首页 > 最新文献

Proceedings of the Southwest State University. Series: Engineering and Technology最新文献

英文 中文
Composition, Structure and Properties of Antifriction Alloys Based on the Charge Obtained by Electrodispersion of Bronze Waste BrO5C25 in Kerosene 基于废青铜BrO5C25在煤油中电分散所得电荷的减摩合金的组成、结构和性能
Pub Date : 2023-07-23 DOI: 10.21869/2223-1528-2023-13-2-8-19
E. Ageev, A. Pereverzev, V. Yemelyanov, V. V. Serebrovsky
Purpose. Study of the composition, structure and properties of antifriction alloys based on the electroerosion charge of bronze BrO5C25 obtained in a carbon–containing medium lighting kerosene.Methods. Dispersion of the waste of the BrO5S25 alloy was carried out at an installation for electrodispersing electrically conductive materials. The waste of the BrO5C25 alloy was used as metal waste. Lighting kerosene was used as the working fluid.As a result of exposure to short-term electrical discharges between the electrodes and the waste, their destruction occurred with the formation of fine particles. To obtain compacted materials, a Herzog TP 20 manual table press was used. Modern equipment and complementary methods of physical materials science were used to study the composition, structure and properties of the sintered products obtained.Results. Surface analysis showed that the alloys have a fine-grained structure, uniform phase distribution and a small number of pores. The analysis of the elemental composition found that carbon is contained on the surface of the new alloys, and all other elements Sn, Cu and Pb are distributed relatively evenly. The analysis of the studied alloys showed the presence of phases in them: Cu, CuSn, SnO, CuO, PbO, Pb. There are no carbide-forming elements in the alloy. It has been experimentally established that the composition, structure and properties of the charge dispersed by electroerosion of bronze BrO5C25 affect the tribological properties of the alloy blanks. In particular, the presence of free carbon in the alloy from the electroerosion charge obtained in kerosene, which acts as a solid lubricant, leads to a decrease in the coefficient of friction.Conclusion. It is shown that alloys obtained from an electroerosive charge have higher microhardness values in comparison with an alloy obtained from an industrially used charge. A significant increase in the microhardness of alloys is explained by the presence of highly hard particles formed during the quenching of metal vapors in the working fluid during dispersion. The presence of small fractions in electroerosive materials contributes to an increase in the density of compressions and a decrease in the porosity of workpieces.
目的。以含碳介质照明煤油中获得的BrO5C25青铜的电蚀电荷为基础,研究了抗磨合金的组成、结构和性能。BrO5S25合金废料的分散是在电分散导电材料的装置上进行的。将BrO5C25合金废料作为金属废料加以利用。照明用煤油作为工作液。由于暴露于电极和废物之间的短期放电,它们随着细颗粒的形成而被破坏。为了获得压实的材料,使用了赫尔佐格TP 20手动台式压力机。利用现代设备和物理材料科学的辅助方法,对烧结产物的组成、结构和性能进行了研究。表面形貌分析表明,合金组织晶粒细,相分布均匀,气孔数量少。元素组成分析发现,新合金表面含有碳,其余元素Sn、Cu和Pb分布相对均匀。分析表明,合金中存在Cu、CuSn、SnO、CuO、PbO、Pb等相。合金中没有形成碳化物的元素。通过实验确定了BrO5C25青铜电蚀分散电荷的组成、结构和性能对合金毛坯的摩擦学性能有影响。特别是,在作为固体润滑剂的煤油中获得的电侵蚀电荷在合金中存在游离碳,导致摩擦系数降低。结果表明,用电蚀电荷制备的合金比用工业电荷制备的合金具有更高的显微硬度值。合金显微硬度的显著增加可以解释为在分散过程中工作流体中金属蒸气淬火时形成的高硬度颗粒的存在。电蚀材料中存在的小组分有助于增加压缩密度和减少工件的孔隙率。
{"title":"Composition, Structure and Properties of Antifriction Alloys Based on the Charge Obtained by Electrodispersion of Bronze Waste BrO5C25 in Kerosene","authors":"E. Ageev, A. Pereverzev, V. Yemelyanov, V. V. Serebrovsky","doi":"10.21869/2223-1528-2023-13-2-8-19","DOIUrl":"https://doi.org/10.21869/2223-1528-2023-13-2-8-19","url":null,"abstract":"Purpose. Study of the composition, structure and properties of antifriction alloys based on the electroerosion charge of bronze BrO5C25 obtained in a carbon–containing medium lighting kerosene.Methods. Dispersion of the waste of the BrO5S25 alloy was carried out at an installation for electrodispersing electrically conductive materials. The waste of the BrO5C25 alloy was used as metal waste. Lighting kerosene was used as the working fluid.As a result of exposure to short-term electrical discharges between the electrodes and the waste, their destruction occurred with the formation of fine particles. To obtain compacted materials, a Herzog TP 20 manual table press was used. Modern equipment and complementary methods of physical materials science were used to study the composition, structure and properties of the sintered products obtained.Results. Surface analysis showed that the alloys have a fine-grained structure, uniform phase distribution and a small number of pores. The analysis of the elemental composition found that carbon is contained on the surface of the new alloys, and all other elements Sn, Cu and Pb are distributed relatively evenly. The analysis of the studied alloys showed the presence of phases in them: Cu, CuSn, SnO, CuO, PbO, Pb. There are no carbide-forming elements in the alloy. It has been experimentally established that the composition, structure and properties of the charge dispersed by electroerosion of bronze BrO5C25 affect the tribological properties of the alloy blanks. In particular, the presence of free carbon in the alloy from the electroerosion charge obtained in kerosene, which acts as a solid lubricant, leads to a decrease in the coefficient of friction.Conclusion. It is shown that alloys obtained from an electroerosive charge have higher microhardness values in comparison with an alloy obtained from an industrially used charge. A significant increase in the microhardness of alloys is explained by the presence of highly hard particles formed during the quenching of metal vapors in the working fluid during dispersion. The presence of small fractions in electroerosive materials contributes to an increase in the density of compressions and a decrease in the porosity of workpieces.","PeriodicalId":117184,"journal":{"name":"Proceedings of the Southwest State University. Series: Engineering and Technology","volume":"44 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122206262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Formation of A Hardened Surface Layer Under Complex Laser Action on the Cutting Edge of Parts Made of Structural Carbon Steels 复杂激光作用下碳钢结构钢刃口表面硬化层的形成
Pub Date : 2023-07-23 DOI: 10.21869/2223-1528-2023-13-2-55-69
I. V. Minaev, S. N. Kutepov, D. S. Klementyev, E. Ageev, D. V. Zhurba
The purpose of the work was to study the effect of laser modification of the cutting edge on changes in the structure and mechanical properties of the surface layer of parts made of hot–rolled structural carbon steels of grades 20, 35, 45 using a fiber laser.Methods. Structural carbon steels of grades 20, 35, 45 were selected as the objects of the study. To study the effect of laser modification on changes in the structure and mechanical properties of machine parts using laser cutting, special samples were made in the form of plates with a thickness of 2 mm (st20 and st45) and 4 mm (st35). After gas laser cutting, laser modification of the Q-switch cutting edge was performed with a fiber pulsed laser.Results. The regularities of changes in the structure of the zone of gas-laser thermal exposure after laser treatment (cutting, modification) are revealed. It has been established that repeated laser treatment (laser modification) of the cutting edge does not lead to a change in the structural components and microhardness in the zone of gas-laser thermal effects obtained after laser cutting. It has been established that the nature of the microhardness change is the same for all the studied steel grades: the highest values are reached near the surface of gas-laser treatment and are, for example, for steel grade 35 470-560 HV, which is 3,2-3,9 times greater than the initial microhardness (145 HV). Thus, a hardened layer with increased wear resistance is formed on the surface of the part after laser treatment. It is shown that the use of laser surface modification as an additional operation in the manufacture of parts by laser cutting makes it possible to improve the quality (roughness) of the surface layer. At the same time, the greatest effect of reducing roughness is given by laser modification in three passes along the X-Y plane.Conclusion. The results obtained can be used in the creation of resource-saving material processing processes.
研究了激光对20、35、45级热轧结构钢刃口进行激光改性对零件表层组织和力学性能变化的影响。选取了牌号为20、35、45的结构碳钢作为研究对象。为了研究激光修饰对激光切割机械零件组织和力学性能变化的影响,我们制作了厚度分别为2mm (st20和st45)和4mm (st35)的板材。在气体激光切割后,利用光纤脉冲激光对q开关切割刃进行激光修饰。揭示了激光处理(切割、改性)后气体激光热暴露区结构变化的规律。已经确定,切割刃口的多次激光处理(激光修饰)不会导致激光切割后获得的气体激光热效应区域的结构成分和显微硬度发生变化。研究表明,所有钢种显微硬度变化的性质是相同的:气体激光处理表面附近达到最高值,例如,35 470-560 HV的钢种是初始显微硬度(145 HV)的3,2,3,9倍。因此,在激光处理后的零件表面形成具有增加耐磨性的硬化层。结果表明,在激光切割制造零件时,使用激光表面改性作为一种附加操作,可以改善表面层的质量(粗糙度)。同时,在X-Y平面上进行三次激光修饰,减小粗糙度的效果最大。所得结果可用于资源节约型材料加工工艺的创建。
{"title":"Formation of A Hardened Surface Layer Under Complex Laser Action on the Cutting Edge of Parts Made of Structural Carbon Steels","authors":"I. V. Minaev, S. N. Kutepov, D. S. Klementyev, E. Ageev, D. V. Zhurba","doi":"10.21869/2223-1528-2023-13-2-55-69","DOIUrl":"https://doi.org/10.21869/2223-1528-2023-13-2-55-69","url":null,"abstract":"The purpose of the work was to study the effect of laser modification of the cutting edge on changes in the structure and mechanical properties of the surface layer of parts made of hot–rolled structural carbon steels of grades 20, 35, 45 using a fiber laser.Methods. Structural carbon steels of grades 20, 35, 45 were selected as the objects of the study. To study the effect of laser modification on changes in the structure and mechanical properties of machine parts using laser cutting, special samples were made in the form of plates with a thickness of 2 mm (st20 and st45) and 4 mm (st35). After gas laser cutting, laser modification of the Q-switch cutting edge was performed with a fiber pulsed laser.Results. The regularities of changes in the structure of the zone of gas-laser thermal exposure after laser treatment (cutting, modification) are revealed. It has been established that repeated laser treatment (laser modification) of the cutting edge does not lead to a change in the structural components and microhardness in the zone of gas-laser thermal effects obtained after laser cutting. It has been established that the nature of the microhardness change is the same for all the studied steel grades: the highest values are reached near the surface of gas-laser treatment and are, for example, for steel grade 35 470-560 HV, which is 3,2-3,9 times greater than the initial microhardness (145 HV). Thus, a hardened layer with increased wear resistance is formed on the surface of the part after laser treatment. It is shown that the use of laser surface modification as an additional operation in the manufacture of parts by laser cutting makes it possible to improve the quality (roughness) of the surface layer. At the same time, the greatest effect of reducing roughness is given by laser modification in three passes along the X-Y plane.Conclusion. The results obtained can be used in the creation of resource-saving material processing processes.","PeriodicalId":117184,"journal":{"name":"Proceedings of the Southwest State University. Series: Engineering and Technology","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121138810","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of Powder Charge Composition on the Structure and Properties of T15K6 Hard Alloy 粉末成分对T15K6硬质合金组织和性能的影响
Pub Date : 2023-07-23 DOI: 10.21869/2223-1528-2023-13-2-20-42
А. М. Alimzhanova, Z. Eremeeva, A. V. Nozhkina, V. Levina, N. Nitkin, V. L. Orlov
The purpose of the study is to determine the effect of nanosized additives on the structure and properties of the T15K6 hard alloy.Methods. These studies were carried out using an S-3400N electron microscope. The mechanical and physical properties of the structure of a hard alloy of the WC-TiC-Co system were studied using the example of T15K6 when nanosized tungsten powder and nanosized tungsten carbide powder with cobalt deposited on it were introduced into the initial charge using an optical and electron microscope; An X-ray spectrum analysis of the obtained samples of the T15K6 hard alloy was carried out on a DRON-4 X-ray diffractometer.Results. A hard alloy of the WC-TiC-Co system was studied with the introduction of nanosized tungsten powder into the initial charge, as well as with the introduction of nanosized tungsten carbide with cobalt deposited on its surface.In the work, the used powders of tungsten, nano-tungsten, cobalt, titanium carbide, tungsten carbide, nano-powder of tungsten carbide were studied, and the microstructure of the obtained hard alloys was also studied. It is shown that the coercive force of the T15K6 alloy depends on the size of the cobalt phase regions in the alloy; measuring its value makes it possible to judge the size of carbide grains. To improve the strength properties of hard alloys of the WC-TiCCo system, it is recommended to introduce nanosized WC additives or WC nanopowder with deposited cobalt.Conclusion. To improve the strength properties of hard alloys of the WC-TiC-Co system, it is recommended to introduce nanosized WC additives or WC nanopowder with deposited cobalt. The introduction of these additives into the composition of the powder charge of the T15K6 hard alloy leads to an increase in the ultimate bending strength by 15%. The introduction of nanosized WC additives or WC nanopowder with deposited cobalt makes it possible to obtain a fine-grained structure with a grain size of no more than 4–6 μm.
本研究的目的是确定纳米添加剂对T15K6硬质合金组织和性能的影响。这些研究使用S-3400N电子显微镜进行。以T15K6为例,利用光学显微镜和电子显微镜研究了纳米钨粉和表面沉积钴的纳米碳化钨粉初始电荷对WC-TiC-Co体系硬质合金结构的力学和物理性能的影响;用DRON-4型x射线衍射仪对获得的T15K6硬质合金样品进行了x射线光谱分析。在初始电荷中加入纳米钨粉,并在纳米碳化钨表面沉积钴,研究了WC-TiC-Co体系的硬质合金。研究了钨粉、纳米钨粉、钴粉、碳化钛粉、碳化钨粉、纳米碳化钨粉,并对所得硬质合金的显微组织进行了研究。结果表明:T15K6合金的矫顽力与合金中钴相区大小有关;测量其值可以判断碳化物晶粒的大小。为了提高WC- ticco体系硬质合金的强度性能,建议引入纳米WC添加剂或沉积钴的纳米WC粉。为了提高WC- tic - co体系硬质合金的强度性能,建议引入纳米WC添加剂或沉积钴的WC纳米粉。将这些添加剂添加到T15K6硬质合金的粉末料中,使其极限抗弯强度提高了15%。引入纳米WC添加剂或沉积钴的WC纳米粉可以获得晶粒尺寸不超过4-6 μm的细晶结构。
{"title":"Influence of Powder Charge Composition on the Structure and Properties of T15K6 Hard Alloy","authors":"А. М. Alimzhanova, Z. Eremeeva, A. V. Nozhkina, V. Levina, N. Nitkin, V. L. Orlov","doi":"10.21869/2223-1528-2023-13-2-20-42","DOIUrl":"https://doi.org/10.21869/2223-1528-2023-13-2-20-42","url":null,"abstract":"The purpose of the study is to determine the effect of nanosized additives on the structure and properties of the T15K6 hard alloy.Methods. These studies were carried out using an S-3400N electron microscope. The mechanical and physical properties of the structure of a hard alloy of the WC-TiC-Co system were studied using the example of T15K6 when nanosized tungsten powder and nanosized tungsten carbide powder with cobalt deposited on it were introduced into the initial charge using an optical and electron microscope; An X-ray spectrum analysis of the obtained samples of the T15K6 hard alloy was carried out on a DRON-4 X-ray diffractometer.Results. A hard alloy of the WC-TiC-Co system was studied with the introduction of nanosized tungsten powder into the initial charge, as well as with the introduction of nanosized tungsten carbide with cobalt deposited on its surface.In the work, the used powders of tungsten, nano-tungsten, cobalt, titanium carbide, tungsten carbide, nano-powder of tungsten carbide were studied, and the microstructure of the obtained hard alloys was also studied. It is shown that the coercive force of the T15K6 alloy depends on the size of the cobalt phase regions in the alloy; measuring its value makes it possible to judge the size of carbide grains. To improve the strength properties of hard alloys of the WC-TiCCo system, it is recommended to introduce nanosized WC additives or WC nanopowder with deposited cobalt.Conclusion. To improve the strength properties of hard alloys of the WC-TiC-Co system, it is recommended to introduce nanosized WC additives or WC nanopowder with deposited cobalt. The introduction of these additives into the composition of the powder charge of the T15K6 hard alloy leads to an increase in the ultimate bending strength by 15%. The introduction of nanosized WC additives or WC nanopowder with deposited cobalt makes it possible to obtain a fine-grained structure with a grain size of no more than 4–6 μm.","PeriodicalId":117184,"journal":{"name":"Proceedings of the Southwest State University. Series: Engineering and Technology","volume":"2056 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129811884","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Proceedings of the Southwest State University. Series: Engineering and Technology
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1