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BIODIESEL PRODUCTION FROM MICROWAVE IRRADIATED REACTOR USING HOMOGENEOUS AND HETEROGENEOUS CATALYSIS 均相和多相催化微波反应器制备生物柴油
Pub Date : 2018-06-30 DOI: 10.5380/RETERM.V17I1.62254
S. Rabelo, L. S. Oliveira, A. S. Franca
Biodiesel was successful produced in a microwave irradiation reactor using homogeneous and heterogeneous catalysis. The biodiesel was production by the trasesterification reaction of soybean oil using metanol. Sodium methylate (30% solution in metanol) was used for the homogeneous catalyst and the heterogeneous catalyst was developed using wasted eggshells. The eggshells were calcined and tested pure and doped with potassium hydroxide in 10, 30 and 50% of weight. The power and temperature of the microwave were kept constant in every reaction being 800W and 200º Celsius, respectively. The reaction time was significantly reduced using microwave compared to the conventional process. In only one minute of reaction, the methyl ester (FAME) conversion obtained was 98.9% with the homogeneous catalyst and within 15 minutes, the heterogeneous catalysis accomplished 100%. For heterogeneous catalyst, the best results were acquired when the doped catalyst contained 50% of KOH. The results indicated that the eggshells treated with KOH has a great potential to be used for microwave-assisted transesterification reactions of oils with mild operations conditions: molar ratio oil/alcochol 1:6 and just 5% of catalyst. In addition, the heterogenous catalyst was recovered and reused in other reactions with a relatively satisfying results. The physico-chemical properties of the catalysts were characterized by X-ray diffraction and thermogravimectric analysis.
采用均相和多相催化技术在微波辐照反应器中成功制备了生物柴油。以大豆油为原料,以甲醇为原料进行酯交换反应制备生物柴油。采用甲基化钠(30%甲醇溶液)制备均相催化剂,利用废蛋壳制备多相催化剂。这些蛋壳经过煅烧,并在重量的10%、30%和50%的情况下加入氢氧化钾进行纯度测试。每次反应均保持微波功率800W,温度200℃不变。与传统工艺相比,微波处理显著缩短了反应时间。在1分钟的反应时间内,均相催化剂的甲酯转化率达到98.9%,在15分钟内,非均相催化剂的甲酯转化率达到100%。对于非均相催化剂,KOH掺杂量为50%时效果最好。结果表明,经KOH处理的蛋壳在油醇摩尔比为1:6、催化剂用量为5%的条件下,具有很大的应用前景。此外,该多相催化剂被回收再利用,并在其他反应中取得了较为满意的效果。用x射线衍射和热重分析对催化剂的理化性质进行了表征。
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引用次数: 0
EXPERIMENTAL ANALYSIS OF A SCREEN-COVERED GROOVE HEAT PIPE 屏蔽槽热管的实验分析
Pub Date : 2018-06-30 DOI: 10.26678/ABCM.COBEM2017.COB17-0780
L. Krambeck, P. H. Santos, T. A. Alves
In this research, a heat pipe with screen-covered groove capillary structure was experimentally analyzed. The heat pipe was manufactured from a copper tube with the external diameter of 9.45mm, inner diameter of      6.20mm, and a total length of 200mm. A Wire Electrical Discharge Machining, or Wire-EDM, was used to manufacture axial microgrooves in the heat pipe. A layer of phosphor bronze mesh #100 completed the capillary structure. Distilled water was the working fluid and the loading filling ratio was 60% of the evaporator volume. The condenser was cooled by air forced convection, the adiabatic section was insulated with fiberglass, and the evaporator was heated by an electrical resistor and it was insulated from the environment with aeronautic insulation. The heat pipe was tested in horizontal position, under different heat loads varying from 5 up to 30W. The experimental results showed that the screen-covered groove worked satisfactorily as a capillary structure.
本文对一种具有筛盖槽毛细管结构的热管进行了实验分析。热管材料为铜管,外径9.45mm,内径6.20mm,总长度200mm。采用线材放电加工(Wire- edm)加工热管轴向微槽。一层磷青铜网#100完成了毛细管结构。蒸馏水为工作液,装填比为蒸发器体积的60%。冷凝器采用空气强制对流冷却,绝热部分采用玻璃纤维隔热,蒸发器采用电阻器加热,并采用航空隔热与环境绝缘。在水平位置对热管进行测试,热负荷从5到30W不等。实验结果表明,筛盖槽作为一种毛细管结构工作满意。
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引用次数: 1
THERMODYNAMIC ANALYSIS OF ELECTRIC POWER PRODUCTION TECHNOLOGIES IN COGENERATION SYSTEMS ON FPSO AIMING TO REDUCE CO2 EMISSIONS 以减少二氧化碳排放为目标的浮式储油船热电联产系统发电技术的热力学分析
Pub Date : 1900-01-01 DOI: 10.26678/abcm.encit2020.cit20-0098
A. Gallego, Augusto Cesar Clemente de Souza, P. H. Morais, Marcelo Modesto
Oil platforms are complex structures used to host workers and equipmentneeded in offshore exploration. This study focuses on the platform's heatand electricity cogeneration plant, which supplies a process heat exchangersnet, and provides the necessary electricity for all the equipment used for theprocess and worker's accommodation in the platform. The platform demandwith maximum load is 75 MW, which could be achieved using four gasturbines (25 MW each), one of which is kept for backup purposes or usingsix dual-fuel engines diesel/natural gas (15 MW each), one of which is alsokept for backup purposes. Therefore, the thermodynamic analysis wasperformed - considering five specific demand points of the platform -comparing the two traditional configurations (gas turbines and dual-fuelengines diesel/natural gas) and a combined configuration. The combinedconfiguration is composed of three gas turbines and two dual-fuel enginesdiesel/natural gas (one of the gas turbines kept for backup purposes). Theconfigurations presented respectively 35.5%, 48.4% and 42.6% at highestoverall efficiency; 611.34 g/kWh, 373.45 g/kWh, 472.74 g/kWh at lowestCO2 emissions considering full attendance of electrical and thermaldemands. The configurations using only gas turbines and the combinedfully attended the thermal demand of the platform without using auxiliarypieces of equipment. Therefore, it was possible to observe that thecombined configuration presented several advantages concerning isolatedsystems, proving to be an excellent option for sustainable energygeneration, reducing emissions of polluting gases and greater flexibility ofits operation concerning to configuration only with turbines, and physicaloccupation in relation to configuration only with engines.
石油平台是一种复杂的结构,用于容纳海上勘探所需的工人和设备。本研究的重点是该平台的热电联产装置,该装置提供一个过程热交换网络,并为该过程使用的所有设备和工人在平台上的住宿提供必要的电力。该平台的最大负载需求为75兆瓦,可以使用4台燃气轮机(每台25兆瓦)来实现,其中一台用于备用目的,或者使用6台柴油/天然气双燃料发动机(每台15兆瓦),其中一台也用于备用目的。因此,考虑到平台的五个特定需求点,进行了热力学分析,比较了两种传统配置(燃气轮机和双燃料发动机柴油/天然气)和组合配置。组合配置由三个燃气轮机和两个双燃料发动机组成,柴油/天然气(其中一个燃气轮机用于备用目的)。总效率最高的构型分别为35.5%、48.4%和42.6%;考虑到电力和热力需求,最低二氧化碳排放量分别为611.34 g/kWh、373.45 g/kWh和472.74 g/kWh。仅使用燃气轮机和燃气轮机组合的配置在不使用辅助设备的情况下满足了平台的热需求。因此,可以观察到,与孤立系统相比,组合配置呈现出几个优势,证明是可持续能源发电的绝佳选择,减少了污染气体的排放,并且仅与涡轮机配置有关的操作灵活性更大,与仅与发动机配置有关的物理占用。
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引用次数: 0
THERMAL ANALYSIS OF DIFFERENT CONFIGURATIONS FOR BUILDING INSULATION SYSTEMS WITH ACTUAL MATERIALS USING REAL SOLAR RADIATION AND TEMPERATURE DATA 利用真实太阳辐射和温度数据对实际材料建筑保温系统的不同配置进行热分析
Pub Date : 1900-01-01 DOI: 10.26678/abcm.encit2020.cit20-0574
Carlos A. Sá, M. Curi
Thermal insulation is present in several engineering areas, such as in civilconstruction, in industrial ovens, in satellites and launch vehicles and even indomestic applications, such as refrigerators. This work aims to presentmultilayer insulation for civil construction, thus reducing electrical energyexpenditure on air conditioning the environment and increasing thermalcomfort. To determine the heat flow through the wall, it was necessary tosolve the heat diffusion equation in rectangular Cartesian coordinates for eachinsulation layer, and the boundary conditions of each differential equationdepend on the neighboring layers, thus forming a system of equations. TheWolfram Mathematica computational software was used to solve themathematical equations. The heat flow was determined for the four seasonsof the year throughout the day for different configurations of thermalinsulation, varying the insulating material and its thickness. After analyzingthe results, it was possible to observe the great efficiency of the models withthermal insulation compared to traditional walls, making the internal wall'stemperature profile more constant throughout the day.
隔热存在于几个工程领域,如民用建筑、工业烤箱、卫星和运载火箭,甚至在家庭应用中,如冰箱。本工作旨在为民用建筑提供多层隔热材料,从而减少空调环境的电能消耗,提高热舒适性。为了确定墙体的热流,需要求解每一层保温层的直角坐标下的热扩散方程,而每一个微分方程的边界条件依赖于相邻层,从而形成一个方程组。使用wolfram Mathematica计算软件求解数学方程。在不同的保温材料配置、不同的保温材料及其厚度下,确定了一年中的四个季节全天的热流。在分析结果之后,可以观察到与传统墙壁相比,隔热模型的效率很高,使内墙的温度剖面在一天中更加恒定。
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引用次数: 0
PREMATURE SHUT OFF POSSIBILITY PREDICTION FOR AUTOMOTIVE FUEL TANK SYSTEM 汽车油箱系统过早关闭可能性预测
Pub Date : 1900-01-01 DOI: 10.26678/abcm.encit2020.cit20-0583
F. Maruyama, K. Burr
Prediction of the possibility of a vehicle fuel tank supply process prematureshut off is of main concern for the automotive industry. The main objectiveof this work is to show that premature shut off can be explained by the absenceof a steady state after the initial transient in the fuel supply process. Thevehicle fuel tank considered in this work is composed only of a rectilinearpipe inclined with respect to the horizontal and connected to the top of arectangular tank. The counter-current two-phase flow in the pipe is modeledusing the one-dimensional drift flux model and the tankis modeled as a control volume where mass conservation for each phase isconsidered. Linear stability analysis of the two-phase flow model shows theabsence of the steady state phase for a range of liquid flow rates before theflooding condition is achieved as a function of tube inclination and length.This fact suggests that premature shut off occurs due to the absence of asteady state regime phase during the fuel supply process.
预测汽车油箱供应过程过早关闭的可能性是汽车工业关注的主要问题。这项工作的主要目的是表明过早关闭可以解释为燃料供应过程中初始瞬态后缺乏稳态。本工作中所考虑的汽车油箱仅由一根相对于水平方向倾斜并连接到矩形油箱顶部的直线管组成。采用一维漂移通量模型对管道中的逆流两相流进行建模,并将储罐建模为控制体积,其中考虑了每一相的质量守恒。两相流模型的线性稳定性分析表明,在达到驱油条件之前,液体流速范围内没有稳态相,这是管道倾角和长度的函数。这一事实表明,过早关闭是由于在燃料供应过程中缺乏稳态状态阶段造成的。
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引用次数: 0
Thermoeconomic Simulation of Cascaded and Integrated Vapor Compression-Absorption Refrigeration Systems 级联式和集成蒸汽压缩-吸收式制冷系统的热经济模拟
Pub Date : 1900-01-01 DOI: 10.5380/RETERM.V20I1.80463
F. Carvalho, P. E. Barbieri
The present work is composed by a comparative thermoeconomic analysisbetween two refrigeration systems: Vapor Compression CascadeRefrigeration System (VCCRS) and Integrated Refrigeration System byAbsorption and Vapor Compression (VCACRS). The thermoeconomicanalysis compares the systems under energy, exergy, economic andenvironmental aspects. The development of mathematical models for each ofthe systems is performed through the EES (Engineering Equation Solver)program. The optimized functions are exergy destruction and total cost rate(sum of cost rates of investment, operation, maintenance and enviromental)by minimizing these functions. The optimization method used is theweighted sum of the objectives, this can be achieved by assigning differentweights for each goal, then a new function that represents the linearrelationship between all the objectives is found. In present case the twoobjective functions are exergy destruction and total cost rate. Inmultiobjective optimization, the process of choosing among optimizedsolutions involves the definition of an equilibrium point, also called theideal point. In order to achieve a real solution of the minimum values ofthe described functions simultaneously one must determine which is thesmallest distance from the ideal point to the curve that defines theoptimized solutions. In the study the economical advantage of VCCRS inrelation to VCACRS was demonstrated. VCACRS has a cost 10.26% lowerthan VCCRS while VCCRS has a better exergetic efficiency, with itsdestruction of exergy 38.46% lower than VCACRS.
本文对蒸汽压缩级联制冷系统(VCCRS)和吸收-蒸汽压缩综合制冷系统(VCACRS)两种制冷系统进行了热经济学比较分析。热经济学分析从能源、能源、经济和环境等方面对系统进行了比较。每个系统的数学模型的开发是通过EES(工程方程求解器)程序执行的。通过最小化这些函数,优化的函数是火用破坏和总成本率(投资、运行、维护和环境成本率的总和)。所使用的优化方法是目标的加权和,这可以通过为每个目标分配不同的权重来实现,然后找到一个表示所有目标之间线性关系的新函数。在本例中,两个目标函数是能量破坏和总成本率。在多目标优化中,从最优解中进行选择的过程涉及到平衡点的定义,也称为理想点。为了同时获得所描述函数的最小值的实解,必须确定从理想点到定义优化解的曲线的最小距离。通过与VCACRS的比较,论证了VCCRS的经济优势。VCACRS的成本比VCCRS低10.26%,而VCCRS的火用效率更高,其火用破坏比VCACRS低38.46%。
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引用次数: 0
INFLUENCE OF THERMOPLASTIC PROCESSING PARAMETERS ON THEIR INTERNAL TEMPERATURE 热塑性塑料加工参数对其内部温度的影响
Pub Date : 1900-01-01 DOI: 10.5380/reterm.v20i3.83263
F. A. R. Campos, L. D. da Silva
With technological advances, polymers are increasingly used to manufacture various components that were previously exclusively manufactured with metals. One of the significant challenges in polymer processing is its relatively low thermal resistance, since relatively small temperature variations, especially when compared to metals and ceramics, lead to significant changes in material properties and in the final component geometry. This paper investigated how the internal temperature of polymers, subjected to an intermittent particulate jet deposition process in conjunction with a continuous flow of hot air, is affected by variation in surface roughness, polymer type, and air pressure. As the main result, low efficiency in heat transfer was caused by the combination of the convective nature of the heat exchange with the low thermal conductivity of the polymers. The variables with the most significant influence on the process were the intermittence and pressure of the particulate jet.
随着技术的进步,聚合物越来越多地用于制造以前仅用金属制造的各种部件。聚合物加工中的一个重大挑战是其相对较低的热阻,因为相对较小的温度变化,特别是与金属和陶瓷相比,会导致材料性能和最终组件几何形状的显着变化。本文研究了聚合物的内部温度如何受到间歇颗粒喷射沉积过程和连续热空气流的影响,表面粗糙度、聚合物类型和空气压力的变化。作为主要结果,传热效率低是由热交换的对流性质与聚合物的低导热性相结合造成的。对该过程影响最大的变量是颗粒射流的间歇和压力。
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引用次数: 0
FLAT PLATE PULSATING HEAT PIPES WITH DIFFERENT CHANNEL GEOMETRIES FOR HIGH HEAT FLUX APPLICATIONS 具有不同通道几何形状的高热流应用的平板脉动热管
Pub Date : 1900-01-01 DOI: 10.26678/abcm.encit2020.cit20-0579
L. Krambeck, K. G. Domiciano, L. Betancur-Arboleda, M. Mantelli
The thermal performance of flat plate pulsating heat pipes with differentchannel geometries was performed in this experimental work. The testswere accomplished with two channel profiles, round and grooved. One ofthe channel geometries, located on the evaporator, can be considered novel,consisting of a round channel with two lateral grooves. Diffusion bondingtechnology was used to manufacture the PHPs made of two copper flatplates. Distilled water was used as the working fluid with a filling ratio of50% (17.9 ml) of the total volume. The pulsating heat pipes were tested atone position (vertical) under heat loads from 20 up to 2000 W. Theexperimental results showed that both flat plate pulsating heat pipesoperates successfully for high heat fluxes. The lateral grooves reduced thethermal resistance, being principally efficient in lower loads. Besides that,the novel channel considerably anticipated the operation startup. Therefore,a much better performance was obtained by the grooved channel PHP,which was constructed from a simple, low cost modification of thefabrication process.
实验研究了不同通道几何形状的平板脉动热管的热性能。测试采用了两种通道,圆通道和槽通道。位于蒸发器上的通道几何形状之一可以被认为是新颖的,它由一个圆形通道和两个横向凹槽组成。采用扩散连接技术制备了由两块铜平板组成的PHPs。工作液为蒸馏水,灌装比例为总容积的50% (17.9 ml)。对脉动热管在20 ~ 2000 W的热负荷下进行了纵向测试。实验结果表明,两种平板脉动热管均能在高热流密度下成功运行。横向凹槽减少了热阻,主要是在低负荷下有效。此外,该新通道对运营启动有较大的预见性。因此,通过对制造工艺进行简单、低成本的修改,获得了更好的性能。
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引用次数: 0
ENERGY RECOVERY FROM MUNICIPAL SOLID WASTE: OPPORTUNITIES AND CHALLENGES IN THE BRAZILIAN SCENARIO 城市固体废物的能源回收:巴西情景中的机遇与挑战
Pub Date : 1900-01-01 DOI: 10.5380/reterm.v20i3.83266
Y. L. Pilissão, A. G. Machado, E. Virmond, E. S. Watzko
Municipal solid waste has always been an undesirable asset in society, and its generation grows every year. Inadequate waste disposal may cause many problems, either by the contamination of the environment or by its capacity to serve as a vector for a series of pathogenic elements. The COVID-19 pandemic drew the world’s attention to these challenges and made it clear how they impact society in an unprecedented way. The higher amount of waste and safety supplies discarded, such as masks and facial shields, require an analysis of the current situation of solid waste management along with solutions to increase the capacity for resource recovery. Methods of treating, collecting, transporting, and disposing of municipal solid waste must be integrated with the other levels of the waste hierarchy (prevention, reuse and preparing for reuse, recycling, other recovery (including energy recovery), and disposal). The scientific literature on this subject was verified in this paper, serving as a subsidy for the implementation of possible processes to be used in companies in the area of basic sanitation and city halls, which can benefit from investments that will incur in the generation of products of added value, creating a new link in its business chain. The production and application of integrated municipal solid waste management systems, including energy recovery from refuse derived fuel, can reduce the volume and expenses of municipal administrations with inadequate waste disposal in landfills and promote more sustainable practices in the circular economy scenario. Therefore, this paper sought to highlight the main activities related to municipal solid waste management with an aim to energy recovery.
城市生活垃圾一直是社会的不良资产,其产生量每年都在增长。废物处理不当可能造成许多问题,或污染环境,或使其成为一系列致病因素的媒介。2019冠状病毒病大流行引起了全世界对这些挑战的关注,并清楚地表明它们如何以前所未有的方式影响社会。由于丢弃的废物和安全用品(如口罩和面罩)数量较多,需要对固体废物管理的现状进行分析,并提出提高资源回收能力的解决办法。处理、收集、运输和处置城市固体废物的方法必须与废物层次的其他层次(预防、再利用和准备再利用、循环利用、其他回收(包括能源回收)和处置)相结合。关于这一主题的科学文献在本文中得到了验证,作为对实施可能在基本卫生和市政厅领域的公司使用的过程的补贴,这些公司可以从产生附加价值产品的投资中受益,从而在其业务链中创建新的环节。综合城市固体废物管理系统的生产和应用,包括从垃圾衍生燃料中回收能源,可以减少在垃圾填埋场处理废物不足的市政当局的数量和费用,并在循环经济方案中促进更可持续的做法。因此,本文旨在强调与城市固体废物管理有关的主要活动,以实现能源回收。
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引用次数: 1
DEVELOPMENT OF OFF-DESIGN TURBOCHARGER MODELLING COMBINED WITH 1-D ENGINE MODEL 结合发动机一维模型的非设计涡轮增压器建模研究
Pub Date : 1900-01-01 DOI: 10.26678/abcm.encit2020.cit20-0620
A. Chun, C. Cunha, J. Donatelli, J. J. Santos, C. Zabeu
The present work aims to carry out an off-design turbocharger modellingpowered by exhaust gases from a Wärtsilä 20V34SG engine. First of all, 1-D engine model was already developed in GT-Power software whileconsidering a thermodynamic turbocharger modelling with constantisentropic efficiencies. Secondly, by using the results from 1-D enginemodel, the off-design turbocharger modelling is calibrated separately inEES software, taking into account compressible assumption, trianglevelocities and geometric dimensions. The case study is derived from a R&Dproject (ANEEL PD-06483-0318/2018) that targets to cool and dehumidifythe intake air at compressor’s upstream through a cooling coil, therebyallowing engine’s operation at reduced knocking conditions. The brakemean effective pressure (BMEP) is varied in the range of 20 to 23.45 bar,corresponding to brake power from 8.7 to 10.2 MW, respectively. With theoff-design turbocharger modelling it is possible to analyze its operationalbehavior under higher BMEP, hence, allowing to predict some importantparameters. The results showed that the turbocharger is operating within themanufacturer’s limit for BMEP of 23.45 bar, presenting total-to-staticisentropic efficiencies of 0.81 and 0.784 for compressor and turbine,respectively, rotational speed around 28135 RPM, pressure ratio atcompressor of 4.567 and maintaining control on waste-gate valve.
目前的工作旨在开展一个非设计涡轮增压器模型,该模型由Wärtsilä 20V34SG发动机的废气驱动。首先,在GT-Power软件中已经建立了一维发动机模型,同时考虑了恒定熵效率的热力学涡轮增压器模型。其次,利用一维发动机模型的结果,在考虑可压缩假设、三角水平和几何尺寸的情况下,对非设计涡轮增压器模型分别进行了ines软件标定。该案例研究来源于一个研发项目(ANEEL PD-06483-0318/2018),该项目旨在通过冷却盘管对压缩机上游的进气进行冷却和除湿,从而使发动机在减少爆震的条件下运行。制动有效压力(BMEP)在20 ~ 23.45 bar之间变化,对应的制动功率分别为8.7 ~ 10.2 MW。通过非设计涡轮增压器建模,可以分析其在更高BMEP下的运行行为,从而可以预测一些重要参数。结果表明,涡轮增压器运行在制造商限定的BMEP 23.45 bar范围内,压气机和涡轮的总静态等熵效率分别为0.81和0.784,转速约为28135 RPM,压气机压比为4.567,并保持对废物闸阀的控制。
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引用次数: 2
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Revista de Engenharia Térmica
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