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Advanced Materials and Technologies in Engineering Applications 工程应用中的先进材料和技术
Q4 Physics and Astronomy Pub Date : 2024-03-25 DOI: 10.4028/b-m7wsba
Šárka Nenadálová, Kazuo Umemura, Ian McAndrew, S. Harikrishnan
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引用次数: 0
Improving the Thermo-Physical Properties of Plam Oil with Zeolite Nanoparticles 用沸石纳米颗粒改善 Plam 油的热物理性质
Q4 Physics and Astronomy Pub Date : 2024-03-25 DOI: 10.4028/p-6dmet0
P. Assawasaengrat, Thanasuta Limsakul, Penpichcha Bunprasert, Wasan Chokelarb, Pongsert Sriprom
This research aimed to improve the thermo-physical properties of plam oil with NaA zeolite. Palm oil was selected for heating oil due to its high flash point and environmental friendliness compared to synthetic or mineral oil. The effect of NaA zeolite concentration suspended in palm oil was investigated in terms of the specific heat capacity (Cp), viscosity (μ), viscosity index (VI), thermal analysis (TGA) and density (ρ) of palm oil. The NaA zeolite was synthesized by crystallization technique, and X-ray diffraction analysis was performed to determine NaA zeolite crystallinity. The size of NaA zeolite was measured using a particle size analyzer. The average size of the synthesized NaA zeolite was 4767 nm. After grinding process for 180 min, the average size of zeolite decreased to 632 nm. An average 632 nm NaA zeolite particle size was added to palm oil at 0.25, 0.5, 0.75 and 1 wt%. The results showed that when the NaA zeolite concentration increased, the nanofluid’s viscosity at 40 °C and 100 °C was increased. The addition of 1 wt% NaA zeolite resulted in the nanofluid having a maximum viscosity of 41.31 and 8.47 cSt at 40 °C and 100 °C, respectively. The highest viscosity index was 195 cSt when added with 0.5 wt% NaA zeolite. The density of palm oil slightly increased with increasing NaA zeolite concentrations. The specific heat capacity of palm oil increased when NaA zeolite was added. The results showed that NaA zeolite allowed palm oil to store heat energy better than palm oil, enabling it to release and absorb more heat during heat transfer. Thermogravimetric analysis, palm oil initiated to degrade at 263 °C, while the addition NaA zeolite in palm oil indicated that palm oil initiated to degrade at 350 °C. The shift in the degradation curve demonstrated that the nanofluid could withstand high temperatures. Adding NaA zeolite to palm oil showed that palm oil could endure more heat and has a long service life.
这项研究旨在利用 NaA 沸石改善棕榈油的热物理性质。与合成油或矿物油相比,棕榈油闪点高且环保,因此被选为加热油。研究了悬浮在棕榈油中的 NaA 沸石浓度对棕榈油比热容(Cp)、粘度(μ)、粘度指数(VI)、热分析(TGA)和密度(ρ)的影响。通过结晶技术合成了 NaA 沸石,并进行了 X 射线衍射分析以确定 NaA 沸石的结晶度。使用粒度分析仪测量了 NaA 沸石的粒度。合成的 NaA 沸石的平均粒度为 4767 nm。经过 180 分钟的研磨过程后,沸石的平均粒度减小到 632 nm。将平均粒径为 632 nm 的 NaA 沸石以 0.25、0.5、0.75 和 1 wt% 的比例添加到棕榈油中。结果表明,当 NaA 沸石浓度增加时,纳米流体在 40 °C 和 100 °C 时的粘度增加。添加 1 wt% NaA 沸石后,纳米流体在 40 °C 和 100 °C 时的最大粘度分别为 41.31 和 8.47 cSt。添加 0.5 wt% NaA 沸石时,最高粘度指数为 195 cSt。随着 NaA 沸石浓度的增加,棕榈油的密度略有增加。添加 NaA 沸石后,棕榈油的比热容增加。结果表明,NaA 沸石能比棕榈油更好地储存热能,使其在传热过程中释放和吸收更多的热量。热重分析显示,棕榈油在 263 °C 开始降解,而在棕榈油中添加 NaA 沸石后,棕榈油在 350 °C 开始降解。降解曲线的变化表明纳米流体可以承受高温。在棕榈油中添加 NaA 沸石表明,棕榈油可以承受更多的热量,使用寿命更长。
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引用次数: 0
Mechanical Properties of Luffa Fiber Reinforced Recycled Polymer Composite 丝瓜纤维增强再生聚合物复合材料的力学性能
Q4 Physics and Astronomy Pub Date : 2024-03-25 DOI: 10.4028/p-jrgi9s
H. Kuan, Mohd Khairul Afiq, Scollastica Jane Lumpong
Environmental issues over the eventual fate of post-consumer polymers can be dealt with in two separate ways which is recycling or using biodegradable polymers. However, it is evident that recycling polymers from post-consumer polymers can decrease the mechanical properties over time. Hence, to strengthen the recycled polymers, integrating fibers, such as luffa, into the High-Density Polyethylene (HDPE) matrix, was carried out to produce a fiber reinforced recycled polymer (FRrP) composite. The tensile testing of the FRrP composite shows that the 10% fiber volume fraction (FVF) composite exhibits a higher tensile strength of 3.9% than the neat recycled HDPE (RHDPE). In terms of Young’s Modulus, the 5% FVF of FRrP is shown to have a higher value than the neat RHDPE by 54%. The low density of luffa fibers also contributes to the composites lightweight character. The impact testing shows that the FRrP enhances the impact properties when compared to the neat RHDPE. The peak load, perforation energy, and the total energy absorbed by the FRrP indicate an increasing trend when luffa, of up to 15% FVF, is added as the reinforcement. Thus, the addition of luffa as reinforcement in RHDPE shows significant potential as a high-performance, sustainable, and environmentally friendly material, such as automotive parts and protective gear.
处理消费后聚合物最终归宿的环境问题有两种不同的方法,即回收利用或使用可生物降解的聚合物。不过,从消费后聚合物中回收聚合物显然会随着时间的推移而降低机械性能。因此,为了增强再生聚合物,我们将丝瓜等纤维融入高密度聚乙烯(HDPE)基体中,制成了纤维增强再生聚合物(FRrP)复合材料。FRrP 复合材料的拉伸测试表明,10% 纤维体积分数 (FVF) 复合材料的拉伸强度比纯回收高密度聚乙烯 (RHDPE) 高 3.9%。在杨氏模量方面,5% FVF 的 FRrP 复合材料比纯 RHDPE 高出 54%。丝瓜纤维的低密度也为复合材料的轻质特性做出了贡献。冲击测试表明,与纯 RHDPE 相比,FRrP 增强了冲击性能。当添加高达 15%的丝瓜纤维作为增强材料时,FRrP 的峰值载荷、穿孔能和吸收的总能量都呈上升趋势。因此,在 RHDPE 中添加丝瓜作为增强材料,显示出其作为高性能、可持续和环保材料的巨大潜力,如汽车零件和防护装备。
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引用次数: 0
Light Extraction Efficiency Enhancement of White Organic Light-Emitting Diodes (OLEDs) by Micro/Nano-Patterning the Substrate Layer 通过微/纳米图案化基底层提高白色有机发光二极管 (OLED) 的光提取效率
Q4 Physics and Astronomy Pub Date : 2024-03-25 DOI: 10.4028/p-bx2ouv
Md. Shamim Ahsan, Md. Arif Istiaq Arafat, Tasmima Akter, I. Sohn, Hun-Kook Choi
We demonstrate the enhancement of light extraction efficiency of surface-emitting white Organic Light Emitting Diodes (OLEDs) by incorporating micro/nano-metric structures on the outer surface of the 3-layer substrate (SiO2-Si3N4-SiO2). To enhance light extraction efficiency of the OLEDs, various light scattering structures including plano-convex & plano-concave micro-lens array, flat-top & round-top nano-pillars array, and wavy structures were engraved on the outer surface of the substrate layer. For optimization, we varied the thickness of the internal layers of the OLEDs, and height, width, period, and radius of the micro/nano-scale structures. The performance of the micro/nano-structured OLEDs was simulated and analyzed using Lumerical FDTD and GPVDM simulators. We examined the far field light intensity, transmitted power, angular distribution of light, photon escape probability, photon density, internal & external quantum efficiency, and current-voltage curve of the designed OLEDs. We investigated the results in different locations, especially after the substrate layer: Far Field-1 (0 μm), and Far Field-2 (2.5 μm). Compared to conventional OLEDs, the micro/nano-structured OLEDs showed higher external quantum efficiency. The highest external quantum efficiency of 67.304% (Far Field-1) was detected in the round-top nano-pillars array engraved white OLED having structure period of 1.2 μm. We strongly believe that, the proposed micro/nano-structured white OLEDs are suitable for lighting applications.
我们展示了通过在三层基底(SiO2-Si3N4-SiO2)的外表面加入微米/纳米结构来提高表面发光白光有机发光二极管(OLED)的光萃取效率。为了提高有机发光二极管的光萃取效率,我们在基底层的外表面雕刻了各种光散射结构,包括平凸和平凹微透镜阵列、平顶和圆顶纳米柱阵列以及波浪形结构。为了优化,我们改变了 OLED 内部层的厚度,以及微米/纳米级结构的高度、宽度、周期和半径。我们使用 Lumerical FDTD 和 GPVDM 模拟器模拟和分析了微米/纳米结构 OLED 的性能。我们考察了所设计的有机发光二极管的远场光强、透射功率、光的角度分布、光子逃逸概率、光子密度、内部和外部量子效率以及电流-电压曲线。我们研究了不同位置的结果,尤其是衬底层之后的位置:远场-1(0 μm)和远场-2(2.5 μm)。与传统的有机发光二极管相比,微/纳米结构的有机发光二极管显示出更高的外部量子效率。结构周期为 1.2 μm 的圆顶纳米柱阵列雕刻白光 OLED 的外部量子效率最高,达到 67.304%(Far Field-1)。我们坚信,所提出的微/纳米结构白光有机发光二极管适用于照明应用。
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引用次数: 0
Halloysite Nanotube (HNT) Dispersion Stability in 10% Ethanol-Water Mixture and Water 霍洛石纳米管(HNT)在 10% 乙醇-水混合物和水中的分散稳定性
Q4 Physics and Astronomy Pub Date : 2024-03-25 DOI: 10.4028/p-vu0wmb
Aaron Zaeh F. Dilidili, Jhoneliza B. Habiling, Paul Eric C. Maglalang, J. C. Millare
This study investigates Halloysite Nanotube (HNT) dispersibility in ethanol-water mixtures – 0% and 10% ethanol at 100, 300, and 500 ppm HNT concentrations. Overall, the study finds that changes in HNT concentration linearly affect the response variables and showed that the 10% ethanol solvent has a higher zeta potential, smaller particle size, higher viscosity, and settling velocity. The enlargement of HNT particles at 10% ethanol while keeping better stability than water solvent is unexpected and can open novel studies about the dispersion of HNT in this solvent system.
本研究调查了霍洛石纳米管(HNT)在乙醇-水混合物(0% 和 10%乙醇,HNT 浓度分别为 100、300 和 500 ppm)中的分散性。总体而言,研究发现 HNT 浓度的变化会线性地影响响应变量,并显示 10% 乙醇溶剂具有更高的 zeta 电位、更小的粒度、更高的粘度和沉降速度。与水溶剂相比,10% 乙醇中的 HNT 颗粒更大,同时保持了更好的稳定性,这是出乎意料的,可以开启有关 HNT 在该溶剂体系中分散的新研究。
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引用次数: 0
Comparison of Concrete Mixtures and Alkaline Activated Material with Regard to Selected Properties for Structural Design 混凝土混合物与碱性活性材料在结构设计中的选定性能比较
Q4 Physics and Astronomy Pub Date : 2024-03-25 DOI: 10.4028/p-lc2j6q
Jan Jeřábek
In the field of construction, with regard to social and design requirements, it is necessary to look for innovative and advanced solutions for the materials of building and structural elements. The topic of this paper is precisely from this area, where material engineering and the field of concrete belong. The aim of the research task is to compare the properties of three different mixtures. The main goal is the analysis and comparison of samples after exposure of test samples to elevated temperatures of up to 900 °C. The mixtures are based on the same ingredients. The first mixture was a reference one, where the binder was Portland cement. In the second mix, cement was replaced, and an alkali-activated binder was used. And in the third mix, which was a modification of the first mix, part of the aggregate was replaced with light artificial aggregate. The experimental part also focused on testing and comparing the workability in the fresh state and subsequently the basic mechanical characteristics, which include strength in compression, split tension, or static modulus of elasticity. In addition, tests of resistance to frost and defrosting chemicals or determination of the tear strength of the surface layer on the test beams were also carried out.
在建筑领域,考虑到社会和设计要求,有必要为建筑材料和结构元素寻找创新和先进的解决方案。本文的主题正是来自这一领域,即材料工程和混凝土领域。研究任务的目的是比较三种不同混合物的特性。主要目标是分析和比较将测试样品暴露在高达 900 °C 的高温下后的样品。这些混合物基于相同的成分。第一种混合物是参考混合物,粘合剂是硅酸盐水泥。在第二种混合物中,水泥被取代,并使用了碱激活粘结剂。第三种混合物是对第一种混合物的改良,用轻质人工骨料代替了部分骨料。实验部分还重点测试和比较了新鲜状态下的可操作性以及随后的基本机械特性,包括压缩强度、劈裂拉伸强度或静态弹性模量。此外,还进行了抗霜冻和抗解冻化学品试验,或测定试验梁表层的撕裂强度。
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引用次数: 0
Rheological Properties and Segregation of Fresh UHPC with Fibers Affected by Initial Temperature of Concrete Mix 混凝土拌合物初始温度对含纤维新拌超高性能混凝土流变性能和离析的影响
Q4 Physics and Astronomy Pub Date : 2024-03-25 DOI: 10.4028/p-j1wmcb
Tomáš Bittner, Karel Hurtig, D. Jiroutová
Within the framework of the project GAČR 21-24070S Model of fibre segregation in dependence on rheological properties of fresh HPC, the rheological properties and fibre segregation in fresh concrete mix depending on temperature changes have been verified. The rheological properties and fibre segregation have been verified under three temperature conditions (very low temperatures around 5 °C, normal temperature conditions around 20 °C and high temperatures above 30 °C). Comparison of the properties of UHPC with fibres at different temperature conditions has been performed on fresh mixtures mainly by spill tests. Subsequently, hardened test bodies, i.e. 40/40/160 beams, were verified in tensile bending and compression in all cases. The actual fibre segregation within the individual samples has also been verified by microscopic analysis. Different temperature conditions have been simulated by heating or cooling the input raw materials. The results have been compared by degree of changes in rheological properties and mechanical parameters.
在 GAČR 21-24070S 项目框架内,根据新拌高强混凝土的流变特性建立了纤维离析模型,验证了新拌混凝土的流变特性和纤维离析随温度变化而变化的情况。在三种温度条件下(5 °C左右的极低温度、20 °C左右的正常温度和 30 °C以上的高温)验证了流变特性和纤维离析。对带有纤维的超高性能混凝土在不同温度条件下的特性进行了比较,主要是在新鲜混合物上进行溢出试验。随后,在所有情况下都对硬化试验体(即 40/40/160 梁)进行了拉伸弯曲和压缩验证。单个样品内的实际纤维偏析也通过显微镜分析进行了验证。通过加热或冷却输入的原材料,模拟了不同的温度条件。根据流变特性和机械参数的变化程度对结果进行了比较。
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引用次数: 0
Research on the Influence of Humidity on the Manufacture of GFRP Vessels in the Equatorial 赤道地区湿度对 GFRP 容器制造的影响研究
Q4 Physics and Astronomy Pub Date : 2024-03-25 DOI: 10.4028/p-22wfse
P. Townsend, Cinthya Astudillo, Karla Larrea, Juan Carlos Suárez
The objective of this research work is to analyze the behavior between fiberglass laminate under tensile tests, assembled under different humidity conditions. For which specimens were designed under the regime of the international standard ASTM D3039; which took an assembly process within a controlled environment; the design variables used were relative humidity and curing time. Subsequently, the traction-displacement behavior was checked under a uniaxial force, obtaining the maximum take-off force. In addition, Simpson numerical integration was applied to calculate elastic energy. Obtaining that the relative humidity and the days of curing influence the chemical and mechanical properties of the material. Se shows that the percentage of humidity recommended for assembling laminates in GRP is 66% since it has greater elastic energy and take-off force. Finally, it is concluded that to have a high resistance in the material at least 7 days of curing of the epoxy resin must be applied.
这项研究工作的目的是分析在不同湿度条件下组装的玻璃纤维层压板在拉伸试验中的行为。为此,根据国际标准 ASTM D3039 设计了试样;试样在受控环境中进行组装;设计变量为相对湿度和固化时间。随后,在单轴力作用下检查了牵引-位移行为,获得了最大起飞力。此外,还应用辛普森数值积分计算弹性能量。结果表明,相对湿度和固化天数会影响材料的化学和机械性能。结果表明,在组装玻璃钢层压板时,建议使用 66% 的湿度,因为它具有更大的弹性能和起飞力。最后得出的结论是,要使材料具有较高的耐受性,环氧树脂必须至少固化 7 天。
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引用次数: 0
Usability of the Combination of Fly Ash from Different Species 不同品种粉煤灰组合的可用性
Q4 Physics and Astronomy Pub Date : 2024-03-25 DOI: 10.4028/p-0xrtoo
M. Meruňka, Petr Šperling, M. Ťažký, Rudolf Hela
This article deals with the possible combination of high temperature fly ash with fluidised fly ash. The aim of this experiment is to verify the effect of the combination of these two energy by-products not only on the parameters of cement mortar in the fresh state, but especially on its mechanical parameters in the hardened state.
本文论述了高温粉煤灰与流化粉煤灰的可能组合。该实验的目的是验证这两种能源副产品的组合不仅对水泥砂浆在新鲜状态下的参数有影响,而且特别是对其在硬化状态下的机械参数有影响。
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引用次数: 0
Numerical Analysis of Non-Sphericity of Particles of Powder Material and their Effect on Packing Structure for Concentrated Solar Power Applications 粉末材料颗粒的非球面性及其对聚光太阳能应用中填料结构影响的数值分析
Q4 Physics and Astronomy Pub Date : 2024-03-25 DOI: 10.4028/p-j8hsln
A. Boribayeva, Xeniya Gvozdeva, Boris Golman
Concentrated solar power technology represents a novel approach to generating solar power, characterized by high solar radiation density and uninterrupted operation. To store thermal energy and extend system operating hours, concentrated solar power systems rely on thermal energy storage. Selecting the appropriate heat storage media is crucial for designing a cost-efficient and straightforward system capable of withstanding high processing conditions. Among many powder materials, bauxite powder stands out as alternatives to conventional molten salt for thermal storage media due to its widespread availability and suitability for operating conditions. Particle shape, particularly its sphericity, plays a vital role in efficiently packing particles which directly affects to heat transfer properties. To investigate this effect, three samples of particles with different shape were formed: spheres, ellipses, and cylinders using Discrete Element Method with equal volume and material properties, and only variation of their sphericity factors. The study focused on the analysis of the porosity of the packed bed of particles with different shapes and its influence on the packing structure properties. The analysis of local packing fraction revealed that elliptical and cylindrical particles samples exhibited reduced heap formation and a more uniform distribution along z direction during vertical packing. The coordination number and radial distribution function analyses for these non-spherical particles showed a greater number of contacts between particles and disordered distribution of particles due to mechanical interlocking of non-spherical particles. The results indicated that the deviation of sphericity has a positive impact on the denser packing of particles generated more contacts and higher local packing fraction.
聚光太阳能发电技术是一种新型的太阳能发电方法,具有太阳辐射密度高和不间断运行的特点。为了储存热能并延长系统运行时间,聚光太阳能发电系统需要依靠热能储存。选择合适的储热介质对于设计一个成本效益高且能承受高加工条件的简单系统至关重要。在众多粉末材料中,铝矾土粉末因其广泛的可获得性和对操作条件的适用性,在传统熔盐储热介质的替代品中脱颖而出。颗粒形状,尤其是其球形度,在有效堆积颗粒方面起着至关重要的作用,这直接影响到传热性能。为了研究这种影响,采用离散元素法,在体积和材料属性相同的情况下,仅改变球度系数,形成了三种不同形状的颗粒样品:球形、椭圆形和圆柱形。研究重点是分析不同形状颗粒填料床的孔隙率及其对填料结构特性的影响。对局部堆积分数的分析表明,椭圆形和圆柱形颗粒样品在垂直堆积过程中减少了堆积的形成,沿 Z 方向的分布更加均匀。对这些非球形颗粒的配位数和径向分布函数分析表明,由于非球形颗粒的机械交错,颗粒之间的接触数量增加,颗粒分布紊乱。结果表明,球形度的偏差对粒子的密集堆积有积极影响,会产生更多的接触和更高的局部堆积分数。
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引用次数: 0
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