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Assessment of Physico-Chemical Parameters of Water Samples Collected from the Southern Part of Bangladesh 孟加拉南部水样理化参数的评估
Pub Date : 2022-07-24 DOI: 10.3329/dujs.v70i1.60381
M. Shoeb, F. Sharmin, Md. Nazrul Islam, L. Nahar, Rafiza Islam, N. Parvin
Bangladesh has a vast natural water resources. In order to determine the water quality parameters such as pH, EC, DO, BOD, TOC, ionsi.e., NO3-, SO42-, PO43- and heavy metals, thirty surface water samples were collected from the southern part of Bangladesh includingthe coastal regions of Patuakhali district and Kuakata sea beach area during the dry season. The pH of water samples was ranged from7.58 to 8.77 with an average of 8.15. The average conductivity value was 8.83±2 mS/cm. The average DO was 8.33±1.82 mg/L andBOD was 0.31±0.03 mg/L. TOC was found between 0.78 and 1.78 mg/L with an average of 1.24 mg/L. The concentration of NO3-,SO42-, PO43- was determined by ion chromatography and only sulphate ion was detected in a very low concentration. Water samplesfrom different sources were analysed for five metals by AAS and the concentrations of Pb, Cd, Mn, Hg and As were below 0.2, 0.01,0.22, 0.001 and 0.005 mg/L, respectively.Dhaka Univ. J. Sci. 70(1): 49-57, 2022 (January)
孟加拉国拥有丰富的自然水资源。为了确定水质参数如pH、EC、DO、BOD、TOC、离子等。在孟加拉国南部包括Patuakhali区沿海地区和Kuakata海滩地区,在旱季期间采集了30个地表水样本,包括NO3-、SO42-、PO43-和重金属。水样pH值范围为7.58 ~ 8.77,平均为8.15。平均电导率为8.83±2 mS/cm。平均DO为8.33±1.82 mg/L, bod为0.31±0.03 mg/L。TOC含量在0.78 ~ 1.78 mg/L之间,平均为1.24 mg/L。采用离子色谱法测定NO3-、SO42-、PO43-的浓度,在极低浓度下仅检测到硫酸盐离子。采用原子吸收光谱法对不同来源的水样进行了5种金属的分析,Pb、Cd、Mn、Hg和As的浓度分别低于0.2、0.01、0.22、0.001和0.005 mg/L。达卡大学学报(自然科学版),70(1):49-57,2022 (1)
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引用次数: 0
Proximate Analysis of Melon Seeds Available in Bangladesh 孟加拉国可用瓜子的近似值分析
Pub Date : 2022-07-24 DOI: 10.3329/dujs.v70i1.60382
Md Reazul Alam Refat, M. Shoeb, A. Sultana
The seeds of winter (wax gourd), long (bottle gourd) and large (pumpkin) melon were analyzed for nutritional parameters mainlyprotein, fat/oil, carbohydrate, dietary fiber, protein, minerals and moisture and fatty acids composition. The double beam ultravioletvisible spectrophotometer was used for analysis of total sugar. The protein content was determined using the Kjeldahl method. An atomic absorption spectrophotometer was used to quantify minerals (Fe, Cu, and Zn). Fatty acid was analyzed by gas chromatography(GC) equipped with a flame ionization detector (FID). From the proximate analysis, it was found that the winter melon (wax gourd)seeds contain protein, oil, carbohydrate, soluble dietary fiber, moisture and ash content of 19.71, 16.46, 56.48, 3.10, 68.88 and 4.26%, respectively. Similarly, long melon (bottle gourd) was found to contain 16.12, 13.61, 46.88, 2.2, 76.45 and 5.2% of protein, oil,carbohydrate, soluble dietary fiber, moisture and ash, respectively. The contents of protein, oil, carbohydrate, soluble dietary fiber,moisture and ash in large melon (pumpkin) seeds were found to be 29.64, 18.17, 55.32, 1.3, 79.53 and 5.12%, respectively. In mineralanalysis, iron, copper, and zinc contents were found to be 6.75, 0.62, and 6.10 mg/100g in winter melon; 7.8, 1.63, and 4.25 mg/100gin long melon; and 13.95, 1.15, and 5.11 mg/100g in large melon, respectively.Dhaka Univ. J. Sci. 70(1): 58-63, 2022 (January)
对冬瓜(冬瓜)、长瓜(冬瓜)和大瓜(南瓜)种子的营养参数进行了分析,主要包括蛋白质、脂肪/油、碳水化合物、膳食纤维、蛋白质、矿物质、水分和脂肪酸组成。采用双光束紫外可见分光光度计对总糖进行分析。用凯氏定氮法测定蛋白质含量。原子吸收分光光度计用于定量矿物(铁、铜、锌)。采用气相色谱法(GC)和火焰电离检测器(FID)对脂肪酸进行了分析。结果表明,冬瓜种子蛋白质、油脂、碳水化合物、可溶性膳食纤维、水分和灰分含量分别为19.71、16.46、56.48、3.10、68.88和4.26%。同样,长瓜(葫芦)的蛋白质、油、碳水化合物、可溶性膳食纤维、水分和灰分含量分别为16.12%、13.61%、46.88%、2.2%、76.45%和5.2%。大瓜子的蛋白质、油脂、碳水化合物、可溶性膳食纤维、水分和灰分含量分别为29.64%、18.17%、55.32%、1.3%、79.53%和5.12%。在矿物质分析中,冬瓜的铁、铜和锌含量分别为6.75、0.62和6.10 mg/100g;7.8、1.63、4.25 mg/100gin长瓜;大甜瓜的含铅量分别为13.95、1.15和5.11毫克/100克。达卡大学学报,70(1):58-63,2022 (1)
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引用次数: 0
Composition of Energy Drink Samples in Bangladesh 孟加拉能量饮料样本的成分
Pub Date : 2022-07-24 DOI: 10.3329/dujs.v70i1.60380
Md Reazul Alam Refat, Polash Nandi, M. Shoeb, A. Sultana
The commercial energy drink samples of 10 different brands were analyzed to study the level of alcohol (if any), sodium benzoate,caffeine, vitamin B, and carbohydrates content. Samples were degassed by ultrasonicator, and CO2 was found to be in a range of 1.27± 0.05 to 4.10 ± 0.10 mL per 100 mL sample. The amount of caffeine, sodium benzoate, glucose, and vitamin B were studied by aUV-Visible spectrophotometer. The wavelength of absorption maxima was 224, 272, 489, 445, and 292 nm, respectively, for sodiumbenzoate, caffeine, glucose, vitamin B2, and vitamin B6. The correlation coefficients of the calibration curves were found to be0.998, 0.992, 0.998, 0.997, and 0.989 for caffeine, glucose, sodium benzoate, vitamin B2 and vitamin B6, respectively. The alcoholcontent was studied by gas chromatography equipped with a flame ionization detector. Ethanol was not found to be present in anysample. The caffeine and sodium benzoate content in different samples was found in the range of 147.84 ± 0.53 to 846.78 ± 2.64 and52.92 ± 6.23 to 1575.37 ± 4.99 μg/mL, respectively. The sugar content in different samples was found to be 16.16 ± 4.25 to 338.33± 0.75 mg/mL. Vitamin B2 was found to be 13.21± 0.08 and 1.04 ± 0.002 μg/mL, respectively in Bacchus and Wild Brew samplesand Vitamin B6 was found to be 261.17 ± 8.38 and 115.88 ± 0.31 μg/mL in Red Bull and Bacchus samples, respectively. The pH ofthe samples was found to be in the range of 2.79 ± 0.04 to 4.88 ± 0.04.Dhaka Univ. J. Sci. 70(1): 42-48, 2022 (January)
研究人员分析了10个不同品牌的商业能量饮料样本,研究了酒精(如果有的话)、苯甲酸钠、咖啡因、维生素B和碳水化合物的含量。通过超声波对样品进行脱气,每100 mL样品中CO2含量为1.27±0.05 ~ 4.10±0.10 mL。用紫外可见分光光度计测定了咖啡、苯甲酸钠、葡萄糖和维生素B的含量。对苯甲酸钠、咖啡因、葡萄糖、维生素B2和维生素B6的最大吸收波长分别为224、272、489、445和292 nm。咖啡因、葡萄糖、苯甲酸钠、维生素B2和维生素B6的相关系数分别为0.998、0.992、0.998、0.997和0.989。采用气相色谱法和火焰电离检测器对乙醇含量进行了研究。没有发现任何样品中存在乙醇。不同样品的咖啡因和苯甲酸钠含量分别为147.84±0.53 ~ 846.78±2.64和52.92±6.23 ~ 1575.37±4.99 μg/mL。不同样品的含糖量为16.16±4.25 ~ 338.33±0.75 mg/mL。在酒神酒和野酿酒中,维生素B2含量分别为13.21±0.08和1.04±0.002 μg/mL;在红牛和酒神酒中,维生素B6含量分别为261.17±8.38和115.88±0.31 μg/mL。样品的pH值范围为2.79±0.04 ~ 4.88±0.04。达卡大学学报,70(1):42- 48,2022 (1)
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引用次数: 0
Mixed Ligand Binuclear Complexes of Copper(II) and Cadmium(II) with Adenine and 1,4-Diazabicyclo[2.2.2]octane 铜(II)和镉(II)与腺嘌呤和1,4-重氮杂环[2.2.2]辛烷的混合配体双核配合物
Pub Date : 2022-07-24 DOI: 10.3329/dujs.v70i1.60378
Sumaia Abdullah, M. Rahman, A. Shaikh, P. K. Bakshi
Mixed ligand binuclear complexes of Cu(II) and Cd(II) with adenine (Ade) and 1,4-diazabicyclo[2.2.2]octane (DABCO) havebeen synthesized at a metal to ligands (M:L:L′) molar ratio of 1:1:1 in aqueous medium under ambient conditions. All synthesizedcomplexes are powdery solids of different colours, slightly soluble in hot water and decompose at high temperature. Characterizationof the complexes was accomplished using various analytical techniques, e.g. metal and chloride content analysis, Fourier transformspectrophotometer (FT-IR), UV-visible spectrophotometer, magnetic measurement, and thermal analyses. The metal and chloridecontents analyses of the complexes reveal to their stoichiometry [M2Cl2(Ade)2(H2O)2(DABCO)]Cl2 [M = Cu(II) or Cd(II)]. Analyticaldata suggests that they are homo metal symmetric binuclear complexes comprises of two [MCl(Ade)(H2O)] moieties in betweena DABCO molecule is N,N′-bridge bonded. The arrangements of the ligands around the metal centers are essentially tetrahedralinvolving N(9) of deprotonated imidazole moiety, one Cl- ion, one oxygen from the water molecule and one tertiary N atom fromDABCO completing the coordination. Proton migration occurs from N(9) to the N(1) site resulting into a zwitterionic form ofadenine, additionally N(3) site of which is hydrogen bonded with the coordinated water molecule. Electrochemical redox behaviourof Cu(II) in presence of adenine and DABCO in the aqueous medium was also studied. It exhibits quasi-reversible one-electrontransfer processes. Dhaka Univ. J. Sci. 70(1): 28-33, 2022 (January)
在常压条件下,以金属与配体(M:L:L’)的摩尔比为1:1:1,在水介质中合成了Cu(II)和Cd(II)与腺嘌呤(Ade)和1,4-重氮杂环[2.2.2]辛烷(DABCO)的混合配体双核配合物。所有合成的配合物都是不同颜色的粉状固体,在热水中微溶,在高温下分解。配合物的表征是通过各种分析技术完成的,例如金属和氯化物含量分析,傅里叶变换分光光度计(FT-IR),紫外可见分光光度计,磁测量和热分析。配合物的金属和氯化物含量分析表明它们的化学计量[M2Cl2(Ade)2(H2O)2(DABCO)]Cl2 [M = Cu(II)或Cd(II)]。分析数据表明,它们是由两个[MCl(Ade)(H2O)]基团组成的金属对称双核配合物,其中DABCO分子为N、N '桥键。金属中心周围的配体排列基本上是四面体,包括去质子化咪唑部分的N(9),一个Cl-离子,一个来自水分子的氧和一个来自abco的叔氮原子完成配位。质子从N(9)迁移到N(1)位点,形成两性离子形式的腺嘌呤,另外N(3)位点与配位的水分子形成氢键。研究了Cu(II)在腺嘌呤和DABCO存在下的电化学氧化还原行为。它表现出准可逆的单电子转移过程。达卡大学学报,70(1):28- 33,2022 (1)
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引用次数: 0
Sensitivity of Different Physics Schemes in the Simulation of Heat Wave Events over Bangladesh Using WRF-ARW Model 不同物理方案在WRF-ARW模式模拟孟加拉国热浪事件中的敏感性
Pub Date : 2022-07-24 DOI: 10.3329/dujs.v70i1.60384
Sahadat Jaman, Md. Jafrul Islam, A. Imran, M. Kamruzzaman, M. Mallik, Pappu Paul, Imroj Syed
Heat waves (HWs) are an extreme temperature condition that has a direct impact on human lives. In recent years, a large number ofpeople have died all over the world due to hot weather. The purpose of this study is to predict HWs accurately to mitigate the casualtiescaused by them. Two HW events are selected for this study (Event-1: 0000 UTC of 18 May to 0000 UTC of 25 May 2015, Event-2:0000 UTC of 05 April to 2100 UTC of 08 April 2015). At first, sensitivity tests have been done using different combinations ofphysics schemes. Sensitivity of Planetary boundary layer (PBL) and surface layer (SL) schemes combinations (YSU-Revised MM5,YSU-MM5, MYJ-Eta, and ACM2-Revised MM5) and land surface models (RUC, Noah, Noah-MP, and CLM4) are investigated topredict Comfort Index (CI), which is identified by using Physiological Equivalent Temperature (PET). To simulate PET, the primarymeteorological variables 2-m air temperature (T2), 2-m relative humidity (rh2), mean radiant temperature (TMRT), wind speed at 10m (ws10), and cloud cover data have been used. These parameters were simulated by the WRF model using both single and nesteddomains. The experiments found that the combination of the YSU-MM5 scheme and the Noah land surface model predicted theWRF simulated variables very well. The study also found that the CI exists between the slight heat stress to extreme heat stress andthe maximum PET values were found to be 47.6 ºC and 48.5 ºC for Rajshahi and Khulna event respectively. Dhaka Univ. J. Sci. 70(1): 70-78, 2022 (January)
热浪(HWs)是一种对人类生活有直接影响的极端温度条件。近年来,由于炎热的天气,世界各地有大量的人死亡。本研究的目的是准确预测卫生保健,以减轻卫生保健造成的人员伤亡。本研究选择了两个HW事件(event - 1:20 00 UTC(2015年5月18日至5月25日),event -2:00 UTC(2015年4月5日至2100 UTC(2015年4月8日))。首先,使用不同的物理方案组合进行了灵敏度测试。研究了行星边界层(PBL)和地表(SL)方案组合(YSU-Revised MM5、YSU-MM5、MYJ-Eta和ACM2-Revised MM5)和地表模式(RUC、Noah、Noah- mp和CLM4)对利用生理等效温度(PET)识别的舒适度(CI)的敏感性。为了模拟PET,使用了主要气象变量2m气温(T2)、2m相对湿度(rh2)、平均辐射温度(TMRT)、10m风速(ws10)和云量数据。WRF模型分别使用单域和嵌套域对这些参数进行了模拟。实验发现,YSU-MM5方案与Noah陆面模式的组合对wrf模拟变量的预测效果较好。研究还发现,轻微热应激和极端热应激之间存在CI, Rajshahi和Khulna事件的最大PET值分别为47.6℃和48.5℃。达卡大学学报(自然科学版),70(1):70- 78,2022 (1)
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引用次数: 0
The State of Healthcare Facilities to Provide Diabetes, Cardiovascular and Chronic Respiratory Disease Related Services in Bangladesh 孟加拉国提供糖尿病、心血管和慢性呼吸系统疾病相关服务的保健设施状况
Pub Date : 2022-07-24 DOI: 10.3329/dujs.v70i1.60376
Gaylan Peyari Tarannum Dana, Sawkia Afroz
The rapid rise of diabetes, cardiovascular disease (CVD) and chronic respiratory disease (CRD) are causing serious challenges forBangladesh to achieve the sustainable development goal (SDG) target 3.4 by 2030. The study aims to describe the state of healthcarefacilities to provide diagnosis and treatment for diabetes, CVD and CRD related services in Bangladesh. This cross-sectional studyused data from 2017 Bangladesh Health Facility Survey (BHFS). A total of 406 health facilities providing all three services wereconsidered for this study. Findings of the study illustrated that there were rural-urban disparities in healthcare facilities to providediabetics, CVD, CRD related services. Diabetics and CRD related services were significantly higher in public healthcare facilitiesof urban areas compared to rural areas (P <0.008 and P<0.001, respectively). Also, public health facilities of urban areas were morelikely to provide CVD related services compared to rural areas. While private healthcare facilities of urban areas were more likelyto provide CVD, CRD related services than rural areas. Private healthcare facilities of rural areas were in better condition to providediabetes related services than urban areas. However, the country is yet to attain optimal progress in the overall status of health sector.Therefore, in order to cope up with the rising burden of diabetes, CVD and CRD and to minimize the burden of disease specific outofpocket healthcare expenses, recommendations include strengthening and improving stewardship, improving quality of servicesand improving monitoring as well as supervision of decentralized healthcare facilities. Dhaka Univ. J. Sci. 70(1): 14-21, 2022 (January)
糖尿病、心血管疾病(CVD)和慢性呼吸系统疾病(CRD)的迅速增加给孟加拉国在2030年前实现可持续发展目标(SDG)具体目标3.4带来了严峻挑战。该研究旨在描述孟加拉国提供糖尿病、心血管疾病和慢性肾病相关服务的医疗保健设施的状况。这项横断面研究使用了2017年孟加拉国卫生设施调查(BHFS)的数据。这项研究总共考虑了406家提供这三种服务的卫生机构。研究结果表明,在提供糖尿病、心血管疾病、冠心病相关服务的医疗设施方面存在城乡差异。城市公共卫生机构的糖尿病患者和CRD相关服务明显高于农村地区(P <0.008和P<0.001)。此外,与农村地区相比,城市地区的公共卫生设施更有可能提供心血管疾病相关服务。与农村地区相比,城市地区的私营医疗机构更有可能提供心血管疾病、冠心病相关服务。农村地区私立医疗机构提供糖尿病相关服务的条件优于城市地区。然而,该国在卫生部门的总体状况方面尚未取得最佳进展。因此,为了应对糖尿病、心血管疾病和慢性肾病日益增加的负担,并尽量减少特定疾病的自费医疗费用负担,建议包括加强和改进管理,提高服务质量,改进对分散医疗设施的监测和监督。达卡大学学报(自然科学版),70(1):14- 21,2022 (1)
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引用次数: 1
An Econometric Analysis to Forecast the Food Grain Production in Bangladesh by Using ARIMA and VAR Models 基于ARIMA和VAR模型对孟加拉国粮食产量预测的计量分析
Pub Date : 2022-07-24 DOI: 10.3329/dujs.v70i1.60375
Mehedi Hossain, Murshida Khanam, S. Akhter
In this study, an Econometric analysis has been conducted to identify the important factors that affect the food grain productions inBangladesh. Here, we have considered time series data for the years from 1989- 1990 to 2019-2020. Vector Autoregressive (VAR)Model and Autoregressive Integrated Moving Average (ARIMA) model have been considered in this study. Both these modelshave been considered to forecast the productions of food grains in Bangladesh. The forecasting performances of these two modelshave been compared by using RMSE, MAE, and MAPE. It has been found that the VAR model is better than the ARIMA model toforecast the food grain production. On the other hand, it has been come out from the analysis that there is no significant impact ofchemical fertilizer on the food grain production, but irrigation area has significant impact on the food grain production. Among thethree variables: food grain production, irrigation area and chemical fertilizer, there exists short run relationship. Dhaka Univ. J. Sci. 70(1): 8-13, 2022 (January)
在本研究中,进行了计量经济学分析,以确定影响孟加拉国粮食生产的重要因素。这里,我们考虑了1989- 1990年至2019-2020年的时间序列数据。本研究采用向量自回归(VAR)模型和自回归综合移动平均(ARIMA)模型。这两种模型都被用来预测孟加拉国的粮食产量。利用RMSE、MAE和MAPE对两种模型的预测性能进行了比较。结果表明,VAR模型对粮食产量的预测效果优于ARIMA模型。另一方面,通过分析得出,化肥用量对粮食产量的影响不显著,但灌溉面积对粮食产量的影响显著。粮食产量、灌溉面积和化肥三个变量之间存在短期关系。达卡大学学报(自然科学版),70(1):8- 13,2022 (1)
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引用次数: 1
Scope of Electrochemistry at Liquid/liquid Micro-Interfaces 液体/液体微界面的电化学范围
Pub Date : 2022-07-04 DOI: 10.3329/dujs.v69i3.60029
G. J. Islam, Shaheda Zannah
Electrochemistry at the interface between two immiscible electrolyte solutions (ITIES) has become an important and powerful platform for the detection and characterization of a wide variety of organic and inorganic species. Liquid/liquid electrochemistry overcomes some limitations faced in conventional solid/liquid electrochemistry. These include employment ofion transfer voltammetry across the ITIES as the basis for detection of non-redoxactive ions. The analytical sensitivity increasedon miniaturisation of the interface with an improvement insensitivity due to the enhanced mass transport via convergent diffusionas the size of the ITIES is minimised. In this review article, the ITIES is briefly described along with the scope of electrochemical research at micro-ITIES.Dhaka Univ. J. Sci. 69(3): 186-193, 2022 (June)
两种不混溶电解质溶液(ITIES)界面的电化学已成为检测和表征各种有机和无机物质的重要而有力的平台。液/液电化学克服了传统固/液电化学的一些局限性。这些措施包括使用跨离子束的转移伏安法作为检测非氧化离子的基础。分析灵敏度随着界面的小型化而提高,而灵敏度的提高是由于通过会聚扩散增强的质量传递,从而使界面的尺寸最小化。本文简要介绍了微电极的电化学研究现状,并介绍了微电极的电化学研究范围。达卡大学学报(自然科学版),69(3):186- 193,2022 (6)
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引用次数: 0
Binary Solvent System for Extraction of Cathode Material From Spent Li-ion Batteries 双溶剂萃取废锂离子电池正极材料的研究
Pub Date : 2022-07-04 DOI: 10.3329/dujs.v69i3.60034
N. Hossain, Md. Ismail Hossain, P. Ahamed, M. A. Yousuf
An effective method of water and carbon tetrachloride (CCl4) system has been studied to recover metals ions from spent Li-ion battery cathode materials. Leaching of HCl and HCl + H2O2 has been applied individually to dissolve the collected cathode materials. Metal ions dissolved in HCl and HCl + H2O2 has been treated separately with a solution of hexadecyl amine in CCl4. The formation of metal ions-hexadecyl amine complex has been confirmed from UV-visible spectroscopy. Recovery of metals from the produced complex has been carried out via filtration and calcination. The calcined materials has been characterized using Fourier transform infrared spectroscopy (FT-IR),field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS) andpowder x-ray diffraction (XRD).Dhaka Univ. J. Sci. 69(3): 225-229, 2022 (June)
研究了水-四氯化碳体系回收废旧锂离子电池正极材料中金属离子的有效方法。分别采用HCl和HCl + H2O2浸出法溶解收集的阴极材料。用十六烷基胺CCl4溶液分别处理溶解于HCl和HCl + H2O2中的金属离子。金属离子-十六烷基胺络合物的形成已被紫外可见光谱证实。通过过滤和煅烧从生产的络合物中回收金属。利用傅里叶变换红外光谱(FT-IR)、场发射扫描电镜(FESEM)、能谱(EDS)和粉末x射线衍射(XRD)对煅烧材料进行了表征。达卡大学学报(自然科学版),69(3):225-229,2022 (6)
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引用次数: 0
First-Principles Study of Half Metallic Ferromagnetic and Optical Properties of Nb Doped Cubic ZnS using TB-mBJ Approximation 用TB-mBJ近似研究Nb掺杂立方ZnS半金属铁磁和光学性质的第一性原理
Pub Date : 2022-07-04 DOI: 10.3329/dujs.v69i3.60030
Md. Borhanul Asfia, M. Rashid
Structural, electronic and optical properties of niobium doped ZnS are studied by using full-potential linearized augmented plane wave plus local orbital (FPLAPW+lo) method within the density functional theory (DFT). Computed results of Nb doped ZnS are compared with that of the pristine zinc blende. Tran-Blaha approach of modified Becke and Johnson local spin density approximation (TB-mBJ) is used to study electronic and optical properties. Estimated result shows that Nb reduces the bandgap of ZnS due to hybridization of Nb-4d orbital with S-3p orbital near the Fermi level. Niobium dopant provides half metallic nature to ZnS with 100% spin polarization. Maximum photo-response is noticed in the ultraviolet range for Zn1-xNbxS (x = 25, 12.5, 6.25 %). Highest peaks are shifted toward the lower energy range for higher dopant percentage. All these suggest that Nb doped ZnS solid solutions are suitable candidate for both energy filter of UV spectrum and spintronic device.Dhaka Univ. J. Sci. 69(3): 194-201, 2022 (June)
利用密度泛函理论(DFT)中的全势线性化增广平面波加局域轨道(FPLAPW+lo)方法研究了铌掺杂ZnS的结构、电子和光学性质。将Nb掺杂ZnS的计算结果与原始锌闪锌矿的计算结果进行了比较。采用改进的Becke和Johnson局域自旋密度近似(TB-mBJ)的trans - blaha方法研究其电子和光学性质。估计结果表明,Nb减小了ZnS的带隙,这是由于Nb-4d轨道与S-3p轨道在费米能级附近的杂化作用。铌掺杂使ZnS具有半金属性质,具有100%的自旋极化。Zn1-xNbxS (x = 25, 12.5, 6.25%)在紫外范围内光响应最大。当掺杂率较高时,峰值向较低的能量范围偏移。这些都表明Nb掺杂ZnS固溶体是紫外光谱能量过滤器和自旋电子器件的合适候选材料。达卡大学学报(自然科学版),69(3):194- 2011,2022 (6)
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引用次数: 1
期刊
Dhaka University Journal of Science
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