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REE Mineralization in Alkaline Rhyolites of the Pechalninskii Ore Field (Northeast Russia) Pechalninskii 矿田(俄罗斯东北部)碱性流纹岩中的 REE 成矿作用
IF 0.9 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2024-04-10 DOI: 10.1134/s1028334x24601469
A. V. Grigorieva, A.V. Volkov, N. V. Sidorova

Abstract

For the first time by the method of scanning electron microscopy, REE mineralization studies are conducted in alkaline rhyolites of the Pechalninskii ore field (Northeast Russia), a potentially large-volume source of HREEs. It is shown using the methods of electron microprobe analysis and cathodoluminescence that microcrystalline aggregates of pyroxenes and/or amphiboles in alkaline rhyolites contain the finest inclusions of REE segregations (5–7 µm). Using SEM, it is determined that the largest segregation is cerium phosphate. Concentrically zonal and radial-fibrous REE segregations are revealed in the relics of titanomagnetite crystals by EDS. The first ones are represented by silicates enriched with Y and REEs and the content of each REE varies regularly from the center to the edge. The radial-fibrous aggregates are represented by oxides and/or carbonates containing REEs (La, Ce, and Nd predominate). The results obtained can be used in the development of enrichment technology.

摘要首次采用扫描电子显微镜方法,对俄罗斯东北部佩查尔宁斯基矿区的碱性流纹岩进行了 REE 矿化研究,该矿区可能是 HREEs 的大量来源。使用电子微探针分析和阴极发光的方法表明,碱性流纹岩中的辉石和/或闪石微晶聚集体含有最细小的 REE 分离包裹体(5-7 微米)。利用扫描电子显微镜,可以确定最大的偏析物是磷酸铈。通过 EDS,在钛磁铁矿晶体遗迹中发现了集中的带状和径向纤维状 REE 偏析。前者以富含 Y 和 REE 的硅酸盐为代表,每种 REE 的含量从中心到边缘有规律地变化。径向纤维状聚集体由含有 REEs(主要是 La、Ce 和 Nd)的氧化物和/或碳酸盐组成。所获得的结果可用于开发富集技术。
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引用次数: 0
Composition and Thermochronology of Alkaline Granites of the Ingur Massif: The Problem of Detection of Factors Contributing to Formation of Rare-Metal Mineralization in Alkaline Granites of Western Transbaikalia 因古尔山脉碱性花岗岩的成分和热年代学:探测外贝加尔西部碱性花岗岩中稀有金属成矿因素的问题
IF 0.9 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2024-04-10 DOI: 10.1134/s1028334x24601342
D. A. Lykhin, V. V. Yarmolyuk, A. A. Vorontsov, L. O. Magazina

Abstract

The question of what factors contributed to the formation of rare metal mineralization in alkaline granites of Western Transbaikalia is considered. This work is based on the results of comparison of petro-geochemical characteristics of alkaline granitoids from the nearby ore-bearing Ingur and ore-free Sherbakhtinskii massifs. The rocks of these massifs form a common series of compositions with variations from syenites to alkaline granites (in the Sherbakhtinskii massif) and from alkaline granites to pegmatites (in the Ingur massif). The formation of this series of rocks is associated with a deep differentiation of the original magma common to both massifs, accompanied by a sequential decrease in the magnesium content and the accumulation of rare elements (Be, Ta, Nb, Th, U, HREEs) in residual melts. They reach the highest values in the pegmatites of the Ingur massif, in which rare metal mineralization appears. Its formation is associated with the fact that, according to the thermochronological studies, the Ingur massif was located in the temperature range from 900 to 500°C for 6 Ma. Such a long stay in the region of high temperatures was accompanied not only by deep differentiation of residual melts, but also stimulated fluid activity, which contributed to the redistribution and accumulation of ore elements in pegmatites.

摘 要 本文探讨了在西外贝加尔地区碱性花岗岩中形成稀有金属矿化的因素。这项工作基于对附近含矿的因古尔山和无矿的谢尔巴赫廷斯基山的碱性花岗岩的岩石地球化学特征的比较结果。这些山丘的岩石形成了一个共同的成分系列,从正长岩到碱性花岗岩(在 Sherbakhtinskii 山丘),从碱性花岗岩到伟晶岩(在 Ingur 山丘)。这一系列岩石的形成与两个山丘共同的原始岩浆的深度分异有关,同时伴随着镁含量的连续下降和残留熔体中稀有元素(Be、Ta、Nb、Th、U、HREEs)的积累。在因古尔山脉的伟晶岩中,稀有金属矿化物的含量达到了最高值。它的形成与以下事实有关:根据热年代学研究,英古尔山丘曾在 900 至 500°C 的温度范围内停留了 6 Ma。长时间处于高温区域,不仅伴随着残留熔体的深度分化,而且还刺激了流体活动,从而促进了伟晶岩中矿石元素的重新分布和积累。
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引用次数: 0
Ricker-wavelet-like Strain Waves in Shanxi Rift, North China: Atmospheric Loading Effect of the Squall Line 华北山西裂谷中的里克小波样应变波:湍流线的大气负荷效应
IF 0.9 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2024-04-10 DOI: 10.1134/s1028334x2360367x
Xiaolin Yang, Jinling Yang

Abstract

Deciphering the physical origin of transient crustal deformation is a difficult challenge in the field of continuous borehole observations of crustal movement because the relevant influencing factors of the phenomenon are extremely multifarious. In the Shanxi Rift, squall lines are a frequently occurring mesoscale convective system. Consequently, strain transients are always observed by the borehole dilatometer network within the Shanxi Rift; however, a fundamental understanding of the transient phenomena induced by squall lines remains elusive. To address this challenge, we adopted a second-order Butterworth band-pass filters (0.5–2 h) to retrieve the borehole volumetric deformations excited by a “dry” squall line from September 21, 2017, that occurred in the Shanxi Rift. The elastic loading of Ricker-wavelet-shaped atmospheric waves induced by squall line, which can cause the main signature of transient deformation to adopt a highly similar shape; this pressure-induced deformation process can last approximately 148–164 min and has a maximum magnitude of approximately 19 nstrain. This work of signal processing clearly identifies the crustal transient induced by a squall line and provides new insights into the origin of some short-lasting crustal deformations in the Shanxi Rift and elsewhere.

摘要 在地壳运动连续钻孔观测领域,破译瞬态地壳形变的物理起源是一项艰巨的挑战,因为该现象的相关影响因素极其多样。在山西断裂带,斜纹是一种频繁出现的中尺度对流系统。因此,山西大裂谷内的钻孔扩张仪网络总是能观测到应变瞬变;然而,对卷扬线所诱发的瞬变现象的基本认识却仍是空白。为了解决这一难题,我们采用了二阶巴特沃斯带通滤波器(0.5-2 h)来检索 2017 年 9 月 21 日发生在山西大裂谷的 "干 "暴风线所激发的钻孔体积变形。斜线诱发的Ricker-wavelet形大气波的弹性加载,可使瞬态变形的主要特征采用高度相似的形状;这一压力诱发的变形过程可持续约148-164 min,最大幅度约为19 nstrain。这项信号处理工作清楚地识别了由风切线诱发的地壳瞬变,为山西裂谷和其他地区一些短时地壳变形的起源提供了新的见解。
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引用次数: 0
Structure of the Ocean Floor in the Junction Area of King’s Trough and the Azores–Biscay Rise (North Atlantic) 国王海槽与亚速尔群岛-比斯开湾海隆交界区域(北大西洋)的洋底结构
IF 0.9 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2024-04-10 DOI: 10.1134/s1028334x24601275
S. G. Skolotnev, A. A. Peyve, K. O. Dobrolyubova, A. N. Ivanenko, I. S. Patina, V. A. Bogolyubskiy, V. N. Dobrolyubov, I. A. Veklich, S. A. Dokashenko, V. L. Lyubinetskiy, I. A. Ilyin

Abstract

The structure of King’s Trough and its surroundings (King’s mesostructural cluster), located on the eastern flank of the Mid-Atlantic Ridge in the North Atlantic, is described in this paper. This work is based on geological and geophysical data obtained during the 55th expedition of the R/V Akademik Nikolaj Strakhov. Six provinces were identified within the southeastern part of King’s Trough, based on the results of bathymetric survey. Each province has its own morphostructural feature resulting from multistage tectonic and volcanic processes, which alternate and conjugate with each other in time. According to seismoacoustic profiling data, three main types of seismic facies have been identified: (a) pelagic complexes; (b) deposits of turbidite flows; and (c) chaotic facies of gravity origin. It is shown that the anomalous magnetic field of the study area is the superposition of linear and isometric anomalies. The first were formed during the formation of the oceanic crust in the axial zone of spreading. The second are associated with volcanic massifs formed under intraplate conditions. The obtained data confirm the assumption that the formation of King’s Trough was preceded by the formation of an elongated arched rise, which became a scene of intense intraplate volcanism that increased from southeast to northwest. This stage was followed by subsidence of the axial part of the rise with the formation of King’s Trough and the Peake and Freen Troughs.

摘要 本文介绍了位于北大西洋大西洋中脊东侧的国王海槽及其周边地区(国王中层结构群)的结构。这项工作基于 Akademik Nikolaj Strakhov 号考察船第 55 次考察期间获得的地质和地球物理数据。根据水深测量结果,在国王海槽东南部确定了六个区域。每个区域都有自己的形态结构特征,这些特征是多阶段构造和火山过程造成的,在时间上相互交替和共轭。根据地震声剖面数据,确定了三种主要的地震剖面类型:(a) 水层复合体;(b) 湍流沉积;(c) 重力源混沌面。研究表明,研究区域的异常磁场是线性异常和等距异常的叠加。前者是在轴向扩张带的洋壳形成过程中形成的。第二种异常与板块内部条件下形成的火山丘陵有关。所获得的数据证实了这样一种假设,即在国王海槽形成之前,形成了一个拉长的弧形隆起,成为板内火山活动剧烈的场所,火山活动从东南向西北不断增加。在这一阶段之后,隆起的轴向部分下沉,形成了国王海槽、皮克海槽和弗林海槽。
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引用次数: 0
First Discovery of Paleoproterozoic Aillikite Dikes in Sarmatia: Geochemistry and Petrogenesis 在萨尔马特首次发现古新生代艾利克岩脉:地球化学和岩石成因
IF 0.9 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2024-04-10 DOI: 10.1134/s1028334x24601299
K. A. Savko, A. V. Samsonov, S. V. Tsybulyaev, N. S. Bazikov, E. Kh. Korish, R. A. Terentiev

Abstract

Aillikite dikes of carbonate–biotite composition, intersecting Paleoproterozoic banded iron formations, were discovered in the Kursk block of Sarmatia for the first time. Their age is 2.10–2.07 Ga. The aillikite dikes underwent epidote–amphibolite facies metamorphism (550°С, 2–3 kbar), and they are deformed and foliated. Primary magmatic olivine and pyroxene were not preserved. In terms of geochemistry, ultramafic lamprophyres of the Kursk block are similar to petrotypical aillikites. They are depleted in SiO2 and Al2O3 and enriched in MgO, TiO2, K2O, Cr, Ni, and Nb with highly fractionated LREE and HREE. The highly radiogenic neodymium isotopic composition is indicative of a juvenile enriched (metasomatized) mantle source of aillikites. Positive Nb and Ti anomalies suggest metasomatic alterations of the depleted lithosphere mantle by OIB melts under opening of the Tim back-arc basin. The aillikite dikes and carbonatites of the Dubravinsky complex could have been formed at different melting degrees of a single deep, lithospheric source, enriched in lithophile elements shortly before the melting episode, possibly in a suprasubduction setting about 2.1 Ga.

摘要 在萨尔马特的库尔斯克地块首次发现了碳酸盐-生物岩成分的沸石尖晶石,它们与古近纪带铁地层相交。它们的年龄为 2.10-2.07 Ga。闪长岩尖晶石经历了闪长岩-闪长岩面变质作用(550°С,2-3千巴),并发生了变形和褶皱。原生岩浆橄榄石和辉石没有保存下来。从地球化学角度来看,库尔斯克区块的超基性岩化石类似于典型的岩浆岩。它们的 SiO2 和 Al2O3 含量低,而 MgO、TiO2、K2O、Cr、Ni 和 Nb 含量高,LREE 和 HREE 分馏度高。高放射性钕同位素组成表明榴辉岩来源于幼年富集(变质)地幔。正的 Nb 和 Ti 异常表明,在 Tim 后弧盆地打开的情况下,OIB 熔体对贫化的岩石圈地幔进行了变质改造。Dubravinsky复合体的箭云母尖晶石和碳酸盐岩可能是在一个单一的深岩石圈源的不同熔融程度下形成的,在熔融前不久富含亲岩元素,可能是在大约2.1 Ga的超俯冲环境中形成的。
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引用次数: 0
Picrodolerite Dikes of the Naryn River: Age, Composition, and Position in the Geological History of Southern Tuva (Central Asian Orogenic Belt) 纳伦河的辉绿岩尖峰:图瓦南部地质历史(中亚造山带)中的年龄、成分和位置
IF 0.9 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2024-04-10 DOI: 10.1134/s1028334x24601287
V. V. Yarmolyuk, A. M. Kozlovsky, U. A. Moroz, A. V. Nikiforov

Abstract

New evidence of the Early Silurian sublithospheric magmatic activity in the eastern part of the Altai–Sayan orogen has been obtained. This activity occurred between large-scale mantle-derived magmatic episodes of the Middle–Late Ordovician and Devonian. It involved high-Mg (15–22 wt % MgO) picritic dolerite dikes of the Naryn complex in the western part of the Tuva–Mongolian Superterrane. The dike complex consists of simple picrodolerite dikes and those combined with a central picrodolerite zone and granitoids at contacts with mingling relationships between contrasting rocks. The picrodolerite geochemical signature is similar to enriched basalts of the mid-ocean ridges or intraplate regions and is indicative of a sublithospheric mantle source. Initial picrodolerite melts were formed at a depth of about 120–140 km, a temperature of 1600–1640°C, and a melting degree of up to 20% at a dry peridotite source. These values are consistent with the conditions of the hot spot magmas origin. Granitoids from the combined dikes had a crustal geochemical signature and were formed due to the anatexis of the Tuva–Mongolian Superterrane host rocks initiated by the picrodolerite intrusion. The U–Pb zircon age (SHRIMP-II) of leucogranite from the combined dike is 439 ± 3 Ma interpreted as the age of the Naryn dike complex. The Early Silurian mantle-derived magmatic activity of the Southeastern Tuva most likely caused the migration of the Siberian paleocontinent over the African mantle hot field.

摘要 获得了阿尔泰-萨彦造山带东部早志留纪岩石圈下岩浆活动的新证据。该活动发生在奥陶纪中晚期和泥盆纪大规模地幔岩浆活动之间。它涉及图瓦-蒙古超地层西部纳伦复合体的高镁(15-22 wt % MgO)辉绿岩尖晶石。该斜长岩复合体由简单的辉长岩斜长岩以及与中央辉长岩带和花岗岩相结合的斜长岩斜长岩组成,其接触点与对比强烈的岩石之间存在交融关系。辉绿岩的地球化学特征与大洋中脊或板内地区的富集玄武岩相似,表明其来源于岩石圈下地幔。最初的辉绿岩熔体是在大约120-140千米的深度、1600-1640摄氏度的温度和高达20%的熔化度下在干橄榄岩源形成的。这些数值与热点岩浆的成因条件一致。来自组合尖晶石的花岗岩具有地壳地球化学特征,是由picdolerite侵入体引发的图瓦-蒙古超特异性主岩的无性化作用形成的。来自组合堤的白榴石的 U-Pb 锆石年龄(SHRIMP-II)为 439 ± 3 Ma,被解释为纳伦堤复合体的年龄。图瓦东南部的早志留纪地幔岩浆活动很可能导致了西伯利亚古陆向非洲地幔热田的迁移。
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引用次数: 0
Lithosphere of the Northeastern Part of the Sarmatia Protocraton According to New Seismic Data 新的地震数据显示的萨尔马特原核东北部岩石圈
IF 0.9 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2024-04-10 DOI: 10.1134/s1028334x24601184
V. V. Adushkin, A. G. Goev, Yu. A. Vinogradov, A. V. Shapovalov

Abstract

Deep velocity models of the lithosphere of the Khoper Block and Losevskaya Suture Zone of the Voronezh crystalline massif of the Sarmatia Protocraton are obtained for the first time by the receiver function technique. The crust is determined by a four-layered structure with a waveguide in the lower part of the section. The presence of a zone of lower velocities in the upper mantle at depths of 110–150 km, which mark the mid-lithospheric discontinuity (MLD), as well as their characteristics, is identified for the first time for the Khoper Block. A complex, probably, gradient structure of the crustal–mantle transition is determined.

摘要 通过接收函数技术,首次获得了萨尔马特原核沃罗涅日结晶地块霍珀区块和洛舍夫斯卡娅缝合带岩石圈的深速度模型。地壳由四层结构组成,断面下部有波导。在 Khoper 区块,首次确定了上地幔 110-150 千米深处存在一个速度较低的区域,标志着岩石圈中部的不连续性及其特征。确定了地壳-地幔过渡的复杂梯度结构。
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引用次数: 0
Provenance and Depositional Environment of the Pliocene Sandstones from the Erlian Basin, North China 华北二连盆地上新世砂岩的成因与沉积环境
IF 0.9 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2024-04-10 DOI: 10.1134/s1028334x24600026
Fenquan Xie, Bing Hu, Ning Li, Haojie Xu, Hongda Luo, Xiongfei Wang, Chen Zhang

Abstract

The Erlian Basin is a Mesozoic–Cenozoic rift basin with a large thick Pliocene sandstones deposit, which has important oil, gas, and uranium resources exploration potential. The paleo-sedimentary environment plays an important role in controlling the development of mineral resource. However, provenance and depositional environment of the Pliocene sandstones remain enigmatic. To address it, this study reports the whole rock geochemical compositions of sandstones from the Youqi and Siziwangqi regions to reflect the paleo-sedimentary environment. The Youqi sandstones are classified as litharenite-arkose, whereas the Siziwangqi sandstones exhibit a graywacke affinity. Furthermore, both the Youqi and Siziwangqi sandstones exhibit low CIA, PIA, ICV, and Th/U values, suggesting that their source rocks were of great maturation and experienced low to moderate chemical weathering processes. The Ni/Co, U/Th, and Ce/Ce* values in these sandstones range from 0.4 to 5.9, 0.20 to 0.37, and 0.80 to 1.09, respectively, indicating that these sandstones were formed in an oxygen-rich depositional environment. Additionally, interelement ratios such as Sr/Cu, SiO2/Al2O3, and Rb/Sr suggest a hot and arid paleoclimate during the deposition of these sandstones. Tectonic discrimination diagrams reveal a continental arc environment for the studied sandstones, Combining regional structural background, implying that the Erlian Basin was influenced by both Himalayan and the Pacific-Ocean-surrounding tectonism during the Pliocene period.

摘要 二连盆地是中生代-新生代断裂盆地,具有大型厚上新世砂岩矿床,具有重要的油、气、铀资源勘探潜力。古沉积环境对矿产资源的开发起着重要的控制作用。然而,上新世砂岩的成因和沉积环境仍然是个谜。针对这一问题,本研究报告了尤旗和四子王旗地区砂岩的全岩地球化学成分,以反映古沉积环境。尤旗砂岩被归类为石英-黑云母岩,而四子王旗砂岩则表现为灰岩。此外,尤旗砂岩和四子王旗砂岩的 CIA 值、PIA 值、ICV 值和 Th/U 值都很低,这表明它们的源岩成熟度很高,经历了中低度的化学风化过程。这些砂岩中的 Ni/Co、U/Th 和 Ce/Ce* 值分别为 0.4 至 5.9、0.20 至 0.37 和 0.80 至 1.09,表明这些砂岩是在富氧沉积环境中形成的。此外,Sr/Cu、SiO2/Al2O3 和 Rb/Sr 等元素比值表明,这些砂岩沉积期间的古气候炎热而干旱。构造判别图揭示了所研究砂岩的大陆弧环境,结合区域构造背景,暗示二连盆地在上新世时期受到喜马拉雅和太平洋周边构造的影响。
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引用次数: 0
Crystallization Temperatures of Komatiitic Basalts from the Vetrenyi Belt, Karelia Based on the Alumina Partition between Olivine and Chromite 基于橄榄石和铬铁矿之间的氧化铝分区的卡累利阿 Vetrenyi 地带科马蒂蒂玄武岩的结晶温度
IF 0.9 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2024-04-10 DOI: 10.1134/s1028334x24601305
E. V. Asafov, A. N. Koshlyakova, A. V. Sobolev, D. P. Tobelko, N. N. Koshlyakova, S. V. Mezhelovskaya

Abstract

The Archean–Proterozoic transition in the Earth’s history is marked by significant changes in the mantle dynamics and temperature regimes. A notable consequence is the disappearance of Al-depleted komatiites in the Late Archean and an almost complete absence of Archean-typical peridotitic komatiites since the Proterozoic. This work presents a study of the 2.41 Ga komatiitic basalts from the Vetrenyi Belt, dating back to the early Proterozoic. Unique data on the compositions of olivine and chromite, as well as on the crystallization temperatures based on Al-in-olivine geothermometry for komatiitic basalts from the Vetrenyi Belt are provided. The temperatures of the earliest stages of crystallization were approximately 1240 ± 25°C, which indicates the occurrence of water in the melt and is consistent with measured water contents of 0.4 ± 0.2 wt % H2O in the melt inclusions. However, during crystallization, the komatiitic basalt melt underwent degassing, resulting in mass crystallization of the system and a temperature rise by ~20°C due to the release of the latent heat of crystallization. The degassing of water from the melt suggests crystallization under surface conditions.

摘要地球历史上阿新世-原生代的转变以地幔动力学和温度机制的重大变化为标志。一个显著的后果是晚阿新世贫铝岩的消失,以及自新生代以来几乎完全没有阿新世典型的橄榄岩。本研究对来自 Vetrenyi 带的 2.41 Ga 柯麦饭石玄武岩进行了研究,其年代可追溯到早新生代。该研究提供了关于橄榄石和铬铁矿成分的独特数据,以及基于 Al-in-olivine 测地热法得出的 Vetrenyi 带 komatiitic 玄武岩的结晶温度。结晶最早阶段的温度约为 1240 ± 25°C,这表明熔体中含有水,并与测得的熔体包裹体中 0.4 ± 0.2 wt % H2O 的含水量相符。然而,在结晶过程中,柯马蒂式玄武岩熔体发生了脱气,导致系统大量结晶,并由于结晶潜热的释放而使温度上升了约 20°C。熔体中水的脱气表明结晶是在地表条件下进行的。
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引用次数: 0
Secondary Mineral Resources in Dump Waters of the South Urals 南乌拉尔倾弃水域的二次矿产资源
IF 0.9 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2024-03-27 DOI: 10.1134/s1028334x24601196
R. F. Abdrakhmanov, V. N. Puchkov

Abstract

Natural studies of the South Urals hydromineral deposits, as well as the results of study of the ion and gaseous composition of underground waters, show that the liquid run-off from massive sulfide deposits of the region are promising serious deposits of secondary raw materials. The dump waters are mineral resources for rare metals, the contents of which are comparable with the average content of ores.

摘要 对南乌拉尔水矿物矿床的自然研究,以及对地下水离子和气体成分的研究结果表明,该地区块状硫化物矿床的液态流体是很有前途的二次原材料矿床。地下水是稀有金属的矿产资源,其含量与矿石的平均含量相当。
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引用次数: 0
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Doklady Earth Sciences
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