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SP-202: Third Canmet/ACI International Symposium: Sustainable Development of Cement and Concrete最新文献

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Factor Ten Emmisions Reductions : The Key To Sustainable Development and Economic Prosperity for Cement 减排十大要素:水泥可持续发展和经济繁荣的关键
R. Horton
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引用次数: 1
Mechanical Properties and Durability of Concrete Made With Portland Limestone Cement 石灰石硅酸盐水泥混凝土的力学性能和耐久性
E. Irassar, V. Bonavetti, H. D. G. Menhdez, Cabrera
European countries have a great deal of experience in the use of Portland Limestone Cements (PLC). In Latin America, most of the cement plants use limestone as a raw material and an increase in cement production is expected in the next few years. The manufacture of this cement would represent a rapid increase of production without environmental consequences. This paper synthesizes data from a research program carried out over two years to determine the effects of limestone filler on concrete and mortar behavior. At early age, the influence of limestone filler on workability, bleeding, initial curing and mechanical behavior (modulus of elasticity, compressive and tensile strength) was studied. Sulfate resistance and chloride penetration, the most important durability problems related with PLC, were also studied. The addition of slag was also investigated to improve the long-term strength and the durability of PLC. Results show that cements containing around 10% of limestone filler provide similar or better mechanical behavior than portland cement concrete, without compromising their durability properties where low chloride diffusion and high sulfate resistance is required. In this case, the environmental impact of cement manufacture decreases because the energy consumption and the carbon dioxide emission are reduced per ton of cement and the combination with supplementary cementing materials (slag, fly ash or natural pozzolan) can improve these aspects.
欧洲国家在使用波特兰石灰石水泥(PLC)方面有着丰富的经验。在拉丁美洲,大多数水泥厂使用石灰石作为原料,预计未来几年水泥产量将增加。这种水泥的生产将代表着产量的快速增长,而不会对环境造成影响。本文综合了一项研究计划的数据,该研究计划进行了两年多,以确定石灰石填料对混凝土和砂浆行为的影响。在早期龄期,研究了石灰石填料对和易性、放水、初始养护和力学性能(弹性模量、抗压强度和抗拉强度)的影响。对PLC最重要的耐久性问题——耐硫酸盐性和氯离子渗透性进行了研究。还研究了添加炉渣对PLC长期强度和耐久性的改善作用。结果表明,含有约10%石灰石填料的水泥比波特兰水泥混凝土具有相似或更好的力学性能,并且在要求低氯离子扩散和高硫酸盐抗性的情况下不影响其耐久性。在这种情况下,水泥生产对环境的影响降低了,因为每吨水泥的能耗和二氧化碳排放量都减少了,并且与补充胶凝材料(矿渣、粉煤灰或天然火山灰)结合可以改善这些方面。
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引用次数: 27
Repercussionson Concrete Permeability Due to Recycled Concrete Aggregate 再生混凝土骨料对混凝土渗透性的影响
J. Gomez, L. Agulló, E. Vázquez
This paper presents an experimental analysis of recycled concrete (RC) in which the natural aggregates are replaced by recycled concrete aggregates (RCA). This experimental program covers the specifications of the aggregates employed, together with that of the concrete that is manufactured with them. The considerable effect on the permeability of RC that is produced by the use of RCA is described and discussed. Tests reveal considerable increase in permeability of RC in comparison with the reference concrete. Both the water penetration depths and the permeability coefficients are increased in a manner that may be correlated with the increase in the replacement of natural aggregates by RCA. These increments are attributed to the high porosity of RCA.
本文介绍了用再生混凝土骨料(RCA)代替天然骨料的再生混凝土(RC)试验分析。本实验方案涵盖了所使用的骨料的规格,以及用它们制造的混凝土的规格。描述并讨论了RCA的使用对RC的渗透率产生的相当大的影响。试验表明,与参考混凝土相比,RC的渗透性有相当大的增加。水渗透深度和渗透系数的增加可能与RCA对天然团聚体的替代增加有关。这些增量归因于RCA的高孔隙率。
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引用次数: 6
Pre-Industrial Manufacturing Tests on Construction Blocks Composed of Magnesium Slags 镁渣结构块的工业化前制造试验
R. Cabrillac, J. Gallias, M. Courtial, G. Pierson
The aim of this study is the valorization of magnesium slags in order to recycle them in construction block form. Two kinds of slag with hydraulic properties are obtained according to a 1/3-2/3 ratio: powdered slag similar to cement, and granulated slag similar to sand. A previous laboratory study was carried out in order to obtain sufficient mechanical strength for construction blocks and setting kinetics compatible with an industrial process. The present paper deals with the consecutive implementation of life size tests on an industrial scale. Two pre-industrial tests were carried out in extremely different temperature conditions: 7 degrees C for the first test and 22 degrees C for the second one. Furthermore, the second test benefited from the new casting conditions resulting from updating of the manufacturing unit. The first test showed that the laboratory study permitted to adjust the set kinetics to a level adequate for industrial casting, whereas the mechanical strength obtained was lower than expected when the powdered slag was used as a substitute for cement. The second test enabled the authors to obtain enough mechanical strength for mixtures entirely composed of magnesium slags and proved the possibility of total and simultaneous enhancing value of magnesium slags as construction blocks. More generally, these industrial tests show how difficult the transfer to the industrial scale is.
本研究的目的是对镁渣进行增值处理,以便以砌块形式回收利用。按照1/3-2/3的比例得到两种水力学性能的矿渣:类似水泥的粉状矿渣和类似沙子的粒状矿渣。先前的实验室研究是为了获得足够的机械强度的结构块和设置动力学兼容的工业过程。本论文涉及在工业规模上连续实施寿命尺寸测试。两项工业化前测试在极端不同的温度条件下进行:第一次测试为7摄氏度,第二次测试为22摄氏度。此外,第二次测试得益于制造单元的更新所带来的新的铸造条件。第一次试验表明,实验室研究允许将凝固动力学调整到足以用于工业铸造的水平,而当矿渣粉用作水泥替代品时,获得的机械强度低于预期。第二次试验使作者能够获得完全由镁渣组成的混合物的足够机械强度,并证明了镁渣作为结构块的总增强值和同时增强值的可能性。更一般地说,这些工业试验表明,向工业规模转移是多么困难。
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引用次数: 0
Performance of Alkali -Activated Slag Concrete 碱活化矿渣混凝土性能研究
S. Al-Otaibi, C. J. Lynsdale, J. Sharp
The environmental concerns related to the production of cement in terms of the energy consumption and the emission of CO2 lead to the search for more environmentally viable alternatives to cement. One of those alternative materials is alkali-activated slag (AAS) where ground granulated blast furnace slag is used not as a partial replacement to cement but as the sole binder in the production of concrete. The performance of alkali-activated slag concrete with sodium silicate (water glass) as an activator was studied. The scope of the work covered seven mixes: a normal strength OPC control mix, a blended OPC/Slag mix of similar compressive strength but of lower water to binder ratio, a second OPC control mix of a water to binder ratio similar to that of the OPC/Slag mix, and four alkali-activated slag mixes of the same binder content and the same water to binder ratio as those of the second OPC mix. The AAS mixes were prepared with slag as the sole binder, activated with water glass at two dosages, 4% and 6% Na2O (by weight of slag). Two types of water glass were used, one in a solution form and the other in a solid granules form. The two forms of the activator used were also of different silicate modulus (Ms); 1.65 for the solution form and 1.0 for the granule form. Different curing regimes were used including normal water curing, air dry curing and accelerated autoclave heat curing. The fresh concrete properties studied were setting time, workability and air content. The engineering properties studied were compressive strength, splitting tensile strength, flexural strength, dynamic modulus of elasticity and ultrasonic pulse velocity and drying shrinkage. The durability potential of alkali-activated stag concrete was investigated by testing for oxygen permeability, chloride penetration resistance, porosity, carbonation, and alkali-silica reaction. The hydration of alkali-activated slag was studied using x-ray diffraction and thermogravimetry techniques. Alkali-activated slag concrete was found to achieve good workability which was, comparable to that of OPC and OPCfslag concrete. The increase of the Na2O dosage resulted in a lower workability and the activator with higher silicate modulus exhibited lower workability. AAS concrete however, sets rapidly if not controlled by the addition of lime. The main hydration products in the AAS systems were C-S-H (I) and hydrotalcite as observed in the XRD patterns with autoclaving resulting in the formation of a more crystalline C-S-H gel and the possible formation of xonotlite. The mechanical properties of AAS concrete are highly influenced by the activator's silicate modulus and the Na2O dosage where strength was found to be higher with the higher modulus and dosage. The AAS concrete is very sensitive to curing and dry curing resulted in a reduction in strength for AAS concrete much more than that for OPC concrete. Accelerated curing (autoclave) increased the initial gain of strength in AAS concrete but even
在能源消耗和二氧化碳排放方面,与水泥生产有关的环境问题促使人们寻找对环境更可行的水泥替代品。其中一种替代材料是碱活化矿渣(AAS),其中磨碎的粒状高炉矿渣不是作为水泥的部分替代品,而是作为混凝土生产中的唯一粘合剂。以水玻璃(水玻璃)为活化剂,研究了碱活化矿渣混凝土的性能。研究范围包括七种混合料:一种强度正常的OPC控制混合料,一种抗压强度相似但水胶比较低的OPC/矿渣混合料,一种水胶比与OPC/矿渣混合料相似的第二种OPC控制混合料,以及四种与第二种OPC混合料具有相同粘结剂含量和相同水胶比的碱活性矿渣混合料。以矿渣为唯一粘结剂制备AAS混合料,用水玻璃在4%和6% Na2O(矿渣重量)两种剂量下活化。使用了两种类型的水玻璃,一种是溶液形式,另一种是固体颗粒形式。两种活化剂的硅酸盐模量(Ms)也不同;溶液形式1.65,颗粒形式1.0。采用了不同的养护制度,包括普通水养护,空气干燥养护和加速蒸压罐热养护。研究了新拌混凝土的凝结时间、和易性和空气含量。研究了其抗压强度、劈裂抗拉强度、抗弯强度、动态弹性模量、超声脉冲速度和干燥收缩率等工程性能。通过对碱活化雄鹿混凝土的透氧性、抗氯离子渗透性、孔隙率、碳化和碱-硅反应等测试,研究了其耐久性潜力。采用x射线衍射和热重法研究了碱活性矿渣的水化过程。碱活化渣混凝土具有良好的和易性,与OPC和OPCfslag混凝土相当。随着Na2O用量的增加,活化剂的和易性降低,高硅酸盐模量的活化剂和易性降低。然而,如果不加石灰控制,AAS混凝土会迅速凝结。XRD谱图显示,AAS体系的主要水化产物为C-S-H (I)和水滑石,通过高压灭菌,形成了更结晶的C-S-H凝胶,并可能形成硅钙石。活化剂的硅酸盐模量和Na2O用量对AAS混凝土的力学性能有较大影响,且活化剂的模量和用量越大,强度越高。AAS混凝土对养护和干养护非常敏感,导致AAS混凝土强度的降低远远大于OPC混凝土。加速养护(蒸压釜)增加了AAS混凝土的初始强度增益,但最终的结果接近于水养护。使用Ms = 1.65、Na2O为6%的水玻璃活化剂,干燥收缩率最高,用量越少、模量越低,干燥收缩率越低。AAS混凝土的蒸压釜养护减少了干燥收缩,因为它导致更多水化结晶产物的形成。在活化剂m = 1.0的AAS混凝土中,随着Na2O掺量的增加,孔隙率降低,而在活化剂m = 1.65的AAS混凝土中,随着Na20掺量的增加,孔隙率增加。干养护增加了所有混凝土混合料的孔隙率。孔隙率测试结果受测试前样品预处理的影响。碱-硅试验结果表明,用矿渣代替60%的OPC可减少含活性骨料混凝土柱的膨胀。结果还表明,由于水化产物中碱的结合更强,AAS混凝土对ASR膨胀的敏感性较低。碳化试验结果表明,在相同w/c比下,OPCIslag混凝土的碳化程度高于OPC混凝土。抗压强度在40mpa左右的AAS混凝土与同等级的OPC混凝土相比,碳化率较高,强度越高,碳化率越低。
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引用次数: 10
Microstructure of Concrete from a Crack-Free Structure Designed to Last a Thousand Years 耐久性千年无裂纹结构混凝土的微观结构
J. Asselanis, P. Mehta
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引用次数: 3
Steel Slags in Cement-Making-The Current Status of Development 钢渣在水泥生产中的发展现状
A. Chatterjee
In the production of iron and steel, two different types of slags are generated - one, the blast-furnace slag obtained at the time of iron extraction and the other, the steel slag generated during the conversion of iron to steel in the steel melting shop. The blast-furnace slag, after proper granulation, is used extensively as a supplementary cementitious material in the cement and concrete industry. The steel slag, however, has not found much use and is mostly dumped as a waste material after removing scrap steel. In order to explore the avenues for economical utilization of this slag in cement-making, an extensive literature and patent survey has been carried out. Further, based on the steel slags available from some of the integrated steel plants in India, the material has been characterized in detail and its hydraulic behavior has been studied. Studies relating to the potential use of this slag as a raw material in the production of portland cement clinker as well as in the manufacture of special cements like the calcium suphoaluminoferrite type have been experimentally carried out at a pilot scale. Blended cement formulations with maximized incorporation of steel slag have been prepared and studied. Based on available literature and experimental findings, an attempt has been made to look at the potential scenario of steel slag usage in cement-making with specific emphasis on environmental amelioration and greenhouse gas reduction.
在钢铁生产中,会产生两种不同类型的渣——一种是提铁时获得的高炉渣,另一种是炼钢车间铁炼钢过程中产生的钢渣。高炉矿渣经适当造粒后,广泛用作水泥和混凝土工业的补充胶凝材料。然而,钢渣没有多大的用途,大多是在废钢除去后作为废料倾倒。为了探索该矿渣在水泥生产中的经济利用途径,进行了大量的文献和专利调查。此外,以印度一些综合钢铁厂提供的钢渣为基础,对该材料进行了详细的表征,并研究了其水力性能。在生产波特兰水泥熟料以及生产超铝铁酸钙等特种水泥方面,已经进行了有关该矿渣作为原料的潜在用途的试验。制备并研究了钢渣掺量最大的水泥混合配方。根据现有文献和实验结果,已经尝试研究钢渣在水泥制造中的潜在使用情况,特别强调改善环境和减少温室气体。
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引用次数: 2
German Cement Industry’s Voluntary Efforts on the Issue of Climate Change-A Success Story 德国水泥行业在气候变化问题上的自愿努力——一个成功的故事
V. Hoenig, M. Schneider
In 1995 the German cement industry committed itself to a 20% reduction in its specific fuel energy consumption between 1987 and 2005. In 2000, this commitment has been adapted to the international agreements, particularly to the Kyoto Protocol. Now the voluntary agreement includes a reduction of the specific energy-related carbon dioxide emissions from 1990 to 2008/12 by 28%. As the burning and grinding facilities have been widely optimized during the past years, the German cement industry is planning to increase the substitution of fossil fuels by waste fuels and to promote the marketing of blended cements. From 1987 to 1999 the German cement industry's efforts have led to a reduction of the energy related carbon dioxide emissions by 3.6 million tons per year. The share of waste fuels has been increased from 4 to 23% and the clinker portion in cement has been decreased from 86 to 80.6% by using more granulated blast-furnace slag and unburned limestone as the main constituents in cement. To what extent other instrument like emission trading, joint implementation or clean development mechanism can be used in the future to achieve further reductions, will depend on mutual arrangements and implementation by the international community.
1995年,德国水泥工业承诺在1987年至2005年期间减少20%的特定燃料能源消耗。2000年,这一承诺已适应国际协议,特别是《京都议定书》。现在,自愿协议包括从1990年到2008/12年减少28%的特定能源相关的二氧化碳排放量。随着燃烧和研磨设施在过去几年中得到广泛优化,德国水泥工业正计划增加废燃料对化石燃料的替代,并促进混合水泥的销售。从1987年到1999年,德国水泥工业的努力使每年与能源有关的二氧化碳排放量减少了360万吨。通过在水泥中更多地使用颗粒化的高炉矿渣和未燃烧的石灰石作为主要成分,废燃料的比重从4%提高到23%,水泥中的熟料比例从86%降低到80.6%。未来在多大程度上可以利用排放交易、联合执行或清洁发展机制等其他工具来实现进一步减排,将取决于国际社会的相互安排和执行。
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引用次数: 1
Performance of High-Grade Concrete with Full Substitution of Aggregates by Recycled Concrete 再生混凝土完全替代骨料的高档混凝土性能研究
U. Meinhold, G. Mellmann, M. Maultzsch
On the background of the need for reuse of building rubble and the saving of natural resources, a European Union research project was performed covering concrete technology and durability aspects. A very special precondition was the use of large-scale processed building rubble with unknown origin and the total replacement of aggregates above 2 mm. Comprehensive tests were carried out on the properties of the starting material from different processing plants and fresh concrete, particularly the interdependence of water addition and workability. Investigations on hardened concrete properties included strength development, creep and shrinkage, modulus of elasticity, capillary absorption, freezing and thawing resistance, and carbonation behavior over a long period. The results demonstrate that the industrial production of a high-grade, durable concrete is possible. The project is a promising contribution for sustainable development.
在需要重新利用建筑瓦砾和节约自然资源的背景下,进行了一个欧洲联盟研究项目,涉及混凝土技术和耐久性方面。一个非常特殊的先决条件是使用来历不明的大规模加工过的建筑碎石,并完全替换2毫米以上的集料。对不同加工厂的原料和新拌混凝土的性能进行了综合试验,特别是对加水与和易性的相互关系进行了研究。对硬化混凝土性能的研究包括强度发展、徐变和收缩、弹性模量、毛细吸收、抗冻融性和长时间的碳化行为。结果表明,工业化生产高档、耐用的混凝土是可能的。该项目对可持续发展作出了有希望的贡献。
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引用次数: 26
High Volume Fly Ash RCC for Dams/Mixture Optimization and Mechanical Properties 大坝用大体积粉煤灰碾压混凝土/混合料优化及力学性能
O. Lahus, S. Jacobsen
A series of roller-compacted concrete mixtures were developed for the Norwegian Skjerka hydropower project. The mixture optimization was based on the medium paste concept of the international Committee on Large Dams (ICOLD) using crushed aggregate from the dam site. The mixture optimization consists of a two-step procedure minimizing the paste content, keeping the compacted density about 97.5% of the theoretical air-free density, and giving an optimal loaded Vebe time of 10 - 20 seconds. Nine mixtures were produced using low calcium fly ash and portland cement with various fly ash-cement proportions. The water-binder ratio was kept constant at 0.53 according to the Norwegian code for mass concrete for dams. The laboratory test results showed that 8 of 9 binder combinations produced RCC within the design criteria. The compressive strength development of the water-cured specimens was impressive despite the rather low cement contents, giving 1 year strengths of 2 times the 28-day strengths. The use of high-volume fly ash concrete for RCC dams is one example of concrete in harmony with lower environmental impact and less use of resources.
为挪威Skjerka水电项目开发了一系列碾压混凝土混合物。混合料优化是基于国际大型水坝委员会(ICOLD)的中浆体概念,使用来自坝址的碎骨料。混合物优化包括两个步骤,最大限度地减少膏体含量,保持压实密度约为理论无空气密度的97.5%,并给出最佳加载Vebe时间为10 - 20秒。采用不同粉煤灰-水泥比例的低钙粉煤灰和波特兰水泥配制了9种混合料。根据挪威大坝大体积混凝土规范,水胶比保持恒定在0.53。实验室试验结果表明,9种粘结剂组合中有8种产生的碾压混凝土符合设计标准。水固化试件的抗压强度发展令人印象深刻,尽管水泥含量相当低,1年强度是28天强度的2倍。在碾压混凝土大坝中使用高容量粉煤灰混凝土是混凝土与低环境影响和减少资源使用相协调的一个例子。
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引用次数: 2
期刊
SP-202: Third Canmet/ACI International Symposium: Sustainable Development of Cement and Concrete
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