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Study on fragmentation characteristics of rock mass in bench blasting with different coupling media 不同耦合介质台阶爆破中岩体破碎特性研究
IF 2.9 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-02 DOI: 10.3389/feart.2024.1445990
Tong Li, Ming Chen, Bo-wen Guo, Li Song, Bing Fan, Shan-shan Cui
The fragmentation size distribution is an important index to evaluate blasting effect. Based on stress wave theory, a blasting fragmentation distribution model is established, and the key influencing factors were clarified. Then, the distribution characteristics of rock fragmentation in water-coupled blasting and air-coupled blasting were compared and verified by numerical simulation and field test. The results show that the rock blasting fragmentation size is negatively correlated with borehole pressure and unit explosive consumption when blasting rock is determined. The existence of water slows down the attenuation of blasting load, prolongs the duration, and makes the blasting pressure transmitted to hole wall significantly greater than air-coupled one, which is equivalent to increasing the unit explosive consumption. Moreover, the rock fracture development speed and fragmentation degree of water-coupled blasting is significantly higher than air-coupled blasting. Comprehensively determined in same charging parameters, water-coupled blasting compared with air-coupled blasting can improve the degree of rock fragmentation, the average size of rock after blasting is smaller, more uniform particle size distribution. The research results for the control of blasting and optimization of explosive energy utilization have important reference significance.
破碎粒度分布是评价爆破效果的重要指标。基于应力波理论,建立了爆破破碎粒度分布模型,明确了关键影响因素。然后,通过数值模拟和现场试验,对比验证了水耦合爆破和气耦合爆破的岩石破碎分布特征。结果表明,在确定爆破岩石时,岩石爆破破碎尺寸与钻孔压力和单位炸药消耗量呈负相关。水的存在减缓了爆破载荷的衰减,延长了持续时间,使传递到孔壁的爆破压力明显大于空气耦合压力,相当于增加了单位炸药消耗量。此外,水耦合爆破的岩石裂隙发育速度和破碎程度明显高于空气耦合爆破。综合判定在相同装药参数下,水耦合爆破较空气耦合爆破能提高岩石破碎程度,爆破后岩石平均粒径更小,粒径分布更均匀。该研究成果对于爆破控制和优化炸药能量利用具有重要的参考意义。
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引用次数: 0
Multidimensional evaluation and service strategy analysis of hazard warning and risk reduction 危害预警和风险降低的多维评估与服务策略分析
IF 2.9 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-02 DOI: 10.3389/feart.2024.1362906
Zhiyu Cao, Jiahe Wang, Yingjie Liu, Jingjing Zhao, Yingying Song, Boting Zhao
To refine the meteorological warning service for decision makers and enhance their role in disaster risk reduction, this paper puts forward the efficiency index for warning on disaster risk reduction by analyzing meteorological warnings. The influence factors of the index are investigated, and an index calculation model is established by using Grey relation analysis. The weights of the evaluation factors are determined by entropy weight method to quantify the efficiency of warning. Additionally, the reminder strength of different warning delivery methods to decision makers is studied, and a refined delivery strategy tree for warnings to decision makers is established based on the efficiency index and reminder strength of delivery means. The proposed strategy has been applied to the warning service system in Fujian Province. Results show that its implementation has improved the efficiency of warning dissemination and reduced delivery warning costs.
为了完善气象预警对决策者的服务,增强其在减灾中的作用,本文通过对气象预警的分析,提出了减灾预警效率指数。研究了指数的影响因素,并利用灰色关系分析法建立了指数计算模型。采用熵权法确定评价因子的权重,量化预警效率。此外,还研究了不同预警传递方式对决策者的提醒力度,并根据传递方式的效率指数和提醒力度,建立了精细化的决策者预警传递策略树。所提出的策略已应用于福建省的预警服务系统。结果表明,该策略的实施提高了预警发布效率,降低了预警发布成本。
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引用次数: 0
A novel model for risk prediction of water inrush and its application in a tunnel in Xinjiang, China 新型涌水风险预测模型及其在中国新疆某隧道中的应用
IF 2.9 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-02 DOI: 10.3389/feart.2024.1404133
Yuanyue Pi, Zhong Sun, Yangyang Lu, Jian Xu
Tunnel water inrush may not only cause hundreds of millions of economic losses and serious casualties, but also leads to a series of ecological and environmental problems such as the decline of groundwater level, soil salinization and surface vegetation degradation. In this study, considering hydrogeology, construction, and dynamic monitoring factors, a new risk prediction model of water inrush is proposed based on fuzzy mathematical theory. The element of novelty is that this approach comprehensively considers nonlinearity and randomness factors, and the index values, weights, and membership are expressed as interval numbers instead of constant values. The interval membership degree of each index is calculated by an improved sigmoid membership function (SMF). A coupling algorithm of improved analytic hierarchy process and entropy method is used to calculate the index weight. In addition, the Boolean matrix is introduced into the relative advantage analysis of the interval vector, and the final risk level of water inrush is determined by the ranking result. The proposed model is applied to the analysis of the water inrush risk in the Ka−Shuang 2 (KS2) tunnel in Xinjiang, China. The predicted results align well with the actual excavation results, which indicates that this novel model has high accuracy and reliability. Simultaneously, a risk management response mechanism for different risk levels of water inrush is discussed, which is expected to provide a new research perspective for risk control of other related projects and promote regional sustainable development.
隧道涌水不仅可能造成数以亿计的经济损失和严重人员伤亡,还可能导致地下水位下降、土壤盐碱化、地表植被退化等一系列生态环境问题。本研究综合考虑水文地质、工程建设、动态监测等因素,基于模糊数学理论提出了一种新的涌水风险预测模型。其新颖之处在于,该方法综合考虑了非线性和随机性因素,指标值、权重和成员度均以区间数而非常数表示。每个指数的区间成员度由改进的西格码成员函数(SMF)计算。指数权重的计算采用了改进的层次分析法和熵法的耦合算法。此外,在区间向量的相对优势分析中引入了布尔矩阵,并根据排序结果确定最终的涌水风险等级。所提出的模型被应用于中国新疆卡双 2 号(KS2)隧道的涌水风险分析。预测结果与实际开挖结果非常吻合,这表明该新型模型具有较高的准确性和可靠性。同时,探讨了不同涌水风险等级的风险管理响应机制,有望为其他相关工程的风险控制提供新的研究视角,促进区域可持续发展。
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引用次数: 0
A comparative study of regional rainfall-induced landslide early warning models based on RF、CNN and MLP algorithms 基于 RF、CNN 和 MLP 算法的区域降雨诱发滑坡预警模型比较研究
IF 2.9 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-01 DOI: 10.3389/feart.2024.1419421
Yanhui Liu, Shiwei Ma, Lihao Dong, Ruihua Xiao, Junbao Huang, Pinggen Zhou
Landslide disasters, due to their widespread distribution and clustered occurrences, pose a significant threat to human society. Rainfall is considered a primary triggering factor, and the frequent clustering of landslides underscores the importance of early warning systems for regional landslide disasters in preventing and mitigating rainfall-induced landslides. Research on early warning models is crucial for accurately predicting rainfall-induced landslides. However, traditional models face challenges such as the complexity of landslide causes, insufficient data, and limited analysis methods, resulting in low accuracy and inadequate precision. This study focuses on Fujian Province, China, proposing a four-step process for building a regional landslide early warning model based on machine learning. The process includes data integration and cleaning, sample set construction, model training and validation, and practical application. By integrating and cleaning the latest and most detailed data, a training sample set (15,589 samples) for the regional landslide disaster early warning model is established. Three machine learning algorithms—Random Forest, Multilayer Perceptron, and Convolutional Neural Network—are employed and compared, the evaluation results indicated that the RF-based warning model achieved an accuracy of 0.930–0.957 and an AUC value of 0.955. The CNN-based warning model demonstrated an accuracy of 0.945–0.948 with an AUC value of 0.940. The MLP-based warning model achieved an accuracy of 0.930–0.953 and an AUC value of 0.930. The results showed comparable accuracy metrics among the three models, with RF exhibiting a significant advantage in AUC values. Finally, the models are applied to the regional landslide disasters induced by heavy rainfall in Fujian Province on 5 August 2021. The results showed that in the binary classification warning strategy, the accuracy of the Random Forest and Convolutional Neural Network was 92.9%, while that of the Multilayer Perceptron was 85.8%, all performing well. In the multi-classification hierarchical warning strategy, the Random Forest excelled, while the performance of the Convolutional Neural Network and Multilayer Perceptron was relatively limited. The findings of this study contribute to valuable attempts in landslide disaster warning model research, with anticipated further improvements through the gradual accumulation of samples and practical application verification.
山体滑坡灾害分布广泛,且多发,对人类社会构成严重威胁。降雨被认为是一个主要的诱发因素,而山体滑坡的频繁集群发生则凸显了区域山体滑坡灾害预警系统在预防和减轻降雨引发的山体滑坡方面的重要性。预警模型的研究对于准确预测降雨引发的滑坡至关重要。然而,传统模型面临着滑坡成因复杂、数据不足、分析方法有限等挑战,导致准确率低、精度不够。本研究以中国福建省为研究对象,提出了基于机器学习构建区域滑坡预警模型的四步流程。该流程包括数据整合与清洗、样本集构建、模型训练与验证以及实际应用。通过整合和清洗最新、最详细的数据,建立了区域滑坡灾害预警模型的训练样本集(15589 个样本)。采用随机森林(RF)、多层感知器(Multilayer Perceptron)和卷积神经网络(Convolutional Neural Network)三种机器学习算法进行比较,评估结果表明,基于 RF 的预警模型准确率为 0.930-0.957,AUC 值为 0.955。基于 CNN 的预警模型的准确率为 0.945-0.948,AUC 值为 0.940。基于 MLP 的预警模型的准确率为 0.930-0.953,AUC 值为 0.930。结果表明,三种模型的准确度指标相当,RF 在 AUC 值方面具有明显优势。最后,将模型应用于 2021 年 8 月 5 日福建省暴雨引发的区域性滑坡灾害。结果表明,在二元分类预警策略中,随机森林和卷积神经网络的准确率为 92.9%,多层感知器的准确率为 85.8%,均表现良好。在多分类分层预警策略中,随机森林的表现突出,而卷积神经网络和多层感知器的表现相对有限。本研究的结果为滑坡灾害预警模型研究做出了有价值的尝试,通过样本的逐步积累和实际应用验证,有望得到进一步的改进。
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引用次数: 0
A discovery of nanoscale sulfide droplets in MORB glasses: implications for the immiscibility of sulfide and silicate melts 在 MORB 玻璃中发现纳米级硫化物液滴:对硫化物和硅酸盐熔体不相溶的影响
IF 2.9 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-31 DOI: 10.3389/feart.2024.1403504
Lei Zuo, Peng Zhang, Ya-qin Wang, Rui Liu
Sulfur forms an immiscible liquid upon saturation in magma, and sulfide droplets are commonly found in fresh mid-ocean ridge basalt (MORB). Scanning electron microscopy (SEM) analysis revealed that the fine-grained and weakly phyric MORB samples exhibited hypocrystalline to vitreous textures. Transmission electron microscopy (TEM) of MORB glasses exhibits nanoscale sulfide droplets (10–15 nm) with rounded shapes and smooth edges, showing crystalline and homogeneous composition. Elemental distribution included S, Fe, Cu, and Ni, while Si, Al, and O were lacking. Prior research clarified the immiscibility between sulfide and silicate melts, impacting the size distribution of sulfide droplets. This is the first report on nanoscale sulfide droplets within MORB glasses, and these results suggest that nanoscale sulfide droplets represent the initial phase of sulfide saturation. Such an insight may prove useful in understanding how siderophile and chalcophile elements behaved during sulfide crystallization. In addition, this study determines the immiscibility of sulfides and silicate melts that occur in the early nanometer stage. Therefore, it is speculated that immiscibility phenomena may occur in the nanometer stage during magma evolution.
硫在岩浆中饱和后会形成一种不相溶的液体,而硫化物液滴通常存在于新鲜的洋中脊玄武岩(MORB)中。扫描电子显微镜(SEM)分析表明,细粒度和弱植酸的 MORB 样品呈现出低晶至玻璃状纹理。MORB 玻璃的透射电子显微镜(TEM)显示出纳米级的硫化物液滴(10-15 nm),具有圆形和光滑的边缘,显示出结晶和均匀的成分。元素分布包括 S、Fe、Cu 和 Ni,而缺少 Si、Al 和 O。之前的研究阐明了硫化物和硅酸盐熔体之间的不溶性,这影响了硫化物液滴的大小分布。这是第一份关于 MORB 玻璃中纳米级硫化物液滴的报告,这些结果表明纳米级硫化物液滴代表了硫化物饱和的初始阶段。这种见解可能有助于理解硫化物结晶过程中亲苷元素和亲镓元素的表现。此外,这项研究还确定了硫化物和硅酸盐熔体在早期纳米阶段的不可溶性。因此,推测岩浆演化过程中的纳米阶段可能会出现不溶解现象。
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引用次数: 0
Calcite e-twins as a tectonic indicator, paleo stress pattern and structural evolution of the Zagros hinterland, SE Iran 作为构造指标的方解石电子孪晶、古应力模式和伊朗东南部扎格罗斯腹地的构造演化
IF 2.9 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-31 DOI: 10.3389/feart.2024.1445918
Hamed Dorzadeh, Shahram Shafieibafti, Saeede Keshavarz, Jafar Omrani, Ahmad Rashidi, Majid Nemati, Reza Derakhshani
Through the examination of calcite twins, this research outlines the tectonic development and paleo stress patterns of the Paleozoic Routshon complex situated in the southeastern segment of the Sanandaj–Sirjan zone, a hinterland region of the Zagros orogeny in southeastern Iran. The study of orogenic phase indicates that the deformation event affecting the southern sector of the Sanandaj-Sirjan zone aligns with the Cimmerian orogenic phase of the Late Triassic period. A variety of structural features at both map and outcrop scales highlight the importance of slip partitioning in the structural evolution of this region, driven by inclined transpression. Observations suggest that the deformation related to contractional components includes steeply to moderately plunging folds, dip-slip domain deformation primarily involving thrusts, and ongoing deformation by strike-slip component motion, which results in thrust-related ductile shear zones. The analysis of calcite c-axis fabrics from mylonite samples obtained from these shear zones indicates a low-temperature monoclinic pattern of non-coaxial deformation. This deformation type underscores the impact of the strike-slip component in the development of progressive simple shear within thrust-related shear zones in this segment of the Sanandaj-Sirjan zone. Dynamic analysis of c-axis fabric data reveals a NE-SW orientation for the principal compressive axes (σ1) in this area. This direction, corroborated by additional data such as fault surface, GPS, and earthquake focal mechanism data, confirms that the orientation of the compressive axes (σ1) has remained consistent from the Late Triassic to the present.
本研究通过对方解石孪晶的研究,概述了位于伊朗东南部扎格罗斯造山带腹地萨南达季-锡尔詹地区东南段的古生代鲁特松复合体的构造发展和古应力模式。对造山运动相位的研究表明,影响萨南达季-锡尔詹带南段的变形事件与晚三叠世时期的西梅利亚造山运动相位一致。地图和露头尺度上的各种结构特征突出表明,在倾斜换位的驱动下,滑移分区在该地区结构演变中的重要性。观察结果表明,与收缩成分有关的变形包括陡峭至中等程度的褶皱、主要涉及推力的倾覆滑动域变形,以及由走向滑动成分运动引起的持续变形,这导致了与推力有关的韧性剪切带。对从这些剪切带获得的麦饭石样本中的方解石 c 轴结构进行的分析表明,非同轴变形的低温单斜模式。这种变形类型凸显了在萨南达季-锡尔詹区段与推力相关的剪切带中,走向滑动成分对渐进式简单剪切发展的影响。对 c 轴结构数据的动态分析显示,该地区的主要压缩轴(σ1)呈东北-西南走向。这一方向与断层面、全球定位系统和地震焦点机制数据等其他数据相印证,证实了压缩轴(σ1)的方向从三叠纪晚期至今一直保持一致。
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引用次数: 0
Research on the impact of FDI and environmental regulation on the industrial structure upgrading in the Yellow River Basin 外国直接投资和环境规制对黄河流域产业结构升级的影响研究
IF 2.9 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-31 DOI: 10.3389/feart.2024.1379870
Jinxiu Yu
Introductions: Since the reform and opening up, the inflow of foreign direct investment (FDI) has provided a steady stream of capital, technology, talent and other resources for the development of the Yellow River basin, while caused problems such as environmental pollution, ecological fragility and industrial structure upgrading difficulties to some extent. Environmental regulation is a pivotal initiative to achieve mutual harmony between ecological environment and economic development, which could enhance the quality of the introduction of FDI and accelerate the green transformation of the development mode.Methods: Based on urban panel data from 2006–2019, this study empirically examined the impact of FDI and environmental regulation on industrial structure upgrading in the Yellow River Basin. Moreover, taking environmental regulation as a threshold variable, a panel threshold model was established to further explore the role of environmental regulation in the impact of FDI on industrial structure upgrading in the Yellow River Basin.Results: (1) The relationship between FDI and industrial structure upgrading in the Yellow River Basin is not a simple linear relationship, but an inverted “U”-shaped relationship that rises first and then falls, and the results of this inverted “U”-shaped relationship are still robust after replacing key indicators. (2) The environmental regulation policy has a driving effect on the upgrading of industrial structure in the Yellow River Basin. (3) Environmental regulation has a positive role in the influence of FDI on the industrial structure upgrading in the Yellow River basin, and the positive role increases gradually as the intensity of environmental regulation increases moderately, but if the intensity of environmental regulation is too high, it will have a negative impact on the upgrading of industrial structure in the Yellow River basin to some extent.Discussion: In the future, policymakers should make reasonable and effective use of FDI and improve the quality of FDI; reasonably formulate environmental regulation policies; coordinate the intensity of FDI and environmental regulation; thus, bring into play the promotion effect of FDI and environmental regulation on industrial structure upgrading, and then realize the win-win of ecological protection and high-quality economic development in the Yellow River Basin.
引言:改革开放以来,外商直接投资(FDI)的流入为黄河流域的发展提供了源源不断的资金、技术、人才等资源,同时也在一定程度上造成了环境污染、生态脆弱、产业结构升级困难等问题。环境监管是实现生态环境与经济发展相互协调的关键举措,可以提高引进 FDI 的质量,加快发展方式的绿色转型:本研究基于 2006-2019 年的城市面板数据,实证检验了黄河流域外商直接投资和环境规制对产业结构升级的影响。结果:(1)黄河流域FDI与产业结构升级的关系不是简单的线性关系,而是先上升后下降的倒 "U "型关系,这种倒 "U "型关系的结果在替换关键指标后仍然稳健。(2)环境规制政策对黄河流域产业结构升级具有推动作用。(3)环境规制对黄河流域外商直接投资对产业结构升级的影响具有正向作用,且正向作用随着环境规制强度的适度增加而逐渐增强,但如果环境规制强度过高,则会在一定程度上对黄河流域产业结构升级产生负面影响:未来,决策者应合理有效利用外商直接投资,提高外商直接投资质量;合理制定环境规制政策,协调外商直接投资与环境规制的强度,从而发挥外商直接投资与环境规制对产业结构升级的促进作用,实现黄河流域生态保护与经济高质量发展的双赢。
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引用次数: 0
Prediction of saturation exponent for subsurface oil and gas reservoirs using soft computing methods 利用软计算方法预测地下油气藏的饱和指数
IF 2.9 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-31 DOI: 10.3389/feart.2024.1434820
Anupam Yadav, Saeed Hameed Aldulaimi, Farag M. A. Altalbawy, Praveen K. N. Raja, M. Janaki Ramudu, Nizomiddin Juraev, Hameed Hassan Khalaf, Bassam Farman Bassam, Nada Qasim Mohammed, Dunya Jameel Kassid, Ahmed Elawady, Mohammad Sina
The most widely used equation to calculate water saturation or suitable shaly water saturation in clean or shaly formation, respectively, is the modified Archie formula. The quality of Archie parameters including saturation exponent affects the preciseness of water saturation, and thus estimated oil and gas in place. Therefore, estimating the saturation exponent by the soft computation methods deems to be necessary. In this study, intelligent models such as multilayer perceptron neural network, least squares support vector machine, radial basis function neural network, and adaptive neuro-fuzzy inference system are developed to predict saturation exponent in terms of petrophysical data including porosity, absolute permeability, water saturation, true resistivity, and resistivity index by utilizing a databank for middle east oil and gas reservoirs. The introduced models are optimized using particle swarm optimization, genetic algorithm, and levenberg marquardt techniques. Graphical and statistical methods are used to demonstrate the capability of the constructed models. Based on the statistical indexes obtained for each model, it is found that radial basis function neural network, multilayer perceptron neural network, and least squares support vector machine are the most robust models as they possess the smallest mean squared error, root mean squared error and average absolute relative error as well as highest coefficient of determination. Moreover, the sensitivity analysis indicates that water saturation has the most effect and porosity has the least effect on the saturation exponent. The developed models are simple-to-use and time-consuming tools to predict saturation exponent without needing laboratory methods which are tedious and arduous.
用于计算清洁地层或页岩地层的含水饱和度或合适的页岩含水饱和度的最常用公式是修正的阿奇公式。包括饱和指数在内的阿奇参数的质量会影响含水饱和度的精确性,进而影响油气储量的估算。因此,通过软计算方法估算饱和指数显得十分必要。本研究利用中东油气藏数据库,开发了多层感知器神经网络、最小二乘支持向量机、径向基函数神经网络和自适应神经模糊推理系统等智能模型,根据岩石物理数据(包括孔隙度、绝对渗透率、含水饱和度、真实电阻率和电阻率指数)预测饱和指数。采用粒子群优化、遗传算法和 Levenberg marquardt 技术对引入的模型进行优化。使用图形和统计方法来证明所建模型的能力。根据每个模型获得的统计指标,发现径向基函数神经网络、多层感知器神经网络和最小二乘支持向量机是最稳健的模型,因为它们具有最小的均方误差、均方根误差和平均绝对相对误差以及最高的决定系数。此外,敏感性分析表明,水饱和度对饱和度指数的影响最大,而孔隙度对饱和度指数的影响最小。所开发的模型是一种简单易用、耗时少的饱和指数预测工具,无需使用繁琐而艰苦的实验室方法。
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引用次数: 0
The influence range of the biogas desaturation method for mitigating sand liquefaction 缓解砂土液化的沼气脱饱和法的影响范围
IF 2.9 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-31 DOI: 10.3389/feart.2024.1433507
Erxing Peng, Dandan Li, Xiaoying Hu, Binbin He, Haiming Dang, Youqian Liu
To clarify the influence range and saturation distribution after the biogas desaturation method is applied, a three-dimensional model is established with TOUGH2 software to analyze the effect of construction parameters such as grouting volume, grouting rate, grouting depth, nitrogen source concentration, and soil porosity. After that, the sensitivity of the parameters on the influence range is determined. The grouting volume and soil porosity are the most sensitive to the lateral and vertical influence range, respectively. This study provides a basis for the engineering practice of treating liquefiable subgrade by the biogas desaturation method.
为明确沼气脱饱和法应用后的影响范围和饱和度分布,利用 TOUGH2 软件建立了三维模型,分析了注浆量、注浆率、注浆深度、氮源浓度和土壤孔隙度等施工参数的影响。然后,确定参数对影响范围的敏感性。注浆量和土壤孔隙度分别对横向和纵向影响范围最为敏感。这项研究为采用沼气脱饱和法处理可液化路基的工程实践提供了依据。
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引用次数: 0
Quantification of organic and inorganic hydrogen in mudstones: a novel approach using the difference between organic-rich and organic-free mudstones during pyrolysis process 泥岩中有机氢和无机氢的定量:利用热解过程中富含有机物和不含有机物泥岩之间差异的新方法
IF 2.9 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-31 DOI: 10.3389/feart.2024.1421404
Pengyan Du, Jingong Cai, Huidong Li, Xuejun Zhang, Juan Wang, Liping Yang, Yanzhong Zhen
Whether mudstone is rich in or free of organic matter has a great influence on the occurrence of water. Comparing different types of water in organic-rich and organic-free mudstones is helpful for further understanding the role of water in hydrocarbon generation. Thermogravimetric analysis (TGA) and differential thermal analysis (DTA) combined with mass spectrometry (MS) afford the opportunity to identify the mass change, reactions and products of the sample in a real-time monitored heating process. This study compared the pyrolysis characteristics of an organic-rich mudstone (CN1) and an organic-free mudstone (CW1) by using the TGA/DTA-MS method to estimate the content of different types of H2O and CO2 in organic-rich mudstones. The results show that the mass changes in CN1 and CW1 can be divided into the three thermogravimetric (TG) stages of 0°C–200°C, 200°C–650°C, and 650°C–900°C, while the peak temperatures of H2O and CO2 obtained through MS are different for CN1 and CW1. The differences in mineral components and organic matter between CN1 and CW1 suggest that the MS peaks of H2O and CO2 in CW1 are mainly influenced by clay and carbonate minerals, and that those of CN1 are also influenced by organic matter. In addition, quantification equations for CO2 and H2O contents from both the organic and inorganic origin of the organic-rich mudstone can be established by using the MS peak area of CO2 and H2O, mass loss in TGA and the mineral composition of the organic-free mudstone. This work provides useful insights for further understanding the hydrocarbon generation mechanism, as well as quantifying different types of water in organic-rich mudstones.
泥岩富含或不含有机物对水的出现有很大影响。比较富含有机物和不含有机物泥岩中不同类型的水有助于进一步了解水在碳氢化合物生成过程中的作用。热重分析法(TGA)和差热分析法(DTA)与质谱法(MS)相结合,可在实时监测的加热过程中确定样品的质量变化、反应和产物。本研究利用 TGA/DTA-MS 方法比较了富含有机质的泥岩(CN1)和不含有机质的泥岩(CW1)的热解特征,以估算富含有机质的泥岩中不同类型的 H2O 和 CO2 的含量。结果表明,CN1 和 CW1 的质量变化可分为 0°C-200°C、200°C-650°C 和 650°C-900°C三个热重(TG)阶段,而通过 MS 获得的 H2O 和 CO2 的峰值温度在 CN1 和 CW1 中是不同的。CN1 和 CW1 在矿物成分和有机物方面的差异表明,CW1 中 H2O 和 CO2 的 MS 峰值主要受粘土和碳酸盐矿物的影响,而 CN1 中的 H2O 和 CO2 峰值也受有机物的影响。此外,利用 CO2 和 H2O 的 MS 峰面积、TGA 中的质量损失以及无机泥岩的矿物组成,可以建立富有机泥岩中有机和无机来源的 CO2 和 H2O 含量的量化方程。这项工作为进一步了解碳氢化合物的生成机制以及量化富含有机质泥岩中不同类型的水提供了有益的启示。
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Frontiers in Earth Science
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