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Sustainable Bio-Adsorbents From Banana Post-Harvest Agricultural Residues: Kinetics, Equilibrium, and Mechanism Prospection of Methylene Blue Dye Adsorption
IF 1.5 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2024-11-19 DOI: 10.1002/clen.202400020
Laura Alessandra Prado Milani, Ana Carolini Córneo Zanette, Natalí Bianca Rafael Olária Dauzacher, Denis Depieri Crippa, Graziele Vefago Boaventura Possenti, Rodrigo Battisti

Water pollution from industrial-colored effluents, generated by large volumes of liquid effluents containing synthetic dyes, generally harmful and non-biodegradable, affects environmental biota and human health. Considering the potential use as bio-adsorbents of agro-industrial residues, in the present work insights into the kinetics, equilibrium, and mechanism of the methylene blue (MB) dye adsorption by six bio-adsorbents produced from the post-harvest residues from the banana tree, a widely cultivated crop in Brazil, were investigated. The six prepared bio-adsorbents were tested to verify the adsorption capacity as gross residues, after carbonization, and after alkaline-chemical activation. Bench-scale experiments conducted at different conditions showed that experimental data were better described by the Langmuir isotherm, by the intraparticle diffusion model (with external diffusion being the dominant step), followed by the pseudo-second-order model, indicating the predominance of monolayer chemisorption. In addition, maximum adsorption capacities ranged between 10.55 and 25.51 mg/g, with a higher dye removal rate at alkaline pH. The adsorption of the MB dye onto the six produced bio-adsorbents occurred through both polar and nonpolar interactions. The overall study indicated that both the pseudo-stem and the leaves from post-harvest banana crops could be a cost-effective natural bioresource for producing efficient and sustainable bio-adsorbents for treating colored liquid effluents.

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引用次数: 0
Issue Information: Clean Soil Air Water. 11/2024 问题信息:清洁土壤、空气和水。11/2024
IF 1.5 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2024-11-16 DOI: 10.1002/clen.202470111
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引用次数: 0
Comparison of Machine Learning Algorithms for Prediction of Textile Effluent Treatment Efficiency Using Anaerobic Process
IF 1.5 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2024-11-08 DOI: 10.1002/clen.202400009
Saurabh Samuchiwal, Saurabh Saraswat, Vivek Kumar Nair, Aman Chaudhary, Anushree Malik

The prediction of pollutants removal efficiency from the generated effluent of a treatment plant is valuable and can reduce the time, sampling and energy required during performance assessment. The present study aims to predict the effect of different input parameters on the treatment efficiency of the developed microbial-based anaerobic process for textile effluent using machine leaning algorithms. The decolourisation and chemical oxygen demand (COD) reduction of the treated effluent were predicted on the basis of the three different input parameters pH, COD and colour value of the textile wastewater. The effectiveness of different machine learning algorithms, support vector machines (SVM), random forest (RF), gradient boost regressor (GBR), AdaBoost, extreme gradient boosting (XGB) regressor and voting regressor, were evaluated based on the correlation coefficient (R2) value. The results revealed that the RF achieved the highest accuracy for decolourisation (training data R2: ∼0.85 and test data R2: ∼0.84) as well as COD reduction (training data R2: ∼0.87 and test data R2: ∼0.94) compared to the other algorithms. These results were validated experimentally, confirming that RF can be used as a tool to predict the performance efficiency of a microbial-based treatment system.

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引用次数: 0
A Comprehensive Review on the Biofilm-Mediated Removal of Nitrogen and Chemical Oxygen Demand From Different Wastewater Sources 生物膜对不同废水源中氮和化学需氧量的去除研究综述
IF 1.5 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2024-11-07 DOI: 10.1002/clen.202300282
Modhurima Misra, Pranati Das, Anshita Mehra, Soham Chattopadhyay

Discharging effluents with high chemical oxygen demand (COD) and nitrogen content into the environment threatens human and aquatic life. An increase in nitrogen load results in depletion of dissolved oxygen (DO), eutrophication, ecological stress, and biodiversity loss. Intake of water containing excess nitrate can cause different diseases. Conventional physicochemical nitrogen removal techniques are expensive and also generate secondary pollutants. In contrast, biological methods offer effective and economical outcomes with global acceptance. Biofilm-based techniques have the advantages of low space requirement, resistance toward toxic shocks, and absence of sludge backflow. The carriers used in biofilm reactors allow the growth of heterogeneous microbial consortia, which can simultaneously remove COD, nitrogenous compounds, and phosphates. This review aims to summarize the outcomes of the individual lab-scale research in this area, critically analyze the scientific findings, and understand the research gap. Conventional nitrification–denitrification and anammox have often been replaced by more efficient approaches such as simultaneous nitrification–denitrification, partial nitrification–denitrification, partial nitritation and anammox, and simultaneous partial nitrification, anammox, and denitrification. Multistage moving bed biofilm reactors have been specially designed with step feeding for complete nitrogen removal. Through anammox in a sequencing batch reactor, a high rate of denitrification could be obtained, whereas simultaneous nitrification–denitrification using a membrane bioreactor resulted in almost complete removal of nitrogen. We expect that this review will provide the direction for designing experiments on enhanced removal of nitrogen and COD from different wastewater sources using microbial biofilms.

向环境排放高化学需氧量(COD)和高氮含量的废水对人类和水生生物构成威胁。氮负荷增加导致溶解氧(DO)耗竭、富营养化、生态压力和生物多样性丧失。摄入含有过量硝酸盐的水会引起不同的疾病。传统的物理化学脱氮技术不仅成本昂贵,而且会产生二次污染物。相比之下,生物方法提供了全球认可的有效和经济的结果。基于生物膜的技术具有空间要求低、抗毒性冲击、无污泥回流等优点。生物膜反应器中使用的载体允许异质微生物群落的生长,可以同时去除COD,氮化合物和磷酸盐。本文旨在总结该领域的个别实验室规模的研究成果,批判性地分析科学发现,并了解研究差距。传统的硝化-反硝化和厌氧氨氧化经常被更有效的方法所取代,如同时硝化-反硝化、部分硝化-反硝化、部分硝化-厌氧氨氧化、同时部分硝化-厌氧氨氧化和反硝化。多级移动床生物膜反应器采用分步进料的特殊设计,可完全去除氮。在序批式反应器中厌氧氨氧化可获得较高的反硝化速率,而在膜生物反应器中同时硝化-反硝化几乎可以完全去除氮。希望本文的研究成果能为微生物膜强化去除不同废水源中的氮和COD的实验设计提供指导。
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引用次数: 0
Water Quality Evaluation With Entropy Weight‒Grey Correlation Technique for Fishing Operation Area in Tianjin, China
IF 1.5 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2024-11-07 DOI: 10.1002/clen.202300356
Hui Yuan, Shaoqiang Han, Ye Tian, Ying Zhang, Zhe Bo, Jiahong Liu

The discharge of domestic sewage and waste oil from fishery activities can cause adverse impacts on coastal seawater in bays and estuaries. The Bohai Sea near Tianjin features strong water closure and weak self-purification ability. The objective evaluation and analysis of pollution characteristics are crucial for assessing the quality of coastal seawater. This evaluation is essential for the sustainable development of traditional marine fisheries and serves as a powerful tool for government decision-making. To this end, we constructed an entropy weight‒grey correlation technique for order preference by similarity to an ideal solution (TOPSIS) model (EWGCT) based on the traditional TOPSIS evaluation approach to evaluate the water quality of five fishing ports and operation areas. The spatial distribution characteristics, pollution characteristics, and key impactful indicators were identified via a geographic information system (GIS) and multivariate statistical analysis. The results show that (1) the EWGCT has the ability to rank water quality universally and evaluate it based on the comprehensive impact of all pollution factors; (2) petroleum (PETRO) was affected mainly by the waste oil discharged, and suspended solids (SS), dissolved inorganic phosphate (DIP), and fecal coliform bacteria (FCB) were affected mainly by the domestic sewage discharged; and (3) effective management of fishing vessel discharge is important for ensuring the quality of the seawater environment. By establishing the EWGCT, the reliability and rationality of the evaluation results are verified, which can provide a reference for the formulation of development strategies for coastal cities.

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引用次数: 0
Effect of Intercropping Soybean on the Diversity of the Rhizosphere Soil Arbuscular Mycorrhizal Fungi Communities in Wheat Field 间作大豆对小麦田根瘤土壤丛枝菌根真菌群落多样性的影响
IF 1.5 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-25 DOI: 10.1002/clen.202400348
Lu Xingli

CLEAN—Soil, Air, Water, 2022, 50 (6). 2100014. http://doi.org/10.1002/clen.202100014.

In the initially published article, the units of the crop yield in Table 5 were calculated in jin mu−1, not kg hm−2 due to my careless. 1 jin mu−1 = 500 g/666.67 m2.

In the published article, Table 5 is given as:

The new version of the table is:

Further, on Page 4, Section 2.5 “Effects of Different Intercropping Models on Crop Yield,” the current sentence:

“The group yield was highest under the RSW model (1515.97 kg ha−1).” should be given as:

“The group yield was highest under the RSW model (11369.76 kg ha−1).”

In addition, the study was supported by National Natural Science Foundation of China (31860361), The fourth lifting project of Ningxia young scientific and technological talents (TJGC2019075), National Natural Science Foundation of Ningxia (2019AAC03055).

The calculation error does not affect the results or conclusions of the manuscript. The author apologizes for any inconvenience or misunderstanding that this error may have caused.

CLEAN-Soil, Air, Water, 2022, 50 (6).2100014. http://doi.org/10.1002/clen.202100014.In 在最初发表的文章中,由于我的粗心,表 5 中作物产量的计算单位是斤亩-1,而不是 kg hm-2。1斤亩产=500克/666.67平方米。在发表的文章中,表 5 的单位为:新版表格为:此外,在第 4 页第 2.5 节 "不同间作模式对作物产量的影响 "中,目前的句子:"在 RSW 模式下,群体产量最高(1515.97 千克公顷-1)。"应改为:"在 RSW 模式下,群体产量最高(11369.76 kg ha-1)。"此外,该研究得到了国家自然科学基金(31860361)、宁夏第四批青年科技人才提升工程(TJGC2019075)、宁夏国家自然科学基金(2019AAC03055)的资助,计算错误不影响稿件的结果和结论。该计算错误不影响稿件的结果和结论,如因此造成不便或误解,作者深表歉意。
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引用次数: 0
Short-Term Benefits of Tillage and Agronomic Biofortification for Soybean–Wheat Cropping in Central India 印度中部大豆-小麦作物耕作和农艺生物强化的短期效益
IF 1.5 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-12 DOI: 10.1002/clen.202300300
Raghavendra Nargund, Rakesh Kumar Verma, Aketi Ramesh, Mahaveer Prasad Sharma, Hanamant Mudakappa Halli, Prabhu Govindasamy

In a changing climate, conservation tillage and agronomic biofortification are essential for enhancing crop yield, nutritional security, carbon stocks, and soil quality. Consequently, a field study was conducted in central India to assess the short-term (4 years) effects of crop establishment techniques (CETs) and agronomic biofortification methods (ABMs) on soil health indicators, grain yield, and quality in the soybean–wheat cropping system. The experiment followed a split-plot design with two CETs in the main plots (permanent broad bed furrow, PBBF, and conventional tillage, CT) and eight ABMs, each with three replications. The results indicated that PBBF and ABMs (seed inoculation with the microbial strains MDSR 14 + MDSR 34, and soil and foliar application of Zn+Fe) improved soil carbon stock (by 49.6% and 52.4%), available nitrogen, phosphorus, potassium, available Zn (by 30.0%), and Fe (by 21.9%) after the fourth year of the study. Similarly, PBBF and microbial inoculation increased soil enzyme activities (dehydrogenase, acid phosphatase, and β-glucosidase), substrate-induced respiration, and microbial biomass carbon content. As a result, a higher soybean equivalent yield (5.59% higher in PBBF and 14.2% higher with foliar spray of Zn+Fe) and seed quality attributes (crude protein yield, grain Zn, and Fe) were observed in PBBF and the foliar spray of Zn and Fe treatments compared to CT and control, respectively. Overall, adopting the short-term PBBF system, microbial inoculation, and soil and foliar application of Zn and Fe improved rhizosphere biochemical properties, yield, and seed quality in the soybean–wheat system.

在气候不断变化的情况下,保护性耕作和农艺生物强化对提高作物产量、营养安全、碳储量和土壤质量至关重要。因此,在印度中部开展了一项田间研究,以评估作物种植技术(CET)和农艺生物强化方法(ABM)对大豆-小麦种植系统中土壤健康指标、谷物产量和质量的短期(4 年)影响。试验采用分小区设计,在主小区采用两种 CET(永久性宽床沟播(PBBF)和常规耕作(CT))和八种农艺生物强化方法,每种方法有三次重复。结果表明,PBBF 和 ABMs(种子接种微生物菌株 MDSR 14 + MDSR 34,土壤和叶面施肥锌+铁)在研究第四年后改善了土壤碳储量(49.6% 和 52.4%)、可利用氮、磷、钾、可利用锌(30.0%)和铁(21.9%)。同样,PBBF 和微生物接种提高了土壤酶活性(脱氢酶、酸性磷酸酶和 β-葡萄糖苷酶)、底物诱导呼吸和微生物生物量碳含量。因此,与 CT 和对照相比,PBBF 和叶面喷施锌和铁处理的大豆当量产量(PBBF 高 5.59%,叶面喷施锌+铁高 14.2%)和种子质量属性(粗蛋白产量、籽粒锌和铁)分别更高。总之,采用短期 PBBF 系统、微生物接种、土壤和叶面喷施锌和铁改善了大豆-小麦系统的根瘤生化特性、产量和种子质量。
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引用次数: 0
Issue Information: Clean Soil Air Water. 10/2024 问题信息:清洁土壤、空气和水。10/2024
IF 1.5 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-11 DOI: 10.1002/clen.202470101
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引用次数: 0
Microbial Degradation of Polyester Microfibers Using Indigenously Isolated Bacterial Strain Exiguobacterium Sp. 利用本土分离的细菌菌株 Exiguobacterium Sp.
IF 1.5 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-09 DOI: 10.1002/clen.202300343
Sunanda Mishra, Debasis Dash, Alok Prasad Das

Synthetic microfibers are emerging environmental microplastic pollutants released from different industrial and domestic sources. The present investigation describes the isolation of potential bacterial strains from microplastic-contaminated sites of Bhubaneswar city of Odisha, India. Four morphologically distinct bacterial strains were isolated using 2% polyethylene glycol (PEG) supplemented nutrient agar (NA) medium and were screened for their polymer tolerance ability by growing them on 2%–8% PEG. A single microorganism capable of growing on 8% PEG was selected for biodegradation experiment. Through 16S rRNA sequencing, the selected bacterial strain was identified as Exiguobacterium sp. with gene bank accession number ON318396. The microbial strain's microfiber biodegradation ability was assessed in a laboratory setting over a period of 28 ± 2 days, utilizing optimized conditions with an initial pH of 7, 2 mL inoculum volume, an incubation temperature of 30°C ± 2°C, and 150 rpm, using 2 g of polyester microfiber. In optimum conditions, the weight loss of the treated sample with the selected microbial strain was 19.2%. The polyester degradation was confirmed through scanning electron microscopic images viewing the degradation of the polyester microfiber surfaces. Variation in functional groups confirmed through Fourier transform infrared spectrophotometry. Detection of carbonyl (C═O) group stretching band at 1711 cm−1 through ATR-FTIR analysis in the treated sample confirmed the polymer biodegradation. The potential isolate can efficiently degrade polyester and, in the future, can be employed as a promising solution for the sustainable treatment of synthetic microfiber pollution.

合成微纤维是新兴的环境微塑料污染物,来自不同的工业和生活来源。本研究描述了从印度奥里萨邦布巴内斯瓦尔市微塑料污染地点分离出的潜在细菌菌株。用2%聚乙二醇(PEG)补充营养琼脂(NA)培养基分离出4株形态不同的菌株,并在2% ~ 8%聚乙二醇培养基上培养,筛选其耐聚合物能力。选择能在8%聚乙二醇上生长的单一微生物进行生物降解实验。通过16S rRNA测序,鉴定菌株为Exiguobacterium sp.,基因库登录号为ON318396。在28±2天的实验室环境中,采用优化条件,初始pH为7,接种量为2 mL,培养温度为30°C±2°C,转速为150 rpm,使用2g聚酯超细纤维,评估微生物菌株的超细纤维生物降解能力。在最佳条件下,所选菌株处理后的样品失重率为19.2%。通过扫描电镜观察聚酯微纤维表面的降解情况,证实了聚酯的降解。通过傅里叶变换红外分光光度法证实了官能团的变化。通过ATR-FTIR分析,在1711 cm−1处检测到羰基(C = O)基团拉伸带,证实了聚合物的生物降解。该分离物可以有效地降解聚酯,在未来可以作为一种有前途的解决方案,用于合成超细纤维污染的可持续处理。
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引用次数: 0
Geochemical Interaction and Bioavailability of Zinc in Soil Under Long-Term Integrated Nutrient Management in Pearl Millet–Wheat System 珍珠米-小麦系统长期综合养分管理下土壤中锌的地球化学相互作用和生物利用率
IF 1.5 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-08 DOI: 10.1002/clen.202400232
Diksha Saroha, Narender Yadav, Raj Mukhopadhyay, Dev Raj, Manoj Kumar Sharma, Rohtas Kumar, Anil Duhan

The degree and severity of zinc (Zn) deficiency in soil reduced the agricultural yield and quality, thus encouraging malnutrition in humans worldwide. The study was hypothesized to increase the bioavailability and release of Zn in soil and Zn biofortification in wheat grains under integrated nutrient management (INM). The long-term (54 years) experiment laid out in a split-plot design comprising single (W) and dual (PW) applications of farmyard manure (FYM) (0, 5, 10, and 15 Mg ha−1) and nitrogen (0, 60, and 120 kg ha−1) was studied to understand the distribution of different Zn fractions in soil and their relationship to wheat grain yield and Zn uptake. A laboratory incubation study was performed on surface soils to evaluate the release kinetics of native Zn at field capacity. The different fractions of Zn in soil increased with increasing frequency and levels of FYM application. Residual Zn constituted the maximum proportion (89.03%) of total soil Zn. A high positive correlation (p < 0.01) of diethylenetriaminepentaacetic acid (DTPA)-extractable Zn and total grain Zn content were observed with different Zn fractions. The release kinetics of native soil Zn increased up to 10 days and became almost constant, indicating the establishment of chemical equilibria between the soil solid and solution phase. Thus, long-term INM ensured higher wheat production (6.08 Mg ha−1) and Zn biofortification (38.95 mg kg−1) to combat Zn malnutrition and achieve the United Nations’ sustainable development goals on “zero hunger” and “good health and well-being.”

土壤中锌(Zn)缺乏的程度和严重性降低了农业产量和质量,从而导致全球人类营养不良。这项研究的假设是,在综合养分管理(INM)下,提高锌在土壤中的生物利用率和释放量,并对小麦籽粒进行锌生物强化。这项长期(54 年)实验采用分小区设计,包括单一(W)和双重(PW)施用农家肥(FYM)(0、5、10 和 15 兆克/公顷-1)和氮(0、60 和 120 千克/公顷-1),以了解不同锌组分在土壤中的分布及其与小麦产量和锌吸收的关系。对表层土壤进行了实验室培养研究,以评估原生锌在田间容量下的释放动力学。随着施肥频率和施肥量的增加,土壤中不同成分的锌含量也随之增加。残余锌占土壤总锌的比例最大(89.03%)。二乙烯三胺五乙酸(DTPA)提取的锌与谷物总锌含量呈高度正相关(p < 0.01)。原生土壤锌的释放动力学在 10 天内有所增加,之后几乎保持不变,这表明土壤固相和溶相之间建立了化学平衡。因此,长期的 INM 确保了更高的小麦产量(6.08 Mg ha-1)和锌生物强化(38.95 mg kg-1),以消除锌营养不良,实现联合国关于 "零饥饿 "和 "健康和福祉 "的可持续发展目标。
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