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Regularities of Ion-Exchange Extraction of Anions 2(4)-Octylaminopyridines from Aqueous Media 从水介质中离子交换萃取阴离子 2(4)-Octylaminopyridines 的规律性
Pub Date : 2024-04-11 DOI: 10.21869/2223-1528-2024-14-1-161-174
L. S. Ageeva, N. V. Kuvardin, A. P. Shevchenko
Purpose of the study. Based on the results of the study of salts of 2(4)-octylaminopyridines (2(4)-OAP) by physical methods and their distribution in the two-phase system water-chloroform, establish the patterns of ion-exchange extraction of anions using aromatic amines.Methods. Chemical synthesis of 2(4)-OAP and their halides, spectrophotometry to determine the concentration of 2(4)-OAP in the aqueous and organic phase, characterization of 2(4)-OAP and their halides by IR, PMR and ESCA spectroscopy.Results. Synthesized by original methods and identified 2(4)-OAP and their halides. The distribution constants of 2-aminopyridine and 4-OAP salts with a singly charged anion in the water–chloroform two-phase system were determined. It is shown that the obtained constants increase in the following order: F-<Сl-
研究目的根据物理方法研究 2(4)-辛基氨基吡啶(2(4)-OAP)盐及其在水-氯仿两相体系中分布的结果,建立使用芳香胺离子交换萃取阴离子的模式。化学合成 2(4)-OAP 及其卤化物,用分光光度法测定 2(4)-OAP 在水相和有机相中的浓度,用红外光谱、PMR 光谱和 ESCA 光谱鉴定 2(4)-OAP 及其卤化物。采用原始方法合成并鉴定了 2(4)-OAP 及其卤化物。测定了 2-aminopyridine 和 4-OAP 盐与单电荷阴离子在水-氯仿两相体系中的分布常数。结果表明,所得常数按以下顺序增加:F-<Сl-
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引用次数: 0
Analysis of the Glycoside Composition of Calendula Extract 金盏花提取物糖苷成分分析
Pub Date : 2024-04-11 DOI: 10.21869/2223-1528-2024-14-1-175-191
K. F. Yankiv, M. S. Evdokimova, M. I. Gorelova
Purpose of research. The aim of the article is to comparatively analyse the glycoside (flavonoid) composition of liquid dosage forms containing calendula medicinalis as an initial raw material.Methods. To achieve this goal, methods for extracting medicinal plant materials were studied, scientific literature on the research topic was analyzed, qualitative and quantitative analysis was carried out, and the obtained UV spectra were examined. Obtaining liquid dosage forms from Calendula officinalis flowers was carried out using a Soxhlet extractor and the maceration method. The optimal conditions for the extraction of glycosides were determined by varying the ratio of raw materials and extractant, as well as the concentration of the extractant. For quantitative assessment, the content of extractive substances in the resulting dosage forms was calculated. Confirmation of the presence of flavonoid compounds was carried out using UV spectroscopy. A comparative analysis of the content of flavonoids in liquid dosage forms based on calendula officinalis was carried out.Results. As a result, liquid dosage forms were obtained from calendula officinalis flowers by two different methods, using different formulations, extraction was carried out by maceration and circulating extraction in a Soxlet apparatus, in ratios of 1:5 and 1:10, different concentrations of ethyl alcohol were also used (40%, 70%, 96%). Optimal extraction conditions were determined – for this raw material, the best indicators were achieved when obtaining the dosage form using the Soxlet extractor, in addition, according to the experiment, the concentration of ethyl alcohol, which extracts more target components, is 70%, the most effective ratio is 1:5.Conclusion. The study examined changes in the glycosidic (flavonoid) composition in dosage forms prepared independently according to various recipes and drugs obtained in pharmaceutical production. The use of flavonoid extraction methods provides a great opportunity for further scientific research into the extraction of dietary supplements for the purpose of their production.
研究目的本文旨在比较分析以金盏花为初始原料的液体制剂中的苷类(黄酮类)成分。为实现这一目标,研究了提取药用植物材料的方法,分析了有关研究课题的科学文献,进行了定性和定量分析,并对获得的紫外光谱进行了检验。使用索氏提取器和浸渍法从金盏花中提取液体制剂。通过改变原料和萃取剂的比例以及萃取剂的浓度,确定了萃取苷类的最佳条件。为了进行定量评估,计算了所得剂型中萃取物质的含量。使用紫外光谱法确认黄酮类化合物的存在。对基于金盏花的液体制剂中黄酮类化合物的含量进行了比较分析。通过两种不同的方法,使用不同的配方,从金盏花中获得了液体制剂。确定了最佳提取条件--对于这种原料,使用索氏提取器获得剂型时指标最佳,此外,根据实验,提取目标成分较多的乙醇浓度为 70%,最有效的比例为 1:5。本研究考察了根据各种配方独立制备的剂型和药品生产中获得的药物中糖苷(黄酮)成分的变化。黄酮提取方法的使用为进一步科学研究膳食补充剂的提取生产提供了很好的机会。
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引用次数: 0
Mesomorphism and Tribotechnical Characteristics of Lubricant Compositions with Mesogenic Additives Carboxylates Cu(II) 含有介生添加剂羧酸铜(II)的润滑油组合物的介形性和摩擦技术特性
Pub Date : 2024-04-11 DOI: 10.21869/2223-1528-2024-14-1-150-160
L. V. Elnikova, A. T. Ponomarenko, V. G. Shevchenko
The purpose of the work is to characterize the lubricants based on Llitol-24 and synthetic solidol with additives copper(II) carboxylates when using them in friction nodes in loading conditions and temperature. The lubricant compositions with additives copper(II) carboxylates based on synthetic solidol and Litol-24 form the columnar mesophases depending on thermodynamical conditions and concentration of additives.Methods. We study the lubricant compositions with dielectric spectroscopy and и polarization light microscopy. The studies lubricant compositions are tested on the frictional machines by preceding authors, which performed their synthesis and numerical estimations for their geometry parameters. It is shown, that the columnar mesophase formed by the compositions with copper(II) carboxylates simulates favourable tribological conditions for lubrication (reduction of the friction coefficient at the appointed range of additive concentrations and reduction of wear) and unlike to crystalline phases, shows orientation effects at the surface of interacting surfaces of machine elements and devices. These factsmotivate the study of influence of physicochemical properties and composition on mesomorphism of considered lubricant compositions.Results. In our measurements, we found the main dielectric characteristics of two kinds of the lubricant compositions: dielectric constant and dielectric loss, electroconductivity, dissipation factor, the Arrhenius functions are plotted, and the activation energies of the lubricant compositions we study are calculated. The microphotogram for textures of the lubricant compositions depending on temperature and concentrations are received. The differences in mesomorphic properties of the lubricant compositions with additives Cu(II) valerate and isovalerate are confirmed.The conclusion of the work is that the composition of the lubricant is optimized by the choice of additive concentration, the length of the mesogenic chain of the copper(II) carboxylate molecule and its conformation.
这项工作的目的是在加载条件和温度下将含有添加剂羧酸铜(II)的基于利多-24和合成固醇的润滑剂用于摩擦节点时对其进行表征。根据热力学条件和添加剂浓度的不同,基于合成固醇和 Litol-24 的添加剂羧酸铜(II)的润滑剂组合物会形成柱状介相。我们使用介电光谱和偏振光显微镜研究了润滑剂成分。所研究的润滑剂成分已由前人在摩擦机器上进行了测试,并对其几何参数进行了合成和数值估算。结果表明,羧酸铜(II)组合物形成的柱状介相模拟了有利的摩擦学润滑条件(在指定的添加剂浓度范围内降低摩擦系数并减少磨损),与结晶相不同的是,柱状介相在机器元件和设备的相互作用表面上显示出取向效应。这些事实促使我们研究物理化学特性和成分对所考虑的润滑剂成分的介观形态的影响。在测量中,我们发现了两种润滑剂成分的主要介电特性:介电常数和介电损耗、电导率、耗散因子,绘制了阿伦尼乌斯函数,并计算了我们所研究的润滑剂成分的活化能。我们还收到了润滑剂成分质地随温度和浓度变化的微光图。这项研究的结论是,润滑剂成分可通过选择添加剂浓度、羧酸铜(II)分子的中链长度及其构象进行优化。
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引用次数: 0
Study of the Fenton Oxidative Reaction on a Culture of Human Fibroblast Cells Incubated with Ablated CeO2 Particles 用消融 CeO2 粒子培养人成纤维细胞的芬顿氧化反应研究
Pub Date : 2024-04-11 DOI: 10.21869/2223-1528-2024-14-1-115-127
M. A. Pugachevskii, A. A. Kryukov, S. A. Dodonova, E. Artyushkova, V. A. Mamontov, V. V. Rodionov
Purpose. Study of the bioprotective properties of ablated cerium dioxide nanoparticles in relation to immortalized human fibroblasts under conditions of oxidative stress caused by the Fenton reaction.Methods. Cerium dioxide nanoparticles with pronounced antioxidant properties were obtained using laser ablation. The average maximum sizes of ablated particles of oxidized cerium in non-centrifuged and centrifuged at a speed of 1000 rpm nanodispersed aqueous solutions were revealed using the method of atomic force microscopy. The spectrophotometric method revealed that ablated cerium dioxide nanoparticles exhibit antioxidant properties and prevent the degradation of the methylene blue dye during the Fenton reaction. Cell culture samples were mapped using scanning electron microscopy using an energy-dispersive attachment after their incubation with ablated cerium dioxide nanoparticles. Using MTT analysis, the effect of ablated cerium dioxide nanoparticles on the survival of BJ TERT cell culture in the Fenton reaction was studied. Non-centrifuged and centrifuged at a speed of 1000 rpm nanodispersed solutions of oxidized cerium were used. The antioxidant activity of cerium dioxide nanoparticles after 6- and 24-hour incubation was studied.Results. The average limiting sizes of ablated cerium dioxide nanoparticles have been established, the values of which are (61,95±0,1) nm for a non-centrifuged aqueous solution and (56,59±0,1) nm for an aqueous solution centrifuged at a microcentrifuge speed of 1000 rpm. It was revealed that in the presence of ablated cerium dioxide nanoparticles, the degree of oxidative degradation of methylene blue during the Fenton reaction was significantly reduced. It was found that with an increase in the concentration of ablated cerium dioxide nanoparticles from 20 to 1000 mg/l, their antioxidant effect increased. From the obtained SEM images of cell cultures with ablated cerium dioxide nanoparticles, it follows that the nanoparticles are captured by cells during incubation and can have a significant effect on oxidative processes during the Fenton reaction. Statistical analysis based on the results of the MTT assay showed that 6-hour and 24-hour incubation with ablated cerium dioxide nanoparticles had a pronounced protective effect on the BJ TERT cell line.Conclusion. This work shows that during the Fenton reaction, cerium dioxide nanoparticles prevent the oxidative degradation of the methylene blue dye. When immortalized human fibroblasts are incubated, ablated cerium oxide nanoparticles are taken up by the cells and have a significant protective effect on them in the oxidative reaction. The high antioxidant activity of nanoparticles is determined by the high content of functional defects on the surface of nanoparticles obtained under sharply nonequilibrium conditions of laser ablation.
目的在芬顿反应引起的氧化应激条件下,研究烧蚀的二氧化铈纳米颗粒对永生人成纤维细胞的生物保护特性。利用激光烧蚀技术获得了具有明显抗氧化特性的二氧化铈纳米粒子。利用原子力显微镜方法显示了未离心和离心转速为 1000 rpm 的纳米分散水溶液中氧化铈烧蚀颗粒的平均最大尺寸。分光光度法显示,烧蚀的二氧化铈纳米粒子具有抗氧化特性,可防止亚甲基蓝染料在芬顿反应中降解。细胞培养样本与烧蚀的二氧化铈纳米粒子一起培养后,使用扫描电子显微镜和能量色散附件对其进行了绘图。通过 MTT 分析,研究了烧蚀的二氧化铈纳米粒子对 BJ TERT 细胞培养物在芬顿反应中存活的影响。使用了未离心和离心转速为 1000 rpm 的氧化铈纳米分散溶液。研究了纳米二氧化铈颗粒在 6 小时和 24 小时培养后的抗氧化活性。已确定烧蚀的二氧化铈纳米粒子的平均极限尺寸,未离心的水溶液为(61,95±0,1)纳米,以 1000 rpm 的微离心机转速离心的水溶液为(56,59±0,1)纳米。结果表明,在烧蚀二氧化铈纳米粒子的存在下,亚甲基蓝在芬顿反应中的氧化降解程度显著降低。研究发现,随着烧蚀二氧化铈纳米粒子浓度从 20 毫克/升增加到 1000 毫克/升,其抗氧化效果也随之增加。从获得的带有烧蚀二氧化铈纳米粒子的细胞培养物的扫描电镜图像来看,纳米粒子在培养过程中被细胞捕获,并在芬顿反应过程中对氧化过程产生显著影响。根据 MTT 试验结果进行的统计分析显示,用烧蚀的二氧化铈纳米粒子孵育 6 小时和 24 小时对 BJ TERT 细胞系有明显的保护作用。这项研究表明,在芬顿反应过程中,纳米二氧化铈颗粒能阻止亚甲基蓝染料的氧化降解。在培养永生人成纤维细胞时,烧蚀的氧化铈纳米粒子会被细胞吸收,并在氧化反应中对细胞产生显著的保护作用。纳米粒子的高抗氧化活性是在激光烧蚀的急剧非平衡条件下获得的纳米粒子表面的高功能缺陷含量决定的。
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引用次数: 0
Ionization Processes of Negative Corona Discharge Part 1. Review and Experiment 负电晕放电的电离过程,第 1 部分。回顾与实验
Pub Date : 2024-04-11 DOI: 10.21869/2223-1528-2024-14-1-128-149
A. I. Zhakin, A. E. Kuzko
The purpose of the research is an experimental study of physical processes in the near-electrode zones of negative point electrodes in an electronegative gas (air) under the condition of a high-voltage field.Methods. Video image analysis, current-voltage characteristics measurements, and spectroscopy are used. The current-voltage characteristics of the corona discharge ignition voltage in the environment are measured, the problem of experimental identification of surface charges, the mechanism of negative corona discharge ignition, and the ionic structure of streamers is studied, degradation of electrodes during negative corona discharge, spectrum of corona discharge creation and electromagnetic sound.Results. It is shown that at small radii of curvature of needle electrodes, the development of a negative corona discharge is due to the cold emission of electrons, and on flat and slightly curved negative electrodes, due to the capture of surface electrons by electron-withdrawing molecules. The mechanism of ignition of a corona discharge in an electronegative gas with a negative needle, the structure of streamers from negative needles, the emission spectrum and ethonic degradation of electrodes have been studied.Conclusions. The ignition of a negative corona discharge at small radii of the tips of the pointed needles (ro less than tens of microns) is due to the cold emission of electrons followed by impact ionization of neutral molecules. With slightly curved electrodes, the appearance of a negative corona discharge is due to the capture of surface electrons by electronegative gas molecules with subsequent plasma-chemical reactions. The formation of surface electrons depends on many factors: the presence and structure of oxide films (roughness, defects, etc.), which determine the electron work function and form local fields at the tips of microtips. The appearance of a corona discharge leads to degradation of the corona electrodes, expressed in the spraying of the tips of the points and the melting of the needles. In the dark region of the negative corona discharge (U < U*), photons in the in the ultraviolet spectrum (UV spectrum) are emitted, and when U > U*, in addition to UV photons, photons in the visible region of the spectrum are emitted. Glow fluctuations are caused by the chaotic dynamics of the formation of injection centers (melted tubercles - ectons) on the surface of the corona electrode. The ignition of a corona discharge is accompanied by sound emission with a frequency of about 300 Hz.
研究目的是对负电性气体(空气)中负点电极近电极区在高压场条件下的物理过程进行实验研究。方法:采用视频图像分析、电流电压特性测量和光谱分析。测量了环境中电晕放电点火电压的电流-电压特性,研究了表面电荷的实验鉴定问题、负电晕放电点火机理、流线的离子结构、负电晕放电过程中电极的退化、电晕放电产生的光谱和电磁声。结果表明,在小曲率半径的针状电极上,负电晕放电的产生是由于电子的冷发射,而在平坦和略微弯曲的负电极上,负电晕放电的产生是由于表面电子被电子吸收分子捕获。研究了负针负电性气体中电晕放电的点燃机制、负针流线的结构、发射光谱和电极的乙烯退化。在尖针顶端半径较小(ro 小于数十微米)的情况下,负电晕放电的点燃是由于电子的冷发射,然后是中性分子的撞击电离。在电极略微弯曲的情况下,负电晕放电的出现是由于负电气体分子捕获表面电子,随后发生等离子体化学反应。表面电子的形成取决于许多因素:氧化膜的存在和结构(粗糙度、缺陷等),这些因素决定了电子功函数,并在微尖端形成局部场。电晕放电的出现会导致电晕电极退化,表现为针尖喷射和针头熔化。在负电晕放电的暗区(U < U*),会发出紫外光谱(UV 光谱)中的光子;当 U > U* 时,除了 UV 光子外,还会发出可见光谱中的光子。辉光波动是由电晕电极表面形成的注入中心(熔化小瘤--ectons)的混乱动力学引起的。电晕放电点火时会发出频率约为 300 赫兹的声音。
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引用次数: 0
Mechanical Properties and Corrosion Resistance of Hot-Pressed Dysprosium Molybdate Samples 热压钼酸镝样品的力学性能和耐腐蚀性能
Pub Date : 2024-04-10 DOI: 10.21869/2223-1528-2024-14-1-19-29
Z. Eremeeva, G. H. Sharipzyanova, V. V. Levina
The purpose of this work was to study the consolidation features using hot pressing method of dysprosium molybdate billets and to study their mechanical properties and corrosion resistance.Methods. The technological and physical properties of the mechanosynthesised dysprosium molybdate powder were investigated. Properties and structure of the obtained dysprosium molybdate powder were studied by methods of chemical and X-ray phase analyses and scanning electron microscopy. Bulk density of dysprosium molybdate powder was studied according to GOST 19440-94. Flowability of dysprosium molybdate powder was determined according to GOST 20899-75. The specific surface of dysprosium molybdate was determined using a specific surface analyser NOVA 1200e (USA) by the method of low-temperature nitrogen adsorption (BET). X-ray phase analysis of mechanosynthesised dysprosium molybdate powder was carried out on a diffractometerResults. The bending strength of hot-pressed dysprosium molybdate specimens was determined, it was found that the highest value of the bending strength was recorded for these specimens at a pressing pressure of 35 MPa and is 314 MPa. The corrosion resistance of hot-pressed dysprosium molybdate samples in aqueous coolant at a temperature of 100 °C was studied. It was recorded that the mass of the mechanosynthesised dysprosium molybdate specimens remained practically unchanged throughout the corrosion resistance test in aqueous coolant.Conclusion. Tests on corrosion resistance have shown absence of change of mass of samples from dysprosium molybdate during 60 hours. The bending strength of samples from dysprosium molybdate obtained by hot pressing at pressure 35 Pa, temperature 1400 oÑ and time of holding under pressure 5 min is 314 MPa.
这项工作的目的是利用热压法研究钼酸镝坯料的固结特征,并研究其机械性能和耐腐蚀性。研究了机械合成钼酸镝粉末的技术和物理特性。通过化学分析、X 射线相分析和扫描电子显微镜等方法研究了获得的钼酸镝粉末的性能和结构。根据 GOST 19440-94 标准研究了钼酸镝粉末的体积密度。钼酸镝粉末的流动性是根据 GOST 20899-75 测定的。使用比表面分析仪 NOVA 1200e(美国),采用低温氮吸附法(BET)测定了钼酸镝的比表面。在衍射仪上对机械合成的钼酸镝粉末进行了 X 射线相分析。测定了热压钼酸镝试样的抗弯强度,发现这些试样在压制压力为 35 兆帕时的抗弯强度值最高,为 314 兆帕。研究了热压钼酸镝试样在温度为 100 °C 的水冷却液中的耐腐蚀性。根据记录,在水性冷却剂中进行耐腐蚀性试验的整个过程中,机械合成的钼酸镝试样的质量几乎保持不变。耐腐蚀性试验表明,钼酸镝试样在 60 小时内的质量没有变化。在压力为 35 Pa、温度为 1400 oÑ、保压时间为 5 分钟的条件下进行热压,钼酸镝样品的抗弯强度为 314 MPa。
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引用次数: 0
Study of Raman Scattering of Light in Liquid Arenes and Their Halogen-Substituted ones in the Low-Frequency Region of the Spectrum 光谱低频区液态烯类及其卤代烯类中的光拉曼散射研究
Pub Date : 2024-04-10 DOI: 10.21869/2223-1528-2024-14-1-88-103
G. Melnikov, N. M. Ignatenko, L. Petrova, A. Gromkov, O. Manzhos
Purpose. Investigation of Raman scattering of light in liquid arenas and their halogenated ones in the low-frequency range of the spectrum, taking into account the clustering processes in their structure.Methods. Raman spectroscopy methods were used, as well as a modeling method using cluster representations of the structure of liquids. Raman spectra of light in the low-frequency range from 17 to 500 cm–1 were obtained using a LabRAM HR Evolution spectrometer at room temperature (23°C).Results. The analysis of theoretical and experimental work on the properties of dimeric configurations of benzene and on the effect of clustering processes in substances on their IR and Raman spectra is carried out. Low-frequency Raman spectra of liquid benzene, o-xylene, ethylbenzene, fluorobenzene, chlorobenzene, brombenzene, toluene, o-fluorotoluene, m-fluorotoluene, p-fluorotoluene, o-chlorotoluene, m-chlorotoluene, p-chlorotoluene, 2,4-dichlorotoluene, 2,6-dichlorotoluene were obtained. The model of formation and disintegration of cluster formations has been tested. Formulas have been obtained for estimating the minimum frequency of libration oscillations of the ωmin dimer formation in the cluster structure and the position of the maxima of spectral bands in the low-frequency region of the Raman spectrum, depending on the number of particles included in the cluster formations. The theoretical results obtained by ωmin are in satisfactory agreement with the experimental data within the total error.The proposed model makes it possible to predict the position of some spectral bands of the Raman spectrum. The presence of other spectral bands is obviously related to the multiparticle interaction in the cluster structure and requires additional research.Conclusion. The proposed model of formation and decay of cluster formations and the relations following from it allow us to estimate the value of the minimum frequency in the low-frequency range of the Raman spectrum of liquid arenes and their halogenated ones from the known values of the enthalpy of formation and the moment of inertia of the dimer. Conversely, using known values of the minimum frequency, the values of the enthalpy of formation and the moment of inertia of the dimer can be estimated without resorting to complex quantum mechanical calculations.
目的。考虑到液体结构中的聚类过程,研究光谱低频范围内液体场及其卤化场中的光拉曼散射。使用了拉曼光谱方法以及使用液体结构聚类表示的建模方法。在室温(23°C)下使用 LabRAM HR Evolution 光谱仪获得了 17 至 500 cm-1 低频范围内的拉曼光谱。对有关苯的二聚构型特性以及物质中的聚类过程对其红外光谱和拉曼光谱的影响的理论和实验工作进行了分析。获得了液苯、邻二甲苯、乙苯、氟苯、氯苯、溴苯、甲苯、邻氟甲苯、间氟甲苯、对氟甲苯、邻氯甲苯、间氯甲苯、对氯甲苯、2,4-二氯甲苯、2,6-二氯甲苯的低频拉曼光谱。测试了聚类形成和解体的模型。根据团簇结构中包含的粒子数量,得到了估计团簇结构中 ωmin 二聚体形成的最小振荡频率和拉曼光谱低频区光谱带最大值位置的公式。在总误差范围内,ωmin 得出的理论结果与实验数据的一致性令人满意。其他光谱带的存在显然与团簇结构中的多粒子相互作用有关,需要进一步研究。根据所提出的团簇形成和衰减模型及其相关关系,我们可以根据已知的形成焓值和二聚体惯性矩,估算出液态烯烃及其卤代烯烃拉曼光谱低频范围内的最小频率值。相反,利用已知的最低频率值,可以估算出二聚体的形成焓和惯性矩,而无需进行复杂的量子力学计算。
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引用次数: 0
Effect of Ce3+ Concentration and YAG Crystal Particles Size on Photoluminescence Ce3+ 浓度和 YAG 晶体颗粒尺寸对光致发光的影响
Pub Date : 2024-04-10 DOI: 10.21869/2223-1528-2024-14-1-59-75
Е. А. Novikov, A. P. Kuzmenko, V. V. Rodionov, V. M. Emelyanov, D. P. Anikin, Y. A. Neruchev
Purpose of research. Determine the effect on the photoluminescence of phosphors from yttrium-aluminum garnet activated by cerium ions Ce3+, the size of its particles and the concentration of cerium ions in them.Methods. Structural electron and confocal microscopic, fluorescent, microspectral studies using a laser lex = 473 nm as an excitation source, energy dispersive, X-ray diffraction studies, as well as goniophotometric measurements on the radial distribution of light intensity excited by the LED matrix were carried out.Results. A detailed granulometric analysis of the particle sizes of phosphors was carried out for two samples from different manufacturers, cumulative distributions M(d) were constructed and their quantiles were established. Based on the results of measuring photoluminescence from individual particles in the compositions of phosphors based on YAG:Ce3+, a Stokes shift was detected in these samples: short-wavelength – for particles with sizes less than 10 μm and with low concentration and long-wavelength – with sizes greater than 10 μm with an increased concentration of over ~0.2% . The obtained microspectral size-emission dependences lem(d) and energy Imax(d) were consistent with the description based on the proposed physical mechanism of their formation by the 5d → 2F5/2 and 5d → 2F7/2 transitions.Conclusion. A short-wavelength shift of photoluminescence intensity maxima for particles smaller than 10 μm was discovered, due to a significant increase in the influence of surface stresses due to a reduction in the number of atoms. For larger particle sizes, the characteristic photoluminescence intensity maxima cease to depend on the wavelength. The radial distribution of luminous intensity determined by the goniophotometric method made it possible to calculate the value of the luminous flux equal to 1350 lm and 1140 lm, respectively, for LED matrices containing 8 LEDs with the studied phosphors.
研究目的确定铈离子 Ce3+ 对钇铝石榴石活化荧光粉光致发光的影响、其颗粒的大小以及其中铈离子的浓度。方法:使用波长为 473 nm 的激光作为激发光源,进行结构电子显微镜和共聚焦显微镜、荧光、微光谱研究,能量色散、X 射线衍射研究,以及对 LED 矩阵激发的光强度的径向分布进行测角光度测量。对来自不同制造商的两个样品的荧光粉粒度进行了详细的粒度分析,构建了累积分布 M(d),并确定了其定量值。根据对基于 YAG:Ce3+ 的荧光粉成分中单个颗粒的光致发光的测量结果,在这些样品中检测到了斯托克斯偏移:短波长--粒径小于 10 μm 且浓度较低的颗粒;长波长--粒径大于 10 μm 且浓度超过 ~0.2% 的颗粒。所获得的微光谱尺寸-发射依赖性 lem(d) 和能量 Imax(d) 与基于 5d → 2F5/2 和 5d → 2F7/2 转变形成的物理机制的描述一致。发现小于 10 μm 的颗粒的光致发光强度最大值会发生短波长偏移,这是由于原子数量减少导致表面应力的影响显著增加。对于较大尺寸的颗粒,特征光致发光强度最大值不再取决于波长。通过测角光度法确定的发光强度径向分布,可以计算出包含 8 个使用所研究荧光粉的 LED 矩阵的光通量值分别为 1350 lm 和 1140 lm。
{"title":"Effect of Ce3+ Concentration and YAG Crystal Particles Size on Photoluminescence","authors":"Е. А. Novikov, A. P. Kuzmenko, V. V. Rodionov, V. M. Emelyanov, D. P. Anikin, Y. A. Neruchev","doi":"10.21869/2223-1528-2024-14-1-59-75","DOIUrl":"https://doi.org/10.21869/2223-1528-2024-14-1-59-75","url":null,"abstract":"Purpose of research. Determine the effect on the photoluminescence of phosphors from yttrium-aluminum garnet activated by cerium ions Ce3+, the size of its particles and the concentration of cerium ions in them.Methods. Structural electron and confocal microscopic, fluorescent, microspectral studies using a laser lex = 473 nm as an excitation source, energy dispersive, X-ray diffraction studies, as well as goniophotometric measurements on the radial distribution of light intensity excited by the LED matrix were carried out.Results. A detailed granulometric analysis of the particle sizes of phosphors was carried out for two samples from different manufacturers, cumulative distributions M(d) were constructed and their quantiles were established. Based on the results of measuring photoluminescence from individual particles in the compositions of phosphors based on YAG:Ce3+, a Stokes shift was detected in these samples: short-wavelength – for particles with sizes less than 10 μm and with low concentration and long-wavelength – with sizes greater than 10 μm with an increased concentration of over ~0.2% . The obtained microspectral size-emission dependences lem(d) and energy Imax(d) were consistent with the description based on the proposed physical mechanism of their formation by the 5d → 2F5/2 and 5d → 2F7/2 transitions.Conclusion. A short-wavelength shift of photoluminescence intensity maxima for particles smaller than 10 μm was discovered, due to a significant increase in the influence of surface stresses due to a reduction in the number of atoms. For larger particle sizes, the characteristic photoluminescence intensity maxima cease to depend on the wavelength. The radial distribution of luminous intensity determined by the goniophotometric method made it possible to calculate the value of the luminous flux equal to 1350 lm and 1140 lm, respectively, for LED matrices containing 8 LEDs with the studied phosphors.","PeriodicalId":117184,"journal":{"name":"Proceedings of the Southwest State University. Series: Engineering and Technology","volume":"15 12","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140716310","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of the Elemental Composition of Titanium Metal Waste by X-Ray Fluorescence Analysis 通过 X 射线荧光分析研究金属钛废料的元素组成
Pub Date : 2024-04-10 DOI: 10.21869/2223-1528-2024-14-1-8-18
E. Ageev, E. P. Novikov, V. О. Pereverzev, A. Ageeva
The purpose of this work was to study the elemental composition of titanium metal waste to be processed by the method of electroerosive dispersion into spherical powders suitable for additive manufacturing.Methods. When conducting experiments on X-ray fluorescence analysis of chemical composition, pieces of metal waste rods of a titanium alloy of an unknown brand were used. An X-ray fluorescence spectrometer Niton Goldd (USA) was used to determine the elemental composition and percentage of elements in the alloy under study. With this method, X-ray radiation is directed at the sample under study, the reflected wave spectrum is obtained and the characteristics of the spectrum of secondary fluorescent radiation of the sample are analyzed. In this case, electromagnetic waves form secondary X-ray radiation, i.e., characteristic lines that are characteristic of atoms of various elements and have their own individual characteristics. Thus, the elemental composition of the sample under study is determined, and the intensity of these lines shows the quantitative concentration of elements.Results. Using a portable Niton Goldd spectrometer, it was found that titanium metal waste corresponds to the grade of the OT4-0 alloy. The data obtained made it possible to identify samples of the studied metal waste to be processed by the method of electroerosive dispersion into spherical powders suitable for additive manufacturing. As a result of comparing the percentage of chemical elements of the studied metal waste and alloy OT4-0 according to GOST 19807-91, minor discrepancies were found due to the absence of elements such as O, Si, C, N and H. in metal waste. Apparently, this difference is related to their possible presence in small amounts up to 0.1% or complete absence.Conclusion. Renovation of metal waste, including titanium metal waste, will contribute to resource conservation, import substitution and ensuring the technological sovereignty of the Russian Federation.
这项工作的目的是研究钛金属废料的元素组成,这些废料将通过电解分散法加工成适用于快速成型制造的球形粉末。在进行 X 射线荧光化学成分分析实验时,使用了未知品牌的钛合金金属废料棒。使用 X 射线荧光光谱仪 Niton Goldd(美国)来确定所研究合金中的元素成分和百分比。使用这种方法时,X 射线辐射会射向所研究的样品,获得反射波谱,并分析样品二次荧光辐射的光谱特征。在这种情况下,电磁波会形成二次 X 射线辐射,即各种元素原子的特征线,并具有各自的特征。因此,可以确定所研究样品的元素组成,这些线的强度显示了元素的定量浓度。使用便携式 Niton Goldd 光谱仪发现,金属钛废料符合 OT4-0 合金的等级。根据所获得的数据,可以确定所研究的金属废料样品,并通过电解分散法将其加工成适合快速成型制造的球形粉末。根据 GOST 19807-91 对所研究的金属废料和合金 OT4-0 的化学元素百分比进行比较后发现,由于金属废料中缺乏 O、Si、C、N 和 H 等元素,两者之间存在细微差别。显然,这种差异与这些元素可能少量存在(最多 0.1%)或完全不存在有关。金属废料(包括金属钛废料)的翻新将有助于节约资源、进口替代和确保俄罗斯联邦的技术主权。
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引用次数: 0
Forces Between Pair of Rings Made of a Magnetically Soft Ferromagnet in an Axial External Field 轴向外场中一对软磁铁磁环之间的作用力
Pub Date : 2024-04-10 DOI: 10.21869/2223-1528-2024-14-1-46-58
O. Stolbov, Y. Raikher
Purpose. Demonstration of the way to enhance the attraction force between coaxial rings made of a magnetically soft ferromagnet by way of profiling their edges facing each other.Methods. In the framework of magnetostatics numerical calculation is carried out for a system of two coaxial rings made of a magnetically soft ferromagnet under conditions when the system is subjected to a uniform magnetic field directed along the rings’ axis. Such a design prototypes a soft gripper for robotics. On the basis of the found out field distribution, the force of mutual attraction is evaluated. Using a particular example, the advantages of a system where the ring edges facing each other are profiled (tapered) are considered in comparison with the its analog where the rings have rectangular edges.Results. In is shown that tapering of the edges enables one to acquire a notable gain with respect to the attraction strength. The dependences of the force of the force are calculated on the inter-ring distance and on extent of tapering of the edges: replacement of the rectangular shape by a trapezoid one. It is found that the advantages of the tapered system take place only in certain intervals of the respective parameters. For example, tapering entails an order of magnitude enhancement provided that inter-ring gap is sufficiently narrow (much smaller than the thickness of the ring wall) but it loses to a standard system all its advantage when the rings are separated by a distance of the order of their radius or greater. The dependence of the attraction force on the extent of tapering (the ratio of the upper and lower bases of the trapezium) is non-monotonic. Under a weak tapering, this function grows rapidly, then it passes a maximum (its position depends on the magnetic susceptibility of the ring material) and afterwards goes down when the profile of the edge approaches triangular shape.Conclusions. The obtained results enable one to optimize the force interaction in the system under consideration. It is worth noting that the profiling not only augments the mutual attraction force but as well reduces that amount of magnetic material required for the construction.
目的。展示通过将软磁铁磁体制成的同轴环的边缘进行仿形处理来增强它们之间吸引力的方法。在磁静力学框架内,对由磁性软铁磁体制成的两个同轴圆环系统进行了数值计算,计算条件是系统受到沿圆环轴线方向的均匀磁场作用。这种设计为机器人软抓手提供了原型。在发现磁场分布的基础上,对相互吸引力进行了评估。通过一个特殊的例子,考虑了相向的圆环边缘呈异形(锥形)的系统与圆环边缘呈矩形的类似系统的优势。结果表明,边缘变细可显著提高吸引强度。计算了力的大小与环间距离和边缘渐细程度的关系:用梯形代替矩形。结果发现,锥形系统的优势仅体现在相应参数的特定区间内。例如,如果圆环之间的间隙足够窄(远小于圆环壁的厚度),锥形系统的优势就会提高一个数量级,但当圆环之间的距离达到或超过其半径的数量级时,锥形系统的优势就会完全丧失。吸引力与锥度(梯形上底和下底之比)的关系是非单调的。在锥度较弱的情况下,该函数迅速增长,然后通过一个最大值(其位置取决于环材料的磁感应强度),当边缘轮廓接近三角形时,该函数下降。所获得的结果有助于优化所考虑系统中的力相互作用。值得注意的是,剖面不仅增强了相互吸引力,还减少了结构所需的磁性材料数量。
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引用次数: 0
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Proceedings of the Southwest State University. Series: Engineering and Technology
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