.
{"title":"Magnetic Assembly and Functionalization of One-Dimensional Nanominerals in Optical Field","authors":"M. Fu, Zepeng Zhang, R. Jiang, Hongbao Liu","doi":"10.5772/INTECHOPEN.98908","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.98908","url":null,"abstract":"Magnetic particles can be oriented along the magnetic field direction to achieve orderly arrangement under the magnetic field. Optical functional materials such as photonic crystal and liquid crystal can be obtained according to magnetic induced ordered nanostructure assembly. One-dimensional natural clay minerals with unique structure, composition and properties can be used as structural base to prepare anisotropic magnetic nanoparticles by decorated with magnetic particles, achieving unique optical functional properties. In this chapter, one-dimensional clay minerals@Fe3O4 nanocomposites were prepared by co-precipitation. The resulting one-dimensional clay minerals@Fe3O4 nanocomposites are superparamagnetic. They can be oriented along the direction of the magnetic field and produce an instantaneously reversible response. These magnetic mineral materials can be dispersed in a dilute acid solution to form stable colloid solutions. These stable colloid solutions produce a similar magnetically controlled liquid crystal with Bragg diffraction under an external magnetic field. Their optical properties are affected by magnetic field intensity, magnetic field direction and solid content. The results show that the functionalization of one-dimensional clay minerals has potential applications in display devices, photonic switches and other fields.","PeriodicalId":10241,"journal":{"name":"Clay and Clay Minerals [Working Title]","volume":"33 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80426564","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-07-16DOI: 10.5772/INTECHOPEN.98625
Aicha Kourim, M. A. Malouki, A. Ziouche
In this study, the adsorption of Copper Cu (II) and methyl Orange (MO) from aqueous solution, on Tamanrasset’s unmodified and modified Kaolinite clay which as low cost adsorbents, was studied using batch experiments. The adsorption study includes both equilibrium adsorption isotherms, kinetics and thermodynamics study. For the characterization of the adsorbent several properties are determined such as pH, the Specific Surface Area, the Point of Zero Charge and the Cation Exchange Capacity. Indeed, various parameters were investigated such as contact time, initial metal and dye concentration, mass of solid, pH of the solution and temperature. The adsorption process as batch study was investigated under the previews experimental parameters.
{"title":"Thermodynamic and Kinetic Behaviors of Copper (II) and Methyl Orange (MO) Adsorption on Unmodified and Modified Kaolinite Clay","authors":"Aicha Kourim, M. A. Malouki, A. Ziouche","doi":"10.5772/INTECHOPEN.98625","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.98625","url":null,"abstract":"In this study, the adsorption of Copper Cu (II) and methyl Orange (MO) from aqueous solution, on Tamanrasset’s unmodified and modified Kaolinite clay which as low cost adsorbents, was studied using batch experiments. The adsorption study includes both equilibrium adsorption isotherms, kinetics and thermodynamics study. For the characterization of the adsorbent several properties are determined such as pH, the Specific Surface Area, the Point of Zero Charge and the Cation Exchange Capacity. Indeed, various parameters were investigated such as contact time, initial metal and dye concentration, mass of solid, pH of the solution and temperature. The adsorption process as batch study was investigated under the previews experimental parameters.","PeriodicalId":10241,"journal":{"name":"Clay and Clay Minerals [Working Title]","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91322487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-06-30DOI: 10.5772/intechopen.98566
A. Gharzouni, Clément Alizé, S. Rossignol
This chapter aims to highlight the effect of clay mixture mineral composition and alkali concentration of potassium alkaline solutions on the thermal behavior of geopolymer materials. For this, three mixtures composed of kaolin (pure, impure kaolin or mixture of both), calcium carbonate, sand and potassium feldspar and three potassium alkaline silicate solutions with different concentrations were used (5, 6 and 7 mol.L−1). At first, the effect of rotary calcination parameters at 750°C such as the dwell time (30, 60, 120 and 180 min) and weight powder (100, 400 and 500 g) was investigated. It was demonstrated that the kaolin dehydroxylation is quasi complete (> 90%) and do not significantly depend on the dwell time and powder weight. Whereas the carbonate decomposition degree increases with the increase of dwell time and the decrease of powder weight but still not complete (<80%). These differences influence the feasibility of consolidated materials. Indeed, a flash setting occurs for samples based mixtures with high calcium carbonate decomposition degree (> 50%) and low wettability values (500 μL/g) for the three used alkaline solutions. The thermal behavior at 1000°C depends on the chemical composition of the aluminosilicate source and the concentration of alkaline solution. A conservation of the compressive strength at 43 MPa after thermal treatment at 1000°C of geopolymers based on mixture of pure and impure kaolin and a low potassium concentration solution (5 mol.L−1) was evidenced.
{"title":"Fire Resistant Geopolymers Based on Several Clays Mixtures","authors":"A. Gharzouni, Clément Alizé, S. Rossignol","doi":"10.5772/intechopen.98566","DOIUrl":"https://doi.org/10.5772/intechopen.98566","url":null,"abstract":"This chapter aims to highlight the effect of clay mixture mineral composition and alkali concentration of potassium alkaline solutions on the thermal behavior of geopolymer materials. For this, three mixtures composed of kaolin (pure, impure kaolin or mixture of both), calcium carbonate, sand and potassium feldspar and three potassium alkaline silicate solutions with different concentrations were used (5, 6 and 7 mol.L−1). At first, the effect of rotary calcination parameters at 750°C such as the dwell time (30, 60, 120 and 180 min) and weight powder (100, 400 and 500 g) was investigated. It was demonstrated that the kaolin dehydroxylation is quasi complete (> 90%) and do not significantly depend on the dwell time and powder weight. Whereas the carbonate decomposition degree increases with the increase of dwell time and the decrease of powder weight but still not complete (<80%). These differences influence the feasibility of consolidated materials. Indeed, a flash setting occurs for samples based mixtures with high calcium carbonate decomposition degree (> 50%) and low wettability values (500 μL/g) for the three used alkaline solutions. The thermal behavior at 1000°C depends on the chemical composition of the aluminosilicate source and the concentration of alkaline solution. A conservation of the compressive strength at 43 MPa after thermal treatment at 1000°C of geopolymers based on mixture of pure and impure kaolin and a low potassium concentration solution (5 mol.L−1) was evidenced.","PeriodicalId":10241,"journal":{"name":"Clay and Clay Minerals [Working Title]","volume":"54 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74868405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-06-24DOI: 10.5772/intechopen.97672
Neeraj Kumari, C. Mohan
Clay minerals such as kaolinite, smectite, chlorite, micas are main components of raw materials of clay and formed in presence of water. A large number of clays used to form the different structure which completely depends on their mining source. They are known as hydrous phyllosilicate having silica, alumina and water with variable amount of inorganic ions like Mg2+, Na+, Ca2+ which are found either in interlayer space or on the planetary surface. Clay minerals are described by presence of two-dimensional sheets, tetrahedral (SiO4) and octahedral (Al2O3). There are different clay minerals which are categorized based on presence of tetrahedral and octahedral layer in their structure like kaolinite (1:1 of tetrahedral and octahedral layers), smectite group of clay minerals (2:1 of tetrahedral and octahedral layers) and chlorite (2:1:1 of tetrahedral, octahedral and octahedral layers). The particle size of clay minerals is <2microns which can be present in form of plastic in presence of water and solidified when dried. The small size and their distinctive crystal structure make clay minerals very special with their unique properties including high cation exchange capacity, swelling behavior, specific surface area, adsorption capacity, etc. which are described in this chapter. Due to all these unique properties, clay minerals are gaining interest in different fields.
{"title":"Basics of Clay Minerals and Their Characteristic Properties","authors":"Neeraj Kumari, C. Mohan","doi":"10.5772/intechopen.97672","DOIUrl":"https://doi.org/10.5772/intechopen.97672","url":null,"abstract":"Clay minerals such as kaolinite, smectite, chlorite, micas are main components of raw materials of clay and formed in presence of water. A large number of clays used to form the different structure which completely depends on their mining source. They are known as hydrous phyllosilicate having silica, alumina and water with variable amount of inorganic ions like Mg2+, Na+, Ca2+ which are found either in interlayer space or on the planetary surface. Clay minerals are described by presence of two-dimensional sheets, tetrahedral (SiO4) and octahedral (Al2O3). There are different clay minerals which are categorized based on presence of tetrahedral and octahedral layer in their structure like kaolinite (1:1 of tetrahedral and octahedral layers), smectite group of clay minerals (2:1 of tetrahedral and octahedral layers) and chlorite (2:1:1 of tetrahedral, octahedral and octahedral layers). The particle size of clay minerals is <2microns which can be present in form of plastic in presence of water and solidified when dried. The small size and their distinctive crystal structure make clay minerals very special with their unique properties including high cation exchange capacity, swelling behavior, specific surface area, adsorption capacity, etc. which are described in this chapter. Due to all these unique properties, clay minerals are gaining interest in different fields.","PeriodicalId":10241,"journal":{"name":"Clay and Clay Minerals [Working Title]","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76676227","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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