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Energetic, exergetic analysis and machine learning of methane chlorination process for methyl chloride production 甲烷氯化生产过程的能量分析和机器学习
IF 4.2 4区 环境科学与生态学 Q2 ENVIRONMENTAL STUDIES Pub Date : 2022-06-21 DOI: 10.1177/0958305X221109604
Raju Gollangi, K. Nagamalleswara Rao
Nowadays, with the growing demand for energy and effective utilization of various available sources with the exorable techniques and approaches to maximize the efficiency of energy systems. This work has developed the synthesis of Methyl chloride (MC) from the methane chlorination process using the ASPEN HYSYS simulation tool. A Searchable analysis has been done on thermodynamic derivatives (likely Energy, Exergy) to probation on the entire process. This analysis calculates all process components’ energy loss, destruction and energy, and exergy efficiencies. A heavier energy loss has been found at Reactor (ERV) with 1785.5 kW and exergy destruction of 18.8% share. Heat Exchanger Network (HEN) has energy loss (960.32kW) & exergy destruction (791.29kW). The proposed new retrofit sustainable model recovered the waste heat from the HEN and achieved energy efficiency of 87.6% and exergy efficiency of 87.3% of the total MC process. Four Machine learning models were developed for the reactor (ERV) process to predict exergy destruction. The artificial Neural network (ANN) gave good testing predictions, followed by the Random Forest (RF) with a determination coefficient (R2) of 0.999957 and 0.999981.
如今,随着能源需求的不断增长和各种可用资源的有效利用,可采用的技术和方法可以最大限度地提高能源系统的效率。本工作利用ASPEN HYSYS模拟工具开发了甲烷氯化过程中氯甲烷(MC)的合成。一个可搜索的分析已经完成了热力学衍生物(可能是能源,能源),以验证整个过程。该分析计算了所有过程组件的能量损失、破坏和能量,以及能源效率。反应堆(ERV)的能量损失更大,为1785.5 kW,火用损失占18.8%。热交换器网络(HEN)具有能量损失(960.32kW)和火用破坏(791.29kW)。提出的新改造可持续模式回收了HEN的废热,实现了整个MC过程的能源效率为87.6%和火用效率为87.3%。为反应器(ERV)过程开发了四个机器学习模型来预测火用破坏。人工神经网络(ANN)给出了较好的测试预测,其次是随机森林(RF),其决定系数(R2)分别为0.999957和0.999981。
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引用次数: 3
Photocatalytic membrane of TiO2/CNT decorated PAN nanofibers with enhanced performance under LED visible-light irradiation TiO2/CNT修饰PAN纳米纤维的光催化膜在LED可见光照射下性能增强
IF 4.2 4区 环境科学与生态学 Q2 ENVIRONMENTAL STUDIES Pub Date : 2022-06-20 DOI: 10.1177/0958305X221108494
Lathifah Puji Hastuti, A. Kusumaatmaja, A. Darmawan, I. Kartini
Incorporating TiO2 with CNTs and PAN nanofiber structures results in a photocatalytic membrane composite with an attractive response in the visible region. It offers an efficient process without post-treatment separation at the end of the photocatalytic treatment. The composite membranes were fabricated using electrospinning at 7 kV with 10 cm in the distance between needle tip and collector at a flow rate of 1 mL h−1. Polyacrylonitrile (PAN) was used as the polymer matrix. All the as-spun composites exhibited randomly oriented nanofibers. CNT increased the fiber diameters from 324 to 463 nm. The bandgap of TiO2 also shifted from 3.15 to 2.76 eV at the narrowest The color removal kinetics follow the Langmuir-Hinshelwood pseudo-first-order kinetics model with the highest rate constant of 0.0225 min−1 shown by PAN/TiO2/CNT 20%. More than 95% color removal of methylene blue after 100 min irradiation has been achieved using LED lamps of low energy visible light (43.5 W). Such a result is supposed to be the highest employing low energy lamps.
将TiO2与碳纳米管和PAN纳米纤维结构结合在一起,可以得到在可见光区域具有吸引响应的光催化膜复合材料。它提供了一个有效的过程,在光催化处理结束时没有后处理分离。复合膜的制备采用静电纺丝工艺,电流为7 kV,针尖与收集器之间距离为10 cm,流速为1 mL h−1。采用聚丙烯腈(PAN)作为聚合物基体。所有的纺丝复合材料都表现出随机取向的纳米纤维。碳纳米管将纤维直径从324纳米增加到463纳米。TiO2的带隙也从3.15 eV转变为2.76 eV,除色动力学符合Langmuir-Hinshelwood伪一阶动力学模型,PAN/TiO2/CNT的除色速率常数最高为0.0225 min−1,为20%。使用低能量可见光(43.5 W)的LED灯照射100分钟后,亚甲蓝脱色率达到95%以上。这样的结果应该是采用低能量灯的最高结果。
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引用次数: 1
Energy from livestock waste: Using circular economy and territorial intelligence to build sustainable businesses 畜禽废弃物能源:利用循环经济和地域智能建立可持续发展的企业
IF 4.2 4区 环境科学与生态学 Q2 ENVIRONMENTAL STUDIES Pub Date : 2022-06-19 DOI: 10.1177/0958305X221108495
R. Pereira, R. Salvador, Gabriel Fernandes Sales, Jonatas Santana Obal, C. M. Piekarski, A. D. de Francisco
Pig waste can be used to generate energy through biogas and has been gaining importance for being a renewable energy source. The resulting biogas can be used in many forms, such as to produce electricity and supply local networks using microgrids. This helps bring greater stability and energy security to local electricity supply networks. Under this light, this article aims to (i) report on socio-environmental impacts, (ii) present lessons learned (from a circular economy and territorial intelligence perspective), and (iii) point out future business opportunities of value recovery from waste in rural properties. To that end, a case study was carried out in a rural property in Paraná, Brazil. The authors conducted local visits and surveys, and consulted documents provided by the property owners about projects making use of biogas produced from pig waste and used to generate electricity. Different partnerships between the property and public and private bodies enable business opportunities arising from projects that range from the commercialization of carbon credits, decentralized energy generation, to sale of energy to the State's energy provider and establishing Microgrids. From those projects, direct and indirect environmental and social benefits are primarily related to the replacement of non-renewable energy with renewable energy from waste, and impacts avoided from the inadequate handling of pig waste. The results show that it is possible to explore the energy potential of rural properties, based on livestock waste, by developing partnerships with public and private actors, producing energy from biogas, from circular economy and territorial intelligence perspectives.
猪的粪便可以通过沼气产生能量,并且作为一种可再生能源已经变得越来越重要。由此产生的沼气可以以多种形式使用,例如发电和使用微电网为当地网络供电。这有助于提高当地电力供应网络的稳定性和能源安全性。在此背景下,本文旨在(i)报告社会环境影响,(ii)介绍经验教训(从循环经济和领土情报的角度),以及(iii)指出农村物业废物价值回收的未来商业机会。为此,在巴西帕拉纳的一处农村房产进行了案例研究。作者在当地进行了访问和调查,并查阅了业主提供的有关利用猪粪产生的沼气发电项目的文件。财产界与公共和私营机构之间的不同伙伴关系,使从碳信用额商业化、分散能源生产、向国家能源供应商出售能源和建立微电网等项目中产生的商业机会成为可能。从这些项目中,直接和间接的环境和社会效益主要与用废物中的可再生能源替代不可再生能源以及避免因猪废物处理不当而造成的影响有关。结果表明,通过与公共和私人行为体建立伙伴关系,从循环经济和领土情报的角度利用沼气生产能源,可以在牲畜废物的基础上探索农村财产的能源潜力。
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引用次数: 0
Conceptual design and feasibility study of industrial sludge-based biosolid fuel production facility 工业污泥基生物固体燃料生产装置的概念设计与可行性研究
IF 4.2 4区 环境科学与生态学 Q2 ENVIRONMENTAL STUDIES Pub Date : 2022-06-16 DOI: 10.1177/0958305X221108496
S. Sapmaz, İ. Kılıçaslan
Industrial sludge must be disposed of by incineration or storage methods. It is possible to produce energy by incinerating the sludge after drying. However, some sludges cannot be incinerated due to their low calorific value and/or high pollutant load. In this study, a novel process in which sludges with high calorific value and other sludges are mixed, dried and processed to produce solid fuel without using any additives is described. A technical and economic model of the process was established and feasibility analysis was carried out for different capacities. According to the results of the study, with the increase in capacity, the cost for the unit capacity and the return for the unit capacity increase. Most of the plant's income comes from waste disposal. When the investment is made with equity, the payback period is shorter than 2 years for wet feeding capacities of 1 ton/h and above. The cost of the investment increases more than 2 times when 50% of the investment cost is supplied by a bank loan. In this case, the payback period is also increasing. In order for the profitability of the facility to be sustainable, the composition and amounts of sludge produced in the region should be analysed. In this study, it is assumed that the types and amounts of waste that will come to the facility are capable of filling the facility's capacity and providing the required calorific value standards.
工业污泥必须用焚烧或贮存的方法处理。污泥干燥后焚烧可以产生能量。然而,有些污泥由于其低热值和/或高污染物负荷而不能焚烧。在本研究中,描述了一种不使用任何添加剂,将高热值污泥与其他污泥混合、干燥并加工成固体燃料的新工艺。建立了该工艺的技术经济模型,并对不同产能进行了可行性分析。研究结果表明,随着容量的增加,单位容量的成本和单位容量的收益都在增加。该厂的大部分收入来自废物处理。股权投资时,1吨/小时及以上湿给料能力投资回收期短于2年。如果投资成本的50%由银行贷款提供,投资成本将增加2倍以上。在这种情况下,投资回收期也在增加。为了使该设施的盈利能力可持续,应分析该地区产生的污泥的组成和数量。在本研究中,假定将进入该设施的废物的种类和数量能够填补该设施的容量并提供所需的热值标准。
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引用次数: 0
Effects of dust on the performance of solar panels – a review update from 2015–2020 粉尘对太阳能电池板性能的影响——2015-2020年更新回顾
IF 4.2 4区 环境科学与生态学 Q2 ENVIRONMENTAL STUDIES Pub Date : 2022-06-14 DOI: 10.1177/0958305X221105267
Rajni Saini, D. Saini, Rajeev Gupta, Piush Verma, RP Dwivedi, Ashwani Kumar, Diksha Chauhan, Sushil Kumar
Solar power plays a significant role in the contribution of energy worldwide. The performance of solar panels mainly depends upon geographical and environmental factors. Dust is an important well known ecological factor that significantly impacts the performance of solar panels in achieving the overall target of power production by renewable sources. Study about the performance of solar panels under the influence of dust particles becomes more effective when these are to be worked out in hot and dusty areas. The current goal of this review article is to provide the impact of dust particles on the performance of solar panels. To fulfil this goal, the researcher's contribution is updated in minor for 2015 to 2018 and signed for 2019 and 2020.The current authors of this review article also recommended the adoption of a modern cleaning technique for PV modules, which would save time because it could be operated away from the PV modules.
太阳能在全球能源贡献中扮演着重要的角色。太阳能电池板的性能主要取决于地理和环境因素。粉尘是一个重要的众所周知的生态因素,它显著影响太阳能电池板的性能,以实现可再生能源发电的总体目标。在炎热多尘地区对太阳能电池板进行研究,对太阳能电池板在尘埃颗粒影响下的性能研究更为有效。这篇综述文章的当前目标是提供尘埃颗粒对太阳能电池板性能的影响。为了实现这一目标,研究人员的贡献在2015年至2018年期间进行了次要更新,并在2019年和2020年签署。这篇综述文章的现任作者还建议采用现代的光伏组件清洁技术,这将节省时间,因为它可以远离光伏组件进行操作。
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引用次数: 0
Research on the impact of financial development in different regions on the decoupling of carbon emissions from economic growth 不同区域金融发展对碳排放与经济增长脱钩的影响研究
IF 4.2 4区 环境科学与生态学 Q2 ENVIRONMENTAL STUDIES Pub Date : 2022-06-14 DOI: 10.1177/0958305X221107341
Jieming Huang, L. Guo
The decoupling of carbon emissions has also become the dependence of countries’ development. Finance plays an important role in decoupling economic development from carbon emissions. This paper explores the impact of financial development in different regions on the decoupling of carbon emissions from economic growth, using the Tapio decoupling elastic model and the method of fully modified least squares (FMOLS) to study the impact of financial development on carbon emissions in six regional panels from 1995 to 2020: and Foreign direct investment (FDI), urbanization, population, and infrastructure as control variables. The results turn out that financial development will promote the decoupling of carbon emissions from economic growth in the ECA region. For EAP, SSA, AC, SA, and MENA regions, financial development will promote the growth of carbon emissions, and due to the different economic development dynamics of different countries, the positive effects of financial development on carbon emissions are heterogeneous. The impact of FDI, urbanization, and infrastructure on carbon emissions varies from region to region. The population will promote the growth of carbon emissions, regardless of the region. In addition, the ECA region is the most countries that has achieved the strong decoupling and is the first to realize the transition from weak decoupling to strong decoupling. Therefore,the ECA, EAP and AC region should accelerate the construction of a green financial system to promote the decoupling of economic growth and carbon emissions. The SSA, SA and MENA region should speed up the transformation of economic development mode and move towards weak decoupling or even strong decoupling.
碳排放的脱钩也成为各国发展的依赖。金融在经济发展与碳排放脱钩中发挥着重要作用。本文探讨了不同区域金融发展对碳排放与经济增长脱钩的影响,采用Tapio脱钩弹性模型和完全修正最小二乘(FMOLS)方法,研究了1995 - 2020年6个区域面板上金融发展对碳排放的影响,并以外商直接投资(FDI)、城市化、人口和基础设施为控制变量。研究结果表明,金融发展将促进ECA地区碳排放与经济增长脱钩。对于EAP、SSA、AC、SA和MENA地区,金融发展将促进碳排放的增长,由于不同国家的经济发展动态不同,金融发展对碳排放的积极影响具有异质性。FDI、城市化和基础设施对碳排放的影响因地区而异。无论在哪个地区,人口都会促进碳排放的增长。此外,非洲经委会地区是实现强脱钩最多的国家,也是最早实现弱脱钩向强脱钩过渡的国家。因此,ECA、EAP和AC地区应加快构建绿色金融体系,促进经济增长与碳排放的脱钩。撒哈拉以南非洲、撒哈拉以南非洲和中东和北非地区应加快转变经济发展方式,向弱脱钩乃至强脱钩方向发展。
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引用次数: 2
The propellant role of the mega-grid in regional economic growth: Evidence from China base on the panel smooth transition regression model 巨型电网对区域经济增长的推动作用:基于面板平滑过渡回归模型的中国证据
IF 4.2 4区 环境科学与生态学 Q2 ENVIRONMENTAL STUDIES Pub Date : 2022-06-12 DOI: 10.1177/0958305X221107339
Yongpei Wang, Z. Guan, Jia Wen Liang, Qian Zhang
One of the secrets for China's economic growth miracle is continuous investment in infrastructure, and the role of power infrastructure is irreplaceable. However, previous studies mostly focused on generation-side indicators rather than grid-side indicators, ignoring the importance of the mega-grid established in China. As a result, this paper is committed to exploring the economic growth pulling effect of power grids with different voltage levels in the nonlinear framework. On the premise of determining the robustness of estimation parameters by instrumental variable method, the panel smooth transition regression (PSTR) model is used to capture panel heterogeneity. To be exact, the regional economic growth driven by extra-high voltage (EHV) and ultra-high voltage (UHV) power grids presents a regime transition accompanied by the growth of regional power generation and electricity consumption per capita. This means that the mega-grid is more conducive to the economic growth of energy bases and load centers. To further build and improve the state-leveled mega-grid into a nationwide basic platform for trans-regional renewable energy transmission and distribution is a key measure to enhance China's sustainable economic growth under the constraints of carbon peak and carbon neutrality targets.
中国经济增长奇迹的秘诀之一,就是对基础设施的持续投入,而电力基础设施的作用是不可替代的。然而,以往的研究大多侧重于发电侧指标,而不是电网侧指标,忽视了中国建立特大电网的重要性。因此,本文致力于探讨在非线性框架下不同电压水平电网的经济增长拉动效应。在工具变量法确定估计参数稳健性的前提下,采用面板平滑过渡回归(PSTR)模型捕捉面板异质性。确切地说,特高压和特高压电网带动的区域经济增长,伴随着区域发电量和人均用电量的增长,呈现出一种制度变迁。这意味着大电网更有利于能源基地和负荷中心的经济增长。在碳峰值和碳中和目标约束下,进一步建设和完善国家级大电网,使其成为全国性的跨区域可再生能源输配基础平台,是促进中国经济可持续增长的关键举措。
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引用次数: 0
Impact and performance efficiency analysis of grid-tied solar photovoltaic system based on installation site environmental factors 基于安装现场环境因素的并网太阳能光伏系统影响及性能效率分析
IF 4.2 4区 环境科学与生态学 Q2 ENVIRONMENTAL STUDIES Pub Date : 2022-06-08 DOI: 10.1177/0958305X221106618
Saeed Iqbal, Shahid Nawaz Khan, M. Sajid, Jawad Khan, Y. Ayaz, A. Waqas
The performance of solar photovoltaic systems tends to decline if the operating conditions change from the nominal operating cell temperature due to environmental factors. The major factors include temperature and humidity variations, which cause thermal losses and open-circuit voltage drops in photovoltaic panels. This study investigates the correlations between solar photovoltaic performance and environmental factors by quantifying the real-time variables including temperature, humidity, dewpoint temperature, and heat index. Furthermore, the study investigates the difference between real-time measured and theoretically calculated temperature values with the help of weather station data to investigate the impact of temperature difference on the overall percentage power loss of the systems. The panels were installed at three distinct sites (rooftop, parking shed, and ground-mounted) connected to the same grid-tied system. Results reveal that the photovoltaic panel temperature has an inverse relation with the dew temperature and the humidity of the surrounding environment. The heat index value was found slightly less at the peak solar hours during the 24 h cycle of the measurement. The difference and relationship between temperature and humidity are measured and losses are highlighted based on the instantaneous occurrence of variables. Based on a difference between measured and calculated temperature values, results reveal that PV systems faced 27.95%, 5.41%, and 0.82% power losses for ground, roof, and parking installed PV systems, respectively.
由于环境因素的影响,太阳能光伏系统的工作条件从标称工作电池温度变化后,其性能有下降的趋势。主要因素包括温度和湿度的变化,这会导致光伏板的热损失和开路电压下降。本研究通过量化温度、湿度、露点温度和热指数等实时变量,探讨太阳能光伏性能与环境因素的相关性。此外,在气象站数据的帮助下,研究实时测量和理论计算的温度值之间的差异,以研究温差对系统总体功率损耗百分比的影响。这些面板安装在三个不同的地点(屋顶、停车棚和地面安装),连接到同一个并网系统。结果表明,光伏板温度与周围环境的露点温度和湿度呈反比关系。在24 h的测量周期中,热指数值在太阳活动高峰时值稍低。测量温度和湿度之间的差异和关系,并根据变量的瞬时发生突出显示损失。根据实测温度值与计算温度值的差异,结果表明,地面、屋顶和停车场安装的光伏系统分别面临27.95%、5.41%和0.82%的功率损耗。
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引用次数: 8
Greening South Asia with Financial Liberalization, Human Capital, and Militarization: Evidence from the CS-ARDL Approach 用金融自由化、人力资本和军事化来绿化南亚:来自CS-ARDL方法的证据
IF 4.2 4区 环境科学与生态学 Q2 ENVIRONMENTAL STUDIES Pub Date : 2022-06-06 DOI: 10.1177/0958305X221105863
Chien‐Chiang Lee, Farzan Yahya, Asif Razzaq
Green growth is recognized as an adequate mechanism to decelerate environmental turmoil. However, empirical evidence on what determines sustainable economic growth is still underexplored. Apprehending the importance of financial liberalization, human capital, and militarization in the South Asian region, we investigate their short- and long-run effects on green growth using data from 1990 to 2017. To address the cross-sectional dependency (CD) and heterogeneity issue, second-generation cointegration estimation techniques are employed. The findings show a stable and long-run relationship between financial liberalization, human capital, military expenditures, and green growth. The results of CS-ARDL also show the positive long-run effect of financial liberalization and human capital while the negative effect of militarization on green growth. Nonetheless, the interaction effects show the darker side of human capital and the brighter side of militarization in the presence of more financial openness. Results were further validated using the Augmented Mean Group (AMG) and Dumitrescu-Hurlin Granger causality test, highlighting the need to optimally utilize military expenditures, financial liberalization, and human capital for the sustainable growth of the region.
绿色增长被认为是减缓环境动荡的适当机制。然而,关于什么决定可持续经济增长的经验证据仍未得到充分探索。考虑到金融自由化、人力资本和军事化在南亚地区的重要性,我们利用1990年至2017年的数据研究了它们对绿色增长的短期和长期影响。为了解决横截面依赖性和异质性问题,采用了第二代协整估计技术。研究结果表明,金融自由化、人力资本、军事支出和绿色增长之间存在稳定的长期关系。CS-ARDL的结果还表明,金融自由化和人力资本对绿色增长具有积极的长期效应,而军事化对绿色增长具有消极的长期效应。然而,在金融开放程度提高的情况下,这种互动效应显示了人力资本的阴暗面和军事化的光明一面。使用增强均值组(AMG)和dumitrescue - hurlin Granger因果检验进一步验证了结果,强调了优化利用军事支出、金融自由化和人力资本以实现该地区可持续增长的必要性。
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引用次数: 4
The nexus of disaggregated energy sources and cement production carbon emission in China 分类能源与中国水泥生产碳排放的关系
IF 4.2 4区 环境科学与生态学 Q2 ENVIRONMENTAL STUDIES Pub Date : 2022-06-01 DOI: 10.1177/0958305X221102047
A. Alola, F. Bekun, T. Adebayo, G. Uzuner
Cement production reportedly accounts for the largest global materials flow, thus achieving global environmental sustainability through responsible consumption and production is central to the sustainable development scenario. But even that China, the world's largest carbon emitter and largest cement producer, is under-studied. Thus, the current study employed the nonlinear ARDL and frequency domain causality methods to unearth the contributory or mitigating role of energy sources and economic progress in China's cement carbon emission (CCE) over the period 1971-2020. Overall, the study establishes long-run equilibrium relationship between the study variables of interest Subsequently, the baseline regression suggests that a positive shift in economic growth, energy from fossil fuel and primary energy consumption all increase emissions while a negative shift does not have a significant effect on emissions. Moreover, a positive (negative) shift in renewable energy decreases (increases) emissions in both the short and long-run. The result of the Frequency Domain causality analysis resonates with the results of NARDL regression. As a policy, this study infers energy development and economic-related measures are strategically important in achieving sustainable cement production and consumption.
据报道,水泥生产占全球最大的材料流量,因此,通过负责任的消费和生产实现全球环境的可持续性是可持续发展设想的核心。但即便是中国这个世界上最大的碳排放国和最大的水泥生产国,也没有得到充分的研究。因此,本研究采用非线性ARDL和频域因果关系方法来揭示1971-2020年期间能源和经济发展对中国水泥碳排放(CCE)的促进或缓解作用。总体而言,本研究建立了研究变量之间的长期均衡关系。随后,基线回归表明,经济增长、化石燃料能源和一次能源消费的正转移都增加了排放,而负转移对排放没有显著影响。此外,从短期和长期来看,可再生能源的积极(消极)转变会减少(增加)排放。频域因果分析的结果与NARDL回归的结果一致。作为一项政策,本研究推断能源开发和经济相关措施对实现可持续水泥生产和消费具有重要的战略意义。
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引用次数: 1
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