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Nitrate levels in vegetables from markets in Tehran, Iran. 伊朗德黑兰市场蔬菜中的硝酸盐含量。
IF 2.5 3区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2024-09-01 Epub Date: 2024-05-22 DOI: 10.1080/19393210.2024.2351069
Firoozeh Emami Khansari, Fatemeh Sadat Mirmohammadmakki, Mahmoud Ghazi Khansari, Ramona Massoud

This study is aimed at measuring nitrate levels in different vegetables from Tehran's markets that are consumed raw and fresh and to evaluate human health risk. Basil, parsley, radish leaves, cress, leek, radish, spring onion were randomly collected from local markets and the nitrate content was analysed by spectrophotometry. Average nitrate levels in the samples were 40.1, 45.2, 50.0, 51.8, 55.4, 90.2 and 110 mg kg-1 in parsley, leek, basil, radish leaves, cress, radish and spring onion, respectively. The average content in all samples was below Iranian standard limits. Tuber vegetables had significantly higher nitrate content than (green) leafy vegetables.

本研究旨在测量德黑兰市场上生吃和新鲜食用的不同蔬菜中的硝酸盐含量,并评估对人体健康的风险。研究人员从当地市场随机采集了罗勒、欧芹、萝卜叶、芹菜、韭菜、萝卜、葱,并采用分光光度法对硝酸盐含量进行了分析。欧芹、韭菜、罗勒、萝卜叶、芹菜、萝卜和大葱样本中硝酸盐的平均含量分别为 40.1、45.2、50.0、51.8、55.4、90.2 和 110 毫克/千克-1。所有样本的平均含量均低于伊朗标准限值。块茎蔬菜的硝酸盐含量明显高于(绿)叶蔬菜。
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引用次数: 0
Pesticide residues in vegetables from Gansu province, China and risk assessment by Monte Carlo simulation. 中国甘肃省蔬菜中的农药残留及蒙特卡罗模拟风险评估。
IF 2.5 3区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2024-09-01 Epub Date: 2024-07-04 DOI: 10.1080/19393210.2024.2371828
Ping Wang, Yongjun Li, Jianyun Sun, Gexiang Zhang

To assess the dietary exposure risks of pesticide residues in vegetables for the general population, the presence of 39 pesticides was determined in 70 samples, of which 13 were detected. The most frequently detected pesticide was bifenthrin, with a detection rate of 35.7%, mainly found in gingers, followed by isoprocarb and acephate (11.4%) and dimethoate (8.6%). In 17.1% of the samples two or more pesticide residues were found. Acute, chronic and chronic cumulative dietary exposure risk was assessed. Chronic exposure risks were determined by Monte Carlo Simulation (MCS). Estimated chronic exposure to carbofuran, omethoate, disulfoton and dimethoate of approximately 49%, 52%, 40% and 3%, respectively, were at non-carcinogenic human risk. Acute exposure risk to acephate was considered to be of concern due to the high acute hazard quotient (aHQ).

为评估一般市民从膳食摄入蔬菜残余除害剂的风险,我们在 70 个样本中检测了 39 种除害剂,其中 13 种被检出。最常检测到的除害剂是联苯菊酯,检出率为 35.7%,主要存在于蘘荷中,其次是异丙威和乙酰甲胺磷(11.4%)和乐果(8.6%)。在 17.1%的样本中,发现了两种或两种以上的残留农药。评估了急性、慢性和慢性累积膳食暴露风险。慢性接触风险是通过蒙特卡罗模拟(MCS)确定的。呋喃丹、氧化乐果、二磺酰草胺和乐果的估计慢性接触风险分别约为 49%、52%、40% 和 3%,属于非致癌风险。由于乙酰甲胺磷的急性危害商数(aHQ)较高,因此认为其急性接触风险值得关注。
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引用次数: 0
Mercury in four common fishes sold in Algeria and associated humans risk. 阿尔及利亚出售的四种常见鱼类中的汞及其对人体的危害。
IF 2.5 3区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2024-09-01 Epub Date: 2024-05-15 DOI: 10.1080/19393210.2024.2353709
Mohamed Amine Kerdoun, Lyna Alouk, Fatima Morouj Rahmani, Hamza Abdellah Henni, Halima Dali, Elyes Kelai, Hakim Belkhalfa

This study aimed to analyse the concentrations of mercury in fish samples available in the Algerian market and evaluate the potential health risks associated with their consumption. A total of 135 fish samples, representing the species Sardina pilchardus, Merluccius merluccius, Sparus aurata and Auxis rochie, were collected and analysed. Mercury levels were determined using thermal decomposition amalgamation Atomic Absorption Spectrophotometry. Health risks were evaluated by calculating hazard quotients. The overall mean concentration was 0.19 ± 0.11 mg/kg across all species. Individual species concentrations were recorded as 0.17 ± 0.08 mg/kg for Sardina pilchardus, 0.26 ± 0.19 mg/kg for Merluccius merluccius, 0.27 ± 0.18 mg/kg for Sparus aurata and 0.23 ± 0.13 mg/kg for Auxis rochei. Hazard quotients were below 1, indicating low health risk for fish consumers. Nevertheless, it is recommended to conduct periodic monitoring of heavy metal levels in fish, coupled with ongoing risk assessments, to ensure continued consumer protection.

这项研究旨在分析阿尔及利亚市场上鱼类样本中的汞浓度,并评估食用这些鱼类可能带来的健康风险。共收集并分析了 135 份鱼类样本,分别代表沙丁鱼(Sardina pilchardus)、鲻鱼(Merluccius merluccius)、乌鳢(Sparus aurata)和鲈鱼(Auxis rochie)。采用热分解汞齐化原子吸收分光光度法测定汞含量。通过计算危害商数来评估健康风险。所有物种的总平均浓度为 0.19 ± 0.11 mg/kg。单个鱼种的浓度分别为:沙丁鱼 0.17 ± 0.08 毫克/千克、鲻鱼 0.26 ± 0.19 毫克/千克、鮨鱼 0.27 ± 0.18 毫克/千克和 Auxis rochei 0.23 ± 0.13 毫克/千克。危害商低于 1,表明对鱼类消费者的健康风险较低。不过,建议定期监测鱼类中的重金属含量,并持续进行风险评估,以确保持续保护消费者。
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引用次数: 0
Mercury levels in Nile perch fillets in processing industries in Uganda. 乌干达加工业尼罗河鲈鱼片中的汞含量。
IF 2.5 3区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2024-09-01 Epub Date: 2024-05-09 DOI: 10.1080/19393210.2024.2345327
Mathew Mwebaze Kasiiku, Andrew Tamale

Mercury levels of Nile perch fillets to be exported from selected fish processing industries in Uganda were determined by hot digestion in strong acids, followed by analysing the extracts with Inductive Coupled Plasma-Mass Spectroscopy (ICP-MS). There was a clear link between atmospheric mercury and methylmercury accumulation in fish tissues, thus exposing a possible threat for human health. A quantitative cross-sectional study design was undertaken from two fish processing factories around Kampala city. Simple random sampling was utilised where ten fish products were picked for analysis. The results obtained from the analysis of samples from both factories presented mercury levels far below the FAO/WHO guideline level of 0.5 mg/kg for mercury in fish. The mercury levels for both factories were higher than the oral daily recommended dose of 0.001 mg/kg body weight for the vulnerable population raising eyebrows for the general population, since fish is a major contributor to mercury intake for consumers.

通过在强酸中进行热消化,然后用电感耦合等离子体质谱仪(ICP-MS)对提取物进行分析,确定了乌干达选定鱼类加工业出口的尼罗河鲈鱼片的汞含量。大气中的汞与鱼类组织中甲基汞的积累之间存在着明显的联系,因此可能对人类健康造成威胁。研究人员对坎帕拉市附近的两家鱼类加工厂进行了横断面定量研究。研究采用了简单随机抽样的方法,选取了 10 种鱼类产品进行分析。对两家工厂样品的分析结果显示,汞含量远远低于粮农组织/世卫组织规定的鱼类汞含量 0.5 毫克/千克的指导水平。由于鱼类是消费者摄入汞的主要来源,因此两家工厂的汞含量都高于每日口服建议剂量(0.001 毫克/公斤体重),这引起了普通民众的关注。
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引用次数: 0
Aflatoxins in maize and groundnuts on markets in Accra and consumers risk. 阿克拉市场上玉米和花生中的黄曲霉毒素与消费者风险。
IF 2.5 3区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2024-09-01 Epub Date: 2024-05-22 DOI: 10.1080/19393210.2024.2351575
Richard Opoku Boadu, Enock Dankyi, Vitus A Apalangya, Dorcas Osei-Safo

This study presents the results of aflatoxin contamination of maize and groundnuts in major markets in Accra and assesses the population's exposure to aflatoxins. Raw maize and groundnuts from 6 major markets in Accra were sampled and analysed for their aflatoxin content. A total of 92 samples comprising 48 maize and 44 groundnuts were analysed using high-performance liquid chromatography, after extraction with methanol/water and cleanup on an immunoaffinity column. Total aflatoxins were quantified in 98% of the maize samples and 70% of the groundnut samples, with concentrations ranging from 0.60 to 1065 µg/kg and 0.20 to 627 µg/kg, respectively. Exposure assessment showed an estimated daily intake of 0.436 μg/kg bw/day and 0.0632 μg/kg bw/day for maize and groundnut consumption, respectively, suggesting significant health risks for consumers. The high prevalence and concentrations of aflatoxins call for an urgent need for measures to control exposure of the Ghanaian population.

本研究介绍了阿克拉主要市场的玉米和落花生黄曲霉毒素污染情况,并评估了人们接触黄曲霉毒素的情况。研究人员对阿克拉 6 个主要市场的玉米和花生原料进行了采样,并对其黄曲霉毒素含量进行了分析。经甲醇/水提取和免疫亲和柱净化后,采用高效液相色谱法对包括 48 个玉米和 44 个花生在内的 92 个样本进行了分析。98%的玉米样本和70%的落花生样本中的黄曲霉毒素总量被定量,浓度范围分别为每公斤0.60至1065微克和每公斤0.20至627微克。暴露评估显示,玉米和落花生的估计日摄入量分别为 0.436 微克/千克体重/天和 0.0632 微克/千克体重/天,这表明消费者的健康面临重大风险。黄曲霉毒素的高流行率和高浓度要求采取紧急措施,控制加纳人口的黄曲霉毒素摄入量。
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引用次数: 0
Pesticides in vegetables and fruits from Brazil and risk assessment. 巴西蔬菜和水果中的农药及风险评估。
IF 2.5 3区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2024-09-01 Epub Date: 2024-07-11 DOI: 10.1080/19393210.2024.2373347
Graziela Cristina Rossi Moura Andrade, Claudia Maria Barbosa, Meire Staff Zanquetta, Magali Melo Viana, Magda Regina Santiago, Sergio Henrique Monteiro

Levels of 237 pesticides were assessed in 1063 fruit and vegetable samples from 12 São Paulo markets spanning the period May 2015 to December 2022. The QuEChERS method was employed for extraction, followed by GC-MS/MS and LC-MS/MS analysis. Findings indicated that 30% of the samples contained residues below the Maximum Residue Limits (MRLs), while 6% exceeded these. Additionally, 23% exhibited excessive residues for their respective crops and 40% had no detectable residues. Health risk evaluation focused on tomatoes, cabbage and oranges, revealing exposure within 0.002-0.9% of the Acceptable Daily Intake (ADI), indicating no chronic risks. However, pyraclostrobin in orange presented a potential acute risk for adults (112%). These results underscore the necessity for continuous monitoring of pesticide residues in fruits and vegetables to safeguard consumer health, especially considering the significant levels of consumption.

在 2015 年 5 月至 2022 年 12 月期间,对来自圣保罗 12 个市场的 1063 份水果和蔬菜样本中 237 种农药的含量进行了评估。采用 QuEChERS 方法进行提取,然后进行 GC-MS/MS 和 LC-MS/MS 分析。研究结果表明,30% 的样品中残留量低于最高残留限量 (MRL),6% 的样品中残留量超过了最高残留限量。此外,23%的样品中残留物超标,40%的样品中未检测到残留物。健康风险评估的重点是西红柿、卷心菜和橘子,结果显示暴露量在每日允许摄入量(ADI)的 0.002-0.9% 范围内,表明没有慢性风险。不过,橘子中的吡唑醚菌酯对成人有潜在的急性风险(112%)。这些结果表明,有必要对水果和蔬菜中的农药残留进行持续监测,以保障消费者的健康,特别是考虑到水果和蔬菜的消费量很大。
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引用次数: 0
Residues of veterinary drugs and heavy metal contamination in livestock and poultry meat from Hunan Province, China. 中国湖南省畜禽肉中的兽药残留和重金属污染。
IF 2.5 3区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2024-08-18 DOI: 10.1080/19393210.2024.2387708
Ying Yu, Jun Xiang, Zongwu Meng, Kermue Vasco Jarnda, Qi Liu, Ping Ding

Livestock and poultry meat consumption play an important role in the dietary structure of Chinese residents. However, the extent of residues of veterinary drugs and heavy metal contamination in livestock and poultry meat and their by-products within Hunan province is not extensively studied. This survey aimed to fill this gap by assessing the presence of 76 veterinary drug residues in Hunan province. Additionally, heavy metals in pork and pig liver were also assessed. The obtained findings suggest that residues of veterinary drugs are still present in livestock and poultry meat, as well as their by-products, within Hunan province. However, the contamination of heavy metals remained within the food safety limits. These results underscore the significance of establishing more refined criteria for assessing human exposure, taking into account factors such as consumption patterns, product varieties and chemical compounds of interest.

畜禽肉消费在中国居民的膳食结构中占有重要地位。然而,湖南省内畜禽肉及其副产品中兽药残留和重金属污染的程度尚未得到广泛研究。本次调查旨在通过评估湖南省 76 种兽药残留情况来填补这一空白。此外,还对猪肉和猪肝中的重金属进行了评估。调查结果表明,湖南省的畜禽肉及其副产品中仍然存在兽药残留。不过,重金属污染仍在食品安全范围之内。这些结果表明,考虑到消费模式、产品种类和相关化合物等因素,制定更精细的人类暴露评估标准具有重要意义。
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引用次数: 0
Heavy metals and trace elements in milk and dairy products in the Lazio region (Central Italy). 拉齐奥地区(意大利中部)牛奶和乳制品中的重金属和微量元素。
IF 2.5 3区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2024-08-18 DOI: 10.1080/19393210.2024.2389423
Sabrina Battisti, Paola Scaramozzino, Daniela Delfino, Barbara Droghei, Alessandro Ubaldi, Marcello Giovanni Sala, Katia Russo, Bruno Neri

A study was carried out to determine the concentration of heavy metals and trace elements in milk and dairy products collected from local farms, supermarkets, or food retailers in the region of Lazio (Central Italy). Persistent exposure to metal contamination is of particular concern for human health, as it can cause different serious disorders. The monitoring of the matrices studied is therefore important, given their high consumption in the daily diet. The elements determined by ICP-MS (Inductively Coupled Plasma - Mass Spectrometry) were lead (Pb), arsenic (As), mercury (Hg), cadmium (Cd), chromium (Cr), nickel (Ni), molybdenum (Mo) and thallium (Tl), for a total of 151 measurements in 98 samples. The results showed that 11.3% of the measurements were quantifiable but below the legal maximum limits (MLs) set by EU regulations. The data obtained may be useful for dietary exposure information, inter-regional comparisons and for planning regional surveillance strategies.

一项研究旨在确定从拉齐奥地区(意大利中部)的当地农场、超市或食品零售商处收集的牛奶和乳制品中重金属和微量元素的浓度。持续暴露于金属污染对人体健康尤为重要,因为金属污染可导致各种严重疾病。因此,考虑到日常饮食中的高消费量,对所研究的基质进行监测非常重要。采用 ICP-MS(电感耦合等离子体质谱法)测定的元素有铅(Pb)、砷(As)、汞(Hg)、镉(Cd)、铬(Cr)、镍(Ni)、钼(Mo)和铊(Tl),共对 98 个样本中的 151 种元素进行了测定。结果表明,11.3%的测量结果可量化,但低于欧盟法规规定的法定最高限值(ML)。所获得的数据可用于膳食暴露信息、区域间比较和规划区域监控战略。
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引用次数: 0
Al and MCPD in grain products in Gansu province, China and risk assessment. 中国甘肃省粮食产品中的 Al 和 MCPD 含量及风险评估。
IF 2.5 3区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2024-08-12 DOI: 10.1080/19393210.2024.2382222
Ping Wang, Gexiang Zhang

This study conducted a dietary exposure assessment of chloropropanols and aluminium, after quantifying their content in food. The mean dietary exposure to Al from total grain products was found to be 6.4E-04 mg/kg bw/week, not exceeding the provisional tolerable weekly intake (PTWI). The results showed that the mean dietary exposure of 3-monochloro-1,2-propanediol (3-MCPD) from grain products was higher than the tolerable daily intake (TDI). Deterministic evaluations showed that the mean HQ of 1.5 to Al from fried dough twist was higher than 1. However, the HI values to Al were lower than 1 and the Monte Carlo simulation (MCS) showed that the HQ was greater than 1 at the 99% exposure level. Deterministic and probabilistic methods indicated that HQ values of 3-MCPD from grain products were above 1, whereas the mean HI value was 0.62.

这项研究在对食物中的氯丙醇和铝含量进行量化后,对从膳食中摄入氯丙醇和铝的情况进行了评估。结果发现,从全部谷物产品中摄入铝的平均膳食摄入量为 6.4E-04 毫克/千克体重/周,不超过暂定每周可容忍摄入量(PTWI)。结果显示,从谷物产品摄取 3-氯丙二醇的平均膳食摄入量,高于每日可容忍摄入量。确定性评估显示,从油炸面团麻花摄取铝的平均 HQ 值为 1.5,高于 1,但摄取铝的 HI 值则低于 1,而蒙特卡罗模拟(MCS)显示,在 99% 的摄取量水平下,HQ 值高于 1。确定性和概率方法都显示,谷物产品中氯丙二醇的 HQ 值高于 1,而平均 HI 值则为 0.62。
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引用次数: 0
Screening the quality of legal and illegal dietary supplements by LC-MS/MS. 利用 LC-MS/MS 筛选合法和非法膳食补充剂的质量。
IF 2.5 3区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2024-08-06 DOI: 10.1080/19393210.2024.2382221
Krzysztof Adam Stępień, Agnieszka Kalicka, Joanna Giebułtowicz

Dietary supplements are widely consumed. However, the lack of mandatory testing results in limited data on their quality, particularly in Eastern Europe. In this study, 21 legally registered and 9 illegal supplements, seized from an underground facility by the Polish Police, were examined. Contaminants were screened by utilising high-performance liquid chromatography coupled with untargeted mass spectrometry. The analysis identified 32 contaminants in the 30 dietary supplements examined. Untargeted analysis revealed a concerning issue: the intentional adulteration of both legal and illegal supplements with pharmacologically active substances that are prohibited in this category of products. This study indicated that many dietary supplements are of low quality due to deliberate adulteration or inadequate manufacturing conditions. The presence of unregistered or unapproved substances in these supplements poses serious health risks. Strong legal regulations are essential to address this issue effectively.

膳食补充剂被广泛食用。然而,由于缺乏强制性检测,有关其质量的数据十分有限,尤其是在东欧。在这项研究中,我们对波兰警方从地下设施中查获的 21 种合法注册营养补充剂和 9 种非法营养补充剂进行了检测。污染物的筛选采用了高效液相色谱法和非目标质谱法。分析确定了 30 种膳食补充剂中的 32 种污染物。非靶向分析揭示了一个令人担忧的问题:在合法和非法补充剂中故意掺入这类产品中禁止使用的药理活性物质。这项研究表明,由于故意掺假或生产条件不当,许多膳食补充剂质量低下。这些补充剂中含有未经注册或批准的物质,会对健康造成严重危害。要有效解决这一问题,必须制定强有力的法律法规。
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引用次数: 0
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Food additives & contaminants. Part B, Surveillance
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