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Defects analysis of ZnGa2O4 thin-film transistors and related properties study (Conference Presentation) ZnGa2O4薄膜晶体管缺陷分析及性能研究(会议报告)
Pub Date : 2019-03-08 DOI: 10.1117/12.2516745
R. Horng
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引用次数: 0
Metal-insulator transition-induced adaptive multispectral infrared camouflage (Conference Presentation) 金属绝缘体跃迁诱导自适应多光谱红外伪装(会议报告)
Pub Date : 2019-03-08 DOI: 10.1117/12.2508646
S. Chandra, Daniel Franklin, Jared Cozart, A. Safaei, D. Chanda
Performance of adaptive infrared camouflage is usually parameterized in terms of cycle-ability, response time, actuation mechanism, stability etc., however, one of the key components that has not been addressed so far is the spatial density of infrared information that can be encoded and actively manipulated for camouflaging.We report an adaptive infrared camouflage system that can be engineered to operate at any desired wavelength in the technologically relevant, infrared transparent 3 – 5 µm and 8 – 12 µm bands. We exploit the metal-insulator phase transition in VO2 to design an optical cavity coupled infrared absorber where the cavity length can be altered by controlling the VO2 phase. Cavity tuning is done by strategically placing the VO2 layer inside the optical cavity composed of a tri-layer architecture. In its insulating state VO2 is transparent to infrared such that incident light couples to the entire cavity length, however in the metallic state, VO2 behaves like a mirror and shortens the cavity length by reflecting ~80% of incident light. The Maxwell Garnett EMT describes the phase transition dependent optical response of the absorber better than the Bruggeman EMT when compared to the experimental results. We tailor the device parameters to demonstrate adaptive thermal camouflage of multispectral encoded infrared information on a pixelated designer surface with a pixel resolution (~20 µm) and density comparable to the industry standard for infrared sensors. We envision this work will pave the way for novel tunable optical devices for technological advancements in infrared tagging, camouflaging and anti-counterfeiting efforts.
自适应红外伪装的性能通常从循环能力、响应时间、驱动机制、稳定性等方面进行参数化,但其中一个关键组成部分是可编码和主动操纵的红外伪装信息的空间密度,迄今尚未得到解决。我们报告了一种自适应红外伪装系统,该系统可以设计成在技术相关的任何所需波长下工作,红外透明3 - 5µm和8 - 12µm波段。我们利用VO2中的金属-绝缘体相变设计了一种光学腔耦合红外吸收器,通过控制VO2的相位可以改变腔长。通过将VO2层策略性地放置在由三层结构组成的光学腔内来实现腔腔调谐。在其绝缘状态下,VO2对红外线是透明的,使得入射光耦合到整个腔长,然而在金属状态下,VO2表现得像一面镜子,通过反射~80%的入射光来缩短腔长。与实验结果相比,麦克斯韦加内特EMT比布鲁格曼EMT更好地描述了吸收器的相变相关光学响应。我们定制了器件参数,以演示多光谱编码红外信息在像素化设计表面上的自适应热伪装,其像素分辨率(~20µm)和密度与红外传感器的行业标准相当。我们设想这项工作将为红外标签、伪装和防伪技术进步的新型可调谐光学设备铺平道路。
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引用次数: 0
Annealing effect for NOx gas sensor based on ZnGa2O4 epi-layer grown by MOCVD (Conference Presentation) 基于MOCVD生长ZnGa2O4外延层的NOx气体传感器的退火效果(会议报告)
Pub Date : 2019-03-08 DOI: 10.1117/12.2510042
M. Wu, Li-Chung Cheng, Chiung-Yi Huang, R. Horng
The effects of annealing on gas sensing properties of NOx gas sensor based on novel material ZnGa2O4 epi-layer grown by MOCVD were studied. The metal-semiconductor-metal (MSM) structure sensor with Ti/Al/Ni (50/75/25 nm) electrode in the multilayers which were deposited by an E-gun evaporator and patterned by a lift-off process. The devices were annealed at 700 oC in N2 ambient for 1hr, and the sensing area is 30um x 250um. The results show that the sensitivity of the ZnGa2O4 gas sensor increases and the response time reduces after annealing. The sensitivity is defined as Rg/Ra, where Rg is the resistance with analyzed gases, and Ra is the resistance with the dry air. At the operation temperature 300oC, the sensitivity of sensors without thermal treatment are 1.026, 1.015, 1.009, 1.003, and 1 when exposed to NO concentration 6.25ppm, 1ppm, 500ppb, 250ppb, and 125ppb, respectively. After 700oC annealing for 1hr, the sensitivity remarkably increases to 52.108, 10.491, 7.744, 4.961, and 3.942 with the same NO concentration as mentioned above. Not only the sensitivity increases more than 10 times but thin-film can detect extremely low NO concentration (125ppb) after thermal treatment. The sensitivity is linear dependent on the NO concentration. Besides, the response time improved all under 30s with the concentration range from 1ppm to 125ppb. Most important of all, the sensors show excellent selectivity which means the sensitivity were all below 1.02 when exposed to CO, CO2, SO2 gases with 1ppm. The results point out that the ZnGa2O4 gas sensors after annealing exhibit the better NO sensing properties, shorter response time and outstanding selectivity.
研究了退火对基于MOCVD生长的新型材料ZnGa2O4外延层的NOx气体传感器气敏性能的影响。金属-半导体-金属(MSM)结构传感器,电极为Ti/Al/Ni (50/75/25 nm),采用电子枪蒸发器沉积多层材料,并采用升离工艺进行图像化。器件在700℃N2环境中退火1hr,感应面积为30um x 250um。结果表明,经过退火处理后,ZnGa2O4气体传感器的灵敏度提高,响应时间缩短。灵敏度定义为Rg/Ra,其中Rg是与被分析气体的阻力,Ra是与干燥空气的阻力。工作温度300oC时,NO浓度为6.25ppm、1ppm、500ppb、250ppb、125ppb时,未经热处理的传感器灵敏度分别为1.026、1.015、1.009、1.003、1。在相同NO浓度下,700oC退火1hr后,灵敏度显著提高至52.108、10.491、7.744、4.961和3.942。薄膜热处理后不仅灵敏度提高了10倍以上,而且可以检测极低的NO浓度(125ppb)。灵敏度与NO浓度呈线性关系。在1ppm ~ 125ppb浓度范围内,30s以内的响应时间均有提高。最重要的是,传感器表现出优异的选择性,这意味着当暴露于浓度为1ppm的CO, CO2, SO2气体时,灵敏度均低于1.02。结果表明,经退火处理的ZnGa2O4气体传感器具有较好的NO传感性能、较短的响应时间和较好的选择性。
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引用次数: 0
Cubic ZnMgO alloys for deep ultraviolet applications (Conference Presentation) 深紫外应用的立方ZnMgO合金(会议报告)
Pub Date : 2019-03-08 DOI: 10.1117/12.2516975
H. Teisseyre, I. Gorczyca, D. Jarosz, M. Wierzbowska, S. Kret, F. Donatini, D. L. S. Dang
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引用次数: 0
Choosing the correct hybrid for defect calculations: A case study on intrinsic carrier trapping in gallium oxide (Conference Presentation) 为缺陷计算选择正确的杂化:氧化镓中固有载流子俘获的案例研究(会议报告)
Pub Date : 2019-03-08 DOI: 10.1117/12.2515495
M. Lorke, P. Deák, Quoc Duy Ho, B. Aradi, T. Frauenheim
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引用次数: 1
Two-dimensional organic-inorganic hybrid perovskites (Conference Presentation) 二维有机-无机杂化钙钛矿(会议报告)
Pub Date : 2019-03-08 DOI: 10.1117/12.2516752
L. Dou
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引用次数: 0
Beta-Ga2O3: materials synthesis and device demonstration (Conference Presentation) β - ga2o3:材料合成与器件演示(会议报告)
Pub Date : 2019-03-08 DOI: 10.1117/12.2515472
Hongping Zhao
Ultrawide bandgap (UWBG) gallium oxide (Ga2O3) represents an emerging semiconductor material with excellent chemical and thermal stability. It has a band gap of 4.5-4.9 eV, much higher than that of the GaN (3.4 eV) and 4H-SiC (3.2 eV). The monoclinic beta-phase Ga2O3 represents the thermodynamically stable crystal among the known five phases . The breakdown field of beta-Ga2O3 is estimated to be 6-8 MV/cm, which is much larger than that of the 4H-SiC and GaN. These unique properties make beta-Ga2O3 a promising candidate for high power electronic device and solar blind photodetector applications. More advantageously, single crystal beta-Ga2O3 substrates can be synthesized by scalable and low cost melting based growth techniques. Different from the molecular beam epitaxy (MBE) and metalorganic chemical vapor deposition (MOCVD) growth techniques, we have developed a low pressure chemical vapor deposition (LPCVD) method to grow high quality beta-Ga2O3 thin films on both native Ga2O3 and c-sapphire substrates with controllable doping and fast growth rates up to 10 um/hr. In this talk, we present the growth, material characterization and device demonstration of beta-Ga2O3 thin films grown via LPCVD. The beta-Ga2O3 thin films were grown on native beta-Ga2O3 (010), (001) and (-201) substrates and sapphire substrates using high purity gallium and oxygen as the precursors, and argon (Ar) as the carrier gas. The growth temperature ranged between 850 ˚C and 950 ˚C. Fundamental material properties including temperature dependent Hall measurements and device demonstration based on vertical Schottky barrier diodes will be discussed.
超宽带隙(UWBG)氧化镓(Ga2O3)是一种具有优异化学稳定性和热稳定性的新兴半导体材料。其带隙为4.5 ~ 4.9 eV,远高于GaN (3.4 eV)和4H-SiC (3.2 eV)。单斜相Ga2O3是已知五相中热力学稳定的晶体。β - ga2o3的击穿场为6 ~ 8 MV/cm,远远大于4H-SiC和GaN的击穿场。这些独特的性质使β - ga2o3成为高功率电子器件和太阳盲光电探测器应用的有希望的候选者。更有利的是,单晶β - ga2o3衬底可以通过可扩展和低成本的熔融生长技术合成。与分子束外延(MBE)和金属有机化学气相沉积(MOCVD)生长技术不同,我们开发了一种低压化学气相沉积(LPCVD)方法,可以在天然Ga2O3和c-蓝宝石衬底上生长高质量的β -Ga2O3薄膜,掺杂可控,生长速度高达10 um/hr。在这次演讲中,我们介绍了通过LPCVD生长的β - ga2o3薄膜的生长,材料表征和器件演示。以高纯镓和氧为前驱体,氩(Ar)为载气,在天然β - ga2o3(010)、(001)和(-201)衬底和蓝宝石衬底上制备了β - ga2o3薄膜。生长温度在850 ~ 950℃之间。基本的材料性质,包括温度相关的霍尔测量和基于垂直肖特基势垒二极管的器件演示将被讨论。
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引用次数: 0
Tuning the epsilon-near-zero region of ultra-thin Al-doped ZnO through atomic layer deposition (Conference Presentation) 通过原子层沉积调谐超薄al掺杂ZnO的epsilon-近零区(会议报告)
Pub Date : 2019-03-08 DOI: 10.1117/12.2508887
Garand T. Tyson, Sudip Gurung, Subhajit Bej, A. Anopchenko, Howard Lee
In this work, we report on the tunability of carrier concentration and epsilon-near-zero (ENZ) wavelength (i.e. the region where the real dielectric permittivity of a material approaches zero) in ultrathin (<100 nm) Al-doped ZnO (AZO) nano-layers fabricated through the atomic layer deposition (ALD) technique. ALD is a variation of chemical vapor deposition in which a substrate is exposed to only one self-limiting reactant at a time, allowing for ultra-smooth, conformal deposition and precise control over film-thickness at the nanometer scale. To create the AZO meta-films, fused silica substrates are exposed to alternating cycles of Diethylzinc (DEZ) and water vapor, with periodic dopant cycles of Trimethylaluminium (TMA). Optical and material properties of the meta-films are determined using spectroscopic ellipsometry. Using the Drude model and regression analysis with measured values, properties such as film thickness, ENZ wavelength, and complex refractive index are then determined. Furthermore, excitation of ENZ modes in the fabricated films has been demonstrated experimentally using the Kretschmann-Raether configuration. It was found that by varying the deposition temperature, Al:ZnO doping ratio, and film thickness, the ENZ wavelength of AZO thin films could be precisely tuned in the near infrared region from 1520 to 1700 nm. The results of this work allow for the precise engineering of optical properties of AZO films for zero-index photonic applications.
在这项工作中,我们报告了通过原子层沉积(ALD)技术制备的超薄(<100 nm) al掺杂ZnO (AZO)纳米层中的载流子浓度和epsilon-near-zero (ENZ)波长(即材料的实际介电常数接近零的区域)的可调性。ALD是化学气相沉积的一种变体,在这种化学气相沉积中,衬底一次只暴露于一种自限性的反应物,从而实现超光滑、保形沉积和纳米级薄膜厚度的精确控制。为了制造AZO元膜,将熔融二氧化硅衬底暴露于二乙基锌(DEZ)和水蒸气的交替循环中,并定期使用三甲基铝(TMA)的掺杂循环。利用椭偏光谱法测定了元膜的光学性质和材料性质。利用Drude模型和实测值的回归分析,确定了薄膜厚度、ENZ波长和复折射率等特性。此外,利用Kretschmann-Raether结构,实验证明了制备薄膜中ENZ模式的激发。研究发现,通过改变沉积温度、Al:ZnO掺杂比和薄膜厚度,AZO薄膜的ENZ波长可以在近红外区域从1520 nm精确调谐到1700 nm。这项工作的结果允许零折射率光子应用的AZO薄膜光学性质的精确工程。
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引用次数: 0
Coherent gamma-Al2O3/Ga2O3 superlattices grown on MgAl2O4 (Conference Presentation) 在MgAl2O4上生长的相干γ - al2o3 /Ga2O3超晶格(会议报告)
Pub Date : 2019-03-08 DOI: 10.1117/12.2515331
T. Oshima
The rising momentum of research and developments on Ga2O3 has broaden the area of material exploration even for metastable phases. In the field of metastable Ga2O3, we have focused on defective-spinel-structured γ-phase and established some milestones: epitaxial stabilization of single crystalline films on MgAl2O4 [T. Oshima,et al., J. Cryst. Growth 359, 60 (2012).], carrier generation by impurity doping [T. Oshima et al., J. Cryst. Growth 421, 23 (2015).], and band-gap engineering by alloying γ-Al2O3 [T. Oshima et al., Appl. Phys. Express 10, 051104 (2017).]. We consider their results endorse further semiconductor engineering studies on γ-Ga2O3-related materials. Therefore, as a successive study, we have attempted to fabricate first γ-(AlxGa1−x)2O3-based heterostructures, particularly the superlattices (SLs) comprised with the end members of the alloy, to consider the possibility of obtaining coherent heterojunctions for future heterojunction device applications. 10-period γ-Al2O3/Ga2O3 SLs on (001) MgAl2O4 substrate were fabricated by plasma-assisted molecular beam epitaxy. By controlling the each layer thickness, we tuned the average Al composition (x_ave) of the coherent SLs from 0.26 to 0.86, and obtained nearly-lattice-matched SLs to the substrate at x_ave ~ 0.5. The lattice-matched SLs maintained coherent interfaces up to a period length of 7.2 nm (3.2/4.0 nm for γ-Al2O3/Ga2O3 layers) in spite of a large lattice mismatch between the end members (−3.6%). These successful fabrication of γ-Al2O3/Ga2O3 SLs means wide flexibility in designing γ-(AlxGa1−x)2O3-based heterostructures including superlattices for future development of functional heterojunction devices.
Ga2O3的研究和发展势头的上升拓宽了材料探索的领域,甚至是亚稳相。在亚稳Ga2O3领域,我们重点研究了缺陷尖晶石结构的γ相,并建立了一些里程碑:MgAl2O4 [T]上单晶薄膜的外延稳定;J.克里斯特。增长359,60(2012)。],杂质掺杂生成载流子[T。J.克里斯特。增长421,23(2015)。[j],以及γ-Al2O3合金化带隙工程[j]。大岛等人,苹果公司。理论物理。快报10,051104(2017)。我们认为他们的研究结果支持了γ- ga2o3相关材料的进一步半导体工程研究。因此,作为一项连续的研究,我们已经尝试制造第一个基于γ-(AlxGa1−x) 2o3的异质结构,特别是由合金末端成员组成的超晶格(SLs),以考虑为未来异质结器件应用获得相干异质结的可能性。采用等离子体辅助分子束外延技术在(001)MgAl2O4衬底上制备了10周期γ-Al2O3/Ga2O3 SLs。通过控制各层厚度,我们将相干SLs的平均Al组成(x_ave)从0.26调整到0.86,并在x_ave ~ 0.5处获得了与衬底几乎晶格匹配的SLs。晶格匹配的SLs保持了7.2 nm的相干界面(γ-Al2O3/Ga2O3层为3.2/4.0 nm),尽管端元之间存在较大的晶格不匹配(−3.6%)。这些γ- al2o3 /Ga2O3 SLs的成功制造意味着在设计γ-(AlxGa1−x) 2o3基异质结构(包括超晶格)方面具有广泛的灵活性,可用于未来功能异质结器件的开发。
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引用次数: 0
Halide vapor phase epitaxy of a- and b-Ga2O3 films (Conference Presentation) a-和b-Ga2O3薄膜的卤化物气相外延(会议报告)
Pub Date : 2019-03-08 DOI: 10.1117/12.2527567
J. Leach
Thanks to their superior breakdown fields, both beta- and alpha-phase Ga2O3 are poised to achieve ultra-high-performance devices enabling highly efficient, high voltage power switching systems. To realize the thick films required of the highest voltage devices, a growth technique which can achieve high growth rates is desired. Kyma Technologies has developed a low-cost halide vapor phase epitaxy (HVPE) tool for the growth of both beta- phase and alpha- phase Ga2O3 films which boasts high growth rates and smoothness while simultaneously being able to be lightly and controllably doped with Si and free of carbon. We will outline our recent growth results including effects of substrate preparation and growth conditions on epilayer morphology and mobility.
由于其优异的击穿场,β相和α相Ga2O3都可以实现超高性能的器件,从而实现高效、高压的电源开关系统。为了实现高电压器件所需的厚膜,需要一种能够实现高生长速率的生长技术。Kyma技术公司开发了一种低成本的卤化物气相外延(HVPE)工具,用于β相和α相Ga2O3薄膜的生长,该工具具有高生长速率和光滑度,同时能够轻松可控地掺杂Si和无碳。我们将概述我们最近的生长结果,包括底物制备和生长条件对脱毛层形态和移动性的影响。
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引用次数: 0
期刊
Oxide-based Materials and Devices X
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