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Novel Non-Aromatic Non-Ionic Surfactants to Target Deep Carbonate Stimulation 新型非芳香族非离子表面活性剂用于深部碳酸盐岩增产
Pub Date : 2019-03-29 DOI: 10.2118/193596-MS
Khatere Sokhanvarian, C. Stanciu, Jorge Fernandez, A. Ibrahim, H. Nasr-El-Din
Matrix acidizing is used for permeability and productivity enhancement purposes in oil and gas wells. Hydrochloric acid has been always a first choice due to so many advantages that it can offer. However, HCl in high pressure/high-temperature (HP/HT) wells is a concern because of its high reactivity resulting in face dissolution, high corrosion rates, and high corrosion inhibition costs. There are several alternatives to HCl, among them emulsified acid is a favorable choice due to inherent corrosion inhibition, deeper penetration into the reservoir, less asphaltene/sludge problems, and better acid distribution due to its higher viscosity. Furthermore, the success of the latter system is dependent upon the stability of the emulsion especially at high temperatures. The emulsified acid must be stable until it is properly placed and it also should be compatible with other additives in an acidizing package. This study presents the development of a stable emulsified acid at 300°F through investigating some novel aliphatic non-ionic surfactants. This paper introduces new non-aromatic non-ionic surfactant to form an emulsified acid for HP/HT wells where the conventional acidizing systems face some shortcomings. The type and quality of the emulsified acid was assessed through conductivity measurements and drop test. Thermal stability of the system was monitored as a function of time through the use of pressure tubes and a preheated oil bath at 300°F. Lumisizer and Turbiscan were used to determine the stability and average particle size of the emulsion, respectively. The viscosity of the emulsified acid was measured at different temperatures up to 200°F as a function of shear rates (0.1-1000 s-1). The microscopy study was used to examine the shape and distribution of acid droplets in diesel. Coreflood studies at low and high flow rates were conducted to determine the performance of the newly developed stable emulsified acid in creating wormholes. Inductively Coupled Plasma (ICP) and Computed Tomography (CT) scan were used to determine dissolved cations and wormhole propagation, respectively. Superior stimulation results with low pore volume of acid to breakthrough were achieved at 300°F with the newly developed emulsified acid system. The wormhole propagation was narrow and dominant compared to branch wormholes resulted from some of the treatments using conventional emulsified acid systems. The results showed that a non-ionic surfactant with a right chemistry such as suitable hydrophobe chain length and structure can form a stable emulsified acid. This study will assist in creating a stable emulsified acid system through introducing the new and effective aliphatic non-ionic surfactants, which lead to deeper penetration of acid with low pore volume to breakthrough. This new emulsified acid system efficiently stimulates HP/HT carbonate reservoirs.
基质酸化用于提高油气井的渗透率和产能。盐酸一直是首选,因为它可以提供这么多的优点。然而,HCl在高压/高温(HP/HT)井中的应用是一个值得关注的问题,因为它的高反应性导致了表面溶解、高腐蚀速率和高缓蚀成本。HCl有几种替代品,其中乳化酸是一个不错的选择,因为它具有固有的缓蚀性,对储层的渗透性更强,沥青质/污泥问题更少,而且由于其粘度更高,酸分布更好。此外,后一种体系的成功取决于乳液的稳定性,特别是在高温下。乳化酸在被适当放置之前必须是稳定的,并且它还应该与酸化包装中的其他添加剂兼容。本研究通过对一些新型脂肪族非离子表面活性剂的研究,提出了在300°F下稳定乳化酸的发展。本文介绍了一种新型非芳香族非离子表面活性剂,用于高温高压井的乳化酸,解决了传统酸化体系存在的不足。通过电导率测定和跌落试验来评价乳化酸的种类和质量。通过使用压力管和300°F的预热油浴来监测系统的热稳定性作为时间的函数。用发光仪和浊度仪分别测定乳化液的稳定性和平均粒径。在200°F以下的不同温度下,乳化酸的粘度随剪切速率(0.1-1000 s-1)的变化而变化。显微镜研究用于检查柴油中酸滴的形状和分布。进行了低流速和高流速下的岩心驱替研究,以确定新开发的稳定乳化酸在形成虫孔中的性能。电感耦合等离子体(ICP)和计算机断层扫描(CT)分别用于测定溶解阳离子和虫洞传播。新开发的乳化酸体系在300°F的温度下取得了较好的增产效果,酸的孔隙体积较小。与常规乳化酸体系处理的分支虫孔相比,虫孔扩展窄且占优势。结果表明,疏水链长和疏水结构等化学性质合适的非离子表面活性剂可以形成稳定的乳化酸。本研究将通过引入新型有效的脂肪族非离子表面活性剂,帮助建立稳定的乳化酸体系,从而突破低孔体积酸的深层渗透。这种新型乳化酸体系能够有效地增产高温高压碳酸盐储层。
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引用次数: 4
Novel Laser-Hydrothermal Apparatus for Nucleation and Inhibition Study of Scale Minerals at Temperatures up to 250°C 新型激光水热装置在高达250°C的温度下研究结垢矿物的成核和抑制作用
Pub Date : 2019-03-29 DOI: 10.2118/193556-MS
Guannan Deng, A. Kan, Fangfu Zhang, A. Lu, M. Tomson
In this work a new laser-hydrothermal apparatus is designed to evaluate nucleation of scale minerals at temperature up to 250°C, its reliability is proven by measuring induction time data of barite from 90°C to 250°C at various Saturation index (SI) values, with the objective that such a design would contribute to the scale-related research at extreme temperature. Background solution (e.g. 1m NaCl) in a borosilicate glass bottle was placed inside a hydrothermal reactor. GC oven was used for temperature control and a modified Nd-Fe-B magnetic stirrer under the oven was used for stirring. A PFA tubing was selected to be the part with contact with solution for corrosion control. Using a 0.5 ml sample loop in two separate 6-ways switch valves, Ba2+ and SO42-concentrated solutions were simultaneously injected into a background solution. After supersaturation was initiated, a laser beam penetrated through the sight glasses installed on the both sides of the reactor to record the turbidity change during the nucleation process. Induction time (tind) of Saturation index (SI) values from 0.34 to 1.02 was measured at temperatures from 90°C to 250°C. Data correlates well with data from previous laser test at 90°C in a regular beaker experiment. The induction time (tind), that is, how fast a supersaturated solution induces nucleation and crystal growth to form detectable turbidity, decrease with temperature at a fixed SI value. For example, tind of 93 minutes at 150°C decreases to about 2 minutes at 250°C under the the same SI value of 0.65, indicating that increasing temperature facilitates the nucleation process at certain supersaturation levels. This temperature impact can be attributed both by thermodynamics and kinectic aspects.
在这项工作中,设计了一种新的激光热液装置来评估温度高达250°C的水垢矿物的成核,通过测量90°C至250°C的重晶石在各种饱和指数(SI)值下的感应时间数据来证明其可靠性,目的是这样的设计将有助于极端温度下水垢相关的研究。本底溶液(如1m NaCl)装在硼硅酸盐玻璃瓶中,置于水热反应器内。采用气相色谱炉进行温度控制,炉下采用改进的钕铁硼磁力搅拌器进行搅拌。选择PFA管作为与溶液接触的部分进行腐蚀控制。在两个单独的6通开关阀中使用0.5 ml样品环,将Ba2+和so42浓缩溶液同时注入本底溶液中。过饱和启动后,激光束穿过安装在反应器两侧的视镜,记录成核过程中的浊度变化。在90°C ~ 250°C温度范围内测量了饱和指数(SI)值为0.34 ~ 1.02的诱导时间(tind)。数据与之前在90°C的常规烧杯实验中进行的激光测试数据具有良好的相关性。诱导时间(tind),即过饱和溶液诱导成核和晶体生长形成可检测浊度的速度,在固定SI值下随温度降低。例如,在相同SI值为0.65的情况下,150℃下93分钟的温度降低到250℃下2分钟左右,说明温度的升高有利于在一定过饱和水平下的成核过程。这种温度影响可以从热力学和动力学两个方面来解释。
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引用次数: 0
An Ounce of Prevention is Worth a Pound of Biofilm Mitigation 一盎司的预防抵得上一磅的生物膜缓解
Pub Date : 2019-03-29 DOI: 10.2118/193598-MS
Olivia Arends, B. Seymour, B. Benko, M. Elshahed, Lynn Yakoweshen, Sangeeta Ganguly-Mink
Microbial-induced problems in oil and gas incur high costs and cause severe environmental and safety concerns. Most of these problems are directly caused by surface-adhered bacteria colonies known as biofilms. Distinct populations of bacteria within a biofilm can symbiotically alter surrounding conditions that favor proliferation to the extent that leads to corrosion, plugging, and H2S souring. Biocides are antimicrobial products used to eliminate and prevent bacterial growth. The purpose of this initial study is to measure performance of biocides against anaerobic planktonic and sessile bacteria. The three anaerobic conditions tested were biocide performance against planktonic bacteria, against established biofilm, and inhibition of biofilm growth. Biocides containing two types of quaternary ammonium compounds and blends with glutaraldehyde were evaluated against sulfate reducing bacteria (SRB) and acid producing bacteria (APB) in both planktonkic and sessile forms. As expected, all of the biocides tested were effective against planktonic bacteria. Quaternary type biocides were found to be particularly effective at controlling sessile anaerobes. Surprisingly, the addition of glutaraldehyde did not appear to provide synergistic benefits and actually had a negative dilutory effect on the performance against biofilms. In all cases, dialkyl dimethyl ammonium chloride (DDAC) was the most efficient biocide in controlling all bacterial forms tested, both planktonic and sessile.
石油和天然气中微生物引起的问题不仅成本高,而且会引起严重的环境和安全问题。这些问题大多是由表面粘附的细菌菌落(称为生物膜)直接引起的。生物膜内不同的细菌种群可以共生地改变周围环境,有利于细菌的增殖,从而导致腐蚀、堵塞和H2S酸化。杀菌剂是用于消除和防止细菌生长的抗菌产品。本初步研究的目的是测量杀菌剂对厌氧浮游细菌和固定式细菌的性能。测试的三种厌氧条件是对浮游细菌的杀菌剂性能,对已建立的生物膜的杀菌剂性能和对生物膜生长的抑制作用。研究了含两种季铵化合物和戊二醛共混物的杀菌剂对硫酸盐还原菌(SRB)和产酸菌(APB)的杀灭效果。正如预期的那样,所有被测试的杀菌剂对浮游细菌都有效。第四纪杀菌剂对控制无根厌氧菌特别有效。令人惊讶的是,戊二醛的加入似乎没有提供协同效益,实际上对生物膜的性能有负稀释作用。在所有情况下,二烷基二甲基氯化铵(DDAC)是控制所有测试细菌形式(包括浮游和无根细菌)最有效的杀菌剂。
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引用次数: 0
A New Up-Scaled Wormhole Model Grounded on Experimental Results and in 2-Scale Continuum Simulations 基于实验结果和二尺度连续体模拟的新尺度虫洞模型
Pub Date : 2019-03-29 DOI: 10.2118/193616-MS
M. Schwalbert, A. Hill, D. Zhu
The optimum design of matrix acidizing treatments in carbonate reservoirs requires accurate modeling of wormhole propagation. While there are several wormhole correlation models available, most are developed based on small core scale experiments, and result in significant deviation when upscaled to field treatment design. There also exists simulation models (e.g. Two-Scale Continuum or Pore Network models). These models are not practical for field design because of the extensive computation effort involved. Large variations in the wormholing behavior are observed in laboratory experiments using different core sizes and geometries (radial flow versus linear flow). This variation is not captured in the previous models. This work proposes a new multiscale wormhole model that represents the physics of wormholing behavior in matrix acidizing of carbonates both at core and field scales. The derivation of the new semi-empirical model is formulated to represent the experimental data for different core dimensions and flow geometries, as well as field results. In core flooding experiments with different core sizes, the obtained pore volumes to breakthrough and optimal injection velocity are different for each core size. The same behavior is observed in numerical simulations using the Two-Scale Continuum model. That behavior is correctly calculated with the proposed model, which accounts for the dimensions in a function with dependence of the correlation parameters on the wormholed region scale and geometry. Upscaling procedures to linear, radial, elliptical, spherical, and ellipsoidal geometries are presented. The model's results are validated by the Two-Scale Continuum numerical simulations for both linear and radial flow and verified with experimental results with different core sizes and geometries (both linear and radial flow). We further developed the model for field application, and procedure of using the model is illustrated in the paper. The different flow geometries allow predicting the acidizing behavior in common completions, such as openhole, cased and perforated, and limited entry. The model prediction compares very well to the outcome of field cases. The new model reproduces the fractal behavior of the dominant wormhole growth above optimal injection rate, and predicts the injection pressure dependence on time as measured experimentally. The model correctly captured the physics of wormhole propagation phenomenon.
碳酸盐岩储层基质酸化处理的优化设计需要对虫孔扩展进行精确建模。虽然有几种虫孔相关模型可用,但大多数都是基于小型岩心规模实验开发的,当扩大到现场处理设计时,结果会产生显著偏差。也存在模拟模型(如双尺度连续体或孔隙网络模型)。这些模型不适合现场设计,因为涉及大量的计算工作。在使用不同岩心尺寸和几何形状(径向流动与线性流动)的实验室实验中,观察到虫孔行为的巨大变化。在以前的模型中没有捕捉到这种变化。本文提出了一种新的多尺度虫孔模型,该模型代表了岩心和现场尺度碳酸盐基质酸化过程中虫孔行为的物理特性。给出了新的半经验模型的推导公式,以表示不同岩心尺寸和流动几何形状的实验数据以及现场结果。在不同岩心尺寸的岩心驱油实验中,不同岩心尺寸获得的可突破孔隙体积和最佳注入速度不同。在采用双尺度连续体模型的数值模拟中也观察到相同的行为。该模型能够正确地计算出虫洞区域尺度和几何形状对相关参数依赖的函数的维度。升级程序线性,径向,椭圆,球形和椭球几何提出。通过双尺度连续体的线性流和径向流数值模拟,以及不同芯型尺寸和几何形状(线性流和径向流)的实验结果验证了模型的结果。在此基础上进一步发展了该模型,并对模型的使用过程进行了说明。不同的流体几何形状可以预测常见完井的酸化行为,如裸眼、套管井和射孔井以及有限进井。该模型的预测结果与现场实例的结果非常吻合。新模型再现了在最佳注入速率以上优势虫孔生长的分形行为,并预测了实验测量的注入压力随时间的依赖关系。该模型正确地描述了虫洞传播现象的物理性质。
{"title":"A New Up-Scaled Wormhole Model Grounded on Experimental Results and in 2-Scale Continuum Simulations","authors":"M. Schwalbert, A. Hill, D. Zhu","doi":"10.2118/193616-MS","DOIUrl":"https://doi.org/10.2118/193616-MS","url":null,"abstract":"\u0000 The optimum design of matrix acidizing treatments in carbonate reservoirs requires accurate modeling of wormhole propagation. While there are several wormhole correlation models available, most are developed based on small core scale experiments, and result in significant deviation when upscaled to field treatment design. There also exists simulation models (e.g. Two-Scale Continuum or Pore Network models). These models are not practical for field design because of the extensive computation effort involved. Large variations in the wormholing behavior are observed in laboratory experiments using different core sizes and geometries (radial flow versus linear flow). This variation is not captured in the previous models. This work proposes a new multiscale wormhole model that represents the physics of wormholing behavior in matrix acidizing of carbonates both at core and field scales.\u0000 The derivation of the new semi-empirical model is formulated to represent the experimental data for different core dimensions and flow geometries, as well as field results. In core flooding experiments with different core sizes, the obtained pore volumes to breakthrough and optimal injection velocity are different for each core size. The same behavior is observed in numerical simulations using the Two-Scale Continuum model. That behavior is correctly calculated with the proposed model, which accounts for the dimensions in a function with dependence of the correlation parameters on the wormholed region scale and geometry. Upscaling procedures to linear, radial, elliptical, spherical, and ellipsoidal geometries are presented.\u0000 The model's results are validated by the Two-Scale Continuum numerical simulations for both linear and radial flow and verified with experimental results with different core sizes and geometries (both linear and radial flow). We further developed the model for field application, and procedure of using the model is illustrated in the paper. The different flow geometries allow predicting the acidizing behavior in common completions, such as openhole, cased and perforated, and limited entry. The model prediction compares very well to the outcome of field cases.\u0000 The new model reproduces the fractal behavior of the dominant wormhole growth above optimal injection rate, and predicts the injection pressure dependence on time as measured experimentally. The model correctly captured the physics of wormhole propagation phenomenon.","PeriodicalId":11243,"journal":{"name":"Day 2 Tue, April 09, 2019","volume":"426 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81198009","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
Asphaltenes Risk Assessment and Mitigation – Designing Appropriate Laboratory Test Protocols 沥青质的风险评估和缓解。设计适当的实验室试验方案
Pub Date : 2019-03-29 DOI: 10.2118/193560-MS
A. R. Farrell, B. Martin, D. Frigo, G. Graham
Methods currently used to evaluate laboratory performance of asphaltenes inhibitors are non-optimal because the conditions used are so far from those prevailing in the field, leading to incorrect assessment of dose rates or even selection of chemicals that may not be beneficial at all. We present a dynamic flow test method for asphaltenes risk assessment and inhibitor qualification that uses field-representative temperature, pressure and fluid dynamics to enable successful correlation with field behaviour. This paper discusses the most commonly used laboratory test methods for asphaltenes testing and proposes a new dynamic flow method that offers a significant improvement over other widely-used techniques. Reconditioned dead crude oil is co-injected with n-heptane through a steel capillary and an inline filter. Differential pressures are recorded to monitor the extent of asphaltenes precipitation and deposition. We highlight key parameters that should be optimised to ensure that chemical performance is tested against the actual functionality required in the field and under conditions that are as representative as practicable. We present a case study describing the use of the dynamic flow test equipment to assess asphaltenes deposition risk and to qualify asphaltenes inhibitors for field application. We demonstrate that the method is able to rank chemicals for performance at inhibiting deposition under flowing conditions and at more field-representative temperature and pressure, with much lower percentages of n-heptane than required for conventional dispersancy testing. We discuss the effect of critical parameters affecting the extent of asphaltenes deposition. Fluid dynamics are recognised to play a key role in asphaltenes deposition in the field, not least, because at higher wall velocities the erosive force acting on field deposits is high enough to limit further growth and steady state can be reached. Flowing tests were conducted under a number of fluid-dynamic regimes in which asphaltenic crude oil was destabilised by addition of n-heptane. The effects of wall shear stress, wall velocity, residence time, and other factors were evaluated upon asphaltenes deposition in a steel capillary and upon bulk precipitation by subsequent filtration. The results obtained from laboratory tests correlate well with field observations and demonstrate that flow regimes in laboratory tests can approach those occurring in the field. This paper presents the development of a new laboratory test method utilising dead crude both for asphaltenes risk assessment and inhibitor qualification that offers significantly improved correlation with field behaviour over conventional dispersancy testing, yet remains much more cost effective than labour-intensive autoclave testing utilising live fluids. When considering asphaltenes risk analysis the approach also allows for deposition vs. precipitation to be examined under field realistic conditions, and we demonstrate how
目前用于评估沥青质抑制剂实验室性能的方法并不理想,因为所使用的条件与现场的普遍条件相去甚远,导致对剂量率的评估不正确,甚至可能选择根本无益的化学品。我们提出了一种用于沥青质风险评估和抑制剂鉴定的动态流动测试方法,该方法使用具有现场代表性的温度、压力和流体动力学来成功地与现场行为进行关联。本文讨论了沥青质测试中最常用的实验室测试方法,并提出了一种新的动态流动方法,该方法比其他广泛使用的技术有显著的改进。修复后的死原油通过钢毛细管和在线过滤器与正庚烷共注入。记录压差以监测沥青质沉淀和沉积的程度。我们强调了应该优化的关键参数,以确保化学性能根据现场所需的实际功能进行测试,并在尽可能具有代表性的条件下进行测试。我们提出了一个案例研究,描述了动态流动测试设备的使用,以评估沥青质沉积风险,并确定沥青质抑制剂是否适合现场应用。我们证明,该方法能够在流动条件下,在更具现场代表性的温度和压力下,对化学物质的抑制沉积性能进行排序,并且比常规分散性测试所需的正庚烷百分比要低得多。讨论了关键参数对沥青质沉积程度的影响。流体动力学被认为在沥青质的沉积中起着关键作用,尤其是因为在较高的壁速下,作用于现场沉积物的侵蚀力足够大,从而限制了进一步的生长,并可以达到稳定状态。流动试验是在一些流体动力学制度下进行的,其中沥青质原油通过添加正庚烷而不稳定。研究了壁面剪切应力、壁面速度、停留时间和其他因素对沥青质在钢毛细管中的沉积和随后过滤的大块沉淀的影响。实验室试验的结果与现场观测结果吻合良好,并表明实验室试验中的流态可以接近现场发生的流态。本文介绍了一种利用死原油进行沥青质风险评估和抑制剂鉴定的新实验室测试方法的发展,与传统的分散性测试相比,该方法显著提高了与现场行为的相关性,但仍然比使用活流体的劳动密集型高压灭菌器测试更具成本效益。在考虑沥青质风险分析时,该方法还允许在现场实际条件下检查沉积与沉淀,并且我们证明了在例如向含沥青质的原油引入气举时,这是多么重要。
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引用次数: 1
Out with the Old: Developing a New Test Methodology for Paraffin Wax Dispersion and Inhibition Testing 淘汰旧方法:开发一种新的石蜡分散和抑制试验方法
Pub Date : 2019-03-29 DOI: 10.2118/193552-MS
Amanda Miller, Rashod Smith, B. Dufresne, A. Mahmoudkhani
Traditional test methods to evaluate dispersion and inhibition of paraffin wax, which are mainly based on wax gelation and deposition, often fail to distinguish and differentiate between classes of chemistries at a reasonable resolution. Recommended products based on such lab screenings sometimes have a difficult time proving success in the field. The rush for oil production from unconventional shale plays in North America create a need for quick and elaborate testing to effectively evaluate new products for prevention and remediation of known paraffin wax issues. This paper will present a progress made in this area. For our studies a model oil system was used, which consists of field wax deposit dissolved in kerosene. Testing with a model oil allowed us to focus on the chemistries that are effective against paraffin chains known to cause issues. Several different testing conditions were used to push the ability of the chemistries to function. Light scattering was used to monitor transition from turbidity to sedimentation of paraffin wax from bulk solution under static or dynamic conditions. A total of twelve compounds from three classes of polymers and three classes of surfactants were used in treatment of these oil systems. With this new lab testing methodology, we have been able to discover new insights on the chemistries used for paraffin wax dispersion and inhibition. In contrast to methods which only measure the end point, light scattering and transmission methodology provides system details at time intervals of 30 sec or higher. The method also allowed us to differentiate chemistries based on their impact on the separation index and sedimentation rate of targeted paraffin chains under stressed conditions by forced precipitation. It was found that certain classes of chemistries are more suited for dispersion and inhibition of waxy condensates once system passed the critical point, while others fail over time. This new approach is fast and versatile and must be used as part of a suite of lab and field screenings for product development and recommendation. New methodology based on light scattering and transmission of oil systems can provide details not seen before on colloidal stability or instability of waxy crudes under stressed conditions. The method gives an even greater insight to how different chemistries function to mitigate known paraffin issues. Quantitative and reproducible data are obtained allowing faster screening of various chemistries and enhancing product development for new and aging fields.
传统的评价石蜡分散性和抑制性的测试方法主要基于蜡的凝胶化和沉积,往往不能以合理的分辨率区分和区分化学物质的类别。基于这种实验室筛选的推荐产品有时很难在现场证明成功。随着北美非常规页岩油开采热潮的兴起,需要对新产品进行快速、精细的测试,以有效评估新产品,预防和修复已知的石蜡问题。本文将介绍这方面的进展。在我们的研究中,我们使用了一个模型油系统,它由溶解在煤油中的油田蜡沉积物组成。用一种模型油进行测试,使我们能够专注于有效对抗已知引起问题的石蜡链的化学物质。使用了几种不同的测试条件来推动化学物质发挥作用的能力。采用光散射法监测石蜡在静态和动态条件下从体液中由浑浊到沉淀的转变。共使用了3类聚合物和3类表面活性剂的12种化合物来处理这些油体系。通过这种新的实验室测试方法,我们已经能够发现用于石蜡分散和抑制的化学物质的新见解。与只测量终点的方法相比,光散射和透射方法在30秒或更高的时间间隔内提供系统细节。该方法还使我们能够根据化学物质在强迫沉淀条件下对分离指数和目标石蜡链沉降速率的影响来区分化学物质。研究发现,一旦体系超过临界点,某些类别的化学物质更适合于蜡质凝聚物的分散和抑制,而其他化学物质则随着时间的推移而失效。这种新方法快速且通用,必须作为实验室和现场筛选套件的一部分,用于产品开发和推荐。基于油系统的光散射和透射的新方法可以提供以前从未见过的关于蜡质原油在应力条件下的胶体稳定性或不稳定性的细节。该方法更深入地了解了不同的化学物质是如何减轻已知石蜡问题的。获得定量和可重复的数据,可以更快地筛选各种化学物质,并加强新领域和老化领域的产品开发。
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引用次数: 3
Development of Structure-Property Relationships for Steam Foam Additives for Heavy Oil Recovery 稠油采油蒸汽泡沫助剂构效关系研究进展
Pub Date : 2019-03-29 DOI: 10.2118/193634-MS
Thu T. Nguyen, A. Raj, R. Rommerskirchen, Jorge Fernandez
Low steam viscosity during steam injection can cause steam override and channeling issues for heavy oil recovery, resulting in high operating cost and low oil recovery. One of the common methods to increase the viscosity of steam is by co-injecting surfactants that generate stable foams with steam. The objective of this research is to develop structure-property relationships for surfactants in order to identify surfactant candidates as the steam foam additives for heavy oil recovery. In this study, alkyl propoxy ethoxy ether carboxylate (alkyl PO EO ECA) surfactants were evaluated. Surfactant solutions at 1 wt% prepared in 1 wt% NaCl were aged at up to 250 °C in Parr reactors for up to 2 weeks. The degradation of the surfactants was quantified based on High Performance Liquid Chromatography profiles of the surfactants before and after the aging process. The foaming performance of the surfactants was evaluated at 1 wt% concentration at varied temperatures from 100 to 250 °C in a high temperature high pressure visual cell. Sand-packed columns were performed to evaluate the ability of the surfactant to increase the apparent viscosity of steam. The results showed that alkyl PO EO ECA surfactants exhibit excellent chemical stability at up to 250 °C. However, the chemical stability of these surfactants are dependent on the hydrophobe structure as well as the numbers of PO and EO units of the surfactants. Among the studied surfactants, only ECA surfactants with specific structures were able to generate stable foam at 250 °C. It was found that the ECA surfactants with both PO and EO units and a long branched hydrophobe demonstrated to be excellent foaming agents that were able to increase the apparent viscosity of steam by three orders of magnitude at 250 °C in sand-pack columns. In the presence of bitumen, these surfactants were able to increase the steam apparent viscosity by two orders of magnitude. This increase in the steam apparent viscosity is sufficient to overcome the steam override and channeling during steam injection. Past research has randomly identified some sulfonate and ether carboxylate surfactants as foaming agents for steam EOR processes. This work, however, evaluated these surfactants systematically in order to develop the structure-property relationships that can be used to optimize surfactants as steam foaming agents for thermal EOR processes at up to 250 °C.
注汽过程中的低蒸汽粘度会导致稠油开采过程中的蒸汽覆盖和窜流问题,导致作业成本高,采收率低。增加蒸汽粘度的常用方法之一是通过与蒸汽共同注入表面活性剂来产生稳定的泡沫。本研究的目的是建立表面活性剂的结构-性能关系,以确定表面活性剂作为稠油开采蒸汽泡沫添加剂的候选表面活性剂。对烷基丙氧基乙氧基醚羧酸酯(烷基PO EO ECA)表面活性剂进行了评价。在1wt %的NaCl中制备1wt %的表面活性剂溶液,在Parr反应器中在高达250°C的温度下时效长达2周。利用高效液相色谱法测定老化前后表面活性剂的降解情况。在100 ~ 250℃的高温高压视觉池中,以1 wt%的浓度评价表面活性剂的发泡性能。用砂填充柱来评价表面活性剂提高蒸汽表观粘度的能力。结果表明,烷基PO EO ECA表面活性剂在高达250℃的温度下具有优异的化学稳定性。然而,这些表面活性剂的化学稳定性取决于疏水结构以及表面活性剂的PO和EO单元的数量。在所研究的表面活性剂中,只有具有特定结构的ECA表面活性剂能够在250℃下产生稳定的泡沫。研究发现,同时具有PO和EO单元和长支疏水剂的ECA表面活性剂是优异的发泡剂,能够在250°C的砂填料柱中将蒸汽的表观粘度提高三个数量级。在沥青存在的情况下,这些表面活性剂能够将蒸汽表观粘度提高两个数量级。蒸汽表观粘度的增加足以克服注汽过程中的蒸汽覆盖和窜流问题。过去的研究随机确定了一些磺酸盐和醚羧酸盐表面活性剂作为蒸汽提高采收率过程的发泡剂。然而,这项工作系统地评估了这些表面活性剂,以建立结构-性能关系,可用于优化表面活性剂作为蒸汽发泡剂,用于高达250°C的热采收率过程。
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引用次数: 2
Production Chemistry Issues and Solutions Associated with Chemical EOR 与化学提高采收率相关的生产化学问题和解决方案
Pub Date : 2019-03-29 DOI: 10.2118/193568-MS
G. Graham, D. Frigo
Chemical EOR is an increasingly employed approach used to enhance oil recovery by combining changes in fluids mobility, macroscopic sweep, interfacial tension, etc. to essentially improve, or extend the economic life of a water flood. It includes flooding with polymer, surfactant, alkaline/surfactant, alkaline-surfactant-polymer (ASP), CO2 and / or other miscible gases which is often combined with waterflood (e.g., CO2 WAG) etc. However, the improved oil recovery is often accompanied by physical and chemical changes in the produced fluids that cause many production-chemistry (PC)-related challenges when fluids subsequently arrive in the production system, including exacerbation of scale and naphthenates deposition, carboxylate deposits associated with injected polymer, enhanced corrosion and separation issues, etc. Understanding and predicting the production chemistry challenges at producers are further complicated by chemical changes as the fluids propagate through the reservoir such as reaction with reservoir formation minerals, chemical retention, chemical degradation and hydrolysis, etc. More importantly the implications for the production system and processing facilities are not always accounted for and proactively managed. The paper evaluates the main chemical changes that occur in the system for each EOR approach –– and shows how these changes, including in situ reservoir reactions and the stability/instability of the EOR packages themselves can exacerbate a range of PC-related challenges especially when considering the likely production of up to three different fluids: formation water, the EOR flood medium and any previous flood water from previous secondary recovery The paper includes modelling results, laboratory results to validate model predictions as well as examples from field case studies to illustrate the impact of the chemical changes referred to above. Specific highlights include the impact of the use of either high- or low-pH EOR fluids on scale control, corrosion control and asphaltenes control; for scale it examines both inhibitor performance per se as well as retention onto rock during squeeze treatment. Also illustrated are the risk of carboxylate-based deposit derived from polymer flood, and the phenomenon of carboxylate-based solids and soaps, which can exacerbate the separation of an already highly challenging system. The overall conclusion is that chemical EOR can have significant impact on PC and that these should not just be considered at the design stage and not just for the injection system but also to take into account the impact these may have on production wells following breakthrough of flood waters, showing that essentially each new or exacerbated PC issues can be predicted or at least anticipated with the required degree of confidence before implementation of EOR.
化学提高采收率是一种越来越常用的方法,通过结合流体流动性、宏观波及、界面张力等变化来提高采收率,从而从根本上改善或延长注水的经济寿命。它包括聚合物、表面活性剂、碱性/表面活性剂、碱性-表面活性剂-聚合物(ASP)、二氧化碳和/或其他常与水驱(如CO2 WAG)联合使用的可混相气体等驱油。然而,采收率的提高通常伴随着采出液的物理和化学变化,当这些流体随后进入生产系统时,会导致许多与生产化学(PC)相关的挑战,包括垢和环烷酸盐沉积的加剧,与注入聚合物相关的羧酸盐沉积,腐蚀和分离问题的加剧等。随着流体在储层中的传播,化学变化(如与储层矿物的反应、化学滞留、化学降解和水解等)使理解和预测生产商的生产化学挑战变得更加复杂。更重要的是,对生产系统和加工设施的影响并不总是被考虑和主动管理。本文评估了每种EOR方法中系统中发生的主要化学变化,并展示了这些变化(包括储层原位反应和EOR包本身的稳定性/不稳定性)如何加剧与pc相关的一系列挑战,特别是考虑到可能生产多达三种不同的流体时:本文包括建模结果、验证模型预测的实验室结果以及现场案例研究的示例,以说明上述化学变化的影响。具体的重点包括使用高ph值或低ph值的提高采收率液对结垢控制、腐蚀控制和沥青质控制的影响;对于阻垢剂,它可以检测阻垢剂本身的性能以及在挤压处理过程中在岩石上的保留率。此外,还说明了聚合物驱产生羧酸盐沉积物的风险,以及羧酸盐固体和肥皂的现象,这些现象可能会加剧本已极具挑战性的体系的分离。总的结论是,化学提高采收率会对PC产生重大影响,不应该只在设计阶段考虑这些问题,也不应该只考虑注入系统,还应该考虑这些问题在洪水突破后对生产井的影响,这表明基本上每一个新的或加剧的PC问题都是可以预测的,或者至少在实施提高采收率之前有必要的信心进行预测。
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引用次数: 3
Scale Prediction and Mineral Solubility Under HPHT Conditions 高温高压条件下的水垢预测和矿物溶解度
Pub Date : 2019-03-29 DOI: 10.2118/193564-MS
D. Nichols, N. Goodwin, G. Graham, D. Frigo
Accurate scale prediction modelling is only possible when reliable mineral solubility data are available under the required conditions. It is recognised that the relative paucity of high pressure, high temperature (HPHT) solubility data can result in inaccurate predictions as current models extrapolate from data obtained under more conventional conditions. This paper describes the generation of additional fundamental solubility data under HPHT conditions and comparison of the obtained values with several existing models. A purpose-built laboratory test rig capable of making mineral solubility measurements up to 250 °C (480 °F) and up to 30,000 psi has been used in this work. Experimental solubility data have been generated for calcium sulphate at different temperatures and the methodology has been investigated to ensure that equilibrium conditions have been reached. In this work, barium sulphate solubility data have also been generated at conditions up to 200 °C (390 °F) and 19,000 psi. Notably, the solubilities have been determined in the presence of relatively high concentrations of additional ions, e.g., calcium, as it was recognised that available data were limited for more oilfield-representative brine compositions from HPHT reservoirs. The data generated were also compared against solubility predictions for a range of industry models to assess their accuracy in these circumstances. The results obtained for calcium sulphate solubility indicate the importance of validating the test methodology, not just for each mineral, but also under the required temperature and pressure conditions, to verify that equilibrium solubility conditions have been achieved. Barium sulphate solubility increases with the addition of other divalent ions but the extent of the increase is at present not accurately predicted by existing scale prediction models at HPHT conditions. In some cases, the predicted barium sulphate solubility was up to three times greater than the experimentally determined value. It is apparent that there is considerable scope for improvement of scale prediction models under HPHT conditions particularly in complex brine systems and that further fundamental solubility data are required to facilitate this. This paper provides additional data for mineral solubility under HPHT conditions but, more importantly, shows data for complex brines that are more representative of those produced in oilfields. The work further demonstrates the limitations of existing scale prediction modelling software under HPHT conditions, particularly in the presence of other divalent ions, and illustrates areas where additional data and model development is critical to enable more accurate modelling of scale risk under these conditions.
只有在所需条件下获得可靠的矿物溶解度数据时,才有可能进行准确的尺度预测建模。人们认识到,高压高温(HPHT)溶解度数据的相对缺乏可能导致预测不准确,因为目前的模型是从更常规条件下获得的数据推断出来的。本文介绍了在高温高压条件下生成额外的基本溶解度数据,并将所得值与几种现有模型进行了比较。在这项工作中,专门建造的实验室测试平台能够在高达250°C(480°F)和高达30,000 psi的压力下进行矿物溶解度测量。对硫酸钙在不同温度下的溶解度数据进行了实验,并对方法进行了研究,以确保达到平衡条件。在这项工作中,硫酸钡的溶解度数据也在高达200°C(390°F)和19,000 psi的条件下生成。值得注意的是,溶解度是在存在相对高浓度的附加离子(如钙)的情况下确定的,因为人们认识到,对于来自高温高压储层的更具油田代表性的盐水成分,现有数据有限。生成的数据还与一系列行业模型的溶解度预测进行了比较,以评估其在这些情况下的准确性。获得的硫酸钙溶解度结果表明验证测试方法的重要性,不仅针对每种矿物,而且在所需的温度和压力条件下,验证已达到平衡溶解度条件。硫酸钡的溶解度随着其他二价离子的加入而增加,但目前现有的高温条件下的尺度预测模型不能准确预测其增加的程度。在某些情况下,预测的硫酸钡溶解度比实验确定的值大三倍。显然,在高温高压条件下,特别是在复杂的盐水体系中,水垢预测模型还有很大的改进空间,需要进一步的基本溶解度数据来促进这一点。本文提供了高温高压条件下矿物溶解度的额外数据,但更重要的是,给出了更能代表油田生产的复杂盐水的数据。这项工作进一步证明了现有的水垢预测建模软件在高温高压条件下的局限性,特别是在存在其他二价离子的情况下,并说明了在这些条件下,额外的数据和模型开发对于实现更准确的水垢风险建模至关重要。
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引用次数: 2
Cross-Linked Polymeric Controlled Release Particles for Inorganic Scale Inhibition 无机阻垢交联聚合物控释颗粒
Pub Date : 2019-03-29 DOI: 10.2118/193557-MS
Ferm Paul, Germer Jeff, H. Kurt, H. Stuart, R. Andrew, Sanders Jannifer, R. Klin, T. John, Wolf Nick, Zhang Lei
The controlled release of scale inhibitors (SI) and other treatment chemicals in the near-wellbore region is a key strategy to improving water management and extended well production. In addition, during some completion and stimulation operations, it is desired that robust particles providing controlled release be placed in gravel and sand packs. A novel controlled release scale inhibitor particle is presented which provides beneficial properties due to its unique chemistry and polymer processing methods. This technology provides extended feedback of scale inhibitor with tunable release rates.
在近井区域控释阻垢剂(SI)和其他处理化学品是改善水管理和扩大油井生产的关键策略。此外,在一些完井和增产作业中,需要在砾石和砂包中放置具有可控释放功能的坚固颗粒。提出了一种新型缓释阻垢颗粒,由于其独特的化学性质和聚合物加工方法而具有良好的性能。该技术提供了扩展的阻垢剂反馈,释放速率可调。
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引用次数: 1
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Day 2 Tue, April 09, 2019
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