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The effects of various degrees of meteorological drought on forest vegetation in ecologically Fragile Karst Areas of Guangxi, China. 不同程度的气象干旱对中国广西生态脆弱喀斯特地区森林植被的影响。
IF 2.2 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-01 Epub Date: 2024-08-11 DOI: 10.1080/09593330.2024.2386864
Yanli Chen, Ying Xie, Mingzhi Li, Min Xie, Weihua Mo

ABSTRACTDrought presents a major challenge to the management of rocky desertification and ecological restoration in the delicate karst ecosystems of Guangxi. In this study, the normalized difference vegetation index (NDVI), fractional vegetation cover (FVC) and net primary productivity (NPP) were selected as vegetation remote sensing parameters, and the spatial response characteristics of different types of vegetation in karst areas of Guangxi Province to light, moderate, severe and extreme drought were analyzed to provide scientific basis for the evaluation of the impact of drought on vegetation in karst areas. The results are as follows: (1) NDVI, FVC and NPP showed a fluctuating increasing trend from 2000 to 2022, and the increasing rates were 0.058, 6.90%, and 43.3gC.m-2 per decade respectively. During this period, the number of light, moderate and severe drought days showed a decreasing trend, but the number of extreme drought days tended to increase. (2) The negative correlation of NDVI, FVC and NPP and drought increased from moderate to extreme drought, and from light to extreme drought, the negative correlation between NDVI and FVC and drought decreased, while that of NPP increased. (3) Light and moderate droughts had obvious negative impact on Chinese fir and broad-leaved forest, whereas severe and extreme droughts had obvious negative effect on eucalyptus and bamboo forest.

摘要干旱是广西脆弱岩溶生态系统石漠化治理和生态恢复面临的重大挑战。本研究选取归一化差异植被指数(NDVI)、植被覆盖度(FVC)和净初级生产力(NPP)作为植被遥感参数,分析了广西岩溶地区不同类型植被对轻度、中度、重度和极端干旱的空间响应特征,为评价干旱对岩溶地区植被的影响提供科学依据。结果如下(1)2000-2022 年,NDVI、FVC 和 NPP 呈波动上升趋势,上升速率分别为每 10 年 0.058、6.90%和 43.3gC.m-2。在此期间,轻旱、中旱和重旱日数呈下降趋势,但极旱日数呈上升趋势。(2)从中度干旱到特大干旱,NDVI、FVC 和 NPP 与干旱的负相关性增大;从轻度干旱到特大干旱,NDVI 和 FVC 与干旱的负相关性减小,而 NPP 的负相关性增大。(3)轻度和中度干旱对冷杉和阔叶林有明显的负面影响,重度和极端干旱对桉树和竹林有明显的负面影响。
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引用次数: 0
Anodic oxidation by electrical power pulses for alachlor degradation. 利用电力脉冲阳极氧化法降解甲草胺。
IF 2.2 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-01 Epub Date: 2024-08-16 DOI: 10.1080/09593330.2024.2389323
Fares Zouaoui, Didier Floner, Florence Fourcade

This article explores the benefits of electrochemical oxidation in pulsed mode, using potential, current, and power pulses. While potential and current pulse electrochemical technology has been previously studied for wastewater treatment, no study has included power pulses until now. The objective of this work is to highlight the advantages of power pulses by applying this pulse type to the electrochemical oxidation of a probe molecule, alachlor. For this aim, the influence of operating parameters and the comparison of the different pulse modes were investigated and compared to the results obtained with the electrochemical oxidation of alachlor in continuous mode. The study shows that the best results were obtained with the power pulse electrochemical oxidation with 100% alachlor degradation after 180 min and a mineralisation yield of 38.3% after 240 min. These results were better than those reported in the literature for treatments with continuous current input using platinum electrodes. This new technique could be an effective and efficient way to treat contaminated water and reduce the pressure on freshwater reserves.

本文探讨了脉冲模式下使用电位、电流和功率脉冲进行电化学氧化的好处。虽然以前曾对用于废水处理的电位和电流脉冲电化学技术进行过研究,但迄今为止还没有包括功率脉冲在内的研究。这项工作的目的是将功率脉冲应用于探针分子甲草胺的电化学氧化,从而突出功率脉冲的优势。为此,研究了操作参数的影响和不同脉冲模式的比较,并与甲草胺在连续模式下的电化学氧化结果进行了比较。研究结果表明,功率脉冲电化学氧化的效果最好,180 分钟后甲草胺降解率达到 100%,240 分钟后矿化率达到 38.3%。这些结果优于文献中报道的使用铂电极以持续电流输入进行处理的结果。这项新技术可以有效地处理受污染的水,并减轻对淡水储备的压力。
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引用次数: 0
Internal cycling of Fe3+/Fe2+ within Fe3O4 on cathode promotes green degradation of reactive brilliant red X-3B on anode. 阴极上 Fe3O4 中的 Fe3+/Fe2+ 内循环促进了阳极上活性艳红 X-3B 的绿色降解。
IF 2.2 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-01 Epub Date: 2024-08-19 DOI: 10.1080/09593330.2024.2390152
Zhanping Cao, Ye Meng, Sihan Shang, Yuxin Liu

Reactive brilliant red X-3B (RBRX-3B) wastewater is difficult to decolourise, not readily biodegradable, and large in quantity. Therefore, the efficient removal of RBRX-3B is crucial. In this paper, a green and efficient electrochemical-electro-Fenton system with Fe3O4-modified carbon felt bag cathode (ECEF-Fe3O4) was set up to degrade RBRX-3B wastewater. Experiments confirmed that the removal of RBRX-3B by ·OH or H2O2 is quite low, and RBRX-3B can be completely oxidised and degraded directly on the anode. Long-cycle experimental data further shows that the degradation efficiency of RBRX-3B on the anode is 100% at 70 min at the reaction rate constants (k) of 0.071 min-1 in ECEF-Fe3O4 while that of RBRX-3B on the cathode is only 16.8 ± 0.9%. The generation of ·OH is mainly catalysed through the internal cycling of Fe3+/Fe2+ within Fe3O4 on the cathode, and the generation and annihilation of ·OH on the cathode enhance the oxidation efficiency of the anode, achieving the green and effective removal of RBRX-3B by the anode in ECEF-Fe3O4.

活性艳红 X-3B(RBRX-3B)废水难以脱色,不易生物降解,而且量大。因此,高效去除 RBRX-3B 至关重要。本文建立了一个以 Fe3O4 改性碳毡袋为阴极的绿色高效电化学-电-芬顿系统(ECEF-Fe3O4)来降解 RBRX-3B 废水。实验证实,-OH 或 H2O2 对 RBRX-3B 的去除率很低,RBRX-3B 可直接在阳极上被完全氧化和降解。长周期实验数据进一步表明,在 ECEF-Fe3O4 中,当反应速率常数(k)为 0.071 min-1 时,阳极上 RBRX-3B 的降解效率在 70 分钟内达到 100%,而阴极上 RBRX-3B 的降解效率仅为 16.8 ± 0.9%。-OH的生成主要是通过阴极Fe3O4中Fe3+/Fe2+的内循环催化的,阴极上-OH的生成和湮灭提高了阳极的氧化效率,实现了ECEF-Fe3O4中阳极对RBRX-3B的绿色有效去除。
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引用次数: 0
Impact of the hydrated functional zone on the adsorption of ciprofloxacin to microplastics under the influence of UV aging. 紫外线老化作用下水合功能区对环丙沙星在微塑料上吸附的影响。
IF 2.2 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-01 Epub Date: 2024-09-05 DOI: 10.1080/09593330.2024.2398812
Lin Wang, Yang He, Yanhong Zhu, Jianqiang Zhang, Shijie Zheng, Wen Huang

The inevitable UV aging of microplastics (MPs) is one of the key factors affecting their interaction with antibiotics. In this study, polyethylene (PE) and polystyrene (PS) MPs were aged with UV irradiation. The adsorption isotherms and kinetics of ciprofloxacin (CIP) to virgin and aged MPs were investigated through various models, and the effects of pH on the adsorption amount were explored. Characterization revealed that the surfaces of aged MPs became rougher, and the hydrophilicity increased. These aged MPs were still in the early stage of aging on the basis of their carbonyl index (CI) (<0.2) and O/C (<0.04) values. The adsorption isotherms indicated that the adsorption mechanism of aged PE was different from that of virgin PE. Compared with virgin PE, the adsorption amount of aged PE increased by 87.80-95.45%, and the adsorption rate decreased by 65.52-80.74%. However, aging did not significantly affect the equilibrium adsorption amount or adsorption rate of aged PS. The external diffusion rate (Kext) (about 2.29-0.36 h-1) was almost 30 times greater than the internal diffusion rate (Kint) in the film-pore mass transfer (FPMT) model, indicating that CIP adsorption rate was dominated by external diffusion. A hydrated functional zone is thought to form around aged MPs, thus changing the adsorption mechanism and adsorption amount of aged PE. Therefore, more attention should be given to alterations in the hydrated functional zone in the early stage of MPs aging.

微塑料(MPs)不可避免的紫外线老化是影响其与抗生素相互作用的关键因素之一。本研究对聚乙烯(PE)和聚苯乙烯(PS)微塑料进行了紫外线老化处理。通过各种模型研究了环丙沙星(CIP)在原生和老化 MPs 上的吸附等温线和动力学,并探讨了 pH 值对吸附量的影响。表征结果表明,老化 MPs 的表面变得粗糙,亲水性增加。在膜孔传质(FPMT)模型中,这些老化 MPs 的羰基指数(CI)(Kext)(约为 2.29-0.36 h-1)几乎是内部扩散速率(Kint)的 30 倍,表明 CIP 吸附速率以外部扩散为主,因此这些 MPs 仍处于早期老化阶段。水合功能区被认为会在老化聚乙烯周围形成,从而改变老化聚乙烯的吸附机制和吸附量。因此,在 MPs 老化的早期阶段,应更多地关注水合功能区的变化。
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引用次数: 0
Theoretical and experimental studies of cephalexin adsorption on aluminium as a new alternative of removal from wastewater. 将头孢氨苄吸附在铝上作为去除废水的一种新选择的理论和实验研究。
IF 2.2 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-01 Epub Date: 2024-08-19 DOI: 10.1080/09593330.2024.2390150
María Yesenia Díaz-Cárdenas, Victoria Bustos-Terrones, Samantha Giselle López-Aguilar, Angélica Sánchez-Ponce, Jorge Uruchurtu-Chavarín, Gabriela Eleonora Moeller-Chávez

Cephalexin (CPX) is an antibiotic widely used to treat many infections. CPX has become an emerging pollutant present in wastewater. On the other hand, it is well known that organic compounds can be adsorbed over metal surfaces when the metal is in active state such as when it is rusting. This work proposes an alternative for the elimination of CPX from wastewater, applying electrochemical principles using a conventional and cheap substrate, aluminium. The first part consisted of obtaining the active states of aluminium electrodes carrying out voltametric curves at different pH (4, 7 and 9) to find the particular condition of interaction between CPX and metal surface. The potential was used in the potentiostatic tests to set the activation potential of metal at different times. After the treatment, electrolyte solutions were analysed using UV-vis spectra, and the aluminium surfaces were studied by optical micrographs and X-ray diffraction. In addition, aluminium-CPX interactions were corroborated by quantum-chemical calculations and adsorption isotherms. All results indicate that it was possible for the CPX removal at basic pH conditions, where the molecule adsorption on the aluminium substrate occurs due to a strong electrostatic interaction.

头孢氨苄(CPX)是一种广泛用于治疗多种感染的抗生素。CPX 已成为废水中新出现的污染物。另一方面,众所周知,当金属处于生锈等活性状态时,金属表面会吸附有机化合物。这项研究提出了一种消除废水中 CPX 的替代方法,利用电化学原理,使用一种传统而廉价的基质--铝。第一部分包括获取铝电极的活性状态,在不同 pH 值(4、7 和 9)下绘制伏安曲线,以找到 CPX 与金属表面相互作用的特定条件。在恒电位试验中使用该电位来设定金属在不同时间的活化电位。处理后,使用紫外可见光谱分析电解质溶液,并通过光学显微照片和 X 射线衍射研究铝表面。此外,还通过量子化学计算和吸附等温线证实了铝与 CPX 之间的相互作用。所有结果都表明,CPX 可以在碱性 pH 条件下去除,在碱性 pH 条件下,由于强烈的静电作用,分子会吸附在铝基底上。
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引用次数: 0
Efficient removal of organic matter and nitrogen from municipal wastewater in multi-module biochar filters for onsite wastewater treatment.
IF 2.2 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-01 Epub Date: 2024-09-18 DOI: 10.1080/09593330.2024.2402096
Makoto Shigei, Roger B Herbert, Frank Persson, Ekaterina Sokolova, Sahar S Dalahmeh

Biochar is a promising material for wastewater treatment. This study assessed multi-module biochar filters (MmBFs) as onsite wastewater treatment systems (OWTSs), comprising movable modules filled with biochar to remove chemical oxygen demand (COD), nitrogen, phosphorus, and Escherichia coli (E. coli) in wastewater. The MmBF treats wastewater sequentially through six modules: three aerobic modules (M1-M3) for organic matter oxidation and nitrification, two anoxic modules (M4-M5) for denitrification, and an additional module (M6) for the removal of faecal bacteria using biochar and bark. The experiments ran for 381 days using three identical MmBF pilots with two distinct sampling periods, conducted under conditions relevant to OWTSs using municipal wastewater as influent. Water samples were taken from the influent, final effluent, and effluent of each module to evaluate the removal efficiency of organic matter, nitrogen, phosphorus, and E. coli. During the second sampling period, the results showed a 95 ± 2.1% removal of COD, along with a substantial removal of total inorganic nitrogen (71 ± 6.6%). However, phosphate removal was limited (3.4 ± 30.4%). E. coli removal decreased from 2.63 ± 0.93 log10 removal in the first sampling period to 1.8 ± 0.73 log10 removal in the second sampling period. In summary, the MmBFs showed promising potential in treating organic matter, nitrogen, and E. coli, making it an alternative option for OWTS. However, further exploration is needed to assess long-term performance, micropollutant removal, and biological activities. Design enhancements, especially for phosphorus removal are necessary.

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引用次数: 0
Green and sustainable strategies to control scaling in industrial plants: investigation of the efficacy of Rosmarinus officinalis L. Extract against CaCO3 scale using experimental and theoretical approaches. 控制工业厂房结垢的绿色和可持续战略:利用实验和理论方法研究 Rosmarinus officinalis L. 提取物对 CaCO3 结垢的功效。
IF 2.2 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-01 Epub Date: 2024-08-21 DOI: 10.1080/09593330.2024.2391074
Mohamed El Housse, Abdallah Hadfi, Manal A Alossaimi, Ilham Karmal, Brahim E L Ibrahimi, Said Ben-Aazza, M'barek Belattar, D E Abd-El-Khalek, Yassine Riadi, Noureddine Iberache, Imane Ammayen, Mustapha Nassiri, Sara Darbal, Ali Driouiche

In recent years, plant extracts have attracted increased interest as green alternatives to conventional anti-scaling. This is because they contain a wide range of bioactive compounds with high performance against inorganic scale. Additionally, they are biodegradable and pose minimal risks to human health and ecosystems. The present study aimed to assess the protection offered by the Rosmarinus officinalis L. leaf extract for industrial plant surfaces against the CaCO3 scale. Before assessing the anti-scaling performance of the Rosmarinus extract, phytochemical characterisation was performed by quantitative assays and HPLC-DAD analysis. Subsequently, the inhibition potential of the extract was studied using the conductivity and LCEE tests at 25°C and TH = 40°f. In addition, SEM and XRD analysis were used to assess the effect of the extract on scale morphology and crystalline phases. Finally, DFT calculations and Monte Carlo simulation were carried out to enhance knowledge of the interaction between inhibitor molecules and CaCO3(104) and (110) surfaces and optimise [extract molecule - Ca]2+ complexes. Phytochemical analysis revealed the presence of several phenolic compounds (rosmarinic acid, vanillic acid, cinnamic acid, rutin, kaempferol, trans chalcone and quercetin). Further LCEE studies demonstrated the promising anti-scaling activity of the extract at an effective concentration of 54 mg/L. SEM micrographs and XRD diffractograms revealed a significant change in the morphology and phases of precipitated CaCO3 scales upon the addition of the inhibitor. In addition, the computational approach strongly supported the experimental results. These results underlined the Rosmarinus extract's potential as a valuable green and sustainable scaling inhibitor source.

近年来,植物提取物作为传统防垢剂的绿色替代品引起了越来越多的关注。这是因为植物萃取物含有多种生物活性化合物,对无机垢具有很高的防污性能。此外,植物提取物可生物降解,对人类健康和生态系统的危害极小。本研究旨在评估迷迭香叶提取物对工业植物表面 CaCO3 鳞片的保护作用。在评估迷迭香提取物的防垢性能之前,先通过定量检测和 HPLC-DAD 分析进行了植物化学特征描述。随后,在 25°C 和 TH = 40°f 条件下,使用电导率和 LCEE 测试研究了萃取物的抑制潜力。此外,还使用 SEM 和 XRD 分析评估了提取物对鳞片形态和结晶相的影响。最后,还进行了 DFT 计算和蒙特卡罗模拟,以进一步了解抑制剂分子与 CaCO3(104) 和 (110) 表面之间的相互作用,并优化[提取物分子 - Ca]2+ 复合物。植物化学分析显示了几种酚类化合物(香豆酸、香草酸、肉桂酸、芦丁、山柰酚、反式查尔酮和槲皮素)的存在。进一步的 LCEE 研究表明,有效浓度为 54 mg/L 的提取物具有良好的抗垢活性。扫描电镜显微照片和 XRD 衍射图显示,添加抑制剂后,沉淀的 CaCO3 鳞片的形态和相发生了显著变化。此外,计算方法也有力地支持了实验结果。这些结果凸显了迷迭香提取物作为一种有价值的绿色可持续阻垢剂来源的潜力。
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引用次数: 0
Innovative process for sulphur recovery from waste incineration flue gases: production of marketable sodium bisulphite solution. 从垃圾焚烧烟气中回收硫的创新工艺:生产适销对路的亚硫酸氢钠溶液。
IF 2.2 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-01 Epub Date: 2024-10-03 DOI: 10.1080/09593330.2024.2385066
Rodolphe Vautherin, Hélène Métivier, Anne Reguer, Hassen Benbelkacem

This study presents an innovative process for recovering sulphur from hazardous waste incineration flue gases, designed to produce a marketable sodium bisulphite solution while ensuring complete SO2 removal. This new process is characterized by a double absorption strategy at two different pH levels. The first step, at an acidic pH, generates the desired bisulphite solution, while the second step, at a basic pH, produces the sulphite solution for recycling into the first step and ensures total SO2 removal. The process's performance and feasibility were evaluated on a laboratory scale using a batch reactor with synthetic gas. The parametric study focused on the initial sulphite concentration in the absorption solution and the reactor temperature. A removal efficiency exceeding 95% was achieved across all initial sulphite concentrations and temperature ranges, when the pH was maintained above 6. At pH 5, where bisulphites are the predominant sulphur species, the removal efficiency remained substantial at approximately 70%. The oxidation of sulphites/bisulphites by oxygen in the flue gases was minimal, with less than 5% conversion to sulphate. Additionally, pH-controlled experiments were conducted to optimize plant start-up procedures. For the basic reactor, starting with water and adjusting the pH to 8 during SO2 absorption effectively minimized sodium hydroxide consumption. In contrast, for the acidic reactor at pH 5, initiating the process with a concentrated sulphite solution resulted in more stable absorption rates. These findings underscore the process's potential for efficient sulphur recovery and highlight the importance of pH management in optimizing operational stability and chemical consumption.

本研究介绍了一种从危险废物焚烧烟气中回收硫的创新工艺,旨在生产适销对路的亚硫酸氢钠溶液,同时确保完全去除二氧化硫。这种新工艺的特点是在两种不同的 pH 值水平下采用双重吸收策略。第一步在酸性 pH 值下生成所需的亚硫酸氢钠溶液,而第二步在碱性 pH 值下生成亚硫酸氢钠溶液,再循环到第一步,确保完全去除二氧化硫。该工艺的性能和可行性是在实验室规模上使用合成气批量反应器进行评估的。参数研究的重点是吸收溶液中亚硫酸盐的初始浓度和反应器的温度。当 pH 值保持在 6 以上时,在所有亚硫酸盐初始浓度和温度范围内,去除效率都超过了 95%。在 pH 值为 5 时,亚硫酸氢盐是主要的硫化物,去除效率仍然很高,约为 70%。烟气中的氧气对亚硫酸盐/亚硫酸氢盐的氧化作用很小,转化为硫酸盐的比例不到 5%。此外,还进行了 pH 值控制实验,以优化工厂启动程序。对于碱性反应器,在吸收二氧化硫时,先用水并将 pH 值调至 8,可有效地将氢氧化钠的消耗量降至最低。与此相反,对于 pH 值为 5 的酸性反应器,用浓亚硫酸盐溶液启动工艺可获得更稳定的吸收率。这些发现强调了该工艺高效回收硫的潜力,并突出了 pH 值管理在优化运行稳定性和化学品消耗方面的重要性。
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引用次数: 0
Emulsion liquid membrane technique for optimal separation of Ni (II) and Sm (III) using response surface methodology and Box-Behnken experimental setup. 利用响应面方法学和 Box-Behnken 实验装置优化分离 Ni (II) 和 Sm (III) 的乳液膜技术。
IF 2.2 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-01 Epub Date: 2024-08-26 DOI: 10.1080/09593330.2024.2386865
Benderrag Abdelkader, Benabela Imene, Annag Lahouaria, Haddou Boumediene, Kameche Mostefa, Maschke Ulrich

This study evaluated the reliability of the emulsified liquid membrane (ELM) extraction technique for recovering and separating metals, focusing on Nickel (Ni(II)) and Samarium (Sm(III)), both used in electrochemical devices. Key contributions include determining optimal conditions for creating a stable water-in-oil (W/O) emulsion. The optimal conditions were found to be a 5-minute emulsification time, 4 wt.% Span 80 surfactant concentration, a 1.6 volume ratio of the internal phase to the organic phase, 1 M H2SO4 concentration for the internal phase, a 40/160 volume ratio of the emulsion to the external phase, and kerosene as the diluent. Factors affecting the separation of Ni(II) and Sm(III) included the concentrations of the internal aqueous phase, surfactant, and extractant. Under these conditions, an equimolar mixture of Ni(II) and Sm(III) was extracted within 15 min. The study emphasized the importance of phase volume ratio and surfactant concentration for emulsion stability and extraction efficiency. The response surface method (RSM) and Box-Behnken design were used to optimize influential factors, with a modified quadratic model predicting extraction yields of 83.81% for Sm(III) and 15% for Ni(II). The study demonstrates that effective separation of Ni(II) and Sm(III) ions is achievable using this technique, providing valuable insights into efficient and selective metal ion extraction, contributing to the broader field of metal recovery and recycling technologies.

本研究评估了乳化液膜(ELM)萃取技术回收和分离金属的可靠性,重点是电化学装置中使用的镍(Ni(II))和钐(Sm(III))。主要贡献包括确定了形成稳定的油包水(W/O)乳液的最佳条件。最佳条件为:乳化时间为 5 分钟,Span 80 表面活性剂浓度为 4 wt.%,内相与有机相的体积比为 1.6,内相的 H2SO4 浓度为 1 M,乳液与外相的体积比为 40/160,稀释剂为煤油。影响 Ni(II) 和 Sm(III) 分离的因素包括内部水相、表面活性剂和萃取剂的浓度。在这些条件下,Ni(II) 和 Sm(III) 的等摩尔混合物可在 15 分钟内萃取出来。该研究强调了相体积比和表面活性剂浓度对乳液稳定性和萃取效率的重要性。采用响应面法(RSM)和盒-贝肯设计法对影响因素进行了优化,修正的二次模型预测 Sm(III) 的萃取率为 83.81%,Ni(II) 的萃取率为 15%。该研究表明,使用该技术可以有效分离 Ni(II) 和 Sm(III) 离子,为高效和选择性金属离子萃取提供了宝贵的见解,为更广泛的金属回收和循环利用技术领域做出了贡献。
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引用次数: 0
Study on the effect of volatile organic compounds on the treatment of high-salt wastewater by low-temperature evaporation. 挥发性有机化合物对低温蒸发法处理高盐废水的影响研究。
IF 2.2 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-01 Epub Date: 2024-08-11 DOI: 10.1080/09593330.2024.2388313
Yin Mengmeng, Shi Yongxing, Kong Linggang, Liu Jiachen

High-salinity wastewater, owing to its intricate composition and challenging treatment requirements, poses a significant hurdle in water environmental governance. In this study, low-temperature evaporation technology is used to tackle wastewater containing the volatile organic compound such as N,N-dimethylacetamide (DMAC). Utilisation of comprehensive approaches involving experimental testing, mathematical modelling, and Aspen Plus software simulations, The influence of DMAC on evaporation efficiency is researched through the following factors which encompassing its effects on boiling point elevation, partial molar activation energy, and the formation of by-products. Additionally, the comparation of the impact of temperature, ionic strength, intermolecular interactions on the evaporation rate and the concentration of the volatile component DMAC in the condensate is also conducted in this study. After conducting a multiple linear regression analysis of evaporation efficiency using the Statistical Product and Service Solutions (SPSS) tool, it was discovered that temperature serves as the primary determinant influencing the evaporation rate. Additionally, ionic strength impacts solution viscosity, intermolecular interactions, and saturated vapour pressure by altering the intermolecular forces, thereby indirectly influencing both the evaporation rate and the quality of condensate water. The comparative analysis of single-effect and double-effect evaporation indicates that the optimal operating condition for double-effect evaporation yields an evaporation rate of 70%, with a remarkable 88% reduction in steam consumption compared to single one. Based on heat and mass balance principles, the mathematical model for double-effect evaporation is established to offer crucial data support for practical industrial applications.

高盐废水因其复杂的成分和极具挑战性的处理要求,成为水环境治理的一大难题。本研究采用低温蒸发技术处理含有 N,N-二甲基乙酰胺(DMAC)等挥发性有机化合物的废水。通过实验测试、数学建模和 Aspen Plus 软件模拟等综合方法,研究了 DMAC 对蒸发效率的影响,包括对沸点升高、部分摩尔活化能和副产品形成的影响。此外,本研究还比较了温度、离子强度、分子间相互作用对蒸发率和冷凝液中挥发性成分 DMAC 浓度的影响。使用统计产品和服务解决方案 (SPSS) 工具对蒸发效率进行多元线性回归分析后发现,温度是影响蒸发率的主要决定因素。此外,离子强度通过改变分子间作用力影响溶液粘度、分子间相互作用和饱和蒸汽压,从而间接影响蒸发率和冷凝水的质量。单效蒸发和双效蒸发的对比分析表明,双效蒸发的最佳运行条件下,蒸发率可达 70%,蒸汽消耗量比单效蒸发显著减少 88%。根据热量和质量平衡原理,建立了双效蒸发的数学模型,为实际工业应用提供了重要的数据支持。
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Environmental Technology
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